{"id":204413,"date":"2020-07-02T12:00:35","date_gmt":"2020-07-02T04:00:35","guid":{"rendered":"\/\/m.iemloyee.com\/?p=204413"},"modified":"2020-07-02T11:39:01","modified_gmt":"2020-07-02T03:39:01","slug":"%e6%b0%b4%e7%b3%bb%e9%94%8c%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e6%ad%a3%e6%9e%81%e6%ba%b6%e8%a7%a3%e9%97%ae%e9%a2%98%ef%bc%8c%e4%bd%a0%e4%ba%86%e8%a7%a3%e5%a4%9a%e5%b0%91%ef%bc%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=204413","title":{"rendered":"\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6eb6\u89e3\u95ee\u9898\uff0c\u4f60\u4e86\u89e3\u591a\u5c11\uff1f"},"content":{"rendered":"

\u950c\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u4e00\u79cd\u73af\u5883\u53cb\u597d\u3001\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u6027\u548c\u6781\u5177\u6f5c\u529b\u7684\u65b0\u578b\u5927\u89c4\u6a21\u50a8\u80fd\u7cfb\u7edf\u5728\u8fd1\u4e9b\u5e74\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\uff0c\u5c24\u5176\u662f\u5728\u67d4\u6027\u53ef\u7a7f\u6234\u7535\u5b50\u4ea7\u54c1\u7814\u7a76\u4e2d\uff0c\u56e0\u4e3a\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5728\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u65e0\u6cd5\u6ee1\u8db3\u673a\u68b0\u5e94\u529b\u548c\u53d8\u5f62\u5f15\u8d77\u7684\u5b89\u5168\u6027\u9ad8\u8981\u6c42\u3002\u4f46\u662f\uff0c\u4e0e\u5355\u4ef7\u9502\u79bb\u5b50\u76f8\u6bd4\uff0c\u5d4c\u5165\u5bbf\u4e3b\u6750\u6599\u65f6\uff0c\u66f4\u5927\u539f\u5b50\u8d28\u91cf\u548c\u66f4\u9ad8\u7535\u8377\u5bc6\u5ea6\u7684Zn2+<\/sup>\u79bb\u5b50\u4f1a\u4ea7\u751f\u5927\u7684\u9759\u7535\u6392\u65a5\u529b\u548c\u8f83\u5dee\u7684\u4f20\u8f93\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u5bfc\u81f4\u5c42\u95f4\u8ddd\u589e\u52a0\u548c\u52a0\u5feb\u6676\u4f53\u67b6\u6784\u5f2f\u66f2\u632f\u52a8\uff0c\u6700\u7ec8\u5bfc\u81f4\u6676\u4f53\u7ed3\u6784\u574d\u584c\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u5408\u9002\u950c\u79bb\u5b50\u8131\u5d4c\u7684\u6b63\u6781\u6750\u6599\u4ecd\u7136\u662f\u950c\u79bb\u5b50\u7535\u6c60\u53d1\u5c55\u9762\u4e34\u7684\u91cd\u8981\u6311\u6218\u3002\u76ee\u524d\uff0c\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\uff1b\u5176\u4e2d\uff0c\u9492\u57fa\u548c\u9530\u57fa\u6750\u6599\u7531\u4e8e\u6676\u4f53\u7ed3\u6784\u79cd\u7c7b\u591a\u3001\u4ef7\u683c\u4f4e\u5ec9\u548c\u6bd4\u5bb9\u91cf\u9ad8\u7b49\u4f18\u70b9\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u4f46\u662f\u5bfc\u7535\u6027\u5dee\u3001\u6676\u4f53\u7ed3\u6784\u4e0d\u7a33\u5b9a\u548c\u91d1\u5c5e\u5143\u7d20\uff08V\u548cMn\uff09\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u95ee\u9898\u4f1a\u76f4\u63a5\u5f71\u54cd\u5b83\u4eec\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u9488\u5bf9\u5bfc\u7535\u6027\u5dee\u548c\u7ed3\u6784\u4e0d\u7a33\u5b9a\uff0c\u590d\u5408\u5bfc\u7535\u5242\uff08\u78b3\u8d28\u5bfc\u7535\u5242\u548c\u5bfc\u7535\u805a\u5408\u7269\uff09\u3001\u7eb3\u7c73\u6280\u672f\u3001\u7ed3\u6784\u5de5\u7a0b\uff08\u91d1\u5c5e\u79bb\u5b50\u3001\u7ed3\u6676\u6c34\u4ee5\u53ca\u6709\u673a\u7269\u5d4c\u5165\u6676\u4f53\u7ed3\u6784\uff09\u548c\u7f3a\u9677\u5de5\u7a0b\uff08\u6c27\u7a7a\u4f4d\u548c\u9633\u79bb\u5b50\u7f3a\u9677\uff09\u7b49\u65b9\u6cd5\u5df2\u7ecf\u5f97\u5230\u5e7f\u6cdb\u7814\u7a76\u5e76\u53d6\u5f97\u5de8\u5927\u8fdb\u5c55[<\/sup>1-6<\/sup><\/a>]<\/sup>\u00a0\uff0c\u7136\u800c\uff0c\u5bf9\u4e8e\u6b63\u6781\u6750\u6599\u91d1\u5c5e\u5143\u7d20\uff08V\u548cMn\uff09\u6eb6\u89e3\u7684\u95ee\u9898\u5f80\u5f80\u88ab\u5ffd\u7565\uff0c\u76ee\u524d\u7684\u7814\u7a76\u8f83\u5c11\u3002\u8981\u60f3\u5b9e\u73b0\u950c\u79bb\u5b50\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\uff0c\u6291\u5236\u6b63\u6781\u6750\u6599V\u548cMn\u7684\u6eb6\u89e3\u662f\u6700\u5173\u952e\u7684\u95ee\u9898\u4e4b\u4e00\uff0c\u56e0\u4e3a\u6b63\u6781\u6750\u6599\u7684\u6eb6\u89e3\u4f1a\u964d\u4f4e\u6d3b\u6027\u7269\u8d28\u7684\u5229\u7528\u7387\uff0c\u8bf1\u5bfc\u7535\u6781\u754c\u9762\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u8fdb\u800c\u5f15\u8d77\u7ed3\u6784\u9000\u5316\u548c\u6027\u80fd\u8870\u51cf[<\/sup>7-8<\/sup><\/a>]<\/sup>\u3002\u56e0\u6b64\uff0c\u672c\u6587\u5c31\u76ee\u524d\u4e8c\u6b21\u950c\u79bb\u5b50\u7535\u6c60\u9492\u57fa\u3001\u9530\u57fa\u6b63\u6781\u6750\u6599\u91d1\u5c5e\u5143\u7d20\uff08V\u548cMn\uff09\u6eb6\u89e3\u7684\u76f8\u5173\u7814\u7a76\u60c5\u51b5\u548c\u5927\u5bb6\u4e00\u8d77\u4ea4\u6d41\u5b66\u4e60\u3002<\/p>\n

