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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n \u8fd1\u65e5\uff0c\u5728\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u548c\u90d1\u5dde<\/b><\/strong>\u5927\u5b66\u91d1\u9633<\/b><\/strong>\u526f<\/b><\/strong>\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u7b49\u4eba<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u4e0e\u56fd\u7f51\u6c5f\u82cf\u7701\u7535\u529b\u6709\u9650\u516c\u53f8<\/b><\/strong>\u5408\u4f5c\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e\u6355\u83b7H2<\/sub>\u7684\u7075\u654f\u68c0\u6d4b\u65b9\u6cd5\uff0c\u53ef\u4ee5\u68c0\u6d4b\u5fae\u91cf\u9502\u679d\u6676\u7684\u5f62\u6210\u3002\u91d1\u5c5e\u9502\u4e0e\u805a\u5408\u7269\u7c98\u7ed3\u5242\u53cd\u5e94\u751f\u6210H2<\/sub>\u3002\u5373\u4f7f\u662f\u5fae\u7c73\u7ea7\u7684\u9502\u679d\u6676\uff08\u7ea62.8\u00d710\u22124 <\/sup>mg\u548c50\u03bcm\uff09\u7684\u751f\u957f\u4e5f\u80fd\u89e6\u53d1H2<\/sub>\u6355\u83b7\u3002\u7528LiFePO4<\/sub>\u77f3\u58a8\u7535\u6c60\u7ec4\uff088.8 kWh\uff09\u7684\u8fc7\u5145\u7535\u5b9e\u9a8c\u8868\u660e\uff0cH2<\/sub>\u5728H2<\/sub>\u3001CO\u3001CO2<\/sub>\u3001HCL\u3001HF\u3001SO2<\/sub>\u4e2d\u7387\u5148\u6355\u83b7\uff0c\u6355\u83b7\u65f6\u95f4\u6bd4\u70df\u96fe\u65e9639 s\uff0c\u6bd4\u706b\u707e\u65e9769 s\u3002\u4e00\u65e6\u6355\u83b7\u4e86H2<\/sub>\uff0c\u5c31\u53ef\u4ee5\u5b8c\u5168\u963b\u6b62\u9502\u679d\u6676\u7684\u751f\u957f\uff0c\u65e2\u4e0d\u5192\u70df\u4e5f\u4e0d\u53d1\u751f\u706b\u707e\uff0c\u4e3a\u65e9\u671f\u5b89\u5168\u9884\u8b66\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/b><\/strong>Detection of Micro-Scale Li Dendrite via H<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Gas Capture for Early Safety Warning<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Joule<\/b><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n \u56fe<\/b><\/strong>1 <\/b><\/strong>H<\/b><\/strong>2<\/b><\/sub><\/strong>\u6355\u83b7\u68c0\u6d4b<\/b><\/strong>Li<\/b><\/strong>\u679d\u6676\u751f\u957f\u7684\u793a\u610f\u56fe<\/b><\/strong> \uff08A\uff09Li\u679d\u6676\u751f\u957f\u7684\u539f\u4f4d\u5149\u5b66\u89c2\u5bdf\u548cH2<\/sub>\u7684\u539f\u4f4d\u6355\u83b7\u7684\u63d2\u56fe\u3002<\/p>\n \uff08B\uff09H2<\/sub>\u4ea7\u751f\u7684\u673a\u7406\u56fe\u3002Li\u679d\u6676\u4e0ePVDF\u7c98\u7ed3\u5242\u53cd\u5e94\uff0c\u4ece\u800c\u4ea7\u751fH2<\/sub>\u3002<\/p>\n \uff08C\uff09Li\u679d\u6676\u4e0ePVDF\u7c98\u7ed3\u5242\u7684\u5316\u5b66\u53cd\u5e94\u673a\u7406\u3002<\/p>\n \u56fe<\/b><\/strong>2 <\/b><\/strong>\u5b58\u5728\u805a\u5408\u7269\u7c98\u5408\u5242\u7684\u60c5\u51b5\u4e0b<\/b><\/strong>Li<\/b><\/strong>\u679d\u6676\u68c0\u6d4b\u548cH<\/b><\/strong>2<\/b><\/sub><\/strong>\u6355\u83b7\u7684\u539f\u4f4d\u5b9e\u9a8c<\/b><\/strong> \uff08A\uff09\u81ea\u7ec4\u88c5LIBs\u7684\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\uff08\u8d1f\u6781\u9762\u79ef\u4e3a3 cm2<\/sup>\uff0c\u5145\u7535\u7535\u6d41\u4e3a3 mA\uff09\u3002<\/p>\n \uff08B\uff09\u901a\u8fc7\u81ea\u52a8\u6c14\u76f8\u8272\u8c31\u68c0\u6d4b\uff0c\u5728683\u548c472 s\u5206\u522b\u6355\u83b7\u4e24\u79cd\u7ec4\u88c5LIBs\u7684H2<\/sub>\u7684\u3002<\/p>\n \uff08C\uff09\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u77f3\u58a8\u8d1f\u6781\u8868\u9762\u7684\u663e\u5fae\u56fe\u50cf\u3002\u8be5\u7535\u6c60\u7531LiFePO4<\/sub>\u6b63\u6781\u548c\u77f3\u58a8\u8d1f\u6781\uff08\u5e26\u6709PVDF\u7c98\u7ed3\u5242\uff09\u7ec4\u6210\u3002<\/p>\n \uff08D\uff09\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u77f3\u58a8\u7535\u6781\u8868\u9762\u7684\u663e\u5fae\u56fe\u50cf\u3002\u8be5\u7535\u6c60\u7531Li\u91d1\u5c5e\u7535\u6781\u548c\u77f3\u58a8\u7535\u6781\uff08\u5e26\u6709PVDF\u7c98\u7ed3\u5242\uff09\u7ec4\u6210\u3002<\/p>\n \u56fe<\/b><\/strong>3 <\/b><\/strong>\u6ca1\u6709\u805a\u5408\u7269\u7c98\u7ed3\u5242\u7684<\/b><\/strong>Li<\/b><\/strong>\u679d\u6676\u751f\u957f\u7684\u539f\u4f4d\u5b9e\u9a8c<\/b><\/strong> \uff08A\uff09\u81ea\u7ec4\u88c5LIBs\u7684\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\uff08\u8d1f\u6781\u9762\u79ef\u4e3a3 cm2<\/sup>\uff0c\u5145\u7535\u7535\u6d41\u4e3a3 mA\uff09\u3002<\/p>\n \uff08B\uff09\u81ea\u52a8\u6c14\u76f8\u8272\u8c31\u7ed3\u679c\u663e\u793a\u672a\u68c0\u6d4b\u5230H2<\/sub>\u4fe1\u53f7\u3002<\/p>\n \uff08C\uff09\u5145\u7535\u8fc7\u7a0b\u4e2d\u94dc\u7b94\u8868\u9762\u7684\u663e\u5fae\u56fe\u50cf\u3002\u8be5\u7535\u6c60\u7531LiFePO4<\/sub>\u6b63\u6781\u548c\u7eaf\u94dc\u7b94\u96c6\u6d41\u4f53\uff08\u4e0d\u542b\u805a\u5408\u7269\u7c98\u7ed3\u5242\uff09\u7ec4\u6210\u3002<\/p>\n \uff08D\uff09\u77f3\u58a8\u8868\u9762\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u663e\u5fae\u56fe\u50cf\u3002\u8be5\u7535\u6c60\u7531LiFePO4<\/sub>\u6b63\u6781\u548c\u77f3\u58a8\u8d1f\u6781\uff08\u65e0\u805a\u5408\u7269\u7c98\u7ed3\u5242\uff09\u7ec4\u6210\u3002<\/p>\n \u56fe<\/b><\/strong>4 <\/b><\/strong>\u5728\u5b9e\u9645BESS<\/b><\/strong>\u673a<\/b><\/strong>\u8231\u5185\u5728\u7ebf\u68c0\u6d4b\u516d\u79cd\u6c14\u4f53\u7684LiFePO<\/b><\/strong>4<\/b><\/sub><\/strong>\u7535\u6c60\u7ec4\u7684\u8fc7\u5145\u5b9e\u9a8c<\/b><\/strong> \uff08A\uff09\u771f\u5b9eBESS\u673a\u8231\u4e2d\u5b9e\u9a8c\u73af\u5883\u7684\u56fe\u793a\u3002\u8be5\u7535\u6c60\u7ec4\u4e0a\u65b9\u8bbe\u7f6e\u4e86\u516d\u4e2a\u6c14\u4f53\uff08H2<\/sub>\u3001CO\u3001CO2<\/sub>\u3001HF\u3001HCl\u548cSO2<\/sub>\uff09\u4f20\u611f\u5668\u3002<\/p>\n \uff08B\uff09\u8fc7\u5145\u8fc7\u7a0b\u4e2dLiFePO4<\/sub>\u7535\u6c60\u7ec4\u7684\u7535\u538b\u66f2\u7ebf\u548c\u8868\u9762\u6e29\u5ea6\u53d8\u5316\uff08\u5145\u7535\u500d\u7387\uff1a0.5 C\uff09\u3002<\/p>\n \uff08C\uff09\u516d\u79cd\u6c14\u4f53\u76840-1800 s\u7684\u6c14\u4f53\u6d53\u5ea6\u53d8\u5316\u3002<\/p>\n \uff08D\uff09\u56db\u79cd\u6c14\u4f53\u7684960\u20131100 s\u589e\u5927\u7684\u6c14\u4f53\u6d53\u5ea6\u66f2\u7ebf\u3002<\/p>\n \uff08E\uff09LiFePO4<\/sub>\u7535\u6c60\u7ec4\u5728\u4e0d\u540c\u65f6\u95f4\u7684\u5149\u5b66\u56fe\u50cf\u3002t1<\/sub>\u00a0= 0 s\uff0c\u8fc7\u5145\u7535\u7684\u521d\u59cb\u65f6\u95f4\uff1bt2<\/sub>\u00a0= 990 s\uff0c\u68c0\u6d4b\u5230H2<\/sub>\uff1bt3<\/sub>\u00a0= 1425 s\uff0c\u5192\u70df\uff1bt4<\/sub>\u00a0= 1570\uff0c\u8d77\u706b\u7206\u70b8\u3002<\/p>\n \u56fe<\/b><\/strong>5 <\/b><\/strong>\u6355\u83b7H<\/b><\/strong>2<\/b><\/sub><\/strong>\u7684LiFePO<\/b><\/strong>4<\/b><\/sub><\/strong>\u7535\u6c60\u7ec4\uff089\u4e2a\u7535\u6c60\u7ec4\uff0c79.2 kWh\uff09\u7684\u5b89\u5168\u8b66\u544a\u5b9e\u9a8c<\/b><\/strong> \uff08A\uff09\u5728\u4e00\u4e2a\u5b9e\u9645\u7684BESS\u673a\u8231\u4e2d\u7684\u5b9e\u9a8c\u73af\u5883\u7684\u56fe\u793a\uff0c\u5e76\u4e14\u5c06\u4e09\u4e2aH2<\/sub>\u4f20\u611f\u5668\u8bbe\u7f6e\u5728\u4e0d\u540c\u7684\u8ddd\u79bb\u5904\u3002<\/p>\n \uff08B\uff09\u8fc7\u5145\u7535\u671f\u95f4\uff08\u5145\u7535\u500d\u7387\uff1a0.5 