{"id":204525,"date":"2020-07-02T06:30:10","date_gmt":"2020-07-01T22:30:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=204525"},"modified":"2020-07-01T20:06:48","modified_gmt":"2020-07-01T12:06:48","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e5%8d%8e%e7%a7%91%e5%a4%a7am%ef%bc%9a%e5%85%bc%e5%85%b7%e9%ab%98%e4%ba%ae%e5%ba%a6%e5%92%8c%e6%b0%b4%e7%a8%b3%e5%ae%9a%e6%80%a7%e7%9a%84%e9%9d%9e%e9%93%85%e9%87%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=204525","title":{"rendered":"\u534e\u79d1\u5927AM\uff1a\u517c\u5177\u9ad8\u4eae\u5ea6\u548c\u6c34\u7a33\u5b9a\u6027\u7684\u975e\u94c5\u91d1\u5c5e\u5364\u5316\u7269\u56fa\u6eb6\u4f53\u53d1\u5149\u6750\u6599Cs2(Sn,Te)Cl6"},"content":{"rendered":"

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1. \u7814\u7a76\u80cc\u666f<\/strong><\/p>\n

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\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u6211\u4eec\u9009\u62e9Cs2<\/sub>Sn1\u2013x<\/sub>Tex<\/sub>Cl6<\/sub>\u6765\u5f62\u6210\u4e00\u79cd\u65e0\u94c5\u3001\u7a33\u5b9a\u3001\u9ad8\u6548\u7684\u5149\u81f4\u53d1\u5149\u6750\u6599\u3002\u5408\u6210\u7684\u56fa\u6eb6\u4f53\u6750\u6599\u4fdd\u6301\u4e86Cs2<\/sub>BCl6<\/sub>\u7684\u7a7a\u4f4d\u6709\u5e8f\u6676\u4f53\u7ed3\u6784\u3002\u5c3d\u7ba1Te4+<\/sup>\u548cSn4+<\/sup>\u79bb\u5b50\u7684\u5927\u5c0f\u4e0d\u540c\uff0c\u4f46\u7531\u4e8e\u8f83\u5927\u7684Te4+<\/sup>\u79bb\u5b50\u901a\u8fc7\u5728\u516b\u9762\u4f53\u4e4b\u95f4\u7684\u7a7a\u9699\u4e2d\u81a8\u80c0[BCl6<\/sub>]2-<\/sup>\u800c\u7a33\u5b9a\u5728\u6676\u4f53\u7ed3\u6784\u4e2d\uff0c\u56e0\u6b64\u6240\u6709\u7684\u6837\u54c1\u90fd\u80fd\u4fdd\u6301\u539f\u6709\u7ed3\u6784\u3002\u5728\u81a8\u80c0\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u6709\u5229\u4e8e\u63d0\u9ad8\u5149\u53d1\u5c04\u6027\u80fd\u7684Jahn-Teller\u626d\u66f2\u3002\u56e0\u6b64\uff0c\u5f53Te4+<\/sup>\u53d6\u4ee311%\u65f6\uff0c\u5149\u81f4\u53d1\u5149\u5f97\u5230\u663e\u8457\u6539\u5584\uff08\u53d1\u5c04\u5cf0\uff1a580nm\uff0cPLQY:95.4%\uff09\u3002\u8fd9\u662f\u6240\u6709\u9499\u949b\u77ff\u4e2d\u5df2\u77e5\u62a5\u9053\u7684\u6700\u9ad8PLQY\u4e4b\u4e00\u3002\u4e0eCs2<\/sub>SnCl6<\/sub>\uff083.9\u00a0eV\uff09\u76f8\u6bd4\uff0cCs2<\/sub>Sn1\u2013x<\/sub>Tex<\/sub>Cl6<\/sub>\u7684\u5e26\u9699\u660e\u663e\u51cf\u5c0f\u52303.4\u00a0eV\u3002\u7eaf\u65e0\u673a\u6210\u5206\u548cSn4+<\/sup>\u6216Te4+<\/sup>\u7a33\u5b9a\u7684\u6c27\u5316\u72b6\u6001\u4fdd\u8bc1\u4e86\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u6837\u54c1\u53ef\u4ee5\u4e0d\u9700\u8981\u4efb\u4f55\u9884\u5904\u7406\u800c\u627f\u53d7\u6781\u7aef\u7684\u6c34\u6d78\u6761\u4ef6\uff0c\u5e76\u4fdd\u6301\u660e\u4eae\u7684\u53d1\u5149\u3002\u6c34\u7a33\u5b9a\u6027\u7684\u539f\u56e0\u53ef\u80fd\u662f\u5728\u6c34\u5316\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u6709\u9650\u7684\u975e\u6676\u8680\u53d8\u76f8\u3002\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8868\u660e\uff0c\u5728\u6c34\/Cs2<\/sub>SnCl6<\/sub>\uff08111\uff09\u754c\u9762\u4e0a\u672a\u89c2\u5bdf\u5230\u4efb\u4f55\u53cd\u5e94\uff0cCs2<\/sub>SnCl6<\/sub>\u8868\u9762\u4fdd\u6301\u4e86\u539f\u6709\u7684\u7ed3\u6784\uff0c\u8bf4\u660eCs2<\/sub>SnCl6<\/sub>\u5bf9\u6c34\u662f\u7a33\u5b9a\u7684\u3002\u7efc\u4e0a\u6240\u8ff0\uff0cCs2<\/sub>Sn1\u2013x<\/sub>Tex<\/sub>Cl6<\/sub>\u4f5c\u4e3a\u6c34\u4e0b\u7167\u660e\u9ec4\u7eff\u8272\u8367\u5149\u7c89\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002<\/p>\n