\u4e00\u3001<\/b><\/strong>\u9530\u57fa\u6b63\u6781\u6750\u6599<\/b><\/strong>Mn<\/b><\/strong>\u6eb6\u89e3\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u9530\u57fa\u6750\u6599\u7531\u4e8e\u6210\u672c\u4f4e\u5ec9\uff0c\u6676\u4f53\u7ed3\u6784\u591a\u6837\u5316\uff0c\u65e0\u6bd2\uff0c\u9ad8\u7406\u8bba\u5bb9\u91cf\u4e0d\u4ec5\u5728\u9502\/\u94a0\/\u94be\u79bb\u5b50\u7535\u6c60\u5f97\u5230\u5e7f\u6cdb\u7814\u7a76\uff0c\u5728\u4e8c\u4ef7\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u540c\u6837\u4e5f\u88ab\u8ba4\u4e3a\u662f\u4e00\u7c7b\u7406\u60f3\u7684\u6b63\u6781\u6750\u6599\u3002\u4f46\u9530\u57fa\u6750\u6599\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u8f6c\u53d8\u548c\u6b67\u5316\u53cd\u5e94\u5f15\u8d77Mn\u6eb6\u89e3\u7684\u95ee\u9898\u662f\u4e0d\u53ef\u907f\u514d\u7684\u3002\u57fa\u4e8e\u6b64\uff0c\u7f8e\u56fd\u897f\u5317\u592a\u5e73\u6d0b\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5218\u4fca\u6559\u6388\u8bfe\u9898\u7ec4\u9996\u5148\u63d0\u51fa\u57282M ZnSO4<\/sub>\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a00.1M MnSO4<\/sub>\u6765\u6291\u5236\u03b1-MnO2<\/sub>\u4e2dMn\u7684\u6eb6\u89e3[<\/sup>9<\/sup><\/a>]<\/sup>\u00a0\u3002\u4ece\u56fe1a\u53ef\u4ee5\u770b\u51fa\uff0c\u4f7f\u7528\u548c\u4e0d\u4f7f\u7528MnSO4<\/sub>\u65f6\uff0c\u90fd\u663e\u793a\u51fa\u76f8\u4f3c\u7684\u6c27\u5316\u8fd8\u539f\u884c\u4e3a\uff0c\u8868\u660eMnSO4<\/sub>\u6dfb\u52a0\u5242\u4e0d\u4f1a\u5f71\u54cd\u03b1-MnO2<\/sub>\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u4f46\u662f\uff0c\u5728ZnSO4<\/sub>\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a0MnSO4<\/sub>\u6dfb\u52a0\u5242\u540e\uff0c\u03b1-MnO2<\/sub>\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd\u5f97\u5230\u4e86\u663e\u7740\u6539\u5584\uff08\u56fe1b\uff09\uff0c\u8fd9\u662f\u7531\u4e8e\u6dfb\u52a0\u7684Mn2+<\/sup>\u80fd\u591f\u4ece\u7535\u6781\u5230\u7535\u89e3\u8d28\u7684\u6eb6\u89e3\u4e4b\u95f4\u63d0\u4f9b\u9002\u5f53\u7684\u5e73\u8861\uff0c\u6291\u5236\u03b1-MnO2<\/sub>\u4e2dMn\u7684\u6eb6\u89e3\uff0c\u4ece\u800c\u5145\u5206\u5229\u7528\u4e86\u7535\u6781\u6750\u6599\u7684\u6d3b\u6027\u7269\u8d28\u3002\u7c7b\u4f3c\u7684\uff0c\u5357\u5f00\u5927\u5b66\u9648\u519b\u9662\u58eb\u8bfe\u9898\u7ec4\u57283M Zn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u7535\u89e3\u8d28\u4e2d\u6dfb\u52a00.1M Mn(CF3<\/sub>SO3<\/sub>)2<\/sub>\uff0cMn2+<\/sup>\u7684\u6dfb\u52a0\u5b9e\u73b0\u4e86Mn2+<\/sup>\u6eb6\u89e3\u548c\u518d\u6c27\u5316\u4e4b\u95f4\u7684\u5e73\u8861\uff0c\u5e76\u6709\u5229\u4e8e\u5728\u03b2-MnO2<\/sub>\u6b63\u6781\u8868\u9762\u5f62\u6210\u5747\u5300\u7684\u975e\u6676\u6001MnOx<\/sub>\u4fdd\u62a4\u5c42\u6765\u4fdd\u6301\u7535\u6781\u5b8c\u6574\u6027[<\/sup>10<\/sup><\/a>]<\/sup>\uff0c\u8fd9\u79cd\u7b56\u7565\u6781\u5927\u5730\u63d0\u9ad8\u4e86Zn-MnO2<\/sub>\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u56fe2\uff09\u3002<\/p>\n

