{"id":206782,"date":"2020-08-25T06:40:55","date_gmt":"2020-08-24T22:40:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=206782"},"modified":"2020-08-25T10:23:03","modified_gmt":"2020-08-25T02:23:03","slug":"%e5%8d%95%e5%8e%9f%e5%ad%90%e5%92%8cmof%e5%bc%ba%e5%bc%ba%e8%81%94%e6%89%8b%ef%bc%8c%e4%bc%9a%e6%93%a6%e5%87%ba%e6%80%8e%e6%a0%b7%e7%9a%84%e7%81%ab%e8%8a%b1%ef%bc%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=206782","title":{"rendered":"\u5355\u539f\u5b50\u548cMOF\u5f3a\u5f3a\u8054\u624b\uff0c\u4f1a\u64e6\u51fa\u600e\u6837\u7684\u706b\u82b1\uff1f"},"content":{"rendered":"

\u81ea2011\u5e74\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5f20\u6d9b\u9662\u58eb\u3001\u6e05\u534e\u5927\u5b66\u674e\u96bd\u6559\u6388\u53ca\u7f8e\u56fd\u4e9a\u5229\u6851\u90a3\u5dde\u7acb\u5927\u5b66\u5218\u666f\u6708\u6559\u6388\u5171\u540c\u63d0\u51fa\u201c\u5355\u539f\u5b50\u50ac\u5316\u201d\u7684\u6982\u5ff5\uff0c\u53d1\u73b0\u6b64\u7c7b\u50ac\u5316\u5242\u5176\u539f\u5b50\u5229\u7528\u7387\u80fd\u591f\u8fbe\u5230100%\uff0c\u4e0d\u5230\u5341\u5e74\u95f4\uff0c\u5355\u539f\u5b50\u50ac\u5316\u8fc5\u901f\u6210\u4e3a\u50ac\u5316\u9886\u57df\u7684\u7814\u7a76\u524d\u6cbf\u3002\u53e6\u4e00\u79cd\u70ed\u5ea6\u4e0d\u51cf\u7684\u7eb3\u7c73\u6750\u6599\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u5177\u6709\u591a\u5b54\u3001\u8868\u9762\u79ef\u5927\u3001\u7ed3\u6784\u4e0e\u529f\u80fd\u591a\u6837\u3001\u542b\u4e0d\u9971\u548c\u91d1\u5c5e\u4f4d\u70b9\u7b49\u7279\u6027\uff0c\u4f7f\u4e4b\u5177\u5907\u5f3a\u5927\u7684\u5438\u9644\u529f\u80fd\u548c\u50ac\u5316\u529f\u80fd\uff0c\u4e14MOF\u53ef\u7528\u4e8e\u5b58\u50a8\u3001\u5206\u79bb\u3001\u91ca\u653e\u6216\u8005\u4fdd\u62a4\u51e0\u4e4e\u4efb\u4f55\u4e1c\u897f\u3002\u9762\u5bf9\u5355\u539f\u5b50\u8868\u9762\u80fd\u9ad8\u3001\u53ef\u8fc1\u79fb\u3001\u6613\u56e2\u805a\u5bfc\u81f4\u7684\u5355\u539f\u5b50\u4e0d\u7a33\u5b9a\u8fd9\u4e00\u6781\u5177\u6311\u6218\u6027\u7684\u95ee\u9898\uff0cMOF\u5927\u80c6\u5e94\u6218\uff0c\u901a\u8fc7\u5404\u79cd\u5408\u6210\u7b56\u7565\uff0c\u5f97\u5230\u4e86\u4e0d\u5c11\u6781\u5176\u7a33\u5b9a\u4e14\u6027\u80fd\u4f18\u5f02\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u3002\u672c\u6587\u5c31\u5e26\u5927\u5bb6\u4e86\u89e3\u4e00\u4e0bMOF\u548c\u5355\u539f\u5b50\u5f3a\u5f3a\u8054\u624b\u4e4b\u540e\u80fd\u5e26\u7ed9\u6211\u4eec\u54ea\u4e9b\u60ca\u559c\u3002<\/p>\n

\u4e00\u3001Pt\u5355\u539f\u5b50\u9996\u6b21\u88ab\u9650\u57df\u5728MOF\u4e2d[1]<\/sup><\/p>\n

