{"id":205655,"date":"2020-07-20T06:45:43","date_gmt":"2020-07-19T22:45:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=205655"},"modified":"2020-07-19T20:46:04","modified_gmt":"2020-07-19T12:46:04","slug":"%e8%b7%9f%e7%9d%80%e9%a1%b6%e5%88%8a%e5%ad%a6%e6%b5%8b%e8%af%95%ef%bd%9c%e9%a9%ac%e9%87%8c%e5%85%b0%e5%a4%a7%e5%ad%a6afm%e4%b8%89%e7%bb%b4%e8%81%9a%e7%84%a6%e7%a6%bb%e5%ad%90%e6%9d%9f%ef%bc%883d-fib","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=205655","title":{"rendered":"\u8ddf\u7740\u9876\u520a\u5b66\u6d4b\u8bd5\uff5c\u9a6c\u91cc\u5170\u5927\u5b66AFM:\u4e09\u7ef4\u805a\u7126\u79bb\u5b50\u675f\uff083D 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-205656 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/1-11.png\" alt=\"\" width=\"600\" height=\"234\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/1-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/1-11-300x117.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8fd1\u65e5\uff0c\u9a6c\u91cc\u5170\u5927\u5b66Eric Wachsman\u6559\u6388\u56e2\u961f\u4ee5\u201cThe Effects of Constriction Factor and Geometric Tortuosity on Li-Ion Transport in Porous Solid-State Li-Ion Electrolytes\u201d\u4e3a\u9898\u5728Advanced Functional Materials\u671f\u520a\u4e0a\u53d1\u8868\u91cd\u8981\u7814\u7a76\u6210\u679c\u3002\u8be5\u56e2\u961f\u91c7\u7528\u4e09\u7ef4\u805a\u7126\u79bb\u5b50\u675f\u5c42\u6790\u6210\u50cf\u6280\u672f\u5206\u6790\u4e86\u4e0d\u540c\u5b54\u9699\u7387\u7684Li<sub>6.75<\/sub>La<sub>2.75<\/sub>Ca<sub>0.25<\/sub>Zr<sub>1.5<\/sub>Nb<sub>0.5<\/sub>O<sub>12<\/sub>\uff08LLCZN\uff09\u77f3\u69b4\u77f3\u591a\u5b54\u7535\u89e3\u8d28\u7684\u5fae\u89c2\u7ed3\u6784\uff0c\u5e76\u6839\u636eLLCZN\u7684\u4f53\u79ef\u5206\u6570\u3001\u6536\u7f29\u56e0\u5b50\u3001\u51e0\u4f55\u626d\u66f2\u5ea6\u548c\u6e17\u900f\u7cfb\u6570\u7b49\u8ba1\u7b97\u4e86\u7535\u89e3\u8d28\u7684\u7406\u8bba\u6709\u6548\u672c\u5f81\u7535\u5bfc\u7387\u3002<\/p>\n<p>\u591a\u5b54\u7684LLCZN\u6837\u54c1\u88abAllied EpoxyBond 110\u578b\u7c98\u7ed3\u5242\u6d78\u6da6\uff0c\u5e76\u572870 \u2103\u4e0b\u56fa\u5316\uff0c\u5f97\u5230\u73af\u6c27\u6811\u8102\u586b\u5145\u7684\u6837\u54c1\uff0c\u5e76\u5c06\u8fd9\u4e2a\u6837\u54c1\u5728\u53cc\u5149\u675f\u805a\u7126\u79bb\u5b50\u675f\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08FIB-SEM\uff09\u4e2d\u4ee5\u4e8c\u6b21\u7535\u5b50\uff08SE\uff09\u548c\u80cc\u6563\u5c04\u7535\u5b50\uff08BSE\uff09\u6a21\u5f0f\u6210\u50cf\uff0c\u6d4f\u89c8\u56fe\u50cf\u65f6\uff0c\u9009\u62e9\u611f\u5174\u8da3\u533a\u57df\uff08AOI\uff09\u8fdb\u884c3D