{"id":207121,"date":"2020-08-11T06:55:11","date_gmt":"2020-08-10T22:55:11","guid":{"rendered":"\/\/m.iemloyee.com\/?p=207121"},"modified":"2020-08-11T06:02:07","modified_gmt":"2020-08-10T22:02:07","slug":"%e5%8e%a6%e5%a4%a7%e8%a7%a3%e8%8d%a3%e5%86%9b%e5%9b%a2%e9%98%9fchem-eng-j-%ef%bc%9a%e9%9d%a2%e5%90%91%e5%a4%a7%e5%8a%9f%e7%8e%87%e6%bf%80%e5%85%89%e7%85%a7%e6%98%8e%e5%ba%94%e7%94%a8%e7%9a%84calson","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=207121","title":{"rendered":"\u53a6\u5927\u89e3\u8363\u519b\u56e2\u961fChem. Eng. J.\uff1a\u9762\u5411\u5927\u529f\u7387\u6fc0\u5149\u7167\u660e\u5e94\u7528\u7684CALSON:Ce\u4e09\u5143\u56fa\u6eb6\u4f53\u8367\u5149\u7c89"},"content":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n

\u6fc0\u5149\u7167\u660e\u5177\u6709\u8d85\u9ad8\u4eae\u5ea6\u548c\u51c6\u76f4\u6027\uff0c\u5728\u6c7d\u8f66\u5927\u706f\u3001\u822a\u7a7a\u822a\u6d77\u7167\u660e\u3001\u519b\u7528\u624b\u7535\u3001\u6fc0\u5149\u6295\u5f71\u4eea\u548c\u5f71\u9662\u4ee5\u53ca\u6fc0\u5149\u7535\u89c6\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\uff0c\u88ab\u8ba4\u4e3a\u662f\u65b0\u4e00\u4ee3\u7684\u5927\u529f\u7387\u3001\u9ad8\u4eae\u5ea6\u7167\u660e\u6280\u672f\u3002\u76ee\u524d\uff0c\u6fc0\u5149\u7167\u660e\u4e3b\u8981\u7531\u84dd\u5149\u6fc0\u5149\u82af\u7247\u4e0e\u53d1\u5149\u6750\u6599\u8026\u5408\u5f97\u5230\u767d\u5149\u5149\u6e90\u3002\u7531\u4e8e\u6fc0\u5149\u7684\u8d85\u9ad8\u5149\u529f\u7387\u5bc6\u5ea6\uff0c\u5176\u5bf9\u53d1\u5149\u6750\u6599\u53ca\u76f8\u5e94\u7684\u5149\u8f6c\u6362\u5668\u4ef6\u63d0\u51fa\u4e86\u66f4\u4e3a\u4e25\u82db\u7684\u8981\u6c42\u3002\u5e94\u7528\u4e8e\u6fc0\u5149\u7167\u660e\u7684\u53d1\u5149\u6750\u6599\u9700\u5177\u6709\u9ad8\u91cf\u5b50\u6548\u7387\u3001\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u80fd\u548c\u77ed\u7684\u8367\u5149\u5bff\u547d\uff0c\u76f8\u5e94\u7684\u5149\u8f6c\u6362\u5668\u4ef6\u5219\u9700\u8981\u7cbe\u5fc3\u8bbe\u8ba1\u4ee5\u8fbe\u5230\u9ad8\u6548\u6563\u70ed\uff0c\u4ece\u800c\u6709\u6548\u5e94\u5bf9\u6fc0\u5149\u6fc0\u53d1\u5e26\u6765\u7684\u4e25\u91cd\u70ed\u6548\u5e94\u548c\u5149\u9971\u548c\uff0c\u6700\u7ec8\u83b7\u5f97\u9ad8\u5149\u6548\u548c\u9ad8\u53ef\u9760\u6027\u7684\u6fc0\u5149\u9a71\u52a8\u767d\u5149\u5149\u6e90\u3002\u5f53\u524d\uff0c\u6fc0\u5149\u7167\u660e\u6240\u7528\u7684\u53d1\u5149\u6750\u6599\u4e3b\u8981\u662f\u4ee5Y3<\/sub>Al5<\/sub>O12<\/sub>:Ce3+<\/sup>\uff08YAG:Ce\uff09\u4e3a\u4ee3\u8868\u7684\u77f3\u69b4\u77f3\u7ed3\u6784\u8367\u5149\u7c89\uff0c\u5e76\u56f4\u7ed5\u5b83\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u7684\u5355\u6676\u3001\u8367\u5149\u73bb\u7483\uff08PiG\uff09\u3001\u8367\u5149\u9676\u74f7\u7b49\u5149\u8f6c\u6362\u5668\u4ef6\u7684\u8bbe\u8ba1\u3002\u7136\u800c\uff0cYAG:Ce\u672c\u8eab\u7684\u7ea2\u5149\u6210\u5206\u4e0d\u8db3\uff0c\u4e14\u70ed\u731d\u706d\u8f83\u5927\uff0c\u4ecd\u7136\u4e25\u91cd\u5236\u7ea6\u7740\u6fc0\u5149\u7167\u660e\u5149\u6e90\u54c1\u8d28\uff08\u5982\u663e\u8272\u3001\u8272\u5f69\u9971\u548c\u5ea6\u3001\u8272\u6e29\u7b49\uff09\u7684\u63d0\u5347\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u9002\u5408\u6fc0