{"id":206273,"date":"2020-08-27T06:42:53","date_gmt":"2020-08-26T22:42:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=206273"},"modified":"2020-08-26T19:52:56","modified_gmt":"2020-08-26T11:52:56","slug":"mof%e6%9d%a5%e8%a2%ad%ef%bc%8c%e9%a1%b6%e5%88%8a%e6%9c%80%e6%96%b0%e5%8a%a8%e6%80%81%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=206273","title":{"rendered":"MOF\u6765\u88ad\uff0c\u9876\u520a\u6700\u65b0\u52a8\u6001\u901f\u89c8"},"content":{"rendered":"
MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u4e09\u7ef4\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5728\u50ac\u5316\u3001\u50a8\u80fd\u548c\u5206\u79bb\u7b49\u7b49\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u81ea20\u4e16\u7eaa90\u5e74\u4ee3\uff0c\u7b2c\u4e00\u4ee3MOFs\u6750\u6599\u88ab\u5408\u6210\u51fa\u6765\uff0cMOFs\u5df2\u6210\u4e3a\u65e0\u673a\u5316\u5b66\u3001\u6709\u673a\u5316\u5b66\u7b49\u591a\u4e2a\u5316\u5b66\u5206\u652f\u7684\u91cd\u8981\u7814\u7a76\u65b9\u5411\u3002\u7b14\u8005\u5b9a\u671f\u68b3\u7406\u8fd1\u671f\u6750\u6599\u7c7b\u7cfb\u5217\u520a\u4e2dMOFs\u7684\u76f8\u5173\u6587\u7ae0\uff0c\u4e00\u8d77\u4e86\u89e3\u4e0b\u76f8\u5173\u7814\u7a76\uff01<\/p>\n
Nature<\/b><\/strong>\u00a0Commun.: MOF<\/b><\/strong>\u7528\u4e8e\u50ac\u5316\u53ca\u5316\u5b66\u7ed3\u6784\u786e\u5b9a<\/b><\/strong><\/p>\n \u672a\u7ed3\u6676\u7684\u5929\u7136\u4ea7\u7269\u7684\u786e\u5207\u5316\u5b66\u7ed3\u6784\u4ecd\u7136\u662f\u81ea\u7136\u79d1\u5b66\u7684\u4e3b\u8981\u6311\u6218\u4e4b\u4e00\u3002\u5c3d\u7ba1\u5728\u5168\u5408\u6210\u65b9\u9762\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u5bf9\u65e0\u6570\u5177\u6709\u975e\u5e38\u654f\u611f\u5316\u5b66\u529f\u80fd\u7684\u5929\u7136\u4ea7\u7269\u7684\u7edd\u5bf9\u7ed3\u6784\u6d4b\u5b9a\u4ecd\u672a\u5b8c\u6210\u3002\u5728\u8fd9\u91cc\uff0c\u897f\u73ed\u7259\u5df4\u4f26\u897f\u4e9a\u5927\u5b66\u7684Jes\u00fas Ferrando-Soria\u6559\u6388\u3001Emilio Pardo\u6559\u6388\u8054\u5408\u610f\u5927\u5229\u5361\u62c9\u5e03\u91cc\u4e9a\u5927\u5b66Donatella Armentano\u6559\u6388\u7b49\u4eba\u5c55\u793a\u4e86\u4e00\u4e2a\u5438\u9644\u6c34\u7684\u542b\u6709\u7f9f\u57fa\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\uff0c\u53ef\u4ee5\u9009\u62e9\u6027\u6c34\u89e3\u7cd6\u57fa\u952e\uff0c\u901a\u8fc7\u8d85\u5206\u5b50\u79e9\u5e8f\u4e0e\u6240\u5f62\u6210\u7684\u624b\u6027\u7247\u6bb5\uff0c\u5e76\u901a\u8fc7\u5355\u6676x\u5c04\u7ebf\u6676\u4f53\u5b66\u53ef\u4ee5\u786e\u5b9a\u6709\u673a\u7ed3\u6784\u3002\u8fd9\u79cd\u57fa\u4e8e\u4eff\u751f\u3001\u5ec9\u4ef7\u3001\u53ef\u7528\u7684\u56fa\u