\u5168\u6587\u901f\u89c8\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.202002443<\/u><\/a><\/p>\n

2. \u672c\u6587\u4eae\u70b9<\/strong><\/p>\n

\u6587\u4e2d\uff0c\u6211\u4eec\u62a5\u9053\u4e86\u4e00\u79cd\u975e\u94c5\u9499\u949b\u77ff\u578b\u56fa\u6eb6\u4f53\uff0c\u5176\u516c\u5f0f\u4e3aCs2<\/sub>Sn1\u2212x<\/sub>Tex<\/sub>Cl6<\/sub>\u3002\u5f53Sn\/Te\u79bb\u5b50\u4ea4\u6362\u65f6\uff0c\u6676\u683c\u7ed3\u6784\u53d1\u751f\u4e86\u5f3a\u70c8\u7684\u516b\u9762\u4f53Jahn-Teller\u7578\u53d8\u3002Te\u53d1\u5149\u4e2d\u5fc3\u4e0eJahn-Teller\u578b\u81ea\u9677\u6fc0\u5b50\uff08STEs\uff09\u7684\u7ed3\u5408\u4f7f\u8be5\u6750\u6599\u5177\u6709580nm\u7684\u9ec4\u7eff\u8272\u8367\u5149\uff0c\u9ad8\u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08PLQY\u4e3a95.4%\uff09\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u56fa\u6eb6\u4f53\u80fd\u591f\u627f\u53d7\u6d78\u5165\u6c34\u4e2d\u7684\u6781\u7aef\u6761\u4ef6\uff0c\u56e0\u4e3a\u8868\u9762\u53ef\u4ee5\u5f62\u6210\u975e\u6676\u8680\u53d8\u76f8\u3002\u8fd9\u79cd\u826f\u597d\u7684\u6297\u6c34\u7a33\u5b9a\u6027\u4e5f\u5f97\u5230\u4e86\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u7ed3\u679c\u7684\u652f\u6301\uff0c\u5373\u5728\u6c34\/Cs2<\/sub>SnCl6<\/sub>\u754c\u9762\u6ca1\u6709\u53cd\u5e94\u3002\u5176\u9ad8\u4eae\u5ea6\u3001\u5408\u9002\u7684\u6ce2\u957f\u3001\u826f\u597d\u7684\u6c34\u7a33\u5b9a\u6027\u4f7f\u5176\u53ef\u4ee5\u5e94\u7528\u4e8e\u6c34\u4e0b\u7167\u660e\u3002<\/p>\n

3. \u56fe\u6587\u89e3\u8bfb<\/strong><\/p>\n

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4. \u5168\u6587\u5c0f\u7ed3<\/strong><\/p>\n

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\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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