\u4e2d\u56fd\u79d1\u6280\u5927\u5b66\u6c5f\u6d77\u9f99\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u9996\u6b21\u5229\u7528MOF\u6750\u6599\u4f5c\u4e3a\u7a33\u5b9a\u5355\u539f\u5b50\u7684\u8f7d\u4f53\u5e76\u63a2\u7d22\u4e86\u5176\u5728\u5149\u50ac\u5316\u4ea7\u6c22\u65b9\u9762\u7684\u5e94\u7528\uff0c\u540c\u65f6\u5bf9\u5149\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u7535\u8377\u8f6c\u79fb\u4ee5\u53ca\u5149\u50ac\u5316\u673a\u7406\u8fdb\u884c\u4e86\u521d\u6b65\u63a2\u8ba8\u3002MOF\u7a33\u5b9a\u7684\u5355\u539f\u5b50Pt\u590d\u5408\u6750\u6599\uff0c\u80fd\u591f\u5728\u5149\u50ac\u5316\u88c2\u89e3\u6c34\u4ea7\u6c22\u7684\u8fc7\u7a0b\u4e2d\uff0c\u4f7f\u7535\u5b50\u4eceMOF\u5149\u654f\u5242\u8f6c\u79fb\u5230Pt\u7535\u5b50\u53d7\u4f53\uff0c\u5355\u539f\u5b50Pt\u5c55\u73b0\u51fa\u8d85\u9ad8\u7684\u6d3b\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. \u5408\u6210\u793a\u610f\u56fe<\/p>\n

\u6b64\u7814\u7a76\u5229\u7528\u9ad8\u5ea6\u7a33\u5b9a\u7684\u94dd\u57fa\u535f\u5549MOF\uff1aAl\u2010TCPP\uff0c\u901a\u8fc7\u535f\u5549\u63a5\u5934\u5c06\u65e0\u9650\u957f\u7684Al(OH)O4<\/sub>\u94fe\u4e92\u8fde\u62103D\u5fae\u5b54\u9aa8\u67b6\uff0c\u5c06Pt\uff08II\uff09\u91d1\u5c5e\u5316\u6210\u535f\u5549\u4e2d\u5fc3\uff0c\u518d\u7ecf\u8fc7\u7b80\u5355\u8fd8\u539f\uff0c\u5229\u7528Al-TCPP\u4e2d\u5421\u54afN\u539f\u5b50\u4e0ePt\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u83b7\u5f97Pt\u5355\u539f\u5b50\u3002\u5355\u539f\u5b50Pt\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u6d3b\u6027\uff0c\u5176TOF\u4e3a35 h-1<\/sup>\uff0c\u7ea6\u4e3a\u76f8\u540cMOF\u7a33\u5b9a\u7684Pt\u7eb3\u7c73\u9897\u7c92\u7684\u768430\u500d\u3002\u8d85\u5feb\u901f\u77ac\u6001\u5438\u6536\u5149\u8c31\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u88ab\u9650\u57df\u5728MOF\u4e2d\u7684Pt\u5355\u539f\u5b50\u63d0\u4f9b\u4e86\u9ad8\u6548\u7684\u7535\u5b50\u4f20\u8f93\u901a\u9053\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u4e5f\u8868\u660e\uff0c\u5c06Pt\u5355\u539f\u5b50\u5f15\u5165MOF\u63d0\u9ad8\u4e86\u5176\u4e0e\u6c22\u7684\u7ed3\u5408\u80fd\uff0c\u5927\u5927\u63d0\u9ad8\u4e86\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. \u5149\u50ac\u5316\u5236\u6c22\u7684\u81ea\u7531\u80fd\u56fe\u53ca\u5438\u9644\u7ed3\u6784\u56fe<\/p>\n

\u4e8c\u3001MOFs\u7684\u91d1\u5c5e\u8282\u70b9\u539f\u4f4d\u70ed\u89e3\u8fd8\u539f\u5f97\u5230\u5355\u539f\u5b50[2]<\/sup><\/p>\n