\u5149\u6fc0\u53d1\u7684\u65b0\u578b\u53d1\u5149\u6750\u6599\u5907\u53d7\u5173\u6ce8\uff0c\u4f46\u8fc4\u4eca\u4e3a\u6b62\uff0c\u8fdb\u5c55\u7f13\u6162\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u89e3\u8363\u519b\u6559\u6388\u3001\u674e\u6dd1\u661f\u52a9\u7406\u6559\u6388\u548c\u4e2d\u56fd\u8ba1\u91cf\u5927\u5b66\u738b\u4e50\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u91c7\u7528\u56fa\u6eb6\u7b56\u7565\uff0c\u5c06\u540c\u6784\u7684LiSi2<\/sub>N3<\/sub>\u548cSi2<\/sub>N2<\/sub>O\u5f15\u5165\u5230CaAlSiN3<\/sub>\u57fa\u8d28\u4e2d\uff0c\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cd\u4e09\u5143\u56fa\u6eb6\u4f53\u8367\u5149\u7c89Ca1-x<\/em>–y<\/em><\/sub>Lix<\/sub><\/em>Al1-x<\/em>–y<\/em><\/sub>Si1+x<\/em>+y<\/em><\/sub>N3-y<\/em><\/sub>Oy<\/sub><\/em>:Ce3+<\/sup> (CALSON:Ce)\u3002\u8be5\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u5728\u84dd\u5149\uff08\u03bb<\/em>ex<\/sub> = 450 nm\uff09\u6fc0\u53d1\u4e0b\uff0c\u53ef\u5b9e\u73b0\u9ad8\u6548\u7684\u5bbd\u8c31\u6a59\u9ec4\u5149\uff08\u03bb<\/em>em<\/sub> = 580 nm\uff09\u53d1\u5c04\uff0c\u5916\u91cf\u5b50\u6548\u7387\u53ef\u8fbe41.5%\uff1b\u540c\u65f6\u8868\u73b0\u51fa\u5341\u5206\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u80fd\uff0c\u5728200\u2103\u7684\u53d1\u5149\u5f3a\u5ea6\u635f\u5931\u4ec5\u4e3a9%\uff0c\u8fdc\u4f4e\u4e8eCaAlSiN3<\/sub>:Ce3+<\/sup>\uff0825%\uff09\u3002\u901a\u8fc7\u6784\u6548\u5206\u6790\u7684\u7814\u7a76\u8868\u660e\uff0c\u8367\u5149\u7c89\u70ed\u7a33\u5b9a\u6027\u80fd\u7684\u63d0\u5347\u4e3b\u8981\u5f97\u76ca\u4e8e\u56fa\u6eb6\u4f53\u5f62\u6210\u8fc7\u7a0b\u4e2d\u57fa\u8d28\u7981\u5e26\u5bbd\u5ea6\u7684\u5c55\u5bbd\uff085.21 \u2192 5.50 eV\uff09\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u56e2\u961f\u5c06CALSON:Ce\u5236\u6210\u4e86\u8367\u5149\u73bb\u7483\u8584\u819c\uff0c\u7528\u4f5c\u5149\u8f6c\u6362\u5668\u4ef6\u4e0e\u84dd\u5149\u6fc0\u5149\u82af\u7247\u8026\u5408\uff0c\u5176\u53d1\u5149\u9971\u548c\u9608\u503c\u8fbe\u523017.8 W\/mm2<\/sup>\uff0c\u6210\u529f\u83b7\u5f97\u4e86\u8d85\u9ad8\u4eae\u5ea6\u7684\u767d\u5149\u5149\u6e90\uff08\u5355\u4f4d\u5149\u901a\u91cf\u4e3a781 lm\/mm2<\/sup>\uff0c\u663e\u8272\u6307\u6570\u4e3a70\uff09\uff0c\u5e76\u8868\u73b0\u51fa\u4e86\u4f18\u4e8eYAG:Ce\u7684\u5149\u5b66\u54c1\u8d28\u3002\u901a\u8fc7\u591a\u5143\u56fa\u6eb6\u4f53\u7684\u8bbe\u8ba1\uff0c\u8be5\u7814\u7a76\u4e0d\u4ec5\u83b7\u5f97\u4e86\u4e00\u79cd\u975e\u5e38\u6709\u5546\u4e1a\u5e94\u7528\u6f5c\u529b\u7684\u6fc0\u5149\u8367\u5149\u7c89\uff0c\u800c\u4e14\u4e3a\u6fc0\u5149\u8367\u5149\u7c89\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7ed3\u679c\u4ee5\u201cTernary solid solution phosphors Ca1-x<\/em>–y<\/em><\/sub>Lix<\/sub><\/em>Al1-x<\/em>–y<\/em><\/sub>Si1+x<\/em>+y<\/em><\/sub>N3-y<\/em><\/sub>Oy<\/sub><\/em>:Ce3+<\/sup> with enhanced thermal stability for high-power laser lighting\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728Chemical Engineering Journal<\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. <\/strong>\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u7269\u76f8\u53ca\u7ed3\u6784\u6f14\u53d8<\/strong><\/p>\n

