{"id":206051,"date":"2020-08-05T12:00:28","date_gmt":"2020-08-05T04:00:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=206051"},"modified":"2020-08-05T11:45:17","modified_gmt":"2020-08-05T03:45:17","slug":"%e8%b0%a2%e6%af%85%e9%99%a2%e5%a3%ab%ef%bc%8c%e6%9d%8e%e4%ba%9a%e6%a0%8b%e9%99%a2%e5%a3%ab%ef%bc%8c%e6%9d%8e%e7%81%bf%e9%99%a2%e5%a3%ab%ef%bc%8c%e7%ad%89%e4%ba%ba%e8%bf%91%e6%9c%9f%e6%96%87%e7%8c%ae","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=206051","title":{"rendered":"\u8c22\u6bc5\u9662\u58eb\uff0c\u674e\u4e9a\u680b\u9662\u58eb\uff0c\u674e\u707f\u9662\u58eb\uff0c\u7b49\u4eba\u8fd1\u671f\u6587\u732e\u8ddf\u8e2a\uff1a8\u7bc7top\u671f\u520a\u770b\u8fd1\u65e5\u50ac\u5316\u9886\u57df\u7684\u53d1\u5c55"},"content":{"rendered":"
1. \u5f20\u91d1\u9f99\/\u6bb7\u4e9a\u4e1cChem\uff1aMoS<\/b><\/strong>2<\/b><\/sub><\/strong>\u7b49\u786b\u5316\u7269\u5171\u50ac\u5316\u63d0\u5347\u6c61\u67d3\u7269\u964d\u89e3\u6548\u7387<\/b><\/strong><\/p>\n \u91d1\u5c5e\u79bb\u5b50\u5982Fe2+<\/sup>\u548cCu2+<\/sup>\u66fe\u88ab\u7528\u6765\u63d0\u9ad8\u6c27\u5316\u8fc7\u7a0b\u4e2dH2<\/sub>O2<\/sub>\u7684\u5206\u89e3\u6548\u7387\u3002\u4f46\u662f\uff0c\u8fd9\u5e76\u4e0d\u80fd\u5c06\u6210\u672c\u964d\u4f4e\u5230\u53ef\u63a5\u53d7\u7684\u6c34\u5e73\uff0c\u56e0\u4e3a\u9700\u8981\u5927\u5242\u91cf\u7684H2<\/sub>O2<\/sub>\u00a0(30 – 6000 mmol\/L)\u548cFe2+<\/sup>\u00a0(18-410 mmol\/L)\u3002\u5927\u91cf\u7684Fe2+<\/sup>\u4e5f\u4f1a\u9020\u6210\u6c61\u6ce5\u7684\u5f62\u6210\u548c\u50ac\u5316\u5242\u4e2d\u6bd2\u3002\u9274\u4e8e\u6b64\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u5f20\u91d1\u9f99\u3001\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6cb3\u6ee8\u5206\u6821\u6bb7\u4e9a\u4e1c<\/b><\/strong>\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u786b\u5316\u7269\uff08MoS2<\/sub>, WS2<\/sub>, Cr2<\/sub>S3<\/sub>, CoS2<\/sub>, PbS, ZnS\uff09\u4f5c\u4e3a\u5171\u50ac\u5316\u5242\uff0c\u5728H2<\/sub>O2<\/sub>\u5206\u89e3\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u663e\u8457\u63d0\u9ad8\u4e86\u6548\u7387\uff0c\u660e\u663e\u964d\u4f4e\u4e86\u6c27\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u6240\u9700\u7684H2<\/sub>O2<\/sub>\u3001Fe2+<\/sup>\u91cf\u3002<\/p>\n Metal Sulfides as Excellent Co-catalysts for H2<\/sub>O2<\/sub>\u00a0Decomposition in Advanced Oxidation Processes, Chem,\u00a02020, DOI: 10.1016\/j.chempr.2018.03.002.