\u56fe1. \uff08a\uff09\u4e24\u79cd\u4e0d\u540c\u7535\u89e3\u6db2\u4e0b\u03b1-MnO2<\/sub>\u7684CV\u66f2\u7ebf\uff0c\uff08b\uff09\u5faa\u73af\u6027\u80fd\u3002[<\/sup>9<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe2.\u4e0d\u540c\u7535\u89e3\u6db2\u7684\u53ef\u5145\u7535Zn-MnO2\u7535\u6c60\u3002<\/span>[<\/sup>10<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe3.\uff08a\uff09\u03b1-MnO2<\/sub>@\u77f3\u58a8\u70ef\u7684TEM\u548cSEAD\u56fe\uff0c\uff08b\uff09\u03b1-MnO2<\/sub>@\u77f3\u58a8\u70ef\u7684HRTEM\uff0c\uff08c\uff09\u500d\u7387\u6027\u80fd\uff0c\uff08d\uff09\u57280.1 A g-1<\/sup>\u7684\u6d3b\u5316\u540e\uff0c\u03b1-MnO2<\/sub>@\u77f3\u58a8\u70ef\u57280.3\u548c1 A g-1<\/sup>\u7684\u5faa\u73af\u6027\u80fd\u3002[<\/sup>11<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u9664\u4e86\u5728\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a0\u9002\u91cf\u7684\u9530\u76d0\uff0c\u5728\u9530\u57fa\u6750\u6599\u5305\u8986\u4fdd\u62a4\u5c42\u4e5f\u53ef\u4ee5\u6291\u5236Mn\u7684\u6eb6\u89e3\uff0c\u56e0\u4e3a\u9530\u6eb6\u89e3\u884c\u4e3a\u4ec5\u53d1\u751f\u5728\u7535\u6781\u4e0e\u7535\u6781\u6db2\u7684\u754c\u9762\u4e0a\u3002\u57fa\u4e8e\u6b64\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u9ea6\u7acb\u5f3a\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u5728\u03b1-MnO2<\/sub>\u6b63\u6781\u8868\u9762\u5305\u88f9\u4e00\u5c42\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\uff08RGO\uff09\uff08\u56fe3a-b\uff09,\u00a0\u8fd9\u5c42RGO\u65e2\u6709\u6548\u63d0\u9ad8\u03b1-MnO2<\/sub>\u7684\u7535\u5bfc\u7387\uff0c\u53c8\u53ef\u4ee5\u6709\u6548\u5730\u6291\u5236\u9530\u6eb6\u89e3\uff0c\u6700\u7ec8\u5b9e\u73b0\u8f83\u597d\u7684\u500d\u7387\u6027\u80fd\u4e0e\u5faa\u73af\u7a33\u5b9a\u6027\u80fd\uff08\u56fe3c-d\uff09[<\/sup>11<\/sup><\/a>]<\/sup>\u00a0\u3002\u53e6\u5916\uff0c\u8003\u8651\u5230\u9502\/\u94a0\u79bb\u5b50\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u819c\u65e2\u80fd\u591f\u5728\u6eb6\u5242\u4e2d\u7a33\u5b9a\u5b58\u5728\uff0c\u8fd8\u53ef\u4ee5\u6709\u6548\u6291\u5236\u6750\u6599\u7684\u6eb6\u89e3\u548c\u6eb6\u5242\u5206\u5b50\u7684\u5171\u5d4c\u4ee5\u53ca\u4fdd\u62a4\u7535\u6781\u6750\u6599\uff1b\u4e2d\u5357\u5927\u5b66\u5468\u6c5f\u6559\u6388\u8bfe\u9898\u7ec4\u5728Ca2<\/sub>MnO4<\/sub>\u6b63\u6781\u8868\u9762\u901a\u8fc7\u539f\u4f4d\u7535\u5316\u5b66\u5145\u7535\u6765\u5f62\u6210\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762CaSO4<\/sub>\u00b72H2<\/sub>O\u5c42\uff08\u56fe4\uff09\uff0c\u8fd9\u79cdSEI\u819c\u80fd\u6709\u6548\u6291\u5236\u9530\u7684\u6eb6\u89e3\uff0c\u964d\u4f4e\u963b\u6297\uff0c\u6539\u5584\u754c\u9762\uff0c\u964d\u4f4e\u6d3b\u5316\u80fd\uff0c\u5e76\u6709\u5229\u4e8e\u950c\u79bb\u5b50\u7684\u53ef\u9006\u8131\u5d4c[<\/sup>12<\/sup><\/a>]<\/sup>\u00a0\u3002\u6b64\u5916\uff0c\u6dfb\u52a0\u5bfc\u7535\u805a\u5408\u7269\uff08PEDOT\uff09\u4fdd\u62a4\u5c42\u4e5f\u80fd\u591f\u6709\u6548\u6291\u5236\u9530\u57fa\u6750\u6599Mn\u7684\u6eb6\u89e3\uff0c\u4f46\u662f\u8fd9\u79cd\u6291\u5236\u673a\u7406\u5e76\u6ca1\u6709\u8fdb\u884c\u8be6\u7ec6\u7684\u9610\u8ff0[<\/sup>13-14<\/sup><\/a>]<\/sup>\u3002\u53e6\u4e00\u79cd\u7b80\u5355\u4e14\u6709\u6548\u7684\u65b9\u6cd5\u5c31\u662f\u901a\u8fc7\u63ba\u6742\u4e0e\u9530\u57fa\u6750\u6599\u80fd\u591f\u7d27\u5bc6\u7ed3\u5408\u7684\u79bb\u5b50\uff0c\u56e0\u4e3a\u4ece\u70ed\u529b\u5b66\u89d2\u5ea6\u51fa\u53d1\uff0c\u7a33\u5b9a\u7684\u6676\u4f53\u7ed3\u6784\u901a\u5e38\u662f\u70ed\u529b\u5b66\u4e0a\u662f\u4e0d\u4f1a\u6eb6\u89e3\u7684\u3002\u57fa\u4e8e\u6b64\uff0c\u4e2d\u5357\u5927\u5b66\u6881\u53d4\u5168\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7K+<\/sup>\u63ba\u6742\u03b1-MnO2<\/sub>\u6765\u6784\u5efa\u7ed3\u6784\u7a33\u5b9a\u4e14\u5bcc\u542b\u6c27\u7f3a\u9677\u7684K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u6b63\u6781\u6750\u6599[<\/sup>15<\/sup><\/a>]<\/sup>\u3002\u6839\u636e\u7535\u611f\u8026\u5408\u7b49\u79bb\u5b50\u4f53\u53d1\u5c04\u5149\u8c31\u6cd5\uff08ICP-OES\uff09\u5bf92 M ZnSO4<\/sub>\u7535\u89e3\u6db2\u4e2dMn\u6d53\u5ea6\u7684\u5206\u6790\u8868\u660e\uff0c\u76f8\u6bd4\u4e8e\u7eaf\u03b1-MnO2<\/sub>\uff0c\u5bcc\u542b\u6c27\u7f3a\u9677\u7684K0.8<\/sub>Mn8<\/sub>O16<\/sub>\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u9530\u5143\u7d20\u7684\u6eb6\u89e3\u53ef\u4ee5\u5f97\u5230\u6709\u6548\u7f13\u89e3\uff08\u56fe5a\uff09\u3002\u8fd9\u79cd\u6709\u6548\u6291\u5236\u9530\u6eb6\u89e3\u7684\u65b9\u6cd5\u662f\u7531\u4e8eK+\u79bb\u5b50\u7a33\u5b9a\u5730\u63d2\u5165\u03b1-MnO2<\/sub>\u7684\u96a7\u9053\u4e2d\uff0c\u5e76\u4e0eMn\u591a\u9762\u4f53\u952e\u5408\u6765\u589e\u5f3a\u6676\u4f53\u7ed3\u6784\u7a33\u5b9a\u6027\uff08\u56fe5b\uff09\u3002<\/p>\n