\"\"<\/p>\n

(a-b) \u4e8c\u5143\u56fa\u6eb6\u4f53\u8367\u5149\u7c89Ca1-x<\/em><\/sub>Lix<\/sub><\/em>Al1-x<\/em><\/sub>Si1+x<\/em><\/sub>N3<\/sub>:Ce3+<\/sup> (CALSN:Ce, x<\/em> = 0-0.2)\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

(c-d) \u4e09\u5143\u56fa\u6eb6\u4f53\u8367\u5149\u7c89Ca1-x<\/em>–y<\/em><\/sub>Lix<\/sub><\/em>Al1-x<\/em>–y<\/em><\/sub>Si1+x<\/em>+y<\/em><\/sub>N3-y<\/em><\/sub>Oy<\/sub><\/em>:Ce3+<\/sup> (CALSON:Ce, x<\/em> = 0.15, y<\/em> = 0-0.15)\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

(e-f) \u6676\u80de\u53c2\u6570 (a<\/em>\u3001b<\/em>\u548cc<\/em>) \u548c\u6676\u80de\u4f53\u79ef (V<\/em>) \u968fx<\/em>\u548cy<\/em>\u7684\u53d8\u5316\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong>2. <\/strong>\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u7684\u5c40\u57df\u7ed3\u6784\u4e0e\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

(a-c) \u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u768429<\/sup>Si\u300127<\/sup>Al\u548c7<\/sup>Li\u56fa\u6001NMR\u8c31\uff1b<\/p>\n

(d) CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0.10)\u8367\u5149\u7c89\u7684\u8367\u5149\u7167\u7247(\u03bb<\/em>ex<\/sub> = 380 nm)\uff1b<\/p>\n

(e) CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0.10)\u8367\u5149\u7c89\u7684SEM\u7167\u7247\uff1b<\/p>\n

(f-l) CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0.10)\u8367\u5149\u7c89\u7684EDS\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

(m-o) CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0.10)\u8367\u5149\u7c89\u7684TEM\u7167\u7247\u53caSAED\u82b1\u6837\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u7684\u5149\u5b66\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

(a-b) CALSN:0.01Ce (x<\/em> = 0-0.2)\u8367\u5149\u7c89\u7684\u5f52\u4e00\u5316\u6fc0\u53d1\u5149\u8c31(\u03bb<\/em>em<\/sub> = 580 nm)\u4e0e\u53d1\u5c04\u5149\u8c31(\u03bb<\/em>ex<\/sub> = 450 nm)\uff1b<\/p>\n

(c) CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0-0.15)\u8367\u5149\u7c89\u7684\u5f52\u4e00\u5316\u53d1\u5c04\u5149\u8c31(\u03bb<\/em>ex<\/sub> = 450 nm)\uff1b<\/p>\n