\u5434\u5b87\u6069\u6559\u6388\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u901a\u8fc7MOFs\u7684\u91d1\u5c5e\u8282\u70b9\u539f\u4f4d\u70ed\u89e3\u8fd8\u539f\u7684\u65b9\u6cd5\u5236\u5907\u5f97\u5230\u975e\u8d35\u91d1\u5c5eCo\u5355\u539f\u5b50\u50ac\u5316\u5242\u3002\u8be5\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u6781\u5177\u521b\u65b0\u6027\u7684\u7b56\u7565\uff0c\u5728\u6c2e\u63ba\u6742\u7684\u591a\u5b54\u78b3\u4e0a\u5b9e\u73b0\u7a33\u5b9a\u7684Co\u5355\u539f\u5b50\uff08SA\uff09\uff0c\u5176\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u8d85\u8fc74wt%\u3002\u8003\u8651\u5230Co2+<\/sup>\u548cZn2+<\/sup>\u4e0e2-\u7532\u57fa\u54aa\u5511\u5177\u6709\u76f8\u540c\u7684\u65b9\u94a0\u77f3\u914d\u4f4d\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u4e00\u79cdZn\/Co\u5747\u4e00\u5206\u5e03\u7684Zn\/Co\u53cc\u91d1\u5c5eMOF\u3002\u6dfb\u52a0Zn2+<\/sup>\u53ef\u4ee5\u66ff\u4ee3\u4e00\u5b9a\u6bd4\u4f8b\u7684Co2+<\/sup>\u4f4d\u70b9\uff0c\u5e76\u5145\u5f53\u201c\u6805\u680f\u201d\u4ee5\u8fdb\u4e00\u6b65\u6269\u5927Co\u539f\u5b50\u7684\u76f8\u90bb\u8ddd\u79bb\u3002\u4f4e\u6cb8\u70b9\u7684Zn\u539f\u5b50\uff08mp\u00a0420\u00a0\u00b0C\uff0cbp 907\u00a0\u00b0C\uff09\u5728800\u00b0C\u4ee5\u4e0a\u7684\u9ad8\u6e29\u4e0b\u9009\u62e9\u6027\u84b8\u53d1\u6389\uff0c\u6709\u673a\u914d\u4f53\u4e0a\u7684\u78b3\u5316\u4f1a\u539f\u4f4d\u8fd8\u539fCo\u91d1\u5c5e\u8282\u70b9\uff0c\u4ece\u800c\u6700\u7ec8\u5f97\u5230Co\u5355\u539f\u5b50\u50ac\u5316\u5242\u3002\u672c\u6587\u6218\u7565\u6027\u5730\u6784\u5efa\u524d\u4f53\uff0c\u6781\u5927\u5229\u7528\u4e86MOF\u7684\u7ed3\u6784\u53ef\u8c03\u8282\u6027\uff0c\u800c\u4e14\u8fd9\u79cd\u7b56\u7565\u53ef\u4ee5\u63a7\u5236\u5355\u539f\u5b50\u7684\u7a7a\u95f4\u5206\u6563\uff0c\u91d1\u5c5e\u8d1f\u8f7d\u548c\u914d\u4f4d\u7ed3\u6784\uff0c\u8be5\u7b56\u7565\u53ef\u4ee5\u63a8\u5e7f\u5230\u5176\u4ed6\u91d1\u5c5e\u5355\u539f\u5b50\u6750\u6599\u7684\u5236\u5907\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. \u5236\u5907\u793a\u610f\u56fe<\/p>\n

\u4e09\u3001\u975e\u914d\u4f4d\u6c28\u57fa\u951a\u5b9aRu\u5355\u539f\u5b50[3]<\/sup><\/p>\n

