{"id":205683,"date":"2020-07-26T06:51:21","date_gmt":"2020-07-25T22:51:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=205683"},"modified":"2020-07-25T20:57:03","modified_gmt":"2020-07-25T12:57:03","slug":"%e4%b8%8d%e6%98%af%e4%ba%8c%e7%bb%b4%e6%9d%90%e6%96%99%ef%bc%8c%e4%b9%9f%e4%b8%8d%e6%98%af%e7%ba%b3%e7%b1%b3%e6%9d%90%e6%96%99%ef%bc%8c%e8%bf%99%e4%b8%aa%e5%8f%a4%e8%80%81%e7%9a%84%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=205683","title":{"rendered":"\u4e0d\u662f\u4e8c\u7ef4\u6750\u6599\uff0c\u4e5f\u4e0d\u662f\u7eb3\u7c73\u6750\u6599\uff0c\u8fd9\u4e2a\u53e4\u8001\u7684\u7814\u7a76\u9886\u57df\u4e0a\u534a\u5e74\u7adf\u7136\u53d1\u4e8617\u7bc7NS"},"content":{"rendered":"

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1.Science:\u94f1\u50ac\u5316\u7684\u9178\u8f85\u52a9\u809f\u7684\u4e0d\u5bf9\u79f0\u6c22\u5316\u4e3a\u7f9f\u80fa<\/p>\n

\"\"<\/p>\n

\u4e0d\u5bf9\u79f0\u6c22\u5316\u662f\u5728\u5de5\u4e1a\u89c4\u6a21\u4e0a\u5408\u6210\u624b\u6027\u6784\u4ef6\u7684\u6700\u5b9e\u7528\u65b9\u6cd5\u4e4b\u4e00\u3002 \u5c06\u809f\u9009\u62e9\u6027\u8fd8\u539f\u4e3a\u76f8\u5e94\u7684\u624b\u6027\u7f9f\u80fa\u884d\u751f\u7269\u4ecd\u7136\u662f\u4e00\u4e2a\u5177\u6709\u6311\u6218\u6027\u7684\u53d8\u4f53\uff0c\u56e0\u4e3a\u4e0d\u5e0c\u671b\u7684\u5f31\u6c2e-\u6c27\u952e\u88c2\u89e3\u3002<\/p>\n

\u745e\u58eb\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662\u7684<\/strong>Nicolai Cramer<\/strong>\u7814\u7a76\u4e86\u575a\u56fa\u7684\u73af\u91d1\u5c5e\u5316\u94f1\uff08III\uff09\u914d\u5408\u7269\uff0c\u5e26\u6709\u624b\u6027\u73af\u620a\u4e8c\u70ef\u57fa\u914d\u4f53\uff0c\u53ef\u4f5c\u4e3a\u5728\u9ad8\u9178\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\u8be5\u53cd\u5e94\u7684\u6709\u6548\u50ac\u5316\u5242\u3002 \u53ef\u4ee5\u5728\u5ba4\u6e29\u4e0b\u83b7\u5f97\u6709\u4ef7\u503c\u7684N-\u70f7\u6c27\u57fa\u80fa\uff0c\u4e14\u672a\u68c0\u6d4b\u5230N = O\u952e\u7684\u8fc7\u5ea6\u8fd8\u539f\u3002 \u89c2\u5bdf\u5230\u9ad8\u8fbe4000\u7684\u50ac\u5316\u5242\u5468\u8f6c\u7387\u548c\u9ad8\u8fbe98\uff1a2\u7684\u5bf9\u6620\u4f53\u6bd4\u7387\u3002\u8fd9\u4e9b\u53d1\u73b0\u662f\u5f00\u53d1\u5177\u6709\u6311\u6218\u6027\u7684\u5e95\u7269\u7684\u91d1\u5c5e\u50ac\u5316\u5bf9\u6620\u9009\u62e9\u6027\u6c22\u5316\u7684\u84dd\u56fe\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Iridium-catalyzed acid-assisted asymmetric hydrogenation of oximes to hydroxylamines.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.abb2559)<\/strong><\/p>\n

2.Nature:\u5185\u916f\u5316\u4f5c\u4e3a\u901a\u5411\u03b2-C(sp3<\/sup>)-H\u529f\u80fd\u5316\u7684\u4e00\u822c\u9014\u5f84<\/p>\n

\"\"<\/p>\n

\u8102\u80aa\u9178\u7684\u03b2-CH\u952e\u7684\u529f\u80fd\u5316\u6b63\u4f5c\u4e3a\u4e00\u79cd\u6709\u4ef7\u503c\u7684\u5408\u6210\u65ad\u5f00\u8fde\u63a5\u800c\u51fa\u73b0\uff0c\u5b83\u662f\u5bf9\u5404\u79cd\u5171\u8f6d\u52a0\u6210\u53cd\u5e94\u7684\u8865\u5145\u3002\u5c3d\u7ba1\u5728\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u6210\u952e\u53cd\u5e94\u4e2d\u52aa\u529b\u8fdb\u884c\u03b2-C-H\u5b98\u80fd\u5316\uff0c\u4f46\u5b83\u4eec\u4ecd\u5177\u6709\u8bb8\u591a\u5173\u952e\u7684\u5c40\u9650\u6027\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u5de5\u4e1a\u89c4\u6a21\u7684\u5e94\u7528\uff0c\u5305\u62ec\u7f3a\u4e4f\u5355\u9009\u62e9\u6027\uff0c\u4f7f\u7528\u6602\u8d35\u7684\u6c27\u5316\u5242\u548c\u8303\u56f4\u6709\u9650\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u4e9b\u53cd\u5e94\u4e2d\u7684\u5927\u591a\u6570\u4e0e\u6ca1\u6709\u5916\u6e90\u6307\u5bfc\u57fa\u56e2\u7684\u6e38\u79bb\u8102\u80aa\u9178\u4e0d\u76f8\u5bb9\u3002\u8003\u8651\u5230\u53d1\u5c55C\u2013H\u6d3b\u5316\u53cd\u5e94\u7684\u6311\u6218\uff0c\u5728\u6bcf\u79cd\u60c5\u51b5\u4e0b\u5b9e\u73b0\u4e0d\u540c\u7684\u8f6c\u5316\u90fd\u9700\u8981\u72ec\u7acb\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u548c\u76f4\u63a5\u7684\u57fa\u56e2\u4f18\u5316\u4e0d\u8db3\u4e3a\u5947\u3002<\/p>\n

\u7f8e\u56fd<\/strong>Scripps<\/strong>\u7814\u7a76\u6240\u7684\u4f59\u91d1\u6743<\/strong>\u62a5\u9053\u4e86P\u200b\u200bd\u50ac\u5316\u7684\u7531\u5355N\u4fdd\u62a4\u7684\u03b2-\u6c28\u57fa\u9178\u914d\u4f53\u5b9e\u73b0\u7684\u8102\u80aa\u9178\u7684\u03b2-C(sp3<\/sup>)-H\u5185\u916f\u5316\u3002\u9ad8\u5f20\u529b\u548c\u53cd\u5e94\u6027\u5f3a\u7684\u03b2-\u5185\u916f\u4ea7\u54c1\u662f\u591a\u529f\u80fd\u7684\u5173\u952e\uff0c\u53ef\u9009\u62e9\u6027\u5730\u5728\u6bcd\u4f53\u9178\u7684\u03b2\u4f4d\u7f6e\u5355\u4ef7\u5b89\u88c5\u5404\u79cd\u70f7\u57fa\uff0c\u70ef\u57fa\uff0c\u82b3\u57fa\uff0c\u7094\u57fa\uff0c\u6c1f\uff0c\u7f9f\u57fa\u548c\u6c28\u57fa\uff0c\u4ece\u800c\u63d0\u4f9b\u4e86\u901a\u5f80\u8bb8\u591a\u7fa7\u57fa\u7684\u9014\u5f84\u9178\u3002\u4f7f\u7528\u5ec9\u4ef7\u7684\u53d4\u4e01\u57fa\u8fc7\u6c27\u5316\u6c22\u4f5c\u4e3a\u6c27\u5316\u5242\u4ee5\u4fc3\u8fdb\u4ecePd\uff08iv\uff09\u4e2d\u5fc3\u8fdb\u884c\u6240\u9700\u7684\u9009\u62e9\u6027\u8fd8\u539f\u6d88\u9664\uff0c\u4ee5\u53ca\u65e0\u9700\u67f1\u8272\u8c31\u6cd5\u5373\u53ef\u7b80\u4fbf\u5730\u7eaf\u5316\u4ea7\u7269\uff0c\u4f7f\u5f97\u8be5\u53cd\u5e94\u9002\u4e8e\u5428\u7ea7\u751f\u4ea7\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Lactonization as a general route to \u03b2-C(sp3)\u2013H functionalization.<\/strong><\/p>\n