\u56fe4.\u00a0Ca2<\/sub>MnO4<\/sub>\u6b63\u6781\u6750\u6599SEI\u819c\uff08CaSO4<\/sub>\u00b72H2<\/sub>O\uff09\u7684\u5f62\u6210\u673a\u7406\u3002[<\/sup>12<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe5. \uff08a\uff09MnO2<\/sub>\u548cK0.8<\/sub>Mn8<\/sub>O16<\/sub>\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6eb6\u89e3Mn2+<\/sup>\u7684\u5143\u7d20\u5206\u6790\uff08b\uff09\u63ba\u5165\u7a33\u5b9aMn\u591a\u9762\u4f53\u7684K +\u79bb\u5b50\u7684\u793a\u610f\u56fe\u3002[<\/sup>15<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u4e8c\u3001\u9492\u57fa\u6b63\u6781\u6750\u6599V\u6eb6\u89e3\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\u9664\u4e86\u9530\u57fa\u6750\u6599\uff0c\u9492\u57fa\u6750\u6599\u7684\u591a\u79cd\u6c27\u5316\u6001\uff08V2+<\/sup>,V3+<\/sup>,V4+<\/sup>,V5+<\/sup>\uff09\u548c\u6676\u4f53\u7ed3\u6784\u591a\u6837\u5316\uff08\u5c42\u72b6\uff0c\u96a7\u9053\u7b49\uff09\u65e2\u80fd\u4fc3\u8fdb\u5b9e\u73b0\u5c40\u90e8\u7535\u5b50\u4e2d\u6027\u5e76\u7f13\u89e3Zn2+<\/sup>\u79bb\u5b50\u5d4c\u5165\u5f15\u8d77\u7684\u6781\u5316\u95ee\u9898\uff0c\u4e5f\u80fd\u4e3aZn2+<\/sup>\u5d4c\u5165\/\u8131\u5d4c\u63d0\u4f9b\u4e86\u5e7f\u9614\u7684\u7a7a\u95f4\u5c3a\u5bf8\uff0c\u8fd9\u4f7f\u5b83\u88ab\u8ba4\u4e3a\u662f\u53e6\u4e00\u7c7b\u6781\u5177\u6f5c\u529b\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u6b63\u6781\u6750\u6599\u3002\u76f8\u6bd4\u4e8e\u9530\u57fa\u6750\u6599\uff0c\u9492\u57fa\u6750\u6599\u6709\u66f4\u9ad8\u7684\u6bd4\u5bb9\u91cf\uff0c\u4f46\u4ecd\u9762\u4e34\u7740\u7535\u538b\u5e73\u53f0\u4f4e\u3001\u590d\u6742\u7684\u7535\u5316\u5b66\u50a8\u950c\u673a\u5236\u3001\u7535\u5bfc\u7387\u5dee\u4ee5\u53ca\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2dV\u6eb6\u89e3\u7b49\u95ee\u9898[<\/sup>3<\/sup><\/a>, <\/sup>16<\/sup><\/a>]<\/sup>\u3002\u76ee\u524d\uff0c\u5bf9\u4e8e\u9492\u57fa\u6750\u6599\u7814\u7a76\u5927\u90e8\u5206\u8fd8\u662f\u96c6\u4e2d\u5728\u7535\u5316\u5b66\u53cd\u5e94\u673a\u7406\u7814\u7a76\u4ee5\u53ca\u5982\u4f55\u589e\u52a0\u7535\u5316\u5b66\u6027\u80fd\u548c\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u7b49\u65b9\u9762\uff0c\u5bf9\u4e8e\u9492\u57fa\u6750\u6599\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u7684V\u6eb6\u89e3\u7814\u7a76\u8f83\u5c11\u3002\u4e0e\u9530\u57fa\u6750\u6599\u9884\u589e\u52a0Mn\u76d0\u6dfb\u52a0\u5242\u76f8\u6bd4\uff0c\u9492\u57fa\u6750\u6599\u7531\u4e8e\u5176\u66f4\u7a33\u5b9a\u7684\u6c27\u5316\u6001\u53d8\u4f53\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u800c\u9762\u4e34\u7684V\u6eb6\u89e3\u95ee\u9898\u76f8\u5bf9\u8f83\u5c11\uff0c\u56e0\u6b64\uff0c\u5c1a\u672a\u6709\u62a5\u9053\u8fc7\u9884\u6dfb\u52a0\u9492\u76d0\u7684\u65b9\u6cd5\u6765\u6291\u5236V\u6eb6\u89e3[<\/sup>3<\/sup><\/a>]<\/sup>\u3002\u4f46\u5bf9\u4e8e\u91d1\u5c5e\u9492\u9178\u76d0\u6765\u8bf4\uff0c\u9664\u4e86V\u6eb6\u89e3\u5916\uff0c\u5176\u5b83\u91d1\u5c5e\u4e5f\u6709\u53ef\u80fd\u4f1a\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u53d1\u751f\u6eb6\u89e3\u3002\u8003\u8651\u5230\u8fd9\u4e00\u70b9\uff0c\u5357\u5f00\u5927\u5b66\u9648\u519b\u9662\u58eb\u8bfe\u9898\u7ec4\u57281M ZnSO4<\/sub>\u7535\u89e3\u6db2\u4e2d\u52a0\u51651M Na2<\/sub>SO4<\/sub>\u6765\u7814\u7a76NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u6b63\u6781\u6750\u6599\u7684\u50a8\u950c\u6027\u80fd[<\/sup>17<\/sup><\/a>]<\/sup>\u3002\u4ece\u56fe6a\u53ef\u4ee5\u770b\u51fa\uff0c\u968f\u7740\u5faa\u73af\u6b21\u6570\u7684\u589e\u52a0\uff0c\u5728\u7eafZnSO4<\/sub>\u7535\u89e3\u8d28\u4e2dNaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u6027\u80fd\u6025\u5267\u4e0b\u964d\uff0c\u8fd9\u662f\u56e0\u4e3aNaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u7535\u6781\u4f1a\u5728ZnSO4<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u7684\u5feb\u901f\u6eb6\u89e3\uff08\u56fe6a\u63d2\u56fe\uff09\u3002\u5f53\u52a0\u5165Na2<\/sub>SO4<\/sub>\u76d0\u65f6\uff0cNaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6781\u5927\u5730\u63d0\u9ad8\uff0c\u8fd9\u5f52\u56e0\u4e8e\u52a0\u5165\u7684Na+<\/sup>\u80fd\u6539\u53d8NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u6b63\u6781\u5bf9Na+<\/sup>\u7684\u6eb6\u89e3\u5e73\u8861\u6765\u9650\u5236NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u7684\u8fde\u7eed\u6eb6\u89e3\u3002\u6b64\u5916\uff0c\u6839\u636e\u9759\u7535\u5c4f\u853d\u673a\u7406\uff0c\u901a\u8fc7\u5411\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a0\u8fd8\u539f\u7535\u4f4d\u8f83\u4f4e\u7684Na+<\/sup>\u6b63\u79bb\u5b50\uff0c\u53ef\u4ee5\u907f\u514d\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u679d\u6676\u6c89\u79ef\uff08\u56fe6b\uff09\u3002<\/p>\n