\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u9662\u58eb\u548c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5434\u5b87\u6069\u6559\u63882017\u5e74\u5728\u00a0JACS\u4e0a\u53d1\u8868\u4e86\u975e\u914d\u4f4d\u6c28\u57fa\u951a\u5b9aRu\u5355\u539f\u5b50\u7684\u7814\u7a76\u3002\u4f5c\u8005\u5229\u7528\u4e86\u4f4d\u4e8eUiO-66-NH2<\/sub>\u4e2d\u5bf9\u82ef\u4e8c\u7532\u9178\u8fde\u63a5\u57fa\u4e0a\u7684\u975e\u914d\u4f4d-NH2<\/sub>\u4f5c\u4e3a\u8def\u6613\u65af\u78b1\u6765\u7a33\u5b9aRuCl3<\/sub>\uff0c\u884d\u751f\u7269UiO-66-NH2<\/sub>\u5c06BDC\uff08BDC = 1,4-\u82ef\u4e8c\u7532\u9178\uff09\u5b98\u80fd\u5316\uff0c\u80fd\u5f88\u5927\u7a0b\u5ea6\u4e0a\u7ee7\u627fUiO-66\u7684\u5bf9\u79f0\u6027\u548c\u5f62\u8c8c\u3002\u8def\u6613\u65af\u78b1N\u4e2d\u5b64\u5bf9\u7535\u5b50\u4e0e\u91d1\u5c5eRu\u7684d\u8f68\u9053\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u786e\u4fddRu\u5355\u539f\u5b50\u88ab\u9650\u57df\u5728MOF\u7684\u5b54\u4e2d\uff0c\u5e76\u9632\u6b62\u5b83\u4eec\u5728\u9ad8\u6e29\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u805a\u96c6\u3002\u7ecf\u9ad8\u6e29\u70ed\u89e3\u540e\uff0c\u6709\u673a\u914d\u4f53\u8f6c\u5316\u4e3a\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\uff08N\u2212C\uff09\uff0c\u91d1\u5c5e\u9633\u6781\u8f6c\u5316\u4e3aZrO2<\/sub>\u7eb3\u7c73\u7c92\u5b50\uff0cRu\u524d\u9a71\u4f53\u88ab\u70ed\u89e3\u751f\u6210\u7684C\u539f\u4f4d\u8fd8\u539f\u3002\u6ca1\u6709\u6e38\u79bb\u7684-NH2<\/sub>\u5236\u5907\u7684\u7684\u5bf9\u6bd4\u6837\u54c1\u4e2dRu\u4f1a\u5f62\u6210\u91d1\u5c5e\u56e2\u7c07\u800c\u4e0d\u662f\u4ee5\u5355\u539f\u5b50\u5f62\u5f0f\u5206\u6563\u5728\u591a\u5b54\u78b3\u4e0a\u3002\u8fd9\u4e9b\u805a\u96c6\u7a0b\u5ea6\u4e0d\u540c\u7684Ru\u50ac\u5316\u5242\u5bf9\u55b9\u8bfa\u916e\u7684\u6c22\u5316\u53cd\u5e94\u8868\u73b0\u51fa\u5177\u6709\u5c3a\u5bf8\u4f9d\u8d56\u6027\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5c55\u793a\u4e86\u4e00\u79cd\u901a\u8fc7\u539f\u5b50\u5c3a\u5ea6\u8bbe\u8ba1\u6765\u8c03\u6574\u548c\u4f18\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u53ef\u9760\u9014\u5f84\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. Ru\u5355\u539f\u5b50\u50ac\u5316\u5242\u5236\u5907\u793a\u610f\u56fe<\/p>\n

\u56db\u3001\u8d85\u9ad8\u542b\u91cfPt\u5355\u539f\u5b50\u7684\u8d85\u8584MOF\u7eb3\u7c73\u7247[4]<\/sup><\/p>\n

\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u5468\u6c38\u4e30\u6559\u6388\u56e2\u961f\u5efa\u7acb\u4e86\u8868\u9762\u6d3b\u6027\u5242\u8f85\u52a9\u81ea\u7ec4\u88c5\u65b0\u65b9\u6cd5\uff0c\u9009\u62e9\u542bPt\u7684\u535f\u5549\u6709\u673a\u914d\u4f53\u548c\u94dc\u79bb\u5b50\u4f5c\u4e3aMOF\u7684\u6784\u7b51\u5355\u5143\uff0c\u5728\u8868\u9762\u6d3b\u6027\u5242\u805a\u4e59\u70ef\u5421\u54af\u70f7\u916e\uff08PVP\uff09\u7684\u8f85\u52a9\u4f5c\u7528\u4e0b\uff0c\u901a\u8fc7\u7fa7\u57fa\u4e0e\u94dc\u79bb\u5b50\u7684\u914d\u4f4d\u81ea\u4e0b\u800c\u4e0a\u5730\u5236\u5907\u4e86\u5177\u6709\u8d85\u9ad8\u542b\u91cfPt\u5355\u539f\u5b50\u7684\u8d85\u8584MOF\u7eb3\u7c73\u7247\u3002\u8be5\u7eb3\u7c73\u7247\u7528\u4f5cOER\u7535\u50ac\u5316\u5242\u65f6\uff0c\u7535\u6d41\u5bc6\u5ea6\u8fbe\u523010\u00a0mA cm-2<\/sup>\u65f6\uff0c\u8fc7\u7535\u4f4d\u4ec5\u4e3a250\u00a0mV\u3002\u4f5c\u8005\u901a\u8fc7\u4e00\u7cfb\u5217\u8868\u5f81\u624b\u6bb5\u8bc1\u660e\u8d85\u8584MOF\u7eb3\u7c73\u7247\u4e2d\u7684\u8868\u9762\u539f\u5b50\u662f\u4e0d\u9971\u548c\u914d\u4f4d\u7684\uff0c\u5b83\u4eec\u5177\u6709\u5f00\u653e\u7684\u5438\u9644\u4f4d\u70b9\uff08\u5305\u62ecX\u5c04\u7ebf\u5149\u8c31\u6cd5\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff09\u3002\u914d\u4f4d\u4e0d\u9971\u548c\u91d1\u5c5e\u539f\u5b50\u662f\u4e3b\u8981\u7684\u6d3b\u6027\u4e2d\u5fc3\uff0c\u800c\u954d\u548c\u94b4\u91d1\u5c5e\u4e4b\u95f4\u7684\u5076\u8054\u4f5c\u7528\u5bf9\u4e8e\u8c03\u8282\u7535\u50ac\u5316\u6d3b\u6027\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5. Pt-TCPP\u5236\u5907\u793a\u610f\u56fe\u53ca\u7ed3\u6784\u8868\u5f81\u56fe<\/p>\n