FIB\u65ad\u5c42\u626b\u63cf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-205657 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/2-11.png\" alt=\"\" width=\"586\" height=\"545\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/2-11.png 586w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/2-11-300x279.png 300w\" sizes=\"(max-width: 586px) 100vw, 586px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1.\u00a0 A) Trilayer 1, B) Porous 1, C) Porous 2, D) Porous 3<\/strong><strong>\u7684\u4e09\u7ef4\u6784\u5efa\uff0c<\/strong><strong>LLCZN<\/strong><strong>\u76f8\u4e3a\u9ec4\u8272\uff0c\u4efb\u4f55\u4e8c\u6b21\u76f8\u4e3a\u7ea2\u8272\u3002<\/strong><\/p>\n<p>\u9009\u62e9\u56db\u4e2a\u6837\u54c1\u8fdb\u884c3D 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-205658 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/3-11.png\" alt=\"\" width=\"600\" height=\"388\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/3-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/3-11-300x194.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2. Trilayer 1<\/strong><strong>\u6837\u54c1\u6cbf<\/strong><strong> X<\/strong><strong>\u3001<\/strong><strong>Y<\/strong><strong>\u3001<\/strong><strong>Z<\/strong><strong>\u8f74\u6b63\u5411\u7d2f\u79ef\u51e0\u4f55\u5f2f\u66f2\u5ea6\u7684\u4e09\u7ef4\u53ef\u89c6\u5316\uff0c\u4ee5\u53ca\u5e73\u5747\u7d2f\u79ef\u51e0\u4f55\u5f2f\u66f2\u5ea6\u548c\u6807\u51c6\u5dee\u3002<\/strong><\/p>\n<p>\u56fe2A-C\u663e\u793a\u4e86\u6cbf\u7740X\u3001Y\u548cZ\u8f74\u7684\u6b63\u5411\u8ba1\u7b97\u65f6\u201cTrilayer 1\u201d\u6837\u672c\u7d2f\u79ef\u51e0\u4f55\u5f2f\u66f2\u5ea6\u7684\u4e09\u7ef4\u53ef\u89c6\u5316\u56fe\u50cf\uff0c\u7bad\u5934\u8868\u793a\u8ba1\u7b97\u65b9\u5411\u3002\u5f2f\u5ea6\u521d\u59cb\u503c\u4e3a1.0(\u84dd\u8272)\uff0c\u4f46\u65e9\u671f\u504f\u79bb\u76f4\u7ebf\u5bfc\u81f4\u5f2f\u5ea6\u8fc5\u901f\u589e\u52a0\u52301.5(\u7ea2\u8272)\u4ee5\u4e0a\u3002\u5f53\u4e09\u7ef4\u56fe\u50cf\u533a\u57df\u8fdb\u884c\u8ba1\u7b97\u65f6\uff0c\u7d2f\u79ef\u7684\u51e0\u4f55\u5f2f\u5ea6\u964d\u4f4e\uff0c\u5e76\u4e14\u7531\u4e8e\u5c40\u90e8\u53d8\u5316\u88ab\u5168\u5c40\u5c5e\u6027\u5e73\u6ed1\u800c\u53d8\u5f97\u66f4\u52a0\u540c\u8d28\u3002\u5f53\u4f5c\u4e3a\u4f20\u64ad\u8ddd\u79bb\u7684\u51fd\u6570\u6d4b\u91cf\u65f6\uff0c\u8fd9\u79cd\u884c\u4e3