{"id":205275,"date":"2020-07-14T06:23:02","date_gmt":"2020-07-13T22:23:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=205275"},"modified":"2020-07-13T22:23:21","modified_gmt":"2020-07-13T14:23:21","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%e5%ae%8b%e6%99%ba%e5%b9%b3energy-storage-mater-%ef%bc%9a%e9%ab%98%e6%b5%93%e5%ba%a6%e7%94%b5%e8%a7%a3%e6%b6%b2%e5%ae%9e%e7%8e%b0%e5%b0%8f%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=205275","title":{"rendered":"\u6b66\u6c49\u5927\u5b66\u5b8b\u667a\u5e73Energy Storage Mater.\uff1a\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u5b9e\u73b0\u5c0f\u5206\u5b50\u6709\u673a\u7535\u6781\u6750\u6599\u7684\u7a33\u5b9a\u5faa\u73af"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u76ee\u524d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5df2\u7ecf\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u5546\u4e1a\u6210\u529f\uff0c\u4f46\u7531\u4e8e\u6b63\u6781\u6750\u6599\u6240\u9700\u7684\u94b4\u3001\u954d\u7b49\u8fc7\u6e21\u91d1\u5c5e\u8d44\u6e90\u6709\u9650\uff0c\u56e0\u6b64\u9762\u4e34\u8d44\u6e90\u53ef\u6301\u7eed\u6027\u7684\u95ee\u9898\u3002\u4f46\u662f\u4e0d\u65ad\u589e\u957f\u7684\u7535\u52a8\u6c7d\u8f66\u548c\u50a8\u80fd\u5e02\u573a\uff0c\u9700\u8981\u5bfb\u6c42\u66f4\u9ad8\u6548\u3001\u66f4\u53ef\u6301\u7eed\u7684\u7535\u6c60\uff0c\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u4e86\u6709\u673a\u7535\u6781\u6750\u6599\uff08OEM\uff09\u7684\u53d1\u5c55\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u57fa\u4e8e\u5171\u8f6d\u7fb0\u57fa\u7684OEM\u5177\u6709\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3001\u8d44\u6e90\u53ef\u7528\u6027\u3001\u5e7f\u6cdb\u7684\u7ed3\u6784\u548c\u6027\u80fd\u591a\u6837\u6027\u3002\u7136\u800c\uff0c\u7fb0\u57faOEM\u7684\u5e94\u7528\u9762\u4e34\u6d3b\u6027\u7269\u8d28\u5728\u975e\u8d28\u5b50\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\uff0c\u5bfc\u81f4\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u548c\u4e0d\u5229\u7684\u201c\u7a7f\u68ad\u6548\u5e94\u201d\u7b49\u95ee\u9898\uff0c\u8fd9\u4e0eLi-S\u7535\u6c60\u975e\u5e38\u76f8\u4f3c\u3002\u7531\u4e8e\u6eb6\u89e3\u884c\u4e3a\u662fSMOEM\u4e0e\u7535\u89e3\u6db2\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u540e\u8005\u53ef\u80fd\u5728\u5f71\u54cd\u6eb6\u89e3\u6027\u4ee5\u53ca\u5faa\u73af\u6027\u80fd\u65b9\u9762\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002\u7136\u800c\uff0c\u5148\u524d\u7684\u7814\u7a76\u5927\u591a\u5ffd\u7565\u4e86\u7535\u89e3\u6db2\u7684\u4f5c\u7528\uff0c\u5e76\u4e14\u5173\u4e8eSMOEM\u6750\u6599\u7684\u7535\u89e3\u6db2\u5f88\u5c11\u8fdb\u884c\u4f18\u5316\u5206\u6790\u3002\u6b64\u5916\uff0c\u867d\u7136\u666e\u904d\u8ba4\u4e3a\u5bb9\u91cf\u4e0b\u964d\u548c\u5e93\u4ed1\u6548\u7387\u4f4e\u7684\u6839\u6e90\u662f\u6eb6\u89e3\u95ee\u9898\uff0c\u4f46\u662fOEM\u7684\u5177\u4f53\u6eb6\u89e3\u6027\u4ee5\u53ca\u4e0e\u7535\u89e3\u6db2\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u673a\u7406\u4ecd\u4e0d\u6e05\u695a\u3002\u56e0\u6b64\uff0c\u4f5c\u8005\u5e0c\u671b\u901a\u8fc7\u4e00\u79cd\u7b80\u4fbf\u7684\u7535\u89e3\u6db2\u4f18\u5316\u7b56\u7565\u6765\u6539\u5584SMOEM\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u800c\u65e0\u9700\u4efb\u4f55\u5176\u4ed6\u7684\u590d\u6742\u8fc7\u7a0b\uff0c\u5e76\u63d0\u4f9b\u5bf9\u8be6\u7ec6\u673a\u7406\u7684\u66f4\u6df1\u5165\u7684\u7406\u89e3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 NTCDA<\/strong>\u548c<\/strong>PTCDA<\/strong>\u7684\u6676\u4f53\u7ed3\u6784\u548c\u7535\u5316\u5b66\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09NTCDA(CCDC\uff1a129443)\u7684\u6676\u683c\u7ed3\u6784\uff1b<\/p>\n

