{"id":207287,"date":"2020-08-12T06:30:29","date_gmt":"2020-08-11T22:30:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=207287"},"modified":"2020-12-29T15:02:12","modified_gmt":"2020-12-29T07:02:12","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e5%8c%97%e5%b7%a5%e5%a4%a7%e6%96%b0%e8%83%bd%e6%ba%90%e6%89%80%e6%b1%aa%e6%b5%a9%e9%9f%a9%e6%98%8c%e6%8a%a5%e5%9b%a2%e9%98%9fees%e5%8d%95%e5%8e%9f%e5%ad%90pt","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=207287","title":{"rendered":"\u5317\u5de5\u5927\u65b0\u80fd\u6e90\u6240\u6c6a\u6d69@\u97e9\u660c\u62a5\u56e2\u961fEES:\u5355\u539f\u5b50Pt\u4fee\u9970\u7684Co(OH)2@Ag NWs\u7528\u4e8e\u9ad8\u6548HER"},"content":{"rendered":"

\u5f15\u8a00<\/b><\/strong><\/p>\n

\u6c22\u6c14\u56e0\u5176\u73af\u4fdd\u7684\u53cd\u5e94\u8fc7\u7a0b\u548c\u8f83\u9ad8\u7684\u80fd\u6e90\u5bc6\u5ea6\u6210\u4e3a\u4e86\u6700\u5177\u53d1\u5c55\u524d\u666f\u7684\u80fd\u6e90\u8f7d\u4f53\u4e4b\u4e00\u3002\u7535\u89e3\u6c34\u6790\u6c22\uff08HER\uff09\u56e0\u5177\u6709\u4ea7\u54c1\u7eaf\u5ea6\u9ad8\u3001\u5de5\u4e1a\u5316\u6210\u719f\u3001\u65e0\u6c61\u67d3\u4e14\u539f\u6750\u6599\u8d44\u6e90\u4e30\u5bcc\u7b49\u4f18\u70b9\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u901a\u5411\u6c22\u80fd\u6e90\u7ecf\u6d4e\u7684\u6700\u4f73\u9014\u5f84\u3002\u800c\u7535\u89e3\u6c34\u6280\u672f\u53d1\u5c55\u7684\u74f6\u9888\u662f\u7535\u89e3\u80fd\u8017\u8f83\u9ad8\uff0c\u9700\u8981\u9ad8\u6548\u7684\u50ac\u5316\u5242\u6765\u964d\u4f4e\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7535\u4f4d\u3002\u5728HER\u50ac\u5316\u5242\u4e2d\uff0cPt\u5177\u6709\u8f83\u4f4e\u7684\u8fc7\u7535\u4f4d\u548c\u66f4\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u7136\u800c\uff0c\u9ad8\u6210\u672c\u548c\u7a00\u7f3a\u6027\u963b\u788d\u4e86\u5176\u5927\u89c4\u6a21\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5355\u539f\u5b50\u50ac\u5316\u5242\u53ef\u4ee5\u6700\u5927\u7a0b\u5ea6\u5730\u63d0\u9ad8\u91d1\u5c5e\u539f\u5b50\u5229\u7528\u7387\uff0c\u901a\u8fc7\u5c11\u91cf\u7684\u8d35\u91d1\u5c5e\u4fee\u9970\u6765\u63d0\u9ad8\u50ac\u5316\u5242\u50ac\u5316\u6d3b\u6027\u88ab\u8ba4\u4e3a\u662f\u4fc3\u8fdbHER\u5e94\u7528\u7684\u6709\u6548\u9014\u5f84\u3002\u968f\u7740\u539f\u5b50\u914d\u4f4d\u7ed3\u6784\u7684\u53d8\u5316\uff0cPt\u5355\u539f\u5b50\u50ac\u5316\u5242\u5c55\u73b0\u51fa\u53ef\u8c03\u63a7\u7684HER\u53cd\u5e94\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u5bf9\u94c2\u65cf\u5143\u7d20\u5c40\u90e8\u539f\u5b50\u914d\u4f4d\u73af\u5883\u7684\u8c03\u63a7\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\uff0c\u53ef\u4ee5\u4e3a\u8c03\u8282\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784\u548c\u51e0\u4f55\u7ed3\u6784\u63d0\u4f9b\u65b0\u7684\u9014\u5f84\uff0c\u4ece\u800c\u63d0\u9ad8\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