C\uff09LiFePO4<\/sub>\u7535\u6c60\u7ec4\u7684\u7535\u538b\u66f2\u7ebf\u548c\u8868\u9762\u6e29\u5ea6\u53d8\u5316\u3002<\/p>\n \uff08C\uff09\u4e09\u4e2a\u4f20\u611f\u56680\u20132500 s\u7684H2<\/sub>\u6d53\u5ea6\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n \uff08D\uff09\u4e09\u4e2a\u4f20\u611f\u5668900\u20131150 s\u7684\u653e\u5927H2<\/sub>\u6d53\u5ea6\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n \uff08E\uff09\u5f53\u6355\u83b7H2<\/sub>\u5e76\u505c\u6b62\u5145\u7535\u65f6\uff0c\u5728\u521d\u59cb\u65f6\u95f4t1<\/sub>\u00a0= 0 s\u548ct2<\/sub>\u00a0= 994 s\u7684\u5149\u5b66\u56fe\u50cf\u3002<\/p>\n \u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n \u56e2\u961f\u901a\u8fc7H2<\/sub>\u6355\u83b7\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u7075\u654f\u7684\u68c0\u6d4bLIBs\u4e2dLi\u679d\u6676\u751f\u957f\u7684\u68c0\u6d4b\u65b9\u6cd5\uff0c\u7528\u4e8e\u65e9\u671f\u5b89\u5168\u9884\u8b66\u3002\u91d1\u5c5e\u9502\u679d\u6676\u80fd\u88ab\u63a2\u6d4b\u5230\u7684\u6700\u5c0f\u6570\u91cf\u53ea\u67092.8\u00d710-4<\/sup>mg\u3002\u901a\u8fc7\u5728\u771f\u5b9e\u7684BESS\u673a\u8231\u5185\u5bf9LiFePO4<\/sub>\u7535\u6c60\u7ec4\u8fdb\u884c\u6c14\u4f53\u68c0\u6d4b\u5b9e\u9a8c\uff0c\u53d1\u73b0H2<\/sub>\u662f\u68c0\u6d4b\u6700\u7075\u654f\u7684\u6c14\u4f53\uff0c\u6bd4\u5728\u7ebf\u68c0\u6d4b\u5230\u7684\u5176\u4ed6\u4e94\u79cd\u6c14\u4f53\u66f4\u65e9\u6355\u83b7\u3002\u7528\u4e00\u4e2aLiFePO4<\/sub>\u7535\u6c60\u7ec4\u8fdb\u884c\u5b89\u5168\u8b66\u793a\u5b9e\u9a8c\uff0c\u8bc1\u5b9e\u4e86\u5373\u4f7f\u5728\u5176\u4ed6\u7ec4\u7684\u4fdd\u62a4\u4e0b\uff0cH2<\/sub>\u4ecd\u80fd\u5728\u65e9\u671f\u88ab\u63a2\u6d4b\u5230\u3002\u5728H2<\/sub>\u88ab\u6355\u83b7\u7684\u65f6\u5019\uff0c\u901a\u8fc7\u5207\u65ad\u5145\u7535\u5668\uff0c\u53ef\u4ee5\u5b8c\u5168\u9632\u6b62\u7535\u6c60\u5185\u90e8\u7684Li\u679d\u6676\u751f\u957f\u548c\u70ed\u79ef\u7d2f\u8fc7\u7a0b\uff0c\u65e2\u4e0d\u5192\u70df\u4e5f\u4e0d\u7740\u706b\u3002\u672c\u7814\u7a76\u7684H2<\/sub>\u6355\u83b7\u6280\u672f\u4e3a\u5fae\u7c73\u7ea7Li\u679d\u6676\u5f62\u6210\u7684\u65e9\u671f\u5b89\u5168\u9884\u8b66\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7684\u68c0\u6d4b\u65b9\u6cd5\uff0c\u5c06\u63d0\u9ad8Li\u679d\u6676\u7cfb\u7edf\u7684\u5b89\u5168\u6c34\u5e73\u3002<\/p>\n<\/p>\n
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