\u56fe6. \uff08a\uff09NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u6b63\u6781\u5728ZnSO4<\/sub>\u7535\u89e3\u8d28\u4e2d\u7684\u5faa\u73af\u6027\u80fd\uff0c\uff08b\uff09Na2<\/sub>SO4<\/sub>\u6dfb\u52a0\u5242\u6291\u5236NVO\u7eb3\u7c73\u5e26\u6eb6\u89e3\u548cZn\u6811\u679d\u72b6\u6676\u4f53\u5f62\u6210\u7684\u793a\u610f\u56fe\uff0c\uff08c\uff09NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u6b63\u6781\u7684CV\u66f2\u7ebf\uff0c\uff08d\uff09NaV3<\/sub>O8<\/sub>\u00b71.5H2<\/sub>O\u6b63\u6781\u57281 A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002[<\/sup>17<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u6b64\u5916\uff0c\u57fa\u4e8e\u524d\u4eba\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u819c\u548c\u6b63\u6781\u6750\u6599\u4fdd\u62a4\u5c42\u7814\u7a76\u7684\u8003\u8651\uff0c\u76ee\u524d\u5728\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6291\u5236\u9492\u57fa\u6750\u6599V\u6eb6\u89e3\u4e5f\u6709\u76f8\u5173\u7684\u62a5\u9053\u3002 \u65af\u5766\u798f\u5927\u5b66\u7684\u5d14\u5c79\u6559\u6388\u4ee5\u53ca\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\u7684Husam N. Alshareef\u6559\u6388\u7b49\u5229\u7528\u539f\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u5728Zn3<\/sub>V2<\/sub>O7<\/sub>(OH)2<\/sub>\u00b72H2<\/sub>O (ZVO)\u6b63\u6781\u8868\u9762\u8986\u76d6\u4e00\u5c42\u5747\u5300\u81f4\u5bc6\u7684HfO2<\/sub>\u8584\u819c\u4f5c\u4e3a\u4eba\u5de5\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u5c42\uff08\u56fe7\uff09[<\/sup>18<\/sup><\/a>]<\/sup>\uff0c\u8fd9\u79cdSEI\u819c\u5145\u5f53\u9694\u79bb\u7535\u6781\u548c\u7535\u89e3\u8d28\u7684\u7b5b\u7f51\uff0c\u80fd\u51cf\u5c11\u6d3b\u6027\u7269\u8d28ZVO\u5728\u7535\u89e3\u8d28\u4e2d\u7684V\u6eb6\u89e3\u5e76\u6291\u5236\u7edd\u7f18\u526f\u4ea7\u7269\u7684\u5f62\u6210\u3002\u5728\u6dfb\u52a0\u6b63\u6781\u6750\u6599\u4fdd\u62a4\u5c42\u65b9\u9762\uff0c\u4e2d\u56fd\u5730\u8d28\u5927\u5b66\u738b\u6b22\u6587\u6559\u6388\u548c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u80e1\u5148\u7f57\u6559\u6388\u901a\u8fc7\u7535\u6c89\u79ef\u5728V2<\/sub>O5<\/sub>\u7eb3\u7c73\u7247\u9635\u5217\u4e0a\u5747\u5300\u751f\u957f\u22485nm\u539a\u5ea6\u7684\u5bfc\u7535PEDOT\u819c\uff08\u56fe8\uff09[<\/sup>19<\/sup><\/a>]<\/sup>\uff0c\u8fd9\u6709\u6548\u5730\u6539\u5584\u4e86V2<\/sub>O5<\/sub>@PEDOT\/CC\u7535\u6781\u7684\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u548c\u950c\u5b58\u50a8\u6027\u80fd\uff0c\u800c\u4e14\u5bfc\u7535\u6027\u78b3\u5e03\u4e0a\u7684\u7eb3\u7c73\u7247\u9635\u5217\u7ed3\u6784\u4e0ePEDOT\u5916\u58f3\u4fdd\u62a4\u5c42\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u6709\u52a9\u4e8e\u5b9e\u73b0\u9ad8\u500d\u7387\u6027\u80fd\u548c\u957f\u5faa\u73af\u6027\u80fd\u3002\u540c\u6837\u5730\uff0c\u6e58\u6f6d\u5927\u5b66\u6768\u5229\u6587\u6559\u6388\u8bfe\u9898\u7ec4\u5728VO2<\/sub>\u5355\u6676\u7eb3\u7c73\u5e26\u8868\u9762\u6d82\u8986\u4e00\u5c42\u224810nm\u539a\u5ea6\u7684PEDOT\u5bfc\u7535\u819c\uff0c\u7531\u4e8e\u4e24\u8005\u7684\u534f\u540c\u6548\u5e94\uff0cVO2<\/sub>@PEDOT\u590d\u5408\u6750\u6599\u4e5f\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u50a8\u950c\u6027\u80fd[<\/sup>20<\/sup><\/a>]<\/sup>\u3002\u53e6\u5916\u4e00\u79cd\u6709\u6548\u6291\u5236V\u6eb6\u89e3\u7684\u65b9\u6cd5\u5c31\u662f\u57fa\u4e8e\u7a33\u5065\u7684\u6676\u4f53\u7ed3\u6784\u3002\u6700\u8fd1\uff0c\u5c71\u4e1c\u5927\u5b66\u718a\u80dc\u6797\u6559\u6388\u8bfe\u9898\u7ec4\u91c7\u7528\u4e00\u6b65\u6c34\u70ed\u5408\u6210\u6cd5\u5236\u5907\u4e86\u4e00\u79cd\u6c34\u5408\u94a1\u79bb\u5b50\u7a33\u5b9a\u7684\u9492\u9178\u94a1\u4f5c\u4e3a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599[<\/sup>21<\/sup><\/a>]<\/sup>\uff0c\u901a\u8fc7\u8c03\u6574\u94a1\u6e90\u7684\u91cf\u5f97\u5230\u8d85\u7a33\u5b9a\u7684\u5c42\u72b6\u7ed3\u6784\u7684Ba1.2<\/sub>V6<\/sub>O16<\/sub>\u00b73H2<\/sub>O\u00a0\uff08BVO-2\uff0cV3<\/sub>O8<\/sub>-type\uff09\uff0c\u4e0e\u5176\u5b83\u4e24\u79cd\u9492\u9178\u94a1\u76f8\u6bd4\uff0c Bax<\/sub>V2<\/sub>O5<\/sub>\u00b7nH2<\/sub>O (BVO-1\uff0cV2<\/sub>O5<\/sub>-type)\u548cBaV6<\/sub>O16<\/sub>\u00b73H2<\/sub>O (BVO-3\uff0cV3<\/sub>O8<\/sub>-type)\uff0cBa1.2<\/sub>V6<\/sub>O16<\/sub>\u00b73H2<\/sub>O\u5177\u6709\u6700\u597d\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u56fe9a-b\uff09\u3002\u7ed3\u5408\u975e\u539f\u4f4dXRD\u548cFTIR\u5206\u6790\uff0cBa1.2<\/sub>V6<\/sub>O16<\/sub>\u00b73H2<\/sub>O\u5728\u950c\u79bb\u5b50\u5d4c\u5165\u8fc7\u7a0b\u4e2d\u5c55\u73b0\u51fa\u6700\u5c0f\u7684\u526f\u4ea7\u7269\u7684\u7279\u5f81\u5cf0\uff0c\u8868\u660e\u526f\u4ea7\u7269\u7684\u751f\u6210\u5f97\u5230\u4e86\u6709\u6548\u6291\u5236\uff0c\u800c\u6b63\u6781\u6750\u6599\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u9759\u6001\u6d78\u6ce1\u5b9e\u9a8c\u8868\u660e\u9492\u6eb6\u89e3\u5f97\u5230\u4e86\u660e\u663e\u6291\u5236\uff08\u56fe9c-e\uff09\u3002\u8fd9\u8bc1\u660e\u4e86\u8d85\u5f3a\u7684\u6676\u4f53\u7ed3\u6784\u7a33\u5b9a\u6027\u80fd\u591f\u6709\u6548\u6291\u5236V\u7684\u6eb6\u89e3\u3002<\/p>\n