\u4e94\u3001MOF\u884d\u751f\u78b3\u6750\u6599\u8d1f\u8f7d\u5355\u539f\u5b50\u50ac\u5316\u5242\u7814\u7a76\u8fdb\u5c55[5]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe6. MOF\u884d\u751f\u78b3\u6750\u6599\u8d1f\u8f7d\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u5236\u5907\u53ca\u5e94\u7528<\/p>\n

\u5355\u539f\u5b50\u50ac\u5316\u5242\u56e0\u5176\u72ec\u7279\u7684\u50ac\u5316\u6027\u80fd\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u7136\u800c\u5355\u539f\u5b50\u7684\u9ad8\u8868\u9762\u80fd\u7ed9\u5b83\u4eec\u7684\u5236\u5907\u8fc7\u7a0b\u5e26\u6765\u4e86\u6781\u5927\u7684\u6311\u6218\u3002\u4e3a\u4e86\u514b\u670d\u8fd9\u4e2a\u95ee\u9898\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u884d\u751f\u7684\u78b3\u6750\u6599\u7531\u4e8e\u7c92\u5f84\u548c\u5f62\u72b6\u53ef\u8c03\u8282\uff0c\u6bd4\u8868\u9762\u79ef\u5927\uff0c\u5177\u6709\u5b54\u9699\u7387\uff0c\u70ed\u7a33\u5b9a\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u597d\u7684\u4f18\u70b9\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u7406\u60f3\u7684\u5355\u539f\u5b50\u8f7d\u4f53\u6750\u6599\u3002\u5317\u4eac\u5316\u5de5\u5927\u5b66\u7684\u5218\u519b\u67ab\u6559\u6388\/\u5b59\u6653\u660e\u6559\u6388\u8bfe\u9898\u7ec4\u5728Small Methods\u4e0a\u53d1\u8868\u4e86\u5173\u4e8eMOF\u884d\u751f\u78b3\u8d1f\u8f7d\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u7cfb\u7edf\u6027\u7efc\u8ff0\uff0c\u8fd9\u7bc7\u7efc\u8ff0\u7740\u91cd\u4ecb\u7ecd\u4e86MOF\u884d\u751f\u7684\u78b3\u8d1f\u8f7d\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u4e0d\u540c\u7c7b\u578b\u6784\u5efa\u7b56\u7565\uff1a\u76f4\u63a5\u70ed\u89e3\u9884\u8bbe\u8ba1MOFs\u7b56\u7565\u3001\u76f4\u63a5\u70ed\u89e3\u542b\u7a7a\u95f4\u9650\u57df\u91d1\u5c5e\u5206\u5b50\u7684MOFs\u7b56\u7565\u3001\u70ed\u89e3-\u9178\u6d17\u7b56\u7565\u3001\u901a\u8fc7MOF\u70ed\u89e3\u81ea\u4e0a\u800c\u4e0b\u7531\u5757\u4f53\u91d1\u5c5e\u5236\u5907\u5355\u539f\u5b50\u7b56\u7565\u3002\u4f5c\u8005\u4e5f\u603b\u7ed3\u4e86\u8fd9\u4e9bMOF\u884d\u751f\u7684\u78b3\u8d1f\u8f7d\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u5728\u50ac\u5316\u5e94\u7528\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5305\u62ec\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u3001\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94(CO2RR)\u3001\u6790\u6c22\u53cd\u5e94(HER)\u3001\u6c2e\u6c14\u8fd8\u539f(N2RR)\u7b49\u7535\u50ac\u5316\u53cd\u5e94\u548c\u9009\u62e9\u6027\u52a0\u6c22\u7b49\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u3002\u6700\u540e\u5bf9MOF\u884d\u751f\u7684\u78b3\u8d1f\u8f7d\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u5f53\u524d\u6311\u6218\u548c\u672a\u6765\u673a\u9047\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u89c1\u89e3\u3002\u6b64\u6587\u732e\u662f\u4f17\u591a\u5355\u539f\u5b50\u50ac\u5316\u5242\u7efc\u8ff0\u4e2d\u4e3a\u6570\u4e0d\u591a\u7684\u5bf9\u4ee5MOF\u884d\u751f\u78b3\u6750\u6599\u4e3a\u57fa\u5e95\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u603b\u7ed3\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/p>\n