3.Science:\u901a\u8fc7\u65e0\u65b9\u5411\u7684\u787c\u5316\u5bf9\u5f3a\u70f7\u57faCH\u952e\u7684\u4e0d\u540c\u5b98\u80fd\u5316<\/p>\n

\"\"<\/p>\n

\u6709\u673a\u5206\u5b50\u4e2d\u5f3a\u800c\u5178\u578b\u7684\u60f0\u6027\u78b3\u6c22\u952e\uff08C\u2013H\uff09\u7684\u9009\u62e9\u6027\u529f\u80fd\u5316\u6b63\u5728\u6539\u53d8\u5408\u6210\u5316\u5b66\u3002\u4f46\u662f\uff0c\u5f88\u5c11\u6709\u521d\u7ea7C\u2013H\u952e\u7684\u65e0\u65b9\u5411\u6027\u5b98\u80fd\u5316\u800c\u6ca1\u6709\u6b21\u7ea7C\u2013H\u952e\u7684\u7ade\u4e89\u6027\u5b98\u80fd\u5316\u3002\u70f7\u57faC\u2013H\u952e\u7684\u787c\u9178\u916f\u5316\u4ee5\u524d\u66fe\u4ee5\u8fd9\u79cd\u9009\u62e9\u6027\u53d1\u751f\uff0c\u4f46\u7f13\u6162\u7684\u901f\u7387\u8981\u6c42\u5e95\u7269\u6210\u4e3a\u6eb6\u5242\u6216\u5927\u91cf\u8fc7\u91cf\u3002<\/p>\n

\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/strong>John Hartwig<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u75312-\u7532\u57fa\u83f2\u54af\u5549\u8fde\u63a5\u7684\u94f1\u50ac\u5316\u5242\uff0c\u5177\u6709\u4ee5\u5e95\u7269\u4e3a\u9650\u5236\u5242\u7684\u6d3b\u6027\uff0c\u53ef\u4ee5\u4f7f\u521d\u7ea7C\u2013H\u952e\u65e0\u89c4\u787c\u5316\uff0c\u5e76\u4e14\u5f53\u4e0d\u5b58\u5728\u6216\u5c01\u95ed\u521d\u7ea7C\u2013H\u952e\u65f6\uff0c\u53ef\u4ee5\u4f7f\u5f3a\u6b21\u7ea7C\u2013H\u787c\u5316\u3002\u6240\u4ea7\u751f\u7684\u78b3-\u787c\u952e\u7684\u53cd\u5e94\u8868\u660e\uff0c\u8fd9\u4e9b\u787c\u57fa\u5316\u4f5c\u7528\u5982\u4f55\u5bfc\u81f4\u5728\u4ee5\u524d\u65e0\u6cd5\u63a5\u8fd1\u7684\u6709\u673a\u5206\u5b50\u4f4d\u7f6e\u4e0a\u5b89\u88c5\u5927\u91cf\u7684\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Diverse functionalization of strong alkyl C\u2013H bonds by undirected borylation.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aba6146)<\/strong><\/p>\n

4.Nature:\u901a\u8fc7\u4f4d\u70b9\u9009\u62e9\u6027\u5dee\u5411\u5f02\u6784\u5316\u5408\u6210\u7a00\u6709\u7cd6\u5f02\u6784\u4f53<\/p>\n

\"\"<\/p>\n

\u805a\u7cd6\u5177\u6709\u591a\u79cd\u751f\u7406\u529f\u80fd\uff0c\u8303\u56f4\u4ece\u80fd\u91cf\u5b58\u50a8\u548c\u7ed3\u6784\u5b8c\u6574\u6027\u5230\u7ec6\u80de\u4fe1\u53f7\u4f20\u5bfc\u548c\u7ec6\u80de\u5185\u8fc7\u7a0b\u7684\u8c03\u8282\u3002\u5c3d\u7ba1\u751f\u7269\u91cf\u884d\u751f\u7684\u78b3\u6c34\u5316\u5408\u7269\uff08\u4f8b\u5982d-\u8461\u8404\u7cd6\uff0cd-\u6728\u7cd6\u548cd-\u534a\u4e73\u7cd6\uff09\u662f\u6309\u5546\u4e1a\u89c4\u6a21\u63d0\u53d6\u7684\uff0c\u5e76\u4e14\u53ef\u4f5c\u4e3a\u53ef\u518d\u751f\u7684\u5316\u5b66\u539f\u6599\u548c\u57fa\u7840\u6750\u6599\uff0c\u4f46\u4ecd\u6709\u6570\u767e\u79cd\u4e0d\u540c\u7684\u5355\u7cd6\uff0c\u901a\u5e38\u65e0\u6cd5\u4ece\u5176\u5929\u7136\u7269\u4e2d\u5206\u79bb\u51fa\u6765\u3002\u5fc5\u987b\u901a\u8fc7\u591a\u6b65\u5316\u5b66\u6216\u9176\u4fc3\u5408\u6210\u6765\u5236\u5907\u3002\u8fd9\u4e9b\u201c\u7a00\u6709\u201d\u7cd6\u5728\u5177\u6709\u751f\u7269\u6d3b\u6027\u7684\u5929\u7136\u4ea7\u54c1\u548c\u836f\u7269\uff08\u5305\u62ec\u6297\u75c5\u6bd2\u836f\uff0c\u6297\u83cc\u836f\uff0c\u6297\u764c\u836f\u548c\u5fc3\u810f\u836f\u7269\uff09\u4e2d\u5177\u6709\u7a81\u51fa\u7684\u5730\u4f4d\u3002<\/p>\n

\u9ebb\u7701\u7406\u5de5\u7684<\/strong>Alison E. Wendlandt<\/strong>\u901a\u8fc7\u4f4d\u70b9\u9009\u62e9\u6027\u5dee\u5411\u5f02\u6784\u5316\u53cd\u5e94\u76f4\u63a5\u4ece\u751f\u7269\u8d28\u78b3\u6c34\u5316\u5408\u7269\u5236\u5907\u7a00\u6709\u7cd6\u5f02\u6784\u4f53\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u4e9b\u53cd\u5e94\u662f\u5728\u52a8\u529b\u5b66\u63a7\u5236\u4e0b\u8fdb\u884c\u7684\uff0c\u662f\u901a\u8fc7\u4e24\u4e2a\u4e0d\u540c\u7684\u50ac\u5316\u5242\u4ecb\u5bfc\u7684\u6c22\u539f\u5b50\u63d0\u53d6\u548c\u6c22\u539f\u5b50\u6350\u8d60\u7684\u987a\u5e8f\u6b65\u9aa4\u8fdb\u884c\u7684\u3002\u8fd9\u79cd\u5408\u6210\u7b56\u7565\u4e3a\u6b64\u7c7b\u6709\u4ef7\u503c\u7684\u5929\u7136\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u7b80\u6d01\u4e14\u53ef\u80fd\u5e7f\u6cdb\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Synthesis of rare sugar isomers through site-selective epimerization.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-1937-1)<\/strong><\/p>\n