u548c\u53cd\u5e94\u9009\u62e9\u6027\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u6c6a\u6d69\u6559\u6388\u548c\u97e9\u660c\u62a5\u6559\u6388\u56e2\u961f\u5728\u5355\u539f\u5b50\u50ac\u5316\u5242\u6784\u7b51\u53ca\u9ad8\u6548\u7535\u50ac\u5316\u4ea7\u6c22\uff08HER\uff09\u7684\u5e94\u7528\u7814\u7a76\u4e2d\u53d6\u5f97\u91cd\u8981\u7a81\u7834\u3002\u8be5\u56e2\u961f\u5f00\u521b\u6027\u5730\u5728\u9ad8\u5bfc\u7535\u6027\u7684\u94f6\u7eb3\u7c73\u7ebf\u7f51\u7edc\u7cfb\u7edf\u4e2d\u5bf9\u5355\u539f\u5b50\u94c2\u7684\u7535\u5b50\u7ed3\u6784\u8fdb\u884c\u6709\u6548\u8c03\u63a7\uff0c\u5b9e\u73b0\u4e86\u50ac\u5316\u6d3b\u6027\u7684\u663e\u8457\u589e\u5f3a\uff0c\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u7684HER\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff08PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\uff09\u3002\u5176\u4e2d\uff0cAg NWs\u7684\u5f15\u5165\u4e3a\u7535\u50ac\u5316\u4ea7\u6c22\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7535\u5b50\u4f20\u8f93\u63d0\u4f9b\u4e86\u4fbf\u6377\u7684\u901a\u9053\uff0c\u6709\u6548\u964d\u4f4e\u4e86\u7535\u5b50\u7684\u754c\u9762\u8f6c\u79fb\u7535\u963b\u3002\u591a\u7ea7\u7684\u7eb3\u7c73\u7ed3\u6784\u66b4\u9732\u4e86\u66f4\u591a\u7684\u5355\u539f\u5b50\u6d3b\u6027\u4f4d\u70b9\uff0c\u4e3a\u50ac\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u5927\u7684\u7535\u5316\u5b66\u8868\u9762\u79ef\u548c\u4f20\u8d28\u901a\u9053\u3001\u4fc3\u8fdb\u4e86\u6c22\u7684\u5feb\u901f\u751f\u6210\u548c\u91ca\u653e\u3002X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\uff08XAFS\uff09\u7814\u7a76\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u8868\u660e\uff0cPt\u539f\u5b50\u4e0eCo(OH)2<\/sub>\u4e2d\u7684O\u6210\u952e\u5f62\u6210Pt-O\u914d\u4f4d\u7ed3\u6784\uff0c\u5728Pt\u539f\u5b50\u9876\u7aef\u5f62\u6210\u7535\u8377\u5bcc\u96c6\u7684\u5c40\u90e8\u7535\u573a\u3002\u8fd9\u79cd\u7535\u573a\u7279\u5f81\u5bfc\u81f4\u4e86H*\u81ea\u7531\u80fd\u66f4\u9002\u4e2d\u3002\u8be5\u4f53\u7cfb\u4e2d\uff0cPt\u7684\u5f15\u5165\u63d0\u5347\u4e86\u6574\u4e2a\u50ac\u5316\u5242\u4f53\u7cfb\u5728\u8d39\u7c73\u80fd\u7ea7\u5904\u7684d<\/i><\/em>\u7535\u5b50\u5bc6\u5ea6\uff0c\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u4e86H2<\/sub>O\u7684\u5438\u9644\u3002\u57fa\u4e8e\u4ee5\u4e0a\u7279\u5f81\uff0c\u00a0PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\u50ac\u5316\u5242\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u8868\u73b0\u51fa\u6770\u51fa\u7684HER\u6d3b\u6027\uff0c\u572810 mA cm-2<\/sup>\u5904\uff0c\u4ec5\u5177\u670929 mV\u7684\u8d85\u7535\u52bf\uff0c\u5176\u8d28\u91cf\u6d3b\u6027\u6bd4\u5546\u4e1aPt\/C\u50ac\u5316\u5242\u9ad822.5\u500d\u3002\u672c\u7814\u7a76\u7ed3\u679c\u5bf9\u539f\u5b50\u5c3a\u5ea6\u4e0a\u5408\u7406\u8bbe\u8ba1\u548c\u8c03\u63a7\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u610f\u4e49\u3002\u8be5\u6210\u679c\u4ee5\u201cSeamlessly