\u56fe7. \u539f\u59cbZVO\u6b63\u6781\u548cHfO2<\/sub>\u5305\u8986ZVO\u6b63\u6781\u7684\u539f\u5b50\u5c42\u6c89\u79ef\u5236\u9020\u5de5\u827a\u793a\u610f\u56fe\u3002[<\/sup>18<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe8. \uff08a\uff09\u5236\u5907V2<\/sub>O5<\/sub>@PEDOT\/CC\u7684\u793a\u610f\u56fe\uff0c\uff08b-c\uff09V2<\/sub>O5<\/sub>\/CC\u548c\uff08d-e\uff09V2<\/sub>O5<\/sub>@PEDOT\/CC\u7684SEM\u56fe\u50cf\uff0c\uff08f\uff09SAED\u6a21\u5f0f\uff0c\u4ee5\u53ca\uff08g\uff09V2<\/sub>O5<\/sub>@PEDOT\u7eb3\u7c73\u7247\u9635\u5217\u7684TEM\u56fe\u50cf\u3002[<\/sup>19<\/sup><\/a>]<\/sup><\/p>\n

\"\"<\/p>\n

\u56fe9. \uff08a\uff09\u500d\u7387\u6027\u80fd\uff08b\uff09\u5faa\u73af\u6027\u80fd\u548c\uff08c\uff09BVO-2\u7535\u6781\u7684\u5f02\u4f4dFTIR\u5149\u8c31\u3002\uff08d\uff09\u4e09\u79cd\u9492\u9178\u94a1\u5728\u5b8c\u5168\u653e\u7535\u72b6\u6001\u4e0b\u7684FTIR\u5149\u8c31\uff08e\uff09\u57282 M ZnSO4<\/sub>\u7535\u89e3\u8d28\u4e2d\u4e09\u79cd\u9492\u9178\u94a1\u5728\u4e0d\u540c\u65f6\u95f4\u6bb5\u7684\u5149\u5b66\u56fe\u50cf\u3002[<\/sup>21<\/sup><\/a>]<\/sup><\/p>\n