5.Nature:\u80fa-\u7fa7\u9178\u5076\u8054\u4f53\u7cfb<\/p>\n

\"\"<\/p>\n

\u5316\u5b66\u8f6c\u5316\u51b3\u5b9a\u4e86\u4ea7\u54c1\u7684\u7ed3\u6784\uff0c\u8fdb\u800c\u51b3\u5b9a\u4e86\u4ea7\u54c1\u7684\u6027\u80fd\uff0c\u8fdb\u800c\u5f71\u54cd\u4e86\u590d\u6742\u7684\u5b8f\u89c2\u529f\u80fd\uff0c\u4f8b\u5982\u836f\u7269\u7684\u4ee3\u8c22\u7a33\u5b9a\u6027\u6216\u9999\u6c34\u7684\u6325\u53d1\u6027\u3002\u56e0\u6b64\uff0c\u53cd\u5e94\u9009\u62e9\u53ef\u4ee5\u5f71\u54cd\u5019\u9009\u5206\u5b50\u6210\u529f\u6216\u5931\u8d25\u4ee5\u6ee1\u8db3\u529f\u80fd\u76ee\u6807\u3002\u80fa\u4e0e\u7fa7\u9178\u7684\u5076\u8054\u4ee5\u5f62\u6210\u9170\u80fa\u952e\u662f\u7528\u4e8e\u836f\u7269\u53d1\u73b0\u7684\u6700\u6d41\u884c\u7684\u5316\u5b66\u53cd\u5e94\u3002\u4f46\u662f\uff0c\u8fd8\u6709\u8bb8\u591a\u5176\u4ed6\u65b9\u6cd5\u53ef\u4ee5\u5c06\u8fd9\u4e24\u4e2a\u5e38\u7528\u529f\u80fd\u7ec4\u8fde\u63a5\u5728\u4e00\u8d77\u3002<\/p>\n

\u5bc6\u6b47\u6839\u5927\u5b66\u7684<\/strong>Tim Cernak<\/strong>\u901a\u8fc7\u8ba1\u7b97\u8868\u660e\u80fa\u548c\u9178\u53ef\u4ee5\u901a\u8fc7\u6570\u767e\u79cd\u5047\u8bbe\u7684\u4f46\u5408\u7406\u7684\u8f6c\u5316\u8fdb\u884c\u5076\u8054\uff0c\u5e76\u4e14\u901a\u8fc7\u5b9e\u9a8c\u8bc1\u660e\u4e86\u5341\u51e0\u79cd\u6b64\u7c7b\u53cd\u5e94\u7684\u5e94\u7528\u3002\u4e3a\u4e86\u7814\u7a76\u5316\u5b66\u8f6c\u5316\u5bf9\u7279\u6027\u7684\u8d21\u732e\uff0c\u4ed6\u4eec\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e\u5b57\u7b26\u4e32\u7684\u8868\u793a\u6cd5\uff0c\u5e76\u4f7f\u7528\u679a\u4e3e\u7ec4\u5408\u65b9\u6cd5\u751f\u6210\u4e86\u53ef\u4ee5\u60f3\u8c61\u7684\u80fa-\u9178\u5076\u8054\u8f6c\u5316\u56fe\uff0c\u53ef\u4ee5\u4f7f\u7528\u5316\u5b66\u4fe1\u606f\u6280\u672f\u7ed8\u5236\u56fe\u8868\u3002\u4f5c\u8005\u53d1\u73b0\uff0c\u53d6\u51b3\u4e8e\u9009\u62e9\u7684\u8f6c\u5316\uff0c\u4ea7\u7269\u7684\u5173\u952e\u7269\u7406\u5316\u5b66\u53c2\u6570\uff0c\u4f8b\u5982\u5206\u914d\u7cfb\u6570\u548c\u6781\u6027\u8868\u9762\u79ef\uff0c\u4f1a\u53d1\u751f\u5f88\u5927\u53d8\u5316\u3002\u6b64\u5904\u5f00\u53d1\u7684\u80fa-\u9178\u5076\u8054\u7cfb\u7edf\u7684\u6570\u636e\u6316\u6398\u5e94\u8be5\u80fd\u591f\u8fdb\u884c\u53cd\u5e94\u53d1\u73b0\uff0c\u4f5c\u8005\u901a\u8fc7\u5f00\u53d1\u5728\u6620\u5c04\u7a7a\u95f4\u5185\u53d1\u73b0\u7684\u916f\u5316\u53cd\u5e94\u6765\u8bc1\u660e\u8fd9\u4e00\u70b9\u3002\u5728\u80fa-\u9178\u5076\u8054\u4f53\u7cfb\u4e2d\u4e5f\u53ef\u4ee5\u53d1\u73b0\u5177\u6709\u4e0d\u540c\u6027\u8d28\u7684\u590d\u6742\u5206\u5b50\uff0c\u6b63\u5982\u4f5c\u8005\u901a\u8fc7\u836f\u7269\u548c\u5929\u7136\u4ea7\u7269\u7684\u540e\u671f\u5206\u6563\u6240\u663e\u793a\u7684\u90a3\u6837\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

A map of the amine\u2013carboxylic acid coupling system.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2142-y)<\/strong><\/p>\n

6.Nature:\u53cc\u5149\u9a71\u52a8\u94af\u50ac\u5316\u5242\u2014\u2014\u7a81\u7834\u7fb0\u57fa\u5316\u53cd\u5e94\u7684\u969c\u788d<\/p>\n

\"\"<\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u5df2\u6210\u4e3a\u73b0\u4ee3\u5408\u6210\u4e2d\u6700\u91cd\u8981\u7684\u5de5\u5177\u4e4b\u4e00\u3002\u4f46\u662f\uff0c\u8fd9\u4e9b\u53cd\u5e94\u7684\u56fa\u6709\u5c40\u9650\u6027\u662f\u9700\u8981\u5e73\u8861\u64cd\u4f5c\uff0c\u56e0\u4e3a\u6709\u5229\u4e8e\u901a\u8fc7\u6c27\u5316\u52a0\u6210\u88c2\u89e3\u952e\u7684\u56e0\u7d20\u6700\u7ec8\u4f1a\u901a\u8fc7\u8fd8\u539f\u6d88\u9664\u6765\u6291\u5236\u952e\u7684\u5f62\u6210\u3002<\/p>\n

\u9ea6\u5409\u5c14\u5927\u5b66\u7684<\/strong>Bruce A. Arndtsen<\/strong>\u63cf\u8ff0\u4e86\u4e00\u79cd\u66ff\u4ee3\u7b56\u7565\uff0c\u8be5\u7b56\u7565\u5229\u7528\u94af\u7684\u7b80\u5355\u53ef\u89c1\u5149\u6fc0\u53d1\u6765\u4ee5\u4f4e\u52bf\u5792\u9a71\u52a8\u6c27\u5316\u52a0\u6210\u548c\u8fd8\u539f\u6d88\u9664\u3002\u56e0\u6b64\uff0c\u94af\u50ac\u5316\u7684\u7fb0\u57fa\u5316\u53cd\u5e94\u53ef\u4ee5\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u4ee5\u5177\u6709\u6311\u6218\u6027\u7684\u82b3\u57fa\u6216\u70f7\u57fa\u5364\u5316\u7269\u548c\u56f0\u96be\u7684\u4eb2\u6838\u8bd5\u5242\u8fdb\u884c\uff0c\u5e76\u4ee5\u73b0\u5728\u901a\u7528\u7684\u65b9\u5f0f\u751f\u6210\u6709\u4ef7\u503c\u7684\u7fb0\u57fa\u884d\u751f\u7269\uff0c\u4f8b\u5982\u9170\u6c2f\uff0c\u916f\uff0c\u9170\u80fa\u6216\u916e\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u94af\uff080\uff09\u548c\u94af\uff08II\uff09\u4e2d\u95f4\u4f53\u7684\u540c\u65f6\u6fc0\u53d1\u662f\u9020\u6210\u8fd9\u79cd\u6d3b\u6027\u7684\u539f\u56e0\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

A dual light-driven palladium catalyst: Breaking the barriers in carbonylation reactions.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1126\/science.aba5901)<\/strong><\/p>\n

7.Nature:\u53d4\u80fa\u5408\u6210\u7684\u4e00\u822c\u7fb0\u57fa\u70f7\u57fa\u5316\u80fa\u5316\u53cd\u5e94<\/p>\n