[1]Xinzuo Fang, Qichao Shang, Yu Wang, Long Jiao, Tao Yao, Yafei Li, Qun Zhang, Yi Luo, Hai-Long Jiang, Single Pt Atoms Confined into a Metal\u2013Organic Framework for Efficient Photocatalysis, Advanced Materials, 2018 (30) 1705112.<\/p>\n

[2]Peiqun Yin, Tao Yao, Yuen Wu, Lirong Zheng, Yue Lin, Wei Liu, Huanxin Ju, Junfa Zhu, Xun Hong, Zhaoxiang Deng, Gang Zhou, Shiqiang Wei, Yadong Li, Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts, Angewandte Chemie International Edition, 2016 (55) 10800-10805.<\/p>\n

[3]Xin Wang, Wenxing Chen, Lei Zhang, Tao Yao, Wei Liu, Yue Lin, Huanxin Ju, Juncai Dong, Lirong Zheng, Wensheng Yan, Xusheng Zheng, Zhijun Li, Xiaoqian Wang, Jian Yang, Dongsheng He, Yu Wang, Zhaoxiang Deng, Yuen Wu, Yadong Li, Uncoordinated amine groups of metal\u2013organic frameworks to anchor single Ru sites as chemoselective catalysts toward the hydrogenation of quinoline, Journal of the American Chemical Society, 2017 (139) 9419-9422.<\/p>\n

[4]Q. Zuo, T. Liu, C. Chen, Y. Ji, X. Gong, Y. Mai, Y. Zhou, Ultrathin Metal\u2013Organic Framework Nanosheets with Ultrahigh Loading of Single Pt Atoms for Efficient Visible\u2010Light\u2010Driven Photocatalytic H2\u00a0Evolution, Angew. Chem. Int. Ed.\u00a02019,\u00a058, 10198.<\/p>\n

[5]Aijuan Han, Bingqing Wang, Anuj Kumar, Yongji Qin, Jing Jin, Xinhe Wang, Can Yang, Bo Dong, Yin Jia, Junfeng Liu, Recent Advances for MOF\u2010Derived Carbon\u2010Supported Single\u2010Atom Catalysts, Small Methods, 2019 (3) 1800471.<\/p>\n

\u672c\u6587\u7531\u6625\u6625\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u81ea2011\u5e74\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5f20\u6d9b\u9662\u58eb\u3001\u6e05\u534e\u5927\u5b66\u674e\u96bd\u6559\u6388\u53ca\u7f8e\u56fd\u4e9a\u5229\u6851\u90a3\u5dde\u7acb\u5927\u5b66\u5218\u666f\u6708\u6559\u6388\u5171\u540c\u63d0\u51fa\u201c\u5355\u539f\u5b50\u50ac\u5316\u201d\u7684\u6982\u5ff5\uff0c\u53d1\u73b0\u6b64\u7c7b\u50ac\u5316\u5242\u5176\u539f\u5b50\u5229\u7528\u7387\u80fd\u591f\u8fbe…<\/p>\n","protected":false},"author":11454,"featured_media":206783,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-206782","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/206782"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=206782"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/206782\/revisions"}],"predecessor-version":[{"id":208131,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/206782\/revisions\/208131"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/206783"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=206782"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=206782"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=206782"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}