\"\"
\n \u4e09\u3001\u7ed3\u8bed<\/b><\/strong><\/p>\n

\u603b\u4e4b\uff0c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u8fd1\u4e9b\u5e74\u83b7\u5f97\u5feb\u901f\u53d1\u5c55\u5e76\u53d6\u5f97\u8bb8\u591a\u91cd\u5927\u7684\u8fdb\u5c55\uff0c\u4f46\u771f\u6b63\u8981\u5b9e\u73b0\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\uff0c\u4ecd\u8981\u514b\u670d\u5f88\u591a\u79d1\u5b66\u6280\u672f\u96be\u9898\u3002\u5bf9\u4e8e\u6b63\u6781\u6750\u6599\u6765\u8bf4\uff0c\u5c3d\u7ba1\u9530\u57fa\u548c\u9492\u57fa\u90fd\u8868\u73b0\u51fa\u51fa\u8272\u7684\u6027\u80fd\uff0c\u4f46\u5fc5\u987b\u6ce8\u610f\uff0c\u91d1\u5c5e\u5143\u7d20\uff08V\u548cMn\uff09\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u95ee\u9898\u662f\u4e0d\u53ef\u907f\u514d\u7684\u3002\u7efc\u4e0a\u6240\u8ff0\uff0c\u6291\u5236\u6b63\u6781\u6750\u6599Mn\u548cV\u6eb6\u89e3\u7684\u65b9\u6cd5\u4e3b\u8981\u6709\u4ee5\u4e0b\u51e0\u65b9\u9762\uff1a\uff081\uff09\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u9002\u5f53\u589e\u52a0\u6dfb\u52a0\u5242\uff0c\uff082\uff09\u5728\u7535\u6781\u8868\u9762\u6d82\u8986\u4fdd\u62a4\u5c42\uff08\u77f3\u58a8\u70ef\uff0c\u5bfc\u7535\u805a\u5408\u7269\u4ee5\u53caSEI\u819c\uff09\uff0c\uff083\uff09\u5229\u7528\u201cion pillars\u201d\u6765\u6784\u5efa\u7a33\u5b9a\u7684\u6676\u4f53\u7ed3\u6784\u3002\u9274\u4e8e\u7b14\u8005\u5b66\u8bc6\u6709\u9650\uff0c\u4e0a\u8ff0\u4ecb\u7ecd\u6216\u6709\u758f\u6f0f\u548c\u89e3\u8bfb\u4e0d\u5230\u4f4d\u4e4b\u5904\uff0c\u8fd8\u671b\u5404\u4f4d\u8bfb\u8005\u8fa9\u8bc1\u770b\u5f85\uff0c\u5e0c\u671b\u770b\u5b8c\u672c\u6587\u80fd\u591f\u5e2e\u52a9\u5927\u5bb6\u5bf9\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u9492\u57fa\u548c\u9530\u57fa\u6b63\u6781\u6750\u6599\u7684\u6eb6\u89e3\u95ee\u9898\u6709\u8fdb\u4e00\u6b65\u7684\u4e86\u89e3\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

[1] Zhang, N.; Chen, X.; Yu, M.; Niu, Z.; Cheng, F.; Chen, J. Materials chemistry for rechargeable zinc-ion batteries. Chemical Society reviews <\/i><\/em>2020<\/b><\/strong>, DOI: 10.1039\/c9cs00349e.<\/p>\n

[2] Zhang, Y.; Tao, L.; Xie, C.; Wang, D.; Zou, Y.; Chen, R.; Wang, Y.; Jia, C.; Wang, S. Defect Engineering on Electrode Materials for Rechargeable Batteries. Advanced materials <\/i><\/em>2020,<\/b><\/strong>\u00a032<\/i><\/em>\u00a0(7), e1905923, DOI: 10.1002\/adma.201905923.<\/p>\n

[3] Mathew, V.; Sambandam, B.; Kim, S.; Kim, S.; Park, S.; Lee, S.; Alfaruqi, M. H.; Soundhararajan, V.; Islam, S.; Putro, D. Y.; Hwang, J.-Y.; Sun, Y.-K.; Kim, J. Manganese and Vanadium Oxide Cathodes for Aqueous Rechargeable Zinc-ion Batteries: A Focused View on Performance, Mechanism and Developments. ACS Energy Letters <\/i><\/em>2020<\/b><\/strong>, DOI: 10.1021\/acsenergylett.0c00740.<\/p>\n

[4] Wan, F.; Niu, Z. Design Strategies for Vanadium-based Aqueous Zinc-Ion Batteries. Angew Chem Int Ed Engl <\/i><\/em>2019,<\/b><\/strong>\u00a058<\/i><\/em>\u00a0(46), 16358-16367, DOI: 10.1002\/anie.201903941.<\/p>\n

[5] Ling, W.; Wang, P.; Chen, Z.; Wang, H.; Wang, J.; Ji, Z.; Fei, J.; Ma, Z.; He, N.; Huang, Y. Nanostructure Design Strategies for Aqueous Zinc\u2010Ion Batteries. ChemElectroChem <\/i><\/em>2020<\/b><\/strong>, DOI: 10.1002\/celc.202000372.<\/p>\n

[6] Blanc, L. E.; Kundu, D.; Nazar, L. F. Scientific Challenges for the Implementation of Zn-Ion Batteries. Joule <\/i><\/em>2020,<\/b><\/strong>\u00a04<\/i><\/em>\u00a0(4), 771-799, DOI: 10.1016\/j.joule.2020.03.002.<\/p>\n

[7] Tang, B.; Shan, L.; Liang, S.; Zhou, J. Issues and opportunities facing aqueous zinc-ion batteries. Energy & Environmental Science <\/i><\/em>2019,<\/b><\/strong>\u00a012<\/i><\/em>\u00a0(11), 3288-3304, DOI: 10.1039\/c9ee02526j.<\/p>\n

[8] Yang, G.; Li, Q.; Ma, K.; Hong, C.; Wang, C. The degradation mechanism of vanadium oxide-based aqueous zinc-ion batteries. Journal of Materials Chemistry A <\/i><\/em>2020,<\/b><\/strong>\u00a08<\/i><\/em>\u00a0(16), 8084-8095, DOI: 10.1039\/d0ta00615g.<\/p>\n