<\/p>\n https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2451929418301153<\/u><\/a><\/p>\n 2. \u8c22\u6bc5\u9662\u58ebMatter\uff1a\u9ad8\u5bc6\u5ea6\u5e73\u9762\u72b6Fe2<\/sub>N6<\/sub>\u7ed3\u6784\u7528\u4e8e\u9ad8\u6548\u50ac\u5316\u6c27\u8fd8\u539f<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u4e2d\u79d1\u5927\u50a8\u65fa\u76db\u6559\u6388\uff0c\u5434\u957f\u5f81\u6559\u6388\uff0c\u8c22\u6bc5\u9662\u58eb<\/strong>\u62a5\u9053\u4e86\u5177\u6709\u5e73\u9762\u72b6\u7ed3\u6784\u7684Fe2<\/span><\/sub>N6<\/span><\/sub>\u6d3b\u6027\u4e2d\u5fc3\u7528\u4e8ePEMFCs\u7684\u9ad8\u6548\u6c27\u8fd8\u539f\u50ac\u5316\u5242\u3002<\/p>\n \u4eae\u70b9\uff1a<\/p>\n \u2460\u5e73\u9762Fe2<\/sub>N6<\/sub>\u7ed3\u6784\u4f18\u5316\u4e86\u6c27\u8fd8\u539f\u50ac\u5316\u673a\u7406<\/p>\n \u2461\u72ec\u7279\u7684\u6c27\u5316\u8fd8\u539f\u8f6c\u53d8\u89e6\u53d1\u4e86\u4f18\u5316\u7684\u6c27\u4e2d\u95f4\u5438\u9644\u548c\u5f3a\u5927\u7684O-O\u952e\u65ad\u88c2\u9a71\u52a8\u529b\uff0c\u5b9e\u73b0\u52a0\u901f\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u9ad8\u5ea6\u6291\u5236\u526f\u53cd\u5e94\u3002<\/p>\n \u2462\u529f\u7387\u5bc6\u5ea6\u9ad8\u8fbe845 mW cm-2<\/sup>\uff0c\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u7cfb\u7edf\u9886\u57df\u53d6\u5f97\u91cd\u5927\u7a81\u7834\u3002<\/p>\n High-Density Planar-like Fe2<\/span><\/sub>N6<\/span><\/sub> Structure Catalyzes Efficient Oxygen Reduction, Matter (2020), DOI\uff1a1016\/j.matt.2020.06.026<\/p>\n https:\/\/doi.org\/10.1016\/j.matt.2020.06.026<\/a><\/u><\/p>\n 3. \u5b8b\u793cAEM\u7efc\u8ff0\uff1a\u7ed3\u6784\u8c03\u63a7\u548c\u652f\u6491\u5076\u8054\u6548\u5e94<\/b><\/strong>\u7684<\/b><\/strong>\u5355\u539f\u5b50\u591a\u76f8\u50ac\u5316\u5242<\/b><\/strong><\/p>\n \u5355\u539f\u5b50\u50ac\u5316\u5242(SACs)\u96c6\u5747\u76f8\u50ac\u5316\u5242\u548c\u591a\u76f8\u50ac\u5316\u5242\u7684\u4f18\u70b9\u4e8e\u4e00\u8eab\uff0c\u8fd1\u5e74\u6765\u53d7\u5230\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u901a\u8fc7\u4e0d\u540c\u7684\u4e0d\u9971\u548c\u5316\u5b66\u4f4d\u70b9\u6216\u7a7a\u95f4\u9650\u5236\uff0c\u53ef\u4ee5\u5c06\u5355\u4e2a\u91d1\u5c5e\u539f\u5b50\u7a33\u5b9a\u5728\u8f7d\u4f53\u4e0a\uff0c\u4ee5\u8fbe\u5230\u539f\u5b50\u5229\u7528\u6548\u7387\u7684\u6700\u5927\u5316\u3002\u9664\u4e86\u51c6\u5907\u9ad8\u8d1f\u8f7d\u548c\u9ad8\u7eaf\u5ea6\u7684SACs\u7684\u7b56\u7565\uff0c\u8be5\u9886\u57df\u7684\u53e6\u4e00\u4e2a\u5173\u952e\u6311\u6218\u662f\u7cbe\u786e\u5730\u64cd\u7eb5\u50ac\u5316\u6d3b\u6027\u5355\u91d1\u5c5e\u4f4d\u70b9\u7684\u51e0\u4f55\u548c\u7535\u5b50\u7ed3\u6784\uff0c\u4ece\u800c\u4f7f\u50ac\u5316\u5242\u6bd4\u5176\u5757\u4f53\u7684\u540c\u7c7b\u7279\u6b8a\u53cd\u5e94\u3001\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u3002\u4e2d\u79d1\u5927\u5b8b\u793c\u6559\u6388<\/b><\/strong>\u4ece\u5c40\