\uff08d\uff0ce\uff09PTCDA(CCDC\uff1a196996)\u7684\u6676\u683c\u7ed3\u6784\uff1b<\/p>\n

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\u56fe<\/strong> 2 NTCDA<\/strong>\u548c<\/strong>PTCDA<\/strong>\u7684\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong> 3 <\/strong>\u4e0d\u540c\u6d53\u5ea6\u7535\u89e3\u6db2\u4e2d\uff0c<\/strong>PTCDA<\/strong>\u7684\u500d\u7387\u548c\u957f\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572850\u52301000 mA g-1<\/sup>\u4e0b\uff0c\u5728\u6d53\u5ea6\u5206\u522b\u4e3a1\u30012\u30013\u548c4 M\u7684LiTFSI\/DOL+DME\u7535\u89e3\u6db2\u4e2dPTCDA\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08b\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c3 M\u7535\u89e3\u6db2\u4e2dPTCDA\u7684\u76f8\u5e94\u653e\u7535-\u5145\u7535\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u5728100 mA g-1<\/sup>\u4e0b\uff0cPTCDA\u57281 M\u548c3 M\u7535\u89e3\u6db2\u4e2d\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe<\/strong> 4 NTCDA<\/strong>\u548c<\/strong>PTCDA<\/strong>\u7535\u6781\u7684\u6eb6\u89e3\u884c\u4e3a<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09NTCDA\u548cPTCDA\u7535\u6781\u5728\u5145\u7535\u72b6\u6001\uff08\u521d\u59cb\u7535\u6781\uff09\u548c\u653e\u7535\u72b6\u6001\uff08\u653e\u7535\u81f31.5 V\uff09\u4e0b\uff0c\u5728\u4f53\u79ef\u4e3a1 mL\uff0c\u6d53\u5ea6\u5206\u522b\u4e3a1\uff0c2\uff0c3 \u548c4 M\u7684LiTFSI\/DOL+DME\u7535\u89e3\u6db2\u4e2d\uff0c\u5206\u522b\u6d78\u6ce10.5\u30012\u30018\u548c96 h\u540e\u7684\u6570\u7801\u7167\u7247\uff1b<\/p>\n

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\u56fe<\/strong> 5 NTCDA<\/strong>\u548c<\/strong>PTCDA<\/strong>\u7c89\u672b\u53ca\u4e0d\u540c\u72b6\u6001\u4e0b\u7535\u6781\u7684<\/strong>XRD<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong> 6 NTCDA<\/strong>\u548c<\/strong>PTCDA<\/strong>\u7c89\u672b\u53ca\u4e0d\u540c\u72b6\u6001\u4e0b\u7535\u6781\u7684<\/strong>SEM<\/strong>\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\u2013f\uff09NTCDA\u548c\uff08g\u2013l\uff09PTCDA\u7c89\u672b\u548c\u5faa\u73af\u4e0d\u540c\u5468\u6570\u7684\u5145\u7535\u6001\u7535\u6781\u7684SEM\u56fe\u50cf\uff1a<\/p>\n