4f53\u50ac\u5316\u5242\u7684\u7ec4\u5408\u7b56\u7565\uff0c\u4e3a\u786e\u5b9a\u916e\u7c7b\u5316\u5408\u7269\u7684\u7edd\u5bf9\u7ed3\u6784\u800c\u4e0d\u8003\u8651\u964d\u89e3\u654f\u611f\u6027\uff0c\u4e5f\u4e3a\u8bbe\u8ba1\u6781\u6e29\u548c\u7684\u65e0\u91d1\u5c5e\u56fa\u4f53\u50ac\u5316\u8fc7\u7a0b\u800c\u4e0d\u9700\u8981\u9178\u6027\u8d28\u5b50\u6253\u5f00\u4e86\u5927\u95e8\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cHydrolase\u2013like catalysis and structural resolution of natural products by a metal\u2013organic framework\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Commun.\u4e0a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41467-020-16699-3<\/p>\n \u56fe1\u00a0MOF\u50ac\u5316\u8517\u7cd6\u7cd6\u57fa\u952e\u7684\u9009\u62e9\u6027\u6c34\u89e3<\/p>\n J<\/b><\/strong>ACS<\/b><\/strong>\uff1aMOFs\u914d\u4f4d\u5c42\u63d0\u9ad8\u754c\u9762\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u5b9e\u73b0\u9ad8\u6548CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u5149\u8fd8\u539f<\/b><\/strong><\/p>\n \u7535\u5b50\u7a7a\u7a74\u5bf9\u7684\u590d\u5408\u4e25\u91cd\u964d\u4f4e\u4e86\u5149\u50ac\u5316\u5242\u7684\u6548\u7387\u3002\u8fd9\u4e2a\u95ee\u9898\u53ef\u4ee5\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u901a\u8fc7\u4f18\u5316\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u901a\u8fc7\u5408\u7406\u7684\u7ed3\u6784\u8bbe\u8ba1\u5728\u539f\u5b50\u6c34\u5e73\u3002\u4e2d\u79d1\u9662\u798f\u5efa\u7269\u6784\u6240Rong Cao\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u96c6\u5149\u6355\u83b7\u5668\uff0c\u6d3b\u6027\u50ac\u5316\u4f4d\u70b9\u548c\u9ad8\u8868\u9762\u79ef\u4e3a\u4e00\u4f53\u7684\u5421\u5511\u57fa\u535f\u5549\u954d-MOF\uff08PCN-601\uff09\uff0c\u5e76\u901a\u8fc7\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u8be5\u6750\u6599\u662f\u4e00\u79cd\u51fa\u8272\u4e14\u8010\u7528\u7684\u5149\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u9ad8\u6548\u50ac\u5316\u5ba4\u6e29\u4e0b\u53ef\u89c1\u5149\u9a71\u52a8\u7684\u901a\u8fc7H2<\/sub>O\u84b8\u6c14\u7684CO2<\/sub>\u8fd8\u539f\u3002\u52a8\u529b\u5b66\u7814\u7a76\u8868\u660e\uff0c\u5421\u5511\u57fa\u56e2\u548c\u954d\u6c27\u56e2\u7c07\u7684\u5f3a\u914d\u4f4d\u4f7fPCN-601\u5177\u6709\u5408\u9002\u7684\u80fd\u5e26\u6392\u5217\u548c\u8d85\u5feb\u7684\u914d\u4f53\u5230\u8282\u70b9\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u56e0\u6b64\uff0cPCN-601\u50ac\u5316CO2<\/sub>\u8f6c\u5316CH4<\/sub>\u4ea7\u91cf\u8fdc\u8fdc\u8d85\u8fc7\u57fa\u4e8e\u7fa7\u9178\u535f\u5549\u548c\u7ecf\u5178Pt\/CdS\u5149\u50ac\u5316\u5242