u90e8\u7ed3\u6784\u8c03\u63a7\u548c\u91d1\u5c5e\u4e0e\u8f7d\u4f53\u4e4b\u95f4\u7684\u534f\u540c\u8026\u5408\u4f5c\u7528\u7b49\u65b9\u9762\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u5728\u591a\u76f8\u50ac\u5316SACs\u7814\u7a76\u65b9\u9762\u7684\u8fdb\u5c55\u3002\u7279\u522b\u5f3a\u8c03\u4e86\u901a\u8fc7\u5148\u8fdb\u7684\u8868\u5f81\u548c\u7406\u8bba\u7814\u7a76\uff0c\u4ece\u914d\u4f4d\u73af\u5883\u3001\u4ef7\u6001\u548c\u91d1\u5c5e\u652f\u6301\u76f8\u4e92\u4f5c\u7528\u7b49\u65b9\u9762\u9610\u660e\u50ac\u5316\u7ed3\u6784\u4e0e\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u5f3a\u8c03\u4e86\u9009\u62e9\u539f\u4f4d\u6216operando\u8868\u5f81\u6280\u672f\uff0c\u4ee5\u8ddf\u8e2aSACs\u7684\u7ed3\u6784\u6f14\u53d8\u5728\u73b0\u5b9e\u6761\u4ef6\u4e0b\u7684\u91cd\u8981\u6027\u3002\u6700\u540e\uff0c\u8ba8\u8bba\u4e86SACs\u7684\u6311\u6218\u548c\u673a\u9047\uff0c\u4ee5\u63d0\u4f9b\u6d1e\u5bdf\u7406\u6027\u8bbe\u8ba1\u66f4\u6709\u8da3\u7684SACs\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u72ec\u7279\u7684\u5316\u5b66\u9009\u62e9\u6027\u3002<\/p>\n Structural Regulation and Support Coupling Effect of Single-Atom Catalysts for Heterogeneous Catalysis, Adv. Energy Mater. 2020, DOI: 10.1002\/aenm.202001482<\/p>\n https:\/\/doi.org\/10.1002\/aenm.202001482<\/u><\/a><\/p>\n 4. \u674e\u4e9a\u680bEES\uff1a\u4e3b\u65cf\u5355\u539f\u5b50Sb-N4\u6d3b\u6027\u4e2d\u5fc3\u9ad8\u6548\u50ac\u5316CO2RR\u5236\u7532\u9178\u76d0<\/b><\/strong><\/p>\n \u00a0 \u4e3b\u65cf\u5143\u7d20\u9511\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u7535\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u4fc3\u8fdbCO2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO2<\/span><\/sub>RR)\u751f\u6210\u7532\u9178\u76d0\uff0c\u7532\u9178\u76d0\u662f\u4e00\u79cd\u91cd\u8981\u7684\u50a8\u6c22\u6750\u6599\u548c\u8bb8\u591a\u5de5\u4e1a\u53cd\u5e94\u7684\u5173\u952e\u5316\u5b66\u4e2d\u95f4\u4f53\u3002\u8fd1\u65e5\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u9648\u6587\u661f\u526f\u7814\u7a76\u5458\uff0c\u5f20\u52a0\u6d9b\u6559\u6388\uff0c\u6e05\u534e\u5927\u5b66\u738b\u5b9a\u80dc\u526f\u6559\u6388\uff0c\u674e\u4e9a\u680b\u9662\u58eb<\/strong>\u62a5\u9053\u4e86\u4ee5\u6c2e\u63ba\u6742\u78b3\uff08NC\uff09\u7eb3\u7c73\u7247\u4e3a\u8f7d\u4f53\u7684Sb-N4<\/sub>\u5355\u5143\u7ec4\u6210\u7684Sb\u5355\u539f\u5b50\uff08SA\uff09\u6750\u6599\uff08Sb SAs\/NC\uff09\u53ef\u7528\u4e8e\u9ad8\u6548\u50ac\u5316CO2<\/span><\/sub>RR\u5408\u6210\u7532\u9178\u76d0\u3002Sb SAs\/NC\u5728- 0.8 