Conductive Co(OH)2<\/sub>\u00a0Tailored Atomically Dispersed Pt Electrocatalyst in Hierarchical Nanostructure for Efficient Hydrogen Evolution reaction\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8e\u56fd\u9645\u9876\u7ea7\u671f\u520a\u300aEnergy & Environmental Science\u300b\uff08IF\uff1a30.289\uff09\uff08\u6587\u7ae0DOI: 10.1039\/D0EE01347A\uff09\u3002\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u4e3a\u8be5\u8bba\u6587\u7684\u552f\u4e00\u5b8c\u6210\u5355\u4f4d\uff0c\u535a\u58eb\u5468\u5f00\u5cad\u4e3a\u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u97e9\u660c\u62a5\u6559\u6388\u548c\u738b\u957f\u660a\u8bb2\u5e08\u4e3a\u5171\u540c\u901a\u8baf\u3001\u535a\u58eb\u738b\u6cfd\u9716\u3001\u5f20\u5029\u5029\u6559\u6388\u3001\u67ef\u5c0f\u884c\u6559\u6388\u3001\u5218\u6676\u51b0\u526f\u6559\u6388\u548c\u6c6a\u6d69\u6559\u6388\u4e3a\u8bba\u6587\u5408\u4f5c\u8005\u3002\u8be5\u9879\u7814\u7a76\u5de5\u4f5c\u83b7\u5f97\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u5317\u4eac\u5e02\u79d1\u6280\u65b0\u661f\u8ba1\u5212\u9879\u76ee\u3001\u5317\u4eac\u5e02\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe1. <\/b><\/strong>PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\u50ac\u5316\u5242\u5408\u6210\u793a\u610f\u56fe<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe2. <\/b><\/strong>PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\u50ac\u5316\u5242\u7ed3\u6784\u8868\u5f81.<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe3. <\/b><\/strong>PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\u50ac\u5316\u5242\u7684\u539f\u5b50\u7ed3\u6784\u5206\u6790\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe4. <\/b><\/strong>PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\u50ac\u5316\u5242HER\u6027\u80fd\u6d4b\u8bd5\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe5. <\/b><\/strong>PtSA<\/sub>-Co(OH)2<\/sub>@Ag NWs\u7684HER\u50ac\u5316\u673a\u7406\u63a2\u7a76\u3002<\/p>\n

\u603b\u7ed3\u548c\u5c55\u671b<\/b><\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u7814\u7a76\u4ece\u50ac\u5316\u5242\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1\u548c\u672c\u5f81\u6d3b\u6027\u589e\u5f3a\u4e24\u4e2a\u65b9\u9762\u540c\u65f6\u5165\u624b\uff0c\u901a\u8fc7\u5728\u4e00\u7ef4\u7684Ag