\"\"<\/p>\n

\u53d4\u70f7\u57fa\u80fa\u5728\u836f\u7269\u548c\u519c\u7528\u5316\u5b66\u8bd5\u5242\uff0c\u5929\u7136\u4ea7\u7269\u548c\u5c0f\u5206\u5b50\u751f\u7269\u63a2\u9488\u4e2d\u7684\u666e\u904d\u5b58\u5728\u523a\u6fc0\u4e86\u5176\u7b80\u5316\u5408\u6210\u7684\u52aa\u529b\u3002\u53ef\u4ee5\u8bf4\uff0c\u6700\u6709\u6548\u7684\u53d4\u70f7\u57fa\u80fa\u5408\u6210\u65b9\u6cd5\u662f\u7fb0\u57fa\u8fd8\u539f\u80fa\u5316\uff0c\u5b83\u5305\u62ec\u4e24\u4e2a\u57fa\u672c\u6b65\u9aa4\uff1a\u4ef2\u70f7\u57fa\u80fa\u4e0e\u8102\u65cf\u919b\u7684\u7f29\u5408\u5f62\u6210\u5168\u70f7\u57fa\u4e9a\u80fa\u79bb\u5b50\uff0c\u968f\u540e\u88ab\u6c22\u5316\u7269\u8bd5\u5242\u8fd8\u539f\u3002\u901a\u8fc7\u70f7\u57fa\u7247\u6bb5\u4e0e\u539f\u4f4d\u751f\u6210\u7684\u70f7\u57fa\u4e9a\u80fa\u79bb\u5b50\u7684\u5076\u5408\uff0c\u5df2\u7ecf\u5bfb\u6c42\u4e86\u76f4\u63a5\u53cd\u5e94\u7b56\u7565\uff0c\u4ee5\u5b9e\u73b0\u8be5\u53cd\u5e94\u7684\u201c\u66f4\u9ad8\u9636\u201d\u53d8\u4f53\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u4ed8\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\uff0c\u4f46\u5c1a\u672a\u6210\u529f\u5b9e\u73b0\u201c\u7fb0\u57fa\u70f7\u57fa\u5316\u80fa\u5316\u201d\u3002<\/p>\n

\u5251\u6865\u5927\u5b66Matthew J. Gaunt\u4ecb\u7ecd\u4e86\u901a\u8fc7\u5c06\u70f7\u57fa\u57fa\u56e2\u52a0\u6210\u5168\u70f7\u57fa\u4e9a\u80fa\u79bb\u5b50\u6765\u5408\u6210\u53d4\u70f7\u57fa\u80fa\u7684\u5b9e\u7528\u65b9\u6cd5\u3002\u53ef\u89c1\u5149\u548c\u7845\u70f7\u8fd8\u539f\u5242\u4fc3\u8fdb\u4e86\u8be5\u8fc7\u7a0b\uff0c\u5b83\u4eec\u89e6\u53d1\u4e86\u72ec\u7279\u7684\u81ea\u7531\u57fa\u5f15\u53d1\u6b65\u9aa4\u4ee5\u5efa\u7acb\u94fe\u5f0f\u8fc7\u7a0b\u3002\u901a\u8fc7\u919b\u548c\u4ef2\u80fa\u4e0e\u70f7\u57fa\u5364\u7684\u5076\u5408\uff0c\u8fd9\u79cd\u64cd\u4f5c\u7b80\u5355\uff0c\u65e0\u91d1\u5c5e\u4e14\u6a21\u5757\u5316\u7684\u8f6c\u5316\u5f62\u6210\u53d4\u80fa\u800c\u65e0\u7ed3\u6784\u9650\u5236\u3002\u8fd9\u4e9b\u6613\u4e8e\u83b7\u5f97\u7684\u524d\u4f53\u7684\u7ed3\u6784\u548c\u529f\u80fd\u591a\u6837\u6027\u4e3a\u7b80\u5316\u7684\u590d\u6742\u53d4\u80fa\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u7075\u6d3b\u7684\u7075\u6d3b\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

A general carbonyl alkylative amination for tertiary amine synthesis.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2213-0)<\/strong><\/p>\n

8.Nature:\u540e\u671f\u6c27\u5316C(sp3<\/sup>)-H\u7532\u57fa\u5316<\/p>\n

\"\"<\/p>\n

\u901a\u5e38\u88ab\u79f0\u4e3a\u201c\u795e\u5947\u7684\u7532\u57fa\u6548\u5e94\u201d\uff0c\u7532\u57fa\u7684\u5b89\u88c5-\u7279\u522b\u662f\u6742\u539f\u5b50\uff08\u03b1\uff09\u7684\u90bb\u8fd1-\u5df2\u663e\u793a\u51fa\u53ef\u5927\u5927\u63d0\u9ad8\u751f\u7269\u6d3b\u6027\u5206\u5b50\u7684\u6548\u80fd\u3002\u4f46\u662f\uff0c\u73b0\u6709\u7684\u7532\u57fa\u5316\u65b9\u6cd5\u663e\u793a\u8303\u56f4\u6709\u9650\uff0c\u5e76\u4e14\u5c1a\u672a\u5728\u590d\u6742\u7684\u73af\u5883\u4e2d\u5f97\u5230\u8bc1\u660e\u3002<\/p>\n

\u4f0a\u5229\u8bfa\u4f0a\u9999\u69df\u5206\u6821\u7684<\/strong>M. Christina White<\/strong>\u62a5\u544a\u4e0e\u836f\u7269\u652f\u67b6\u548c\u5929\u7136\u4ea7\u7269\u7684\u540e\u671f\u529f\u80fd\u5316\u517c\u5bb9\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u5316\u5b66\u9009\u62e9\u6027\u6c27\u5316C(sp3<\/sup>)-H\u7532\u57fa\u5316\u65b9\u6cd5\u3002\u8fd9\u7ed3\u5408\u4e86\u9ad8\u4f4d\u70b9\u9009\u62e9\u6027\u548c\u5316\u5b66\u9009\u62e9\u6027\u7684C\u2013H\u7f9f\u57fa\u5316\u4ee5\u53ca\u6e29\u548c\u7684\uff0c\u5bf9\u529f\u80fd\u57fa\u56e2\u8010\u53d7\u7684\u7532\u57fa\u5316\u3002\u4f7f\u7528\u5c0f\u5206\u5b50\u9530\u50ac\u5316\u5242Mn(CF3<\/sub>PDP)\uff0c\u5728\u4f4e\u8d1f\u8f7d\uff08\u5e95\u7269\/\u50ac\u5316\u5242\u6bd4\u4e3a200\uff09\u4e0b\uff0c\u53ef\u5728\u6742\u73af\u6838\u4e0a\u9776\u5411C\u2013H\u7f9f\u57fa\u5316\uff0c\u540c\u65f6\u4fdd\u7559\u7535\u5b50\u4e2d\u6027\u548c\u5bcc\u7535\u5b50\u82b3\u57fa\u3002\u6c1f\u6216\u8def\u6613\u65af\u9178\u8f85\u52a9\u7684\u53cd\u5e94\u6027\u4e9a\u80fa\u6216\u6c27\u9393\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\u4f7f\u5f97\u80fd\u591f\u4f7f\u7528\u6e29\u548c\u7684\u4eb2\u6838\u6709\u673a\u94dd\u7532\u57fa\u5316\u8bd5\u5242\uff0c\u8be5\u8bd5\u5242\u4fdd\u7559\u4e86\u5e95\u7269\u4e0a\u7684\u5176\u4ed6\u4eb2\u7535\u5b50\u529f\u80fd\u3002\u4f5c\u8005\u572841\u4e2a\u5e95\u7269\u4e0a\u663e\u793a\u4e86\u8fd9\u79cd\u665a\u671fC(sp3<\/sup>)\u2013H\u7532\u57fa\u5316\uff0c\u8be5\u5e95\u7269\u5bb9\u7eb316\u4e2a\u4e0d\u540c\u7684\u533b\u5b66\u4e0a\u91cd\u8981\u7684\u6838\uff0c\u5305\u62ec\u5bcc\u7535\u5b50\u82b3\u57fa\uff0c\u6742\u73af\uff0c\u7fb0\u57fa\u548c\u80fa\u3002\u5177\u6709\u7ade\u4e89\u6027\u4f4d\u70b9\u768418\u4e2a\u4e0e\u836f\u7406\u76f8\u5173\u7684\u5206\u5b50-\u5305\u62ec\u836f\u7269\uff08\u4f8b\u5982tedizolid\uff09\u548c\u5929\u7136\u4ea7\u7269-\u5728\u6700\u5bcc\u7535\u5b50\uff0c\u4f4d\u963b\u6700\u5c11\u7684\u4f4d\u7f6e\u88ab\u9009\u62e9\u6027\u5730\u7532\u57fa\u5316\u3002\u4f5c\u8005\u901a\u8fc7\u836f\u7269\u6216\u5176\u665a\u671f\u524d\u4f53\u7684\u540e\u671f\u7532\u57fa\u5316\uff0c\u8bc1\u660e\u4e86\u4e24\u79cd\u795e\u5947\u7684\u7532\u57fa\u5e95\u7269\u7684\u5408\u6210-\u6838\u53d7\u4f53RORc\u7684\u53cd\u5411\u6fc0\u52a8\u5242\u548c\u9798\u6c28\u9187-1-\u78f7\u9178\u53d7\u4f531\u7684\u62ee\u6297\u5242\u3002\u4f5c\u8005\u8fd8\u663e\u793a\u4e86\u963f\u6bd4\u7279\u9f99\u7c7b\u4f3c\u7269\u7684B\u73af\u78b3\u73af\u7684\u8fdc\u7a0b\u7532\u57fa\u5316\u3002\u5728\u540e\u671f\u5c06\u8fd9\u79cd\u590d\u6742\u5206\u5b50\u7532\u57fa\u5316\u7684\u80fd\u529b\u5c06\u51cf\u5c11\u5408\u6210\u5de5\u4f5c\uff0c\u4ece\u800c\u52a0\u5feb\u5bf9\u795e\u5947\u7532\u57fa\u6548\u5e94\u7684\u66f4\u5e7f\u6cdb\u63a2\u7d22\uff0c\u4ee5\u5bfb\u6c42\u65b0\u7684\u5c0f\u5206\u5b50\u6cbb\u7597\u5242\u548c\u5316\u5b66\u63a2\u9488\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Late-stage oxidative C(sp3)\u2013H methylation.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2137-8)<\/strong><\/p>\n