a\u5728\u7d2f\u79ef\u51e0\u4f55\u5f2f\u5ea6\u7684\u5e73\u5747\u503c\u548c\u6807\u51c6\u504f\u5dee\u4e2d\u53ef\u89c1(\u56fe2D-F)\u3002\u6839\u636e\u524d\u8fdb\u65b9\u5411\u7684\u6700\u7ec8\u7d2f\u79ef\u51e0\u4f55\u626d\u66f2\u5ea6\u503c\u53ef\u4ee5\u770b\u51fa\uff0cX\u8f74\u7684\u6700\u5927\u5f2f\u66f2\u5ea6\u4e3a1.142\u00b10.028\uff0cY\u8f74\u7684\u5f2f\u66f2\u5ea6\u4e3a1.108\u00b10.028\uff0cZ\u8f74\u7684\u5f2f\u66f2\u5ea6\u6700\u5c0f\uff0c\u4e3a1.080\u00b10.068\u3002\u5f53\u5c06\u6b63\u5411\u548c\u53cd\u5411\u65b9\u5411\u53d6\u5e73\u5747\u503c\u65f6\uff0c\u8fd9\u79cd\u6a21\u5f0f\u6301\u7eed\u5b58\u5728\uff0c\u5bfc\u81f4X\u8f74\u65b9\u5411\u7684\u5e73\u5747\u626d\u66f2\u5ea6\u4e3a1.143\u00b10.028\uff0cY\u8f74\u626d\u66f2\u5ea6\u4e3a1.111\u00b10.030\uff0cZ\u8f74\u626d\u66f2\u5ea6\u4e3a1.083\u00b10.066\u3002\u6839\u636e\u5404\u4e2a\u8f74\u7684\u4e0d\u540c\u626d\u66f2\u5ea6\u503c\u8868\u660e\uff0c\u5fae\u89c2\u7ec4\u7ec7\u5177\u6709\u4e00\u5b9a\u7684\u5404\u5411\u5f02\u6027\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5728\u70e7\u7ed3\u8fc7\u7a0b\u4e2d\u5b54\u9699\u584c\u9677\u7684\u7ed3\u679c\u5bfc\u81f4\u7684\u3002<\/p>\n<p>\u56fe3A\u4e2d\u5c55\u793a\u4e86\u6bcf\u4e2a\u5fae\u89c2\u7ed3\u6784\u7684\u603b\u4f53\u7ed3\u679c\u548c\u5bf9\u5e94\u7684\u62df\u5408\u66f2\u7ebf\uff0c\u5728\u56fe3B\u4e2d\u662f\u4ee5\u5bf9\u6570\u5c3a\u5ea6\u7ed8\u5236\u7684\u3002\u4ece\u5355\u4e2a\u6570\u636e\u70b9\u6765\u770b\uff0cLLCZN\u4f53\u79ef\u5206\u6570\u548c\u6536\u7f29\u56e0\u5b50\u662fM\u56e0\u5b50\u4e2d\u6700\u91cd\u8981\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u51e0\u4f55\u5f2f\u5ea6\u662f\u7b2c\u4e09\u91cd\u8981\u7684\u3002\u591a\u5b543(26.45%)\u6837\u54c1\u4e2d\uff0c\u6536\u7f29\u7cfb\u6570\u6bd4LLCZN\u4f53\u79ef\u5206\u6570\u66f4\u91cd\u8981\uff0c\u5176\u4f59\u6837\u54c1\u4e2d\uff0cLLCZN\u4f53\u79ef\u5206\u6570\u4e0e\u6536\u7f29\u7cfb\u6570\u540c\u7b49\u91cd\u8981\u6216\u7565\u91cd\u8981\u3002\u8fd9\u8868\u660e\uff0c\u572826.45% &#8211; 40.58%\u7684\u5b54\u9699\u5ea6\u4e4b\u95f4\uff0c\u9502\u79bb\u5b50\u4f20\u8f93\u7684\u4e3b\u8981\u9650\u5236\u53d1\u751f\u4e86\u8f6c\u53d8\uff0c\u5728\u4f4e\u5b54\u9699\u7387\u548c\u5bfc\u7535\u76f8\u5206\u6570\u65f6\uff0c\u7f3a\u9677\u662f\u4e3b\u8981\u9650\u5236\uff0c\u5728\u9ad8\u5b54\u9699\u7387\u65f6\uff0c\u7f3a\u9677\u4e5f\u540c\u6837\u91cd\u8981\u3002\u8fd9\u8868\u660e\uff0c\u6d88\u9664\u591a\u5b54\u7ed3\u6784\u4e2d\u7684\u7f3a\u9677\u662f\u5b9e\u73b