\uff08a\uff0cg\uff09NTCDA\u548cPTCDA\u7c89\u672b\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff0ch\uff09NTCDA\u548cPTCDA\u521d\u59cb\u7535\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff0ci\uff09\u57281 M\u7535\u89e3\u6db2\u4e2d\uff0c1\u5468\u548c\uff08d\uff0cj\uff09100\u5468\u5faa\u73af\u540e\u7684\u7535\u6781\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff0ck\uff09\u57283 M\u7535\u89e3\u6db2\u4e2d\uff0c1\u5468\u548c\uff08f\uff0cl\uff09100\u5468\u5faa\u73af\u540e\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 7 Li\/NTCDA<\/strong>\u548c<\/strong>Li\/PTCDA<\/strong>\u7535\u6c60\u5728\u4e0d\u540c\u72b6\u6001\u4e0b\u7684<\/strong>EIS<\/strong>\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u57281 M\u548c3 M LiTFSI\/DOL+DME\u7535\u89e3\u6db2\u4e2d\uff0cLi\/NTCDA\u7535\u6c60\u5faa\u73af\u524d\u548c1\u30015\u300120\u548c100\u5468\u540e\u7684EIS\u56fe\uff1b<\/p>\n

\uff08a\uff0cb\uff09\u57281 M\u548c3 M LiTFSI\/DOL+DME\u7535\u89e3\u6db2\u4e2d\uff0cLi\/PTCDA\u7535\u6c60\u5faa\u73af\u524d\u548c1\u30015\u300120\u548c100\u5468\u540e\u7684EIS\u56fe\u3002<\/p>\n

\u56fe<\/strong> 8 <\/strong>\u5728<\/strong>1 M<\/strong>\u548c<\/strong>3 M LiTFSI\/DOL+DME<\/strong>\u7535\u89e3\u6db2\u4e2d\uff0c<\/strong>NTCDA<\/strong>\u548c<\/strong>PTCDA<\/strong>\u7535\u6781\u7684\u6f14\u53d8\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Stable cycling of small molecular organic electrode materials enabled by high concentration electrolytes<\/strong><\/a>\uff08Energy Storage Materials, 2020, DOI: 10.1016\/j.ensm.2020.06.032\uff09\u3002<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u3010\u56e2\u961f\u5728\u6709\u673a\u7535\u6781\u6750\u6599\u65b9\u9762\u7684\u5de5\u4f5c\u6c47\u603b\u3011<\/strong><\/p>\n

[1] Taotao Cai, Yan Han, Qing Lan, Feng Wang, Jun Chu, Hui Zhan, Zhiping Song*, Stable cycling of small molecular organic electrode materials enabled by high concentration electrolytes, Energy Storage Mater., 2020. doi:10.1016\/j.ensm.2020.06.032.<\/p>\n

\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u5b9e\u73b0\u5c0f\u5206\u5b50\u6709\u673a\u7535\u6781\u6750\u6599\u7684\u7a33\u5b9a\u5faa\u73af<\/p>\n

[2] Ning Liu, Yuzhu Liu, Yali Zhao, Yutao Liu, Qing Lan, Jian Qin, Zhiping Song*, Hui Zhan*, CNT-intertwined polymer electrode toward the pratical application of wearable devices, ACS Appl. Mater. Interfaces, 2019, 11, 46726-46734.<\/p>\n

\u9759\u7535\u7eba\u4e1d\u5236\u5907Polyimide\/CNT\u67d4\u6027\u7535\u6781<\/p>\n

[3] Jian Qin, Qing Lan, Ning Liu, Yali Zhao, Zhiping Song*, Hui Zhan*, A metal-free battery working at \u201380 \u00b0C, Energy Storage Mater., 2019, 26, 585-592.<\/p>\n

\u201380 \u2103\u5de5\u4f5c\u7684\u65e0\u91d1\u5c5e\u7535\u6c60<\/p>\n

[4] Jian Qin, Qing Lan, Ning Liu, Fang Men, Xin Wang, Zhiping Song*, Hui Zhan*, A metal-free battery with pure ionic liquid electrolyte, iScience, 2019, 15, 16-27.<\/p>\n

\u57fa\u4e8e\u7eaf\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u6db2\u7684\u65e0\u91d1\u5c5e\u7535\u6c60<\/p>\n

[5] Zhiping Song, Yumin Qian, Minoru Otani, Haoshen Zhou*, Stable Li-organic batteries with Nafion-based sandwich-type separators, Adv. Energy Mater., 2016, 6, 7.<\/p>\n

\u57fa\u4e8eNafion\u7684\u4e09\u660e\u6cbb\u7ed3\u6784\u79bb\u5b50\u9009\u62e9\u6027\u9694\u819c\u6291\u5236\u7a7f\u68ad\u6548\u5e94<\/p>\n