9.Science:\u7531\u624b\u6027\u9633\u79bb\u5b50\u63a7\u5236\u7684\u5bf9\u6620\u9009\u62e9\u6027\u8fdc\u7a0bCH\u6d3b\u5316<\/p>\n

\"\"<\/p>\n

\u624b\u6027\u9633\u79bb\u5b50\u5df2\u88ab\u5e7f\u6cdb\u7528\u4f5c\u6709\u673a\u50ac\u5316\u5242\uff0c\u4f46\u5b83\u4eec\u5728\u4f7f\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u8fc7\u7a0b\u5177\u6709\u5bf9\u6620\u9009\u62e9\u6027\u65b9\u9762\u7684\u5e94\u7528\u4ecd\u7136\u5f88\u5c11\u3002\u5c3d\u7ba1\u6709\u7c7b\u4f3c\u7684\u7535\u8377\u8f6c\u5316\u7b56\u7565\u6210\u529f\u5b9e\u65bd\uff0c\u5176\u4e2d\u9633\u79bb\u5b50\u91d1\u5c5e\u7edc\u5408\u7269\u4e0e\u624b\u6027\u9634\u79bb\u5b50\u914d\u5bf9\u3002<\/p>\n

\u5251\u6865\u5927\u5b66\u7684Robert J. Phipps\u62a5\u9053\u4e00\u79cd\u7b56\u7565\uff0c\u4f7f\u4e00\u79cd\u5e38\u89c1\u7684\u8054\u5421\u5576\u914d\u4f53\u9634\u79bb\u5b50\u5316\uff0c\u5e76\u5c06\u5176\u94f1\u914d\u5408\u7269\u4e0e\u884d\u751f\u81ea\u594e\u5b81\u7684\u624b\u6027\u9633\u79bb\u5b50\u914d\u5bf9\u3002\u4f5c\u8005\u5df2\u7ecf\u901a\u8fc7\u5bf9\u6620\u9009\u62e9\u6027\u7684C\u2013H\u787c\u5316\u4f5c\u7528\u5c06\u8fd9\u4e9b\u79bb\u5b50\u5bf9\u914d\u5408\u7269\u5e94\u7528\u4e8e\u4f4d\u4e8e\u78b3\u6216\u78f7\u4e2d\u5fc3\u7684\u53cc\u8054\u4e8c\u82b3\u57fa\u57fa\u5e8f\u7684\u53bb\u5bf9\u79f0\u5316\u4e2d\u7684\u8fdc\u8ddd\u79bb\u4e0d\u5bf9\u79f0\u8bf1\u5bfc\u3002\u539f\u5219\u4e0a\uff0c\u8bb8\u591a\u5e38\u89c1\u7c7b\u522b\u7684\u914d\u4f53\u540c\u6837\u9002\u7528\u4e8e\u8fd9\u79cd\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Enantioselective remote C\u2013H activation directed by a chiral cation.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aba1120)<\/strong><\/p>\n

10.Nature:\u7531\u82ef\u5236\u5907\u73af\u5df1\u70ef\u5f02\u6784\u4f53\u548c\u7acb\u4f53\u5f02\u6784\u4f53<\/p>\n

\"\"<\/p>\n

\u6c22\u540c\u4f4d\u7d20\u6c18\uff08D\uff09\u548c\u6c1a\uff08T\uff09\u5df2\u6210\u4e3a\u5316\u5b66\uff0c\u751f\u7269\u5b66\u548c\u533b\u5b66\u4e2d\u5fc5\u4e0d\u53ef\u5c11\u7684\u5de5\u5177\u3002\u9664\u4e86\u5c06\u5b83\u4eec\u5e7f\u6cdb\u5730\u7528\u4e8e\u5149\u8c31\u5b66\uff0c\u8d28\u8c31\u5b66\u4ee5\u53ca\u673a\u7406\u548c\u836f\u4ee3\u52a8\u529b\u5b66\u7814\u7a76\u4e4b\u5916\uff0c\u4eba\u4eec\u8fd8\u5bf9\u5c06\u6c18\u63ba\u5165\u836f\u7269\u5206\u5b50\u4e2d\u4ea7\u751f\u4e86\u6d53\u539a\u7684\u5174\u8da3\u3002\u6c18\u82ef\u4e01\u55ea\u662f\u4e00\u79cd\u6c18\u5316\u836f\u7269\uff0c\u6709\u671b\u7528\u4e8e\u6cbb\u7597\u4ea8\u5ef7\u987f\u6c0f\u75c5\uff0c\u6700\u8fd1\u83b7\u5f97\u4e86\u7f8e\u56fd\u98df\u54c1\u548c\u836f\u7269\u7ba1\u7406\u5c40\u7684\u6279\u51c6\u3002\u6bd4\u8f83\u5316\u5408\u7269\u7684\u5316\u5b66\u53cd\u5e94\u901f\u7387\u548c\u6c18\u4ee3\u7684\u5316\u5b66\u53cd\u5e94\u901f\u7387\u7684\u6c18\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u53ef\u80fd\u5f88\u91cd\u8981\u3002\u7528\u6c18\u5bf9\u6c22\u7684\u6218\u7565\u66ff\u4ee3\u53ef\u4ee5\u5f71\u54cd\u5316\u5408\u7269\u7684\u4ee3\u8c22\u901f\u7387\u548c\u4ee3\u8c22\u4ea7\u7269\u7684\u5206\u5e03\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u836f\u7269\u7684\u529f\u6548\u548c\u5b89\u5168\u6027\u3002\u6c18\u4ee3\u5316\u5408\u7269\u7684\u836f\u4ee3\u52a8\u529b\u5b66\u53d6\u51b3\u4e8e\u6c18\u7684\u4f4d\u7f6e\u3002\u5c3d\u7ba1\u5728\u836f\u7269\u5408\u6210\u7684\u65e9\u671f\u548c\u665a\u671f\u5747\u53ef\u91c7\u7528\u63ba\u5165\u6c18\u7684\u65b9\u6cd5\uff0c\u4f46\u8fd9\u4e9b\u8fc7\u7a0b\u901a\u5e38\u662f\u975e\u9009\u62e9\u6027\u7684\uff0c\u7acb\u4f53\u540c\u4f4d\u7d20\u7eaf\u5ea6\u5f88\u96be\u6d4b\u91cf\u3002<\/p>\n