\u7c7b\u4f3cMOFs\u76843\u500d\u548c20\u500d\u4ee5\u4e0a\u3002\u8be5\u53cd\u5e94\u907f\u514d\u4e86\u6e05\u9664\u5b54\u5242\u7684\u4f7f\u7528\uff0c\u5728\u6c14\u76f8\u4e2d\u8fdb\u884c\uff0c\u53ef\u4ee5\u5145\u5206\u5229\u7528MOFs\u9ad8\u7684\u6c14\u4f53\u5438\u6536\u91cf\u3002\u7814\u7a76\u8868\u660e\uff0c\u5408\u7406\u8bbe\u8ba1MOF\u7ed3\u6784\u914d\u4f4d\u7403\u4e0d\u4ec5\u53ef\u4ee5\u89e3\u51b3\u53cd\u5e94\u6027\u4e0e\u7a33\u5b9a\u6027\u4e4b\u95f4\u7684\u77db\u76fe\uff0c\u800c\u4e14\u53ef\u4ee5\u6781\u5927\u5730\u4fc3\u8fdb\u754c\u9762\u7535\u8377\u8f6c\u79fb\uff0c\u5b9e\u73b0\u52a8\u529b\u5b66\u4f18\u5316\uff0c\u4e3a\u8bbe\u8ba1\u9ad8\u6548MOF\u5149\u50ac\u5316\u5242\u63d0\u4f9b\u6307\u5bfc\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBoosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 <\/sub>Photoreduction via Rational Design of Coordination Spheres on Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/jacs.0c05530<\/p>\n \u56fe2\u00a0PCN-601 CO2<\/sub>\u5149\u8fd8\u539f\u6027\u80fd<\/p>\n J<\/b><\/strong>ACS:<\/b><\/strong>\u6297\u8f90\u5c04\u948d\u8054\u8418\u915aMOF<\/b><\/strong><\/p>\n \u7f8e\u56fd\u5723\u6bcd\u5927\u5b66Peter C. Burns\u7b49\u4eba\u5408\u6210\u4e86\u4e00\u79cd\u516d\u805a\u4f53\u7684\u542b\u948d\u6709\u673a\u9aa8\u67b6(TOF-16)\uff0c\u5e76\u5bf9\u5176\u8fdb\u884c\u4e86\u8868\u5f81\u548c\u8f90\u5c04\u68c0\u6d4b\u3002\u8f90\u5c04\u7a33\u5b9a\u6027\u6d4b\u8bd5\u4f7f\u7528\u7684\u662f\u03b3\u5c04\u7ebf\u548c5MeV He2+<\/sup>\u79bb\u5b50\u6a21\u62df\u7c92\u5b50\u30024 MGy\u5242\u91cf\u7167\u5c04TOF-16\u65f6\uff0cX\u5c04\u7ebf\u884d\u5c04\u770b\u4e0d\u5230\u660e\u663e\u7684\u4f53\u7ed3\u6784\u635f\u4f24\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63a2\u6d4b\u8f90\u5c04\u7a33\u5b9a\u6027\uff0c\u5bf9MOF\u8fdb\u884c\u4e86He2+<\/sup>\u79bb\u5b50\u8f90\u7167\u7814\u7a76\u3002\u884d\u5c04\u6570\u636e\u8868\u660e\u5728\u5927\u7ea615 MGy\u7684\u7167\u5c04\u4e0b\u7ed3\u6676\u5ea6\u5f00\u59cb\u4e0b\u964d\uff0c\u5728\u5927\u7ea625 MGy\u7684He2+<\/sup>\u79bb\u5b50\u7167\u5c04\u4e0b\u7ed3\u6676\u5ea6\u5b8c\u5168\u4e0b\u964d\u3002\u89c2\u5bdf\u5230\u7684\u9ad8\u8f90\u5c04\u6297\u6027\u8868\u660e\uff0cMOFs\u53ef\u4ee5\u627f\u53d7\u6838\u5e9f\u6599\u6d41\u4e2d\u53d1\u73b0\u7684\u5242\u91cf\u7684\u8f90\u5c04\u7167\u5c04\uff0c\u8fd9\u7a81\u51fa\u8868\u660e\u9700\u8981\u6709\u7cfb\u7edf\u7684\u65b9\u6cd5\u6765\u7406\u89e3\u5e76\u6700\u7ec8\u8bbe\u8ba1\u5177\u6709\u7279\u6b8a\u8f90\u5c04\u6297\u6027\u7684\u6846\u67b6\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cUnprecedented Radiation