(d) \u4e0d\u540c\u63ba\u6742\u6d53\u5ea6\u7684CALSON:z<\/em>Ce (x<\/em> = 0.15, y<\/em> = 0-0.15, z<\/em> = 0.002-0.05)\u8367\u5149\u7c89\u7684\u5f52\u4e00\u5316\u53d1\u5c04\u5149\u8c31(\u03bb<\/em>ex<\/sub> = 450 nm)\uff0c\u5185\u63d2\u4e3a\u76f8\u5e94\u7684\u8272\u5750\u6807\uff1b<\/p>\n

(e) CaAlSiN3<\/sub>:0.01Ce\u3001CALSN:0.01Ce (x<\/em> = 0.15)\u3001CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0.1)\u7684\u53d1\u5149\u8870\u51cf\u66f2\u7ebf\uff1b<\/p>\n

(f-g) \u8367\u5149\u5bff\u547d\u4e0ex<\/em>\u3001y<\/em>\u7684\u5173\u7cfb\uff1b<\/p>\n

(h) CaAlSiN3<\/sub>:Ce\u3001CALSN:Ce (x<\/em> = 0.15)\u3001CALSON:Ce (x<\/em> = 0.15, y<\/em> = 0.1)\u7684\u7981\u5e26\u53d8\u5316\u53caCe3+<\/sup>-5d\u80fd\u7ea7\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u7684\u70ed\u731d\u706d\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a) CaAlSiN3<\/sub>:0.01Ce\u3001CALSN:0.01Ce (x<\/em> = 0.15)\u3001CALSON:0.01Ce (x<\/em> = 0.15, y<\/em> = 0.1)\u7684\u53d8\u6e29\u5149\u8c31\uff1b<\/p>\n

(b-c) \u53d1\u5149\u5f3a\u5ea6\u6bd4IT<\/sub><\/em>\/I<\/em>0<\/sub>\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff0c\u5b9e\u7ebf\u4e3a\u62df\u5408Arrhenius\u516c\u5f0f\uff1b<\/p>\n

(d-e) ln(I<\/em>0<\/sub>\/IT<\/sub><\/em> – 1)\u4e0e1\/kT<\/em>\u7684\u5173\u7cfb\uff0c\u5185\u63d2\u4e3a\u62df\u5408\u5f97\u5230\u7684\u70ed\u731d\u706d\u6fc0\u6d3b\u80fdE<\/em>a<\/sub>\u968fx<\/em>\u3001y<\/em>\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe<\/strong>5. <\/strong>\u5927\u529f\u7387\u6fc0\u5149\u7167\u660e\u5668\u4ef6<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5927\u529f\u7387\u84dd\u5149\u6fc0\u5149\u6fc0\u53d1\u4e0bCASN-PiG\u4e0eCALSON-PiG\u8584\u819c\u5149\u901a\u91cf\u5bf9\u6bd4\uff0c\u5185\u63d2\u4e3a\u76f8\u5e94\u7684\u8584\u819c\u7167\u7247\uff1b<\/p>\n

(b-c, e) \u84dd\u5149\u6fc0\u5149\u6fc0\u53d1\u4e0b\uff0c2c-PiG\uff08La3<\/sub>Si6<\/sub>N11<\/sub>:Ce + CALSON:0.02Ce\uff09\u8584\u819c\u5149\u8f6c\u6362\u5668\u4ef6\u7684\u53d1\u5c04\u5149\u8c31\uff0c\u5149\u901a\u91cf\u3001\u6d41\u660e\u6548\u7387\u4e0e\u6fc0\u5149\u529f\u7387\u5bc6\u5ea6\u7684\u5173\u7cfb\uff0c\u4ee5\u53ca\u76f8\u5e94\u8272\u5750\u6807\uff1b<\/p>\n