\u5f17\u5409\u5c3c\u4e9a\u5927\u5b66\u7684W. Dean Harman\u63cf\u8ff0\u4e86\u7528\u4e8e\u836f\u7269\u7814\u7a76\u7684\u7acb\u4f53\u9009\u62e9\u6027\u6c18\u4ee3\u6784\u5efa\u57fa\u5757\u7684\u5236\u5907\u3002\u4f5c\u4e3a\u6982\u5ff5\u7684\u8bc1\u660e\uff0c\u6211\u4eec\u8bc1\u660e\u4e86\u901a\u8fc7\u4e0e\u94a8\u914d\u5408\u7269\u7684\u7ed3\u5408\uff0c\u82ef\u4ee5\u56db\u6b65\u65b9\u5f0f\u8f6c\u5316\u4e3a\u5177\u6709\u4e0d\u540c\u6c18\u63ba\u5165\u5ea6\u7684\u73af\u5df1\u70ef\u3002\u4f7f\u7528\u6c18\u4ee3\u548c\u86cb\u767d\u5316\u7684\u9178\u548c\u6c22\u5316\u7269\u8bd5\u5242\u7684\u4e0d\u540c\u7ec4\u5408\uff0c\u53ef\u4ee5\u7cbe\u786e\u63a7\u5236\u73af\u5df1\u70ef\u73af\u4e0a\u7684\u6c18\u4ee3\u4f4d\u7f6e\u3002\u603b\u7684\u6765\u8bf4\uff0c\u53ef\u4ee5\u4ee5\u5341\u79cd\u4e0d\u540c\u7684\u540c\u4f4d\u7d20\u5f02\u6784\u4f53\u7684\u5f62\u5f0f\u83b7\u5f97\u72ec\u7279\u7684\u73af\u5df1\u70ef\u7acb\u4f53\u5f02\u6784\u4f53\u3002\u8be5\u6982\u5ff5\u53ef\u4ee5\u6269\u5c55\u4e3a\u5236\u5907\u529f\u80fd\u5316\u73af\u5df1\u70ef\u7684\u79bb\u6563\u7acb\u4f53\u5f02\u6784\u4f53\u3002\u8fd9\u79cd\u5236\u5907\u4f5c\u4e3a\u79bb\u6563\u7acb\u4f53\u5f02\u6784\u4f53\u7684\u836f\u7406\u6d3b\u6027\u5316\u5408\u7269\u7684\u7cfb\u7edf\u65b9\u6cd5\u53ef\u4ee5\u6539\u5584\u836f\u7269\u7684\u836f\u7406\u5b66\u548c\u6bd2\u7406\u5b66\u6027\u8d28\uff0c\u5e76\u63d0\u4f9b\u4e0e\u5176\u5728\u4f53\u5185\u7684\u5206\u5e03\u548c\u4ee3\u8c22\u6709\u5173\u7684\u673a\u7406\u4fe1\u606f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Preparation of cyclohexene isotopologues and stereoisotopomers from benzene.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2268-y)<\/strong><\/p>\n

11.Science:\u5916\u6d88\u65cb\u70f7\u57fa\u4eb2\u6838\u4f53\u548c\u4eb2\u7535\u4f53\u7684\u50ac\u5316\u5242\u63a7\u5236\u7684\u53cc\u5bf9\u6620\u4f53\u6536\u655b\u8026\u5408<\/p>\n

\"\"<\/p>\n

\u5728\u70f7\u57fa\u4eb2\u7535\u4f53\u548c\u70f7\u57fa\u4eb2\u6838\u4f53\u4e4b\u95f4\u7684\u78b3-\u78b3\u952e\u7684\u6784\u5efa\u4e2d\u7684\u7acb\u4f53\u5316\u5b66\u63a7\u5236\u662f\u6709\u673a\u5408\u6210\u4e2d\u7684\u6301\u7eed\u6311\u6218\u3002 \u901a\u8fc7SN1\u548cSN2\u9014\u5f84\u8fdb\u884c\u7684\u7ecf\u5178\u53d6\u4ee3\u53cd\u5e94\u4ea7\u751f\u78b3-\u78b3\u952e\u7684\u80fd\u529b\u53d7\u5230\u9650\u5236\uff08\u7531\u4e8e\u526f\u53cd\u5e94\uff0c\u5982\u91cd\u6392\u548c\u6d88\u9664\uff0c\u4f5c\u7528\u8303\u56f4\u4e0d\u5145\u5206\uff09\uff0c\u5e76\u4e14\u5728\u4ece\u6613\u4e8e\u83b7\u5f97\u7684\u5916\u6d88\u65cb\u539f\u6599\uff08\u5916\u6d88\u65cb\u4ea7\u7269\uff09\u5f00\u59cb\u65f6\u63a7\u5236\u7acb\u4f53\u5316\u5b66\u7684\u80fd\u529b\u53d7\u5230\u9650\u5236\u3002<\/p>\n

\u52a0\u5dde\u7406\u5de5\u7684<\/strong>Gregory C. Fu<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u624b\u6027\u954d\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u5c06\u5916\u6d88\u65cb\u4eb2\u7535\u4f53\uff08\u7094\u4e19\u57fa\u5364\u5316\u7269\uff09\u4e0e\u5916\u6d88\u65cb\u4eb2\u6838\u4f53\uff08\u03b2-\u950c\u9170\u80fa\uff09\u5076\u8054\uff0c\u5728\u53cc\u7acb\u4f53\u6536\u655b\u8fc7\u7a0b\u4e2d\u5f62\u6210\u78b3-\u78b3\u952e\uff0c\u4ece\u53cd\u5e94\u7269\u7684\u4e24\u79cd\u7acb\u4f53\u5316\u5b66\u6df7\u5408\u7269\u4e2d\u83b7\u5f97\u4e86\u5355\u4e00\u7684\u7acb\u4f53\u5f02\u6784\u4f53\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Catalyst-controlled doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aaz3855)<\/strong><\/p>\n

12.Science:\u94cb\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u6c1f\u5316\u82b3\u57fa\u787c\u9178\u916f<\/p>\n

\"\"<\/p>\n

\u94cb\u50ac\u5316\u4f20\u7edf\u4e0a\u4f9d\u8d56\u4e8e\u5904\u4e8e\u56fa\u5b9a\u6c27\u5316\u6001\u7684\u5143\u7d20\u7684\u8def\u6613\u65af\u9178\u6027\u3002\u5fb7\u56fd\u9a6c\u666e\u6240\u7684<\/strong>Josep Cornella<\/strong>\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u94cb\u7edc\u5408\u7269\uff0c\u5b83\u4eec\u53ef\u4ee5\u4ee5\u7c7b\u4f3c\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u7684\u65b9\u5f0f\u7ecf\u5386\u6c27\u5316\u52a0\u6210\uff0c\u8fd8\u539f\u6d88\u9664\u548c\u91d1\u5c5e\u8f6c\u79fb\u3002\u5408\u7406\u7684\u914d\u4f53\u4f18\u5316\uff08\u5177\u6709\u4e9a\u781c\u4e9a\u80fa\u90e8\u5206\uff09\u4ea7\u751f\u4e86\u4e00\u79cd\u901a\u8fc7\u94cb\uff08III\uff09\/\u94cb\uff08V\uff09\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u6c1f\u5316\u82b3\u57fa\u787c\u9178\u916f\u7684\u6d3b\u6027\u50ac\u5316\u5242\u3002\u6240\u6d89\u53ca\u7684\u4e0d\u540c\u94cb\u7269\u79cd\u7684\u6676\u4f53\u5b66\u8868\u5f81\uff0c\u4ee5\u53ca\u5bf9\u78b3-\u6c1f\u952e\u5f62\u6210\u4e8b\u4ef6\u7684\u673a\u7406\u7814\u7a76\uff0c\u786e\u5b9a\u4e86\u7ed3\u5408\u8d77\u6765\u4ee5\u5b9e\u73b0\u5b8c\u6574\u50ac\u5316\u5faa\u73af\u7684\u5173\u952e\u7279\u5f81\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Fluorination of arylboronic esters enabled by bismuth redox catalysis.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aaz2258)<\/strong><\/p>\n

13.Nature:\u81ea\u52a8\u5f84\u5411\u5408\u6210\u6709\u673a\u5206\u5b50<\/p>\n

\"\"<\/p>\n

\u81ea\u52a8\u5316\u5408\u6210\u5e73\u53f0\u901a\u8fc7\u6d88\u9664\u6709\u673a\u5408\u6210\u7684\u7269\u7406\u969c\u788d\u6765\u52a0\u901f\u548c\u7b80\u5316\u5206\u5b50\u7684\u5236\u5907\u3002\u901a\u8fc7\u53ef\u91cd\u73b0\u548c\u76f4\u63a5\u53ef\u6bd4\u7684\u5316\u5b66\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u4e0d\u53d7\u9650\u5236\u5730\u83b7\u53d6\u751f\u7269\u805a\u5408\u7269\u548c\u5c0f\u5206\u5b50\u3002\u5f53\u524d\u7684\u81ea\u52a8\u5316\u591a\u6b65\u5408\u6210\u4f9d\u8d56\u4e8e\u8fed\u4ee3\u6216\u7ebf\u6027\u8fc7\u7a0b\uff0c\u5e76\u4e14\u5728\u591a\u529f\u80fd\u6027\u548c\u8bbe\u5907\u4f7f\u7528\u65b9\u9762\u9700\u8981\u6298\u8877\u3002<\/p>\n