0\u66f4\u9ad8\u6709\u6548\u7535\u5bfc\u7387\u7684\u5173\u952e\u3002\u7ec4\u5408\u7684M\u56e0\u5b50\u4e5f\u5728\u56fe6\u4e2d\u4f53\u73b0\uff0c\u6b63\u5982\u56fe\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\u968f\u7740\u5b54\u9699\u7387\u7684\u589e\u52a0\uff0cM\u56e0\u5b50\u5448\u6307\u6570\u4e0b\u964d\uff0c\u5b54\u9699\u7387\u589e\u52a0\u523056.67%\u65f6\uff0c\u5bf9\u5e94M\u56e0\u5b50\u4e0b\u964d\u4e861\u4e2a\u6570\u91cf\u7ea7\u3002\u8fd9\u662f\u51fa\u4e4e\u610f\u6599\u7684\uff0c\u56e0\u4e3a\u5728\u4f4e\u5b54\u9699\u7387\u60c5\u51b5\u4e0b\uff0c\u7528\u4e8e\u62df\u5408\u5355\u4e2a\u5fae\u89c2\u7ed3\u6784\u9879\u7684\u4e00\u9636\u548c\u4e8c\u9636\u66f2\u7ebf\u4ee5\u53ca\u6536\u7f29\u56e0\u5b50\u504f\u79bb\u4e86\u62df\u5408\u7684\u4e00\u9636\u66f2\u7ebf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-205659 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/4-11.png\" alt=\"\" width=\"600\" height=\"229\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/4-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/07\/4-11-300x115.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u56db\u4e2a<\/strong><strong>FIB<\/strong><strong>\u5c42\u6790\u6210\u50cf\u6837\u54c1\u7684\u5fae\u89c2\u7ed3\u6784\u964d\u4f4e\u6761\u4ef6\u4ee5\u53ca\u7ec4\u5408\u7684<\/strong><strong>M<\/strong><strong>\u56e0\u5b50<\/strong><strong> A<\/strong><strong>\uff09\u5728\u7ebf\u6027\u5782\u76f4\u5c3a\u5ea6\u4e0a\uff0c<\/strong><strong>B<\/strong><strong>\uff09\u5728\u5bf9\u6570\u5782\u76f4\u5c3a\u5ea6\u4e0a\u7684\u62df\u5408\u66f2\u7ebf\u3002<\/strong><\/p>\n<p>\u5c0f\u7ed3\uff1a\u8fd9\u9879\u5de5\u4f5c\u5f3a\u8c03\u4e86\u4e09\u7ef4\u6210\u50cf\u6280\u672f\u5bf9\u4e8e\u7406\u89e3\u548c\u6539\u8fdb\u7535\u5316\u5b66\u7cfb\u7edf\u7684\u91cd\u8981\u6027\u3002\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u4f5c\u8005\u5229\u7528\u4e09\u7ef4FIB\u5c42\u6790\u6210\u50cf\u5f97\u5230\u7684\u53c2\u6570\uff0c\u5c06\u591a\u5b54LLCZN\u6837\u54c1\u7684\u4e0d\u540c\u5fae\u89c2\u7ed3\u6784\u4e0e\u6709\u6548\u672c\u5f81\u7535\u5bfc\u7387\u8054\u7cfb\u8d77\u6765\u3002M\u56e0\u5b50\u5206\u6790\u8868\u660e\uff0cLLCZN\u4f53\u79ef\u5206\u6570\u548c\u6536\u7f29\u56e0\u5b50\u662f\u63a7\u5236\u6709\u6548\u672c\u5f81\u7535\u5bfc\u7387\u7684\u4e3b\u8981\u56e0\u7d20\uff0c\u800c\u51e0\u4f55\u626d\u66f2\u5ea6\u7684\u5f71\u54cd\u76f8\u5bf9\u8f83\u5c0f\u3002\u5f53\u4f7f\u7528M\u56e0\u5b50\u6765\u4f30\u8ba1\u7406\u8bba\u672c\u5f81\u7535