(d)\u5927\u529f\u7387\u6fc0\u5149\u7167\u660e\u5668\u4ef6\u7684\u5b9e\u7269\u7167\u7247\u548c\u5149\u5b66\u7167\u7247\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\uff0c\u672c\u6587\u901a\u8fc7\u56fa\u6eb6\u4f53\u7b56\u7565\uff0c\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u4e09\u5143\u56fa\u6eb6\u4f53\u8367\u5149\u7c89CALSON:Ce\uff0c\u5728\u84dd\u5149\u6fc0\u53d1\u4e0b\u80fd\u591f\u5b9e\u73b0\u9ad8\u6548\u7684\u9ec4\u6a59\u5149\u53d1\u5c04\uff0c\u5e76\u4e14\u5177\u6709\u5341\u5206\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u80fd\uff08200\u2103\u4e0b91%\u7684\u53d1\u5149\u4fdd\u6301\u7387\uff09\uff0c\u80fd\u591f\u6ee1\u8db3\u5927\u529f\u7387\u6fc0\u5149\u6fc0\u53d1\u7684\u8981\u6c42\u3002\u57fa\u4e8e\u8be5\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u5236\u5907\u7684\u5149\u8f6c\u6362\u5668\u4ef6\uff0c\u4e0e\u84dd\u5149\u6fc0\u5149\u8026\u5408\uff0c\u53ef\u83b7\u5f97\u9ad8\u8d28\u91cf\u3001\u9ad8\u4eae\u5ea6\u7684\u6fc0\u5149\u767d\u5149\u5149\u6e90\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u4e00\u79cd\u975e\u5e38\u5177\u6709\u4ea7\u4e1a\u5316\u6f5c\u529b\u7684\u6fc0\u5149\u8367\u5149\u7c89\uff0c\u800c\u4e14\u62d3\u5bbd\u4e86\u56fa\u6eb6\u4f53\u8367\u5149\u7c89\u7684\u8bbe\u8ba1\u601d\u8def\u3002<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u5728\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\/\u9762\u4e0a\u57fa\u91d1\u3001\u4e2d\u56fd\u535a\u58eb\u540e\u521b\u65b0\u4eba\u624d\u652f\u6301\u8ba1\u5212\u7684\u8d44\u52a9\u4e0b\uff0c\u53a6\u95e8\u5927\u5b66\u6750\u6599\u5b66\u9662\u56fd\u5bb6\u7279\u8058\u6559\u6388\u89e3\u8363\u519b\u7684\u7814\u7a76\u56e2\u961f\u5728\u9762\u5411\u9ad8\u4eae\u5ea6\u6fc0\u5149\u7167\u660e\u4e0e\u663e\u793a\u5e94\u7528\u7684\u53d1\u5149\u6750\u6599\u7814\u7a76\u4e2d\u505a\u51fa\u4e86\u591a\u9879\u5f00\u521b\u6027\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u91cd\u8981\u8fdb\u5c55\uff1a<\/p>\n