Resistant Thorium-Binaphthol MOF\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5:\u00a0DOI: 10.1021\/jacs.0c05272<\/p>\n \u56fe3\u00a0He2+<\/sup>\u8f90\u7167\u540eTOF-16\u7684\u5206\u6790<\/p>\n Chem Soc Rev<\/b><\/strong>\uff1a<\/b><\/strong>\u91d1\u5c5e\u6c27\u5316\u7269\u63a7\u5236<\/b><\/strong>M<\/b><\/strong>OF\u548c\u591a\u5b54\u78b3\u6750\u6599\u7684\u5f62\u6001<\/b><\/strong><\/p>\n \u7531\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u548c\u591a\u5b54\u78b3\u7684\u8868\u9762\u79ef\u4e0e\u4f53\u79ef\u548c\u8d28\u91cf\u4e4b\u6bd4\u5f88\u5927\uff0c\u5b83\u4eec\u5f7b\u5e95\u6539\u53d8\u4e86\u8bb8\u591a\u4f9d\u8d56\u4e8e\u8868\u9762\u5316\u5b66\u548c\u7269\u7406\u76f8\u4e92\u4f5c\u7528\u7684\u5e94\u7528\u3002\u7136\u800c\uff0c\u76ee\u524d\u7684\u4e3b\u8981\u6311\u6218\u662f\u5982\u4f55\u5851\u9020\u8fd9\u4e9b\u591a\u5b54\u6750\u6599\uff0c\u5c06\u5176\u5728\u5b9e\u9a8c\u5ba4\u589e\u5f3a\u7684\u6027\u80fd\u8f6c\u5316\u4e3a\u73b0\u5b9e\u4e16\u754c\u7684\u5b8f\u89c2\u5e94\u7528\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u6ce2\u5170\u5bc6\u8328\u51ef\u7ef4\u5947\u5927\u5b66Joanna Goscianska\u6559\u6388\u8054\u5408\u82f1\u56fd\u683c\u62c9\u65af\u54e5\u5927\u5b66Bernhard V. K. J. Schmidt\u6559\u6388\u7b49\u4eba\u5bf9\u5982\u4f55\u5c06\u7cbe\u786e\u7684\u5f62\u6001\u63a7\u5236\u8f6c\u79fb\u5230MOFs\u548c\u591a\u5b54\u78b3\u6750\u6599\u4e0a\u4f5c\u4e86\u5168\u9762\u7684\u7efc\u8ff0\u3002\u56e0\u6b64\uff0c\u53ef\u57280D\u30011D\u30012D\u548c3D\u8bbe\u8ba1\u5b9a\u5236\u6750\u6599\u7ed3\u6784\uff0c\u8fd9\u5bf9\u50a8\u80fd\u3001\u50ac\u5316\u548c\u7eb3\u7c73\u533b\u5b66\u7b49\u5e94\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u56e0\u6b64\uff0c\u5728MOFs\u548c\u591a\u5b54\u78b3\u7684\u5f62\u6001\u63a7\u5236\u65b9\u9762\u7684\u91cd\u5927\u7814\u7a76\u8fdb\u5c55\u5c06\u4fc3\u8fdb\u8fd9\u4e9b\u6750\u6599\u7684\u4f7f\u7528\uff0c\u4ee5\u6ee1\u8db3\u793e\u4f1a\u7684\u4e3b\u8981\u9700\u6c42\uff0c\u7279\u522b\u662f\u80fd\u6e90\u3001\u5065\u5eb7\u548c\u73af\u5883\u7684\u91cd\u5927\u6311\u6218\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cControlling the morphology of metal\u2013organic frameworks and porous carbon materials: metal oxides as primary architecture-directing agents\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chem Soc Rev\u4e0a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1039\/c9cs00871c<\/p>\n \u56fe4\u00a0\u4e0d\u540c\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u591a\u9762\u5f62\u6001\u8f6c\u5316\u4e3aMOFs\u548c\u591a\u5b54\u78b3<\/p>\n Angew<\/b><\/strong>.