[6] Zhiping Song, Yumin Qian, Mikhail L. Gordin, Duihai Tang, Terrence Xu, Minoru Otani, Hui Zhan, Haoshen Zhou*, Donghai Wang*, Polyanthraquinone as a reliable organic electrode for stable and fast lithium storage, Angew. Chem. Int. ed., 2015, 54, 13947-13951.<\/p>\n

\u805a\u84bd\u918cPAQ\uff1a\u9ad8\u6027\u80fd\u6709\u673a\u7535\u6781\u6750\u6599<\/p>\n

[7] Zhiping Song, Yumin Qian, Tao Zhang, Minoru Otani, Haoshen Zhou*, Poly(benzoquinonyl sulfide) as a high-energy organic cathode for rechargeable Li and Na batteries, Adv. Sci., 2015, 2, 1500124. (ESI highly cited paper)<\/p>\n

\u805a\u82ef\u918c\u786b\u919aPBQS\uff1a\u9ad8\u6027\u80fd\u6709\u673a\u7535\u6781\u6750\u6599<\/p>\n

[8] Zhiping Song, Yumin Qian, Xizheng Liu, Tao Zhang, Yanbei Zhu, Haijun Yu, Minoru Otani, Haoshen Zhou*, A quinone-based oligomeric lithium salt for superior Li\u2013organic batteries, Energy Environ. Sci., 2014, 7, 4077-4086.<\/p>\n

\u805a\u4e8c\u7f9f\u57fa\u82ef\u918c\u786b\u919a\u9502\u76d0Li2<\/sub>PDHBQS\uff1a\u9ad8\u6027\u80fd\u6709\u673a\u7535\u6781\u6750\u6599<\/p>\n

[9] Hu Qin#, Zhiping Song#, Hui Zhan*, Yunhong Zhou, Aqueous rechargeable alkali-ion batteries with polyimide anode, J. Power Sources, 2014, 249, 367-372. (co-first author, ESI highly cited paper)<\/p>\n

\u805a\u9170\u4e9a\u80faPI\uff1a\u6c34\u7cfb\u4e8c\u6b21\u7535\u6c60\u8d1f\u6781\u6750\u6599<\/p>\n

[10] Zhiping Song*, Haoshen Zhou*, Towards sustainable and versatile energy storage devices: an overview of organic electrode materials, Energy Environ. Sci., 2013, 6, 2280-2301. (inside back cover, ESI highly cited paper)<\/p>\n

\u9762\u5411\u53ef\u6301\u7eed\u548c\u591a\u529f\u80fd\u50a8\u80fd\u5668\u4ef6\u7684\u6709\u673a\u7535\u6781\u6750\u6599\uff08\u7efc\u8ff0\uff09<\/p>\n

[11] Zhiping Song, Mikhail L. Gordin, Terrence Xu, Ying-Bing Jiang, In-Tae Bae, Qiangfeng Xiao, Hui Zhan, Jun Liu, Donghai Wang*, Polymer-graphene nanocomposites as ultrafast-charge and -discharge cathodes for rechargeable lithium batteries, Nano. Lett. 2012, 12, 2205-2211. (ESI highly cited paper)<\/p>\n

\u5177\u6709\u8d85\u5feb\u5145\u653e\u7535\u80fd\u529b\u7684\u805a\u5408\u7269\/\u77f3\u58a8\u70ef\u7eb3\u7c73\u590d\u5408\u6750\u6599<\/p>\n

[12] Zhiping Song, Hui Zhan*, Yunhong Zhou, Polyimides: promising energy storage materials, Angew. Chem. Int. ed., 2010, 49, 8444-8448. (ESI highly cited paper)<\/p>\n

\u805a\u9170\u4e9a\u80faPI\uff1a\u9ad8\u6027\u80fd\u6709\u673a\u7535\u6781\u6750\u6599<\/p>\n

[13] Zhiping Song, Hui Zhan*, Yunhong Zhou, Anthraquinone based polymer as high performance cathode material for rechargeable lithium batteries, Chem. Comm., 2009, 448-450. (ESI highly cited paper)<\/p>\n

\u805a\u84bd\u918c\u786b\u919aPAQS\uff1a\u9ad8\u6027\u80fd\u6709\u673a\u7535\u6781\u6750\u6599<\/p>\n

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