NWs\u4e0a\u6784\u7b51\u9ad8\u6d3b\u6027\u5355\u539f\u5b50Pt\u4fee\u9970\u7684Co(OH)2<\/sub>\u7eb3\u7c73\u7247\u590d\u5408\u7ed3\u6784\u50ac\u5316\u3002\u901a\u8fc7Pt-Co(OH)2<\/sub>\u76f8\u4e92\u4f5c\u7528\uff0c\u5728\u50ac\u5316\u5242\u8868\u9762\u6210\u4e86\u66f4\u5229\u4e8e*H\u5438\u9644\u81ea\u7531\u80fd\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4e3a\u7406\u89e3\u5355\u539f\u5b50\u672c\u5f81\u50ac\u5316\u6d3b\u6027\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u9014\u5f84\u3002\u6b64\u5916\uff0c\u6574\u4e2a\u5236\u5907\u8fc7\u7a0b\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u8fdb\u884c\uff0c\u4ec5\u6d89\u53ca\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\uff0c\u4e3a\u8d35\u91d1\u5c5e\u53ca\u975e\u8d35\u91d1\u5c5e\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u5236\u5907\u548c\u53d1\u5c55\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u7b80\u4ecb<\/b><\/strong><\/p>\n

\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u65b0\u80fd\u6e90\u6750\u6599\u4e0e\u6280\u672f\u7814\u7a76\u6240\u5728\u4e25\u8f89\u6559\u6388\u3001\u738b\u5982\u5fd7\u6559\u6388\u53ca\u6c6a\u6d69\u6559\u6388\u5e26\u9886\u4e0b\uff0c\u957f\u671f\u4ece\u4e8b\u7eb3\u7c73&\u534a\u5bfc\u4f53\u80fd\u6e90\u6750\u6599\u4e0e\u5668\u4ef6\u7684\u96c6\u6210\u53ca\u667a\u80fd\u5316\u6280\u672f\u5e94\u7528\u7814\u7a76\uff0c\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a\u5982Energy & Environment Science\u3001Advanced Materials\u3001Advanced Functional Materials\u3001ACS Nano\u3001Nano Energy\u3001Chemical Reviews\u7b49\u53d1\u8868\u5b66\u672f\u8bba\u6587800\u4f59\u7bc7\uff0c\u51fa\u7248\u5b66\u672f\u4e13\u845710\u4f59\u90e8\uff0c\u6388\u6743\u53d1\u660e\u4e13\u5229200\u4f59\u9879\uff0c\u5b9e\u73b0\u91cd\u5927\u79d1\u6280\u6210\u679c\u8f6c\u531610\u4f59\u9879\uff0c\u4e3b\u6301\u56fd\u5bb6\u91cd\u70b9\u57fa\u91d1\u3001\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u5317\u4eac\u5e02\u91cd\u70b9\u57fa\u91d1\u53ca\u519b\u5de5\u9879\u76ee\u7b4950\u4f59\u9879\u3002<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u56e2\u961f\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f15\u8a00 \u6c22\u6c14\u56e0\u5176\u73af\u4fdd\u7684\u53cd\u5e94\u8fc7\u7a0b\u548c\u8f83\u9ad8\u7684\u80fd\u6e90\u5bc6\u5ea6\u6210\u4e3a\u4e86\u6700\u5177\u53d1\u5c55\u524d\u666f\u7684\u80fd\u6e90\u8f7d\u4f53\u4e4b\u4e00\u3002\u7535\u89e3\u6c34\u6790\u6c22\uff08HER\uff09\u56e0\u5177\u6709\u4ea7\u54c1\u7eaf\u5ea6\u9ad8\u3001\u5de5\u4e1a\u5316\u6210\u719f\u3001\u65e0\u6c61\u67d3\u4e14\u539f\u6750\u6599\u8d44\u6e90\u4e30\u5bcc\u7b49\u4f18\u70b9\u88ab\u8ba4…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-207287","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/207287"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=207287"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/207287\/revisions"}],"predecessor-version":[{"id":215333,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/207287\/revisions\/215333"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=207287"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=207287"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=207287"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}