\u5fb7\u56fd\u9a6c\u666e\u6240\u7684<\/strong>Kerry Gilmore<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u4e00\u7cfb\u5217\u8fde\u7eed\u6d41\u6a21\u5757\u7684\u5c0f\u5206\u5b50\u81ea\u52a8\u5408\u6210\u65b9\u6cd5\uff0c\u8fd9\u4e9b\u6a21\u5757\u5728\u4e2d\u592e\u4ea4\u6362\u7ad9\u5468\u56f4\u5448\u653e\u5c04\u72b6\u6392\u5217\u3002\u4f7f\u7528\u8fd9\u79cd\u65b9\u6cd5\uff0c\u53ef\u4ee5\u5c06\u7b80\u6d01\u7684\u4f53\u79ef\u66b4\u9732\u4e8e\u6240\u9700\u8f6c\u5316\u6240\u9700\u7684\u4efb\u4f55\u53cd\u5e94\u6761\u4ef6\u4e0b\u3002\u53ef\u4ee5\u5c06\u987a\u5e8f\uff0c\u975e\u540c\u65f6\u7684\u53cd\u5e94\u8fdb\u884c\u7ec4\u5408\u4ee5\u6267\u884c\u591a\u6b65\u8fc7\u7a0b\uff0c\u4ece\u800c\u53ef\u4ee5\u4f7f\u7528\u53ef\u53d8\u7684\u6d41\u91cf\uff0c\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u91cd\u590d\u4f7f\u7528\u53cd\u5e94\u5668\u4ee5\u53ca\u4e2d\u95f4\u4f53\u7684\u5b58\u50a8\u3002\u8fd9\u79cd\u5168\u81ea\u52a8\u4eea\u5668\u80fd\u591f\u8fdb\u884c\u7ebf\u6027\u548c\u6536\u655b\u5408\u6210\uff0c\u5e76\u4e14\u4e0d\u9700\u8981\u5728\u4e0d\u540c\u8fc7\u7a0b\u4e4b\u95f4\u8fdb\u884c\u4eba\u5de5\u914d\u7f6e\u3002\u901a\u8fc7\u6267\u884c\u76ee\u6807\u7684\u4f18\u5316\u548c\u591a\u6b65\u5408\u6210\uff0c\u901a\u8fc7\u5728\u7ebf\u7a00\u91ca\u6539\u53d8\u6d53\u5ea6\uff0c\u63a2\u7d22\u6297\u60ca\u53a5\u836frufnamide\u7684\u591a\u6b65\u5408\u6210\u7684\u51e0\u79cd\u7b56\u7565\uff0c\u5408\u6210\u4e24\u79cd\u884d\u751f\u5e93\u768418\u79cd\u5316\u5408\u7269\uff08\u901a\u8fc7\u4e0d\u540c\u7684\u53cd\u5e94\u9014\u5f84\u5236\u5907\uff09\u6765\u8bc1\u660e\u8fd9\u79cd\u65b9\u6cd5\u7684\u529f\u80fd\u3002\u5e76\u4f7f\u7528\u76f8\u540c\u7684\u8bd5\u5242\u5728\u5149\u5316\u5b66\u6a21\u5757\u4e2d\u8fdb\u884c\u91d1\u5c5e\u6c27\u8fd8\u539f\u6c27\u5316\u78b3-\u6c2e\u4ea4\u53c9\u5076\u8054\uff0c\u800c\u65e0\u9700\u91cd\u65b0\u914d\u7f6e\u4eea\u5668\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Automated radial synthesis of organic molecules.<\/strong><\/p>\n

(Nature, 2020, DOI: 10.1038\/s41586-020-2083-5)<\/strong><\/p>\n

14.Science:\u5168\u5408\u6210\u63ed\u793a\u4e86\u5c0f\u5206\u5b50\u5929\u7136\u4ea7\u7269\u8272\u6c28\u9178A\u4e2d\u7684\u975e\u5178\u578b\u6027\u5f02\u6784\u73b0\u8c61<\/p>\n

\"\"<\/p>\n

\u5206\u5b50\u5f62\u72b6\u5b9a\u4e49\u4e86\u751f\u7269\u5b66\u548c\u6750\u6599\u73af\u5883\u4e2d\u7684\u529f\u80fd\uff0c\u56e0\u6b64\uff0c\u5316\u5b66\u5bb6\u5df2\u7ecf\u5f00\u53d1\u51fa\u8d8a\u6765\u8d8a\u591a\u7684\u63cf\u8ff0\u6027\u767d\u8bdd\u8bed\u6765\u63cf\u8ff0\u8fd9\u4e9b\u5f62\u72b6\u3002\u975e\u89c4\u8303\u7684\u963b\u8f6c\u5f02\u6784\u4f53\uff0c\u5373\u5f62\u5f0f\u4e0a\u5fae\u4e0d\u8db3\u9053\u4f46\u53ea\u80fd\u901a\u8fc7\u590d\u6742\u7684\uff0c\u975e\u7269\u7406\u7684\u591a\u952e\u626d\u8f6c\u4e92\u53d8\u7684\u5f62\u72b6\u5b9a\u4e49\u7684\u5206\u5b50\uff0c\u5f62\u6210\u4e86\u72ec\u7279\u7684\u963b\u8f6c\u5f02\u6784\u4f53\u5b50\u96c6\uff0c\u4e0d\u540c\u4e8e\u89c4\u8303\u7684\u963b\u8f6c\u5f02\u6784\u4f53\uff08\u4f8b\u5982\uff0c\u53cc\u8418\u57fa\uff09\u548c\u62d3\u6251\u5f02\u6784\u4f53\uff08\u5373\u5177\u6709\u76f8\u540c\u8fde\u901a\u6027\u4f46\u5206\u5b50\u56fe\u4e0d\u540c\u7684\u5206\u5b50\uff09\u3002\u4e0e\u751f\u7269\u5927\u5206\u5b50\u76f8\u53cd\uff0c\u5c0f\u5206\u5b50\u4e0d\u4f1a\u8868\u73b0\u51fa\u8fd9\u79cd\u6a21\u68f1\u4e24\u53ef\u7684\u5f62\u72b6\u3002\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u54c8\u4f5b\u5927\u5b66\u7684<\/strong>Jon Clardy<\/strong>\u548c<\/strong>Scripps<\/strong>\u7814\u7a76\u6240\u7684<\/strong>Phil S. Baran<\/strong>\u901a\u8fc7\u5168\u5408\u6210\u63d0\u51fa\u4e86\u80bd\u7c7b\u751f\u7269\u78b1\u8272\u6c28\u9178\u7ea2\u86cb\u767dA\u53ef\u4ee5\u662f\u4e24\u79cd\u975e\u7ecf\u5178\u963b\u8f6c\u5f02\u6784\u4f53\u4e4b\u4e00\u7684\u53d1\u73b0\u3002\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5408\u6210\u7b56\u7565\uff0c\u8be5\u7b56\u7565\u53ef\u9a71\u52a8\u975e\u89c4\u8303\u6027\u7684Atrop\u5b9a\u4e49\u7684\u5c0f\u5206\u5b50\u7684\u7b2c\u4e00\u4e2a\u4f4d\u963b\u5f02\u6784\u5408\u6210\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Total synthesis reveals atypical atropisomerism in a small-molecule natural product, tryptorubin A.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aay9981)<\/strong><\/p>\n

15.Science:\u7532\u70f7\u4f5c\u4e3a\u9170\u80fa\u548c\u8148\u7684\u65bd\u5bc6\u7279\u578b\u5f62\u6210\u4e2d\u7684\u6c2e\u4f9b\u4f53\u00a0\"\"<\/p>\n