V\u00a0vs. RHE\u7684\u5408\u6210\u7532\u9178\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a94.0%\u3002\u539f\u4f4dXAFS\u7814\u7a76\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0c\u4f18\u826f\u7684CO2<\/span><\/sub>RR\u6d3b\u6027\u6765\u81ea\u4e8e\u5e26\u6b63\u7535\u8377\u7684Sb\u03b4+<\/sup>-N4<\/sub> (0< \u03b4 < 3) \u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n Discovery of Main Group Single Sb-N4<\/sub> Active Sites for CO2<\/span><\/sub> Electroreduction to Formate with High Efficiency, Energy Environ. Sci., 2020, DOI: 10.1039\/D0EE01486A<\/p>\n https:\/\/doi.org\/10.1039\/D0EE01486A<\/a><\/u><\/p>\n 5. \u738b\u5fc3\u6668J Catal.\uff1a\u4f18\u5316\u5171\u8f6d\u805a\u5408\u7269\u5149\u50ac\u5316\u5242\u7684\u7ed3\u6676\u8fc7\u7a0b\uff0c\u4fc3\u8fdb\u7535\u5b50\u8f6c\u79fb\u548c\u5206\u5b50\u6c27\u6d3b\u5316<\/b><\/strong><\/p>\n \u5149\u50ac\u5316\u6d3b\u6027\u6c27(ROS)\u8bf1\u5bfc\u53cd\u5e94\u662f\u89e3\u51b3\u73af\u5883\u548c\u80fd\u6e90\u95ee\u9898\u7684\u4e00\u79cd\u5f88\u6709\u5438\u5f15\u529b\u7684\u65b9\u6cd5\uff0c\u800c\u76ee\u524d\u7684\u6c27\u5316\u53cd\u5e94\u7531\u4e8eO2<\/span><\/sub>\u7684\u6d3b\u5316\u8fc7\u7a0b\u4e0d\u53ef\u63a7\uff0c\u666e\u904d\u5b58\u5728\u6548\u7387\u4f4e\u3001\u9009\u62e9\u6027\u5dee\u7684\u95ee\u9898\u3002\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u738b\u5fc3\u6668\u6559\u6388\uff0cMasakazu Anpo\uff0c\u6210\u4f73\u4f73\u526f\u6559\u6388<\/strong>\u62a5\u9053\u4e86\u4ee5\u6c2e\u5316\u78b3\u805a\u5408\u7269\u4e3a\u4f8b\uff0c\u91c7\u7528\u7194\u76d0\u6cd5\u9009\u62e9\u4e0d\u540c\u805a\u5408\u5ea6\u7684\u524d\u9a71\u4f53\uff0c\u5bf9\u6c2e\u5316\u78b3\u805a\u5408\u7269\u7684\u7ed3\u6676\u8fc7\u7a0b\u8fdb\u884c\u4e86\u4f18\u5316\u3002\u5f97\u76ca\u4e8e\u9ad8\u7ed3\u6676\u5ea6\u3001\u6269\u5c55\u7684\u5171\u8f6d\u4f53\u7cfb\u548c\u5c42\u95f4\u5f3a\u8303\u5fb7\u534e\u76f8\u4e92\u4f5c\u7528\uff0c\u6539\u6027\u7684\u6c2e\u5316\u78b3\u805a\u5408\u7269\u5728\u53ef\u89c1\u5149\u4e0b\u8868\u73b0\u51fa\u7535\u8377\u4f20\u8f93\u52a0\u901f\u548c\u7535\u5b50\u8bf1\u5bfc\u5206\u5b50\u6c27\u6d3b\u5316\u53cd\u5e94\u589e\u5f3a\u3002<\/p>\n \u4eae\u70b9\uff1a<\/p>\n \u2460 \u4e3a\u4e86\u63d0\u9ad8\u6c2e\u5316\u78b3\u805a\u5408\u7269\u5149\u50ac\u5316\u5242\u7684\u5206\u5b50\u6c27\u6d3b\u5316\u6027\u80fd\uff0c\u5bf9\u5176\u7ed3\u6676\u8fc7\u7a0b\u8fdb\u884c\u4e86\u4f18\u5316\u3002<\/p>\n \u2461 \u540e\u7eed\u5b9e\u9a8c\u8bc1\u660e\uff0c\u8fdb\u4e00\u6b65\u6269\u5c55\u7684\u00a0\u03c0-\u5076\u8054\u4f53\u7cfb\u548c\u66f4\u7d27\u5bc6\u7684\u5c42\u95f4\u6808\u80fd\u663e\u8457\u63d0\u9ad8CCN\u7684\u5149\u50ac\u5316\u6027\u80fd\u548c\u8f7d\u6d41\u5b50\u8fc1\u79fb\u3002<\/p>\n \u2462 \u6700\u4f73\u7684CCN\u4f7f\u82ef\u787c\u9178\u7684\u8f6c\u5316\u7387\u8fbe\u523099%\u4ee5\u4e0a\uff0c\u5bf9Rh B\u5149\u964d\u89e3\u6d3b\u6027\u63d0\u9ad86\u500d\u3002<\/p>\n \u2463 \u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u8fd9\u4e24\u4e2a\u4ee3\u8868\u6027\u53cd\u5e94\u7684\u673a\u7406\uff0c\u4e86\u89e3\u4e86CCN\u5728\u50ac\u5316ROS\u8bf1\u5bfc\u53cd\u5e94\u4e2d\u7684\u4f18\u52bf\u3002<\/p>\n Optimizing the Crystallization Process of Conjugated Polymer Photocatalysts to Promote Electron Transfer and Molecular Oxygen Activation, Journal of Catalysis,\u00a02020, DOI: 10.1016\/j.jcat.2020.07.005<\/p>\n https:\/\/doi.org\/10.1016\/j.jcat.2020.07.005<\/u><\/a><\/p>\n 6. \u51af\u65b0\u4eaeEES\uff1a\u5de5\u7a0b\u5316\u8d28\u5b50\u4f9b\u7ed9\u4e2d\u5fc3\u4fc3\u8fdb\u6c2e\u63ba\u6742\u5c42\u72b6\u591a\u5b54\u78b3ORR<\/b><\/strong><\/p>\n \u7535\u50ac\u5316\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u662f\u4e0b\u4e00\u4ee3\u7535\u5316\u5b66\u80fd\u91cf\u50a8\u5b58\u548c\u8f6c\u6362\u6280\u672f\uff0c\u5982\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60\u7684\u5173\u952e\u8fc7\u7a0b\u3002ORR\u8fc7\u7a0b\u4e2d\uff0cO2<\/span><\/sub>*\u548cO*\u4e2d\u95f4\u4ea7\u7269\u4e3b\u8981\u4e0e\u8d28\u5b50\u7ed3\u5408\uff0c\u5206\u522b\u5f62\u6210OOH*\u548cOH*\u7269\u8d28\uff0c\u8fd9\u662f\u8d28\u5b50\u8026\u5408\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u4f46\u662f\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u8d28\u5b50\u672c\u8d28\u4e0a\u662f\u7531\u7f13\u6162\u7684\u6c34\u5206\u89e3\u8fc7\u7a0b\u4ea7\u751f\u7684\uff0c\u8fd9\u4e0d\u53ef\u907f\u514d\u5730\u9650\u5236\u4e86ORR\u52a8\u529b\u5b66\u3002\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u51af\u65b0\u4eae\u6559\u6388\uff0c\u897f\u5317\u5de5\u4e1a\u5927\u5b66Jian Zhang<\/b><\/strong>\u62a5\u9053\u4e86\u4ee5\u5747\u5300\u5206\u5e03\u7684\u8d85\u7ec6\u03b1-MoC\u7eb3\u7c73\u7c92\u5b50\uff08\u03b1-MoC\/NHPC\uff09\u4e3a\u6a21\u578b\u7535\u50ac\u5316\u5242\uff0c\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u6c2e\u63ba\u6742\u5c42\u72b6\u591a\u5b54\u78b3\u3002\u7406\u8bba\u7814\u7a76\u63ed\u793a\uff0c\u5728NHPC\u4e0a\u7684\u03b1-MoC\u53ef\u4ee5\u6709\u6548\u5730\u964d\u4f4e\u6c34\u89e3\u79bb\u8fc7\u7a0b\u4ea7\u751f\u8d28\u5b50\u7684\u80fd\u91cf\u52bf\u5792\uff0c\u6700\u7ec8\u4fc3\u8fdb\u8d28\u5b50\u8026\u5408ORR\u52a8\u529b\u5b66\u3002<\/p>\n Promoted oxygen reduction kinetics on nitrogen-doped hierarchically porous carbon by engineering proton-feeding centers, Energy & Environmental Science, 2020, DOI: 10.1039\/D0EE01613F.<\/p>\n<\/p>\n
<\/p>\n
<\/p>\n
<\/b><\/strong><\/p>\n
<\/p>\n
<\/p>\n