\u5bfc\u7387\u65f6\uff0c\u89c2\u5bdf\u5230\u4e86\u7406\u8bba\u548c\u5b9e\u9a8c\u7ed3\u679c\u4e4b\u95f4\u7684\u4e00\u81f4\u7684\u5dee\u5f02\uff0c\u8fd9\u8868\u660eLLCZN\u7684\u672c\u5f81\u7535\u5bfc\u7387\u4e5f\u968f\u7740\u5b54\u9699\u7387\u7684\u589e\u52a0\u800c\u964d\u4f4e\u3002\u5f53\u6d4b\u8bd5\u8303\u56f4\u66f4\u5e7f\u65f6\uff0c\u4e5f\u53ef\u4ee5\u89c2\u5bdf\u5230\u7c7b\u4f3c\u7684\u8d8b\u52bf\uff0c\u8fd9\u8fdb\u4e00\u6b65\u8868\u660e\uff0c\u4ece\u8868\u9762SEM\u56fe\u50cf\u5f97\u5230\u76842D\u76f8\u9762\u79ef\u5206\u6570\u63a5\u8fd13D FIB\u5c42\u6790\u6210\u50cf\u5f97\u5230\u7684\u771f\u5b9e3D\u76f8\u4f53\u79ef\u5206\u6570\u3002\u57fa\u4e8e\u8fd9\u4e9b\u7ed3\u679c\uff0c\u6700\u5927\u9650\u5ea6\u7684\u51cf\u5c11\u5bfc\u7535\u7f51\u7edc\u4e2d\u7f3a\u9677\uff0c\u5bf9\u4e8e\u5236\u5907\u5177\u6709\u591a\u5b54\u5fae\u7ed3\u6784\u7684\u9ad8\u6027\u80fd\u77f3\u69b4\u77f3\u56fa\u4f53\u7535\u89e3\u8d28\u81f3\u5173\u91cd\u8981\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aThe Effects of Constriction Factor and Geometric Tortuosity on Li-Ion Transport in Porous Solid-State Li-Ion Electrolytes. <em>Adv. Funct. Mater<\/em>. 2020, 1910362.<\/p>\n<p>DOI: 10.1002\/adfm.201910362<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adfm.201910362<\/p>\n<p>\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6a21\u62df\u6280\u672f\u7684\u53d1\u5c55\u4f7f\u5f97\u6a21\u62df\u7535\u5316\u5b66\u88c5\u7f6e\u7684\u6027\u80fd\u6210\u4e3a\u53ef\u80fd\uff0c\u524d\u63d0\u662f\u53ef\u4ee5\u7cbe\u786e\u5730\u8868\u793a\u5fae\u89c2\u7ed3\u6784\u548c\u70ed\u529b\u5b66\/\u52a8\u529b\u5b66\u8fc7\u7a0b\u30023D\u6210\u50cf\u6280\u672f\u7684\u4f7f\u7528\uff08\u4f8b\u5982\uff0c\u805a\u7126\u79bb\u5b50\u675f\uff08FIB\uff09\u5c42\u6790\u6210\u50cf\u6280\u672f\u548cX&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-205655","post","type-post","status-publish","format-standard","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/205655"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=205655"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/205655\/revisions"}],"predecessor-version":[{"id":205673,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/205655\/revisions\/205673"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=205655"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=205655"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=205655"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}