\u81ea1923\u5e74\u53d1\u73b0\u4ee5\u6765\uff0c\u65bd\u5bc6\u7279\uff08Schmidt\uff09\u53cd\u5e94\u4e00\u76f4\u662f\u5408\u6210\u9170\u80fa\u548c\u8148\u7684\u4e00\u79cd\u6709\u6548\u4e14\u5e7f\u6cdb\u4f7f\u7528\u7684\u65b9\u6cd5\u3002\u4f46\u662f\uff0c\u5176\u5e94\u7528\u5e38\u5e38\u9700\u8981\u4f7f\u7528\u6325\u53d1\u6027\uff0c\u6f5c\u5728\u7206\u70b8\u6027\u548c\u9ad8\u6bd2\u6027\u7684\u53e0\u6c2e\u5316\u7269\u8bd5\u5242\u3002\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u5317\u4eac\u5927\u5b66\u7126\u5b81\u6559\u6388<\/strong>\u62a5\u9053\u4e86\u4e00\u4e2a\u5e8f\u5217\uff0c\u5176\u4e2d\u4e09\u6c1f\u7532\u9178\u9150\uff0c\u7532\u9178\u548c\u4e59\u9178\u6fc0\u6d3b\u4e86\u5927\u91cf\u7684\u5316\u5b66\u785d\u57fa\u7532\u70f7\uff0c\u5728\u65bd\u5bc6\u7279\u5f0f\u53cd\u5e94\u4e2d\u4ee3\u66ff\u4e86\u53e0\u6c2e\u5316\u7269\uff0c\u5145\u5f53\u4e86\u6c2e\u7684\u4f9b\u4f53\u3002\u8be5\u65b9\u6848\u8fdb\u4e00\u6b65\u6269\u5927\u4e86\u5e95\u7269\u7684\u8303\u56f4\uff0c\u4ee5\u7528\u4e8e\u5236\u5907\u9170\u80fa\u548c\u8148\u7684\u7094\u70c3\u548c\u7b80\u5355\u7684\u70f7\u57fa\u82ef\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Nitromethane as a nitrogen donor in Schmidt-type formation of amides and nitriles.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aay9501)<\/strong><\/p>\n

16.Science:\u7d2b\u6749\u70f7\u4e8c\u841c\u590d\u5408\u7269canataxpropellane\u7684\u5168\u5408\u6210<\/p>\n

\"\"<\/p>\n

Canataxpropellane\u5c5e\u4e8e\u533b\u5b66\u4e0a\u91cd\u8981\u7684\u7d2b\u6749\u70f7\u4e8c\u841c\u5bb6\u65cf\u3002\u6700\u8457\u540d\u7684\u540c\u6e90\u7269\uff0c\u7d2b\u6749\u915a\uff0c\u662f\u5f53\u4eca\u4e34\u5e8a\u4e0a\u6700\u5e38\u7528\u7684\u6297\u764c\u836f\u4e4b\u4e00\u3002Canataxpropellane\u7684\u7d2b\u6749\u70f7\u9aa8\u67b6\u5e26\u6709\u4e09\u4e2a\u989d\u5916\u7684\u73af-C\u952e\uff0c\u4ece\u800c\u5f62\u6210\u603b\u5171\u516d\u4e2a\u8fde\u7eed\u7684\u5b63\u78b3\uff0c\u5176\u4e2d\u56db\u4e2a\u4f4d\u4e8e\u73af\u4e01\u70f7\u73af\u4e0a\u3002 \u4e0d\u5e78\u7684\u662f\uff0c\u4ece\u81ea\u7136\u6765\u6e90\u4e2d\u5206\u79bb\u51fa\u5361\u90a3\u666e\u4e19\u70f7\u662f\u65e0\u6548\u7684\u3002<\/p>\n

\u5eb7\u65af\u5766\u8328\u5927\u5b66\u7684<\/strong>Tanja Gaich<\/strong>\u62a5\u9053\u4e86\uff08-\uff09-Canataxpropellane\u7684\u5168\u5408\u6210\u8fc7\u7a0b\uff0c\u5171\u520626\u6b65\u8fdb\u884c\uff0c\u4ece\u5df2\u77e5\u4e2d\u95f4\u4f53\uff08\u5bf9\u5e94\u4e8e\u5546\u4e1a\u539f\u6599\u768429\u6b65\uff09\u7684\u603b\u6536\u7387\u4e3a0.5\uff05\u3002 \uff08\u2013\uff09-canataxpropellane\uff082\uff09\u7684\u6838\u5fc3\u7ed3\u6784\u4f7f\u7528Diels-Alder\/\u90bb\u94fe\u70ef\u70c3-\u82b3\u70c3\u5149\u73af\u52a0\u6210\u5e8f\u5217\u5206\u4e24\u6b65\u7ec4\u88c5\u3002\u901a\u8fc7\u8bbe\u8ba1\u624b\u6027\u7845\u6c27\u70f7\u4f5c\u4e3aDiels-Alder\u53cd\u5e94\u7684\u52a9\u5242\u6765\u5f15\u5165\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Total synthesis of the complex taxane diterpene canataxpropellane.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aay9173)<\/strong><\/p>\n

17.Science\uff1a\u9ad8\u6d3b\u6027\u9633\u79bb\u5b50\u94b4\uff08II\uff09\u52a0\u6c22\u7532\u9170\u5316\u50ac\u5316\u5242<\/p>\n

\"\"<\/p>\n

\u94b4\u914d\u5408\u7269Hco(CO)4<\/sub>\u548cHco(CO)3<\/sub>(PR3<\/sub>)\u662f\u7528\u4e8e\u4e0e\u6c22\u548c\u4e00\u6c27\u5316\u78b3\u53cd\u5e94\u751f\u6210\u919b\u7684\u70ef\u70c3\u52a0\u6c22\u7532\u9170\u5316\u53cd\u5e94\u7684\u539f\u59cb\u5de5\u4e1a\u50ac\u5316\u5242\u3002\u8f83\u65b0\u7684\u548c\u6602\u8d35\u7684\u94d1\u81a6\u50ac\u5316\u5242\u7684\u6d3b\u6027\u9ad8\u6570\u767e\u500d\uff0c\u5e76\u4e14\u5728\u76f8\u5f53\u4f4e\u7684\u538b\u529b\u4e0b\u8fd0\u884c\u3002\u8def\u6613\u65af\u5b89\u90a3\u5dde\u7acb\u5927\u5b66\u7684<\/strong>George G. Stanley<\/strong>\u62a5\u9053\u4e86\u6bd4\u4f20\u7edf\u4e2d\u6027\u94b4\uff08I\uff09\u50ac\u5316\u5242\u6d3b\u6027\u9ad8\u5f97\u591a\u4e14\u6d3b\u6027\u63a5\u8fd1\u94d1\u50ac\u5316\u5242\u7684\u9633\u79bb\u5b50\u94b4\uff08II\uff09\u53cc\u81a6\u6c22\u5316\u7fb0\u57fa\u50ac\u5316\u5242\u3002\u8fd9\u4e9b\u50ac\u5316\u5242\u5bf9\u7b80\u5355\u7684\u76f4\u94fe\u70ef\u70c3\u5177\u6709\u4f4e\u7684\u76f4\u94fe\u81f3\u652f\u94fe\uff08L\uff1aB\uff09\u533a\u57df\u9009\u62e9\u6027\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u53cc\u81a6\u914d\u4f53\u7684\u9ad8\u70ef\u70c3\u5f02\u6784\u5316\u6d3b\u6027\u548c\u589e\u52a0\u7684\u7a7a\u95f4\u6548\u5e94\uff0c\u5b83\u4eec\u5bf9\u5177\u6709\u70f7\u57fa\u652f\u94fe\u7684\u5185\u90e8\u70ef\u70c3\u5177\u6709\u5f88\u9ad8\u7684L\uff1aB\u9009\u62e9\u6027\u3002\u8fd9\u4e9b\u50ac\u5316\u5242\u663e\u793a\u51fa\u957f\u5bff\u547d\u548c\u5bf9\u964d\u89e3\u53cd\u5e94\u7684\u62b5\u6297\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong><\/p>\n

Highly active cationic cobalt(II) hydroformylation catalysts.<\/strong><\/p>\n

(Science, 2020, DOI: 10.1126\/science.aaw7742)<\/strong><\/p>\n

\u672c\u6587\u7531tt\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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