{"id":206903,"date":"2020-08-06T08:21:27","date_gmt":"2020-08-06T00:21:27","guid":{"rendered":"\/\/m.iemloyee.com\/?p=206903"},"modified":"2020-08-06T21:29:45","modified_gmt":"2020-08-06T13:29:45","slug":"%e6%9c%80%e6%96%b0nature%e6%96%b0%e5%9e%8b%e5%85%89%e5%8c%96%e5%ad%a6%e8%84%b1%e6%b0%a2%e7%ad%96%e7%95%a5%e7%94%a8%e4%ba%8e%e8%8b%af%e8%83%ba%e5%90%88%e6%88%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=206903","title":{"rendered":"\u6700\u65b0Nature:\u65b0\u578b\u5149\u5316\u5b66\u8131\u6c22\u7b56\u7565\u7528\u4e8e\u82ef\u80fa\u5408\u6210"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u80fd\u591f\u5c06\u4e24\u4e2a\u5206\u5b50\u7247\u6bb5\u8fde\u63a5\uff08cross-coupling\uff09\u5728\u4e00\u8d77\u7684\u5316\u5b66\u53cd\u5e94\u5728\u836f\u5b66\u548c\u519c\u5b66\u9886\u57df\u626e\u6f14\u7740\u91cd\u8981\u7684\u89d2\u8272\u3002\u800c\u5728\u82b3\u9999\u65cf\u5316\u5408\u7269\u7279\u5b9a\u4f4d\u70b9\u4e0a\u5f15\u5165\u6c28\u57fa\u7684\u53cd\u5e94\uff0c\u76ee\u524d\u53ea\u80fd\u4f9d\u9760\u9700\u8981\u542b\u5364\/\u787c\u57fa\u8d28\u7684\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5b9e\u73b0\uff0c\u65e0\u6cd5\u771f\u6b63\u6709\u6548\u5730\u9009\u62e9\u6027\u9776\u5411\u53cd\u5e94\u4f4d\u70b9\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong>\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u7684<\/strong><strong>Daniele Leonori<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u975e\u5178\u578b\u7684cross-coupling\u65b9\u6cd5\uff0c\u5229\u7528\u73af\u5df1\u916e\u4f5c\u4e3a\u82b3\u57fa\u4eb2\u7535\u8bd5\u5242\u7528\u4e8e\u82ef\u80fa\uff08anilines\uff09\u7684\u6784\u5efa\u3002\u6c28\u57fa\u548c\u7fb0\u57fa\u7684\u7f29\u5408\u662f\u81ea\u7136\u754c\u4e2d\u7ecf\u5e38\u53d1\u751f\u7684\u53cd\u5e94\uff0c\u80fd\u591f\u5b9e\u73b0\u4f4d\u70b9\u9009\u62e9\u6027\u7684C-N\u6210\u952e\u53cd\u5e94\uff0c\u540c\u65f6\u57fa\u4e8e\u5149\u6c27\u5316\u8fd8\u539f\u4ee5\u53ca\u94b4\u57fa\u50ac\u5316\u7cfb\u7edf\u5219\u53ef\u4ee5\u9010\u6b65\u5730\u51cf\u5c0f\u73af\u5df2\u70ef\u7684\u5316\u5b66\u952e\u9971\u548c\u5ea6\uff0c\u6700\u7ec8\u5f62\u6210\u82ef\u80fa\u3002\u9274\u4e8e\u7fb0\u57fa\u6d3b\u6027\u8f83\u5f3a\u80fd\u591f\u6bd4\u8f83\u5bb9\u6613\u5730\u8fdb\u884c\u73af\u5df1\u916e\u529f\u80fd\u5316\uff0c\u8fd9\u4e00\u65b0\u578b\u78b3\u6c2e\u952ecross-coupling\u65b9\u6cd5\u80fd\u591f\u907f\u514d\u82b3\u57fa\u5316\u5b66\u4e2d\u5e38\u89c1\u7684\u9009\u62e9\u6027\u95ee\u9898\uff0c\u5728\u836f\u7269\u5408\u6210\u548c\u5929\u7136\u4ea7\u7269\u82b3\u9999\u5316\u7b49\u9886\u57df\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u30022020\u5e7408\u670805\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>A photochemical dehydrogenative strategy for aniline synthesis<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728<strong>Nature<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1<\/strong><strong>\u82ef\u80fa\u5408\u6210\u7684<\/strong><strong>cross-coupling<\/strong><strong>\u7b56\u7565<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-206907\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/1-4.jpg\" alt=\"\" width=\"600\" height=\"571\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/1-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/1-4-300x286.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong> <strong>\u8131\u6c22\u6c28\u57fa\u5316\u8fc7\u7a0b\u4e2d\u7684\u80fa\u7c7b\u5316\u5408\u7269<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-206906\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/2-4.jpg\" alt=\"\" width=\"600\" height=\"519\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/2-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/2-4-300x260.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong><strong>\u8131\u6c22\u6c28\u57fa\u5316\u8fc7\u7a0b\u4e2d\u7684\u73af\u5df1\u916e\u7c7b\u5316\u5408\u7269<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-206905\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/3-5.jpg\" alt=\"\" width=\"598\" height=\"492\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/3-5.jpg 598w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/3-5-300x247.jpg 300w\" sizes=\"(max-width: 598px) 100vw, 598px\" \/><\/p>\n<p><strong>\u56fe4 \u590d\u5408\u82ef\u80fa\u7684\u5408\u6210<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-206904\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/4-4.jpg\" alt=\"\" width=\"483\" height=\"562\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/4-4.jpg 483w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/08\/4-4-258x300.jpg 258w\" sizes=\"(max-width: 483px) 100vw, 483px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-020-2539-7\" target=\"_blank\" rel=\"noopener\">A photochemical dehydrogenative strategy for aniline synthesis<\/a>\uff08Nature, 2020, DOI: 10.1038\/s41586-020-2539-7\uff09<\/p>\n<p>\u672c\u6587\u7531NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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