\uff081\uff09\u8bbe\u8ba1\u4e86\u9ad8\u5bfc\u70ed\u590d\u5408YAG-Al2<\/sub>O3<\/sub>\u8367\u5149\u9676\u74f7\uff0c\u53ef\u8010\u53d7\u9ad8\u5149\u529f\u7387\u5bc6\u5ea6\u84dd\u5149\u6fc0\u5149\u7684\u6fc0\u53d1\uff08> 20 W\/mm2<\/sup>\uff09\uff08J. Mater. Chem. C, 2016, 4, 8648, Cover Paper; J. Mater. Chem. C, 2019, 7(13), 3901, Hot Paper\uff09\uff1b\uff082\uff09\u901a\u8fc7\u52a9\u6eb6\u5242\u7684\u4f18\u9009\u548c\u91c7\u7528\u7b49\u79bb\u5b50\u653e\u7535\u70e7\u7ed3\u6280\u672f\u9996\u5148\u5236\u5907\u51fa\u81f4\u5bc6\u5316\u6c2e\u5316\u7269\u7ea2\u8272\u8367\u5149\u9676\u74f7CaAlSiN3<\/sub>:Eu2+<\/sup>\uff0c\u7528\u4e8e\u63d0\u9ad8\u7167\u660e\u5149\u6e90\u7684\u663e\u8272\u54c1\u8d28\u548c\u6fc0\u5149\u663e\u793a\u7684\u7ea2\u8272\u6210\u5206\uff08J. Mater. Chem. C, 2016, 4, 8197, Hot Paper; J. Mater. Chem. C, 2017, 5, 1042, Hot Paper\uff09\uff1b\uff083\uff09\u901a\u8fc7\u4e0e\u84dd\u5b9d\u77f3\u886c\u5e95\u7684\u5171\u70e7\u548c\u5149\u5b66\u9540\u819c\u8bbe\u8ba1\u5236\u5907\u4e86YAG:Ce3+<\/sup>\u548cLa3<\/sub>Si6<\/sub>N11<\/sub>:Ce3+<\/sup>\u590d\u5408\u8367\u5149\u73bb\u7483\u8584\u819c\uff0c\u5b9e\u73b0\u6d41\u660e\u6548\u7387\u9ad8\u8fbe210 lm\/W\u7684\u6fc0\u5149\u9a71\u52a8\u767d\u5149\uff08ACS Appl. Mater. Interfaces, 2018, 10(17), 14930; Laser Photon. Rev., 2019, 13(2), 1800216\uff09\uff1b\uff084\uff09\u5efa\u7acb\u4e86\u6750\u6599\u70ed\u5bfc\u7387\u3001\u70ed\u731d\u706d\u3001\u91cf\u5b50\u6548\u7387\u5bf9\u6fc0\u5149\u6fc0\u53d1\u8fc7\u7a0b\u4e2d\u4ea7\u70ed\u3001\u6563\u70ed\u548c\u6297\u70ed\u7684\u5b9a\u6027\u5b9a\u91cf\u5173\u7cfb\uff0c\u9610\u660e\u4e86\u70ed\u81f4\u9971\u548c\u7684\u4ea7\u751f\u673a\u5236\uff0c\u4e3a\u6fc0\u5149\u9a71\u52a8\u53d1\u5149\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u6307\u5bfc\uff08J. Mater. Chem. C, 2019, 7, 11449, Hot Paper\uff09\uff1b\uff085\uff09\u901a\u8fc7\u8c03\u63a7YAG:Ce\u8367\u5149\u9676\u74f7\u7684\u5fae\u89c2\u7ed3\u6784\uff0c\u5f15\u5165\u4e00\u5b9a\u91cf\u7684\u6c14\u5b54\u4ee5\u589e\u5f3a\u5149\u6563\u5c04\u6548\u679c\uff0c\u5b9e\u73b0\u4e86\u8d85\u9ad8\u4eae\u5ea6\uff08\u900f\u5c04\u6a21\u5f0f\uff1a855 lm\uff1b\u53cd\u5c04\u6a21\u5f0f\uff1a7199 \u00a0lm\uff09\u548c\u8d85\u9ad8\u51c6\u76f4\u6027\u7684\u6fc0\u5149\u7167\u660e\u767d\u5149\u5149\u6e90\uff08Laser Photon. Rev., \u00a02019, 13, 1900147\uff09;\uff086\uff09\u901a\u8fc7\u7ea2\u3001\u7eff\u8367\u5149\u590d\u5408\u73bb\u7483\u8584\u819c\u7684\u5236\u5907\u548c\u7ed3\u6784\u4f18\u5316\uff0c\u4f7f\u7a84\u5e26\u03b2-Sialon:Eu2+<\/sup>\u7eff\u8272\u8367\u5149\u8584\u819c\u7684\u53d1\u5149\u9971\u548c\u9608\u503c\u8fbe\u52306.09 W\/mm2<\/sup>\uff0c\u57fa\u4e8e\u590d\u5408\u8367\u5149\u73bb\u7483\u8584\u819c\u5236\u5907\u7684\u6fc0\u5149\u9a71\u52a8\u53d1\u5149\u5668\u4ef6\u7684\u8272\u57df\u8fbe107% NTSC\u3001\u53d1\u5149\u6548\u7387\u4e3a74.4 lm\/W\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u6fc0\u5149\u663e\u793a\uff08J. Mater. Chem. C, 2020, 8, 1746\uff09\uff1b\uff087\uff09\u7efc\u8ff0\u4e86\u6fc0\u5149\u7167\u660e\u8367\u5149\u8f6c\u6362\u6750\u6599\uff0c\u6982\u62ec\u4e86\u6fc0\u5149\u9a71\u52a8\u8367\u5149\u7c89\u7684\u8bbe\u8ba1\u51c6\u5219\uff0c\u5e76\u5c55\u671b\u53d1\u5149\u6750\u6599\u7684\u672a\u6765\u53d1\u5c55\u8d8b\u52bf\uff08Laser Photon. Rev., 2018, 12(12), 1800173\uff09\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ternary Solid Solution Phosphors Ca1-x<\/em>–y<\/em><\/sub>Lix<\/sub><\/em>Al1-x<\/em>–y<\/em><\/sub>Si1+x<\/em>+y<\/em><\/sub>N3-y<\/em><\/sub>Oy<\/sub><\/em>:Ce3+<\/sup> with Enhanced Thermal Stability for High-Power Laser Lighting<\/a> (Chem. Eng. J.<\/em>, 2020, DOI: 10.1016\/j.cej.2020.126575)<\/p>\n

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