<\/b><\/strong>\uff1a<\/b><\/strong>\u7a33\u5065\u7684Ag<\/b><\/strong>27<\/b><\/sub><\/strong>\u7c07\u57fa\u4e8c\u7ef4<\/b><\/strong>M<\/b><\/strong>OF<\/b><\/strong>\u9ad8\u6548\u50ac\u5316CO<\/b><\/strong>2<\/b><\/sub><\/strong><\/p>\n \u94f8\u9020\u91d1\u5c5e(Cu\u3001Ag\u3001Au)\u57fa\u50ac\u5316\u5242\u5728\u6709\u673a\u5408\u6210\u5316\u5b66\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u800c\u7a33\u5065\u7684\u591a\u76f8\u94f6\u57fa\u50ac\u5316\u5242\u7531\u4e8e\u5176\u9ad8\u5149\u654f\u6027\u548c\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\u800c\u96be\u4ee5\u83b7\u5f97\u3002\u5728\u6b64\uff0c\u5c71\u4e1c\u5927\u5b66Di Sun\uff0cPing Cui\u6559\u6388\u7b49\u62a5\u9053\u4e86\u4e00\u4e2a5,10,15,20-\u56db\uff084-\u5421\u5576\u57fa\uff09\u535f\u5549\uff08TPyP-H2<\/sub>\uff09\u914d\u4f53\u8fde\u63a5\u6709\u57fa\u4e8e\u53ccS2-\u6a21\u677f\u7684Ag27\u56e2\u7c07\u5f62\u6210\u76842D\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08Ag27-MOF\uff09\u6750\u6599\uff0c\u5e76\u5c06\u5176\u7528\u4f5c\u591a\u76f8\u50ac\u5316\u5242\u3002\u8fd9\u79cd\u94f6\u56e2\u7c07\u7ec4\u88c5\u6750\u6599\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u5f02\u76f8\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u5728\u5927\u6c14\u538b\u529b\u4e0b\u672b\u7aef\u548c\u5185\u90e8\u7094\u4e19\u57fa\u80fa\u73af\u5316\u4e0e\u50ac\u5316CO2<\/sub>\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0cAg27-MOF\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u8f83\u5bbd\u7684\u5e95\u7269\u8303\u56f4\uff0c\u8fd9\u662f\u7531\u4e8e\u5176\u5177\u6709\u978d\u72b6\u91d1\u5c5e\u8282\u70b9\uff0c\u5176\u7279\u70b9\u662f\u5177\u6709\u9ad8\u5bc6\u5ea6\u94f6\u539f\u5b50\u7684\u6613\u63a5\u8fd1\u5e73\u53f0\uff0c\u5177\u6709\u9ad8\u5bc6\u5ea6\u94f6\u539f\u5b50\u4f5c\u4e3a\u03c0-\u8def\u6613\u65af\u9178\u4f4d\u70b9\u7528\u4e8e\u6fc0\u6d3bC\u2261C\u4e09\u952e\u3002\u672c\u7814\u7a76\u4e0d\u4ec5\u4e3a\u57fa\u4e8e\u94f6\u7c07\u7684\u4e8c\u7ef4MOF\u6750\u6599\u7684\u7ec4\u88c5\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6848\uff0c\u800c\u4e14\u4e3a\u9ad8\u6548\u94f6\u7c07\u591a\u76f8\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u9014\u5f84\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAmbient Chemical Fixation of CO2<\/sub>\u00a0Using a Robust Ag27 ClusterBased Two-Dimensional Metal-Organic Framework\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/ange.202007122<\/p>\n \u56fe5\u00a0Ag27-MOF\u7684\u62d3\u6251\u7ed3\u6784\u53ca\u914d\u4f4d\u5f62\u5f0f<\/p>\n
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