[9] Pan, H.; Shao, Y.; Yan, P.; Cheng, Y.; Han, K. S.; Nie, Z.; Wang, C.; Yang, J.; Li, X.; Bhattacharya, P.; Mueller, K. T.; Liu, J. Reversible aqueous zinc\/manganese oxide energy storage from conversion reactions. Nature Energy <\/i><\/em>2016,<\/b><\/strong>\u00a01<\/i><\/em>\u00a0(5), DOI: 10.1038\/nenergy.2016.39.<\/p>\n

[10] Zhang, N.; Cheng, F.; Liu, J.; Wang, L.; Long, X.; Liu, X.; Li, F.; Chen, J. Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities. Nature communications <\/i><\/em>2017,<\/b><\/strong>\u00a08<\/i><\/em>\u00a0(1), 405, DOI: 10.1038\/s41467-017-00467-x.<\/p>\n

[11] Wu, B.; Zhang, G.; Yan, M.; Xiong, T.; He, P.; He, L.; Xu, X.; Mai, L. Graphene Scroll-Coated alpha-MnO2 Nanowires as High-Performance Cathode Materials for Aqueous Zn-Ion Battery. Small <\/i><\/em>2018,<\/b><\/strong>\u00a014<\/i><\/em>\u00a0(13), e1703850, DOI: 10.1002\/smll.201703850.<\/p>\n

[12] Guo, S.; Liang, S.; Zhang, B.; Fang, G.; Ma, D.; Zhou, J. Cathode Interfacial Layer Formation via in Situ Electrochemically Charging in Aqueous Zinc-Ion Battery. ACS nano <\/i><\/em>2019,<\/b><\/strong>\u00a013<\/i><\/em>\u00a0(11), 13456-13464, DOI: 10.1021\/acsnano.9b07042.<\/p>\n

[13] Zeng, Y.; Zhang, X.; Meng, Y.; Yu, M.; Yi, J.; Wu, Y.; Lu, X.; Tong, Y. Achieving Ultrahigh Energy Density and Long Durability in a Flexible Rechargeable Quasi-Solid-State Zn-MnO2 Battery. Advanced materials <\/i><\/em>2017,<\/b><\/strong>\u00a029<\/i><\/em>\u00a0(26), DOI: 10.1002\/adma.201700274.<\/p>\n

[14] Zhang, H. Extracting Oxygen Anions from ZnMn2O4: Robust Cathode for Flexible All-Solid-State Zn-Ion Batteries. Energy Storage Materials <\/i><\/em>2018<\/b><\/strong>, DOI: 10.1016\/j.ensm.2018.12.019.<\/p>\n

[15] Fang, G.; Zhu, C.; Chen, M.; Zhou, J.; Tang, B.; Cao, X.; Zheng, X.; Pan, A.; Liang, S. Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High\u2010Energy\u2010Density and Durable Aqueous Zinc\u2010Ion Battery. Advanced Functional Materials <\/i><\/em>2019,<\/b><\/strong>\u00a029<\/i><\/em>\u00a0(15), 1808375, DOI: 10.1002\/adfm.201808375.<\/p>\n

[16] Liu, S.; Kang, L.; Kim, J. M.; Chun, Y. T.; Zhang, J.; Jun, S. C. Recent Advances in Vanadium\u2010Based Aqueous Rechargeable Zinc\u2010Ion Batteries. Advanced Energy Materials <\/i><\/em>2020<\/b><\/strong>, 2000477, DOI: 10.1002\/aenm.202000477.<\/p>\n

[17] Wan, F.; Zhang, L.; Dai, X.; Wang, X.; Niu, Z.; Chen, J. Aqueous rechargeable zinc\/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers. Nature communications <\/i><\/em>2018,<\/b><\/strong>\u00a09<\/i><\/em>\u00a0(1), 1656, DOI: 10.1038\/s41467-018-04060-8.<\/p>\n

[18] Guo, J.; Ming, J.; Lei, Y.; Zhang, W.; Xia, C.; Cui, Y.; Alshareef, H. N. Artificial Solid Electrolyte Interphase for Suppressing Surface Reactions and Cathode Dissolution in Aqueous Zinc Ion Batteries. ACS Energy Letters <\/i><\/em>2019,<\/b><\/strong>\u00a04<\/i><\/em>\u00a0(12), 2776-2781, DOI: 10.1021\/acsenergylett.9b02029.<\/p>\n

[19] Xu, D.; Wang, H.; Li, F.; Guan, Z.; Wang, R.; He, B.; Gong, Y.; Hu, X. Conformal Conducting Polymer Shells on V2O5Nanosheet Arrays as a High-Rate and Stable Zinc-Ion Battery Cathode. Advanced Materials Interfaces <\/i><\/em>2019,<\/b><\/strong>\u00a06<\/i><\/em>\u00a0(2), 1801506, DOI: 10.1002\/admi.201801506.<\/p>\n

[20] Liu, X.; Xu, G.; Zhang, Q.; Huang, S.; Li, L.; Wei, X.; Cao, J.; Yang, L.; Chu, P. K. Ultrathin hybrid nanobelts of single-crystalline VO2 and Poly(3,4-ethylenedioxythiophene) as cathode materials for aqueous zinc ion batteries with large capacity and high-rate capability. Journal of Power Sources <\/i><\/em>2020,<\/b><\/strong>\u00a0463<\/i><\/em>, 228223, DOI: 10.1016\/j.jpowsour.2020.228223.<\/p>\n

[21] Wang, X.; Xi, B.; Ma, X.; Feng, Z.; Jia, Y.; Feng, J.; Qian, Y.; Xiong, S. Boosting Zinc-Ion Storage Capability by Effectively Suppressing Vanadium Dissolution Based on Robust Layered Barium Vanadate. Nano letters <\/i><\/em>2020,<\/b><\/strong>\u00a020<\/i><\/em>\u00a0(4), 2899-2906, DOI: 10.1021\/acs.nanolett.0c00732.<\/p>\n

\u672c\u6587\u7531Fred Lan\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u950c\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u4e00\u79cd\u73af\u5883\u53cb\u597d\u3001\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u6027\u548c\u6781\u5177\u6f5c\u529b\u7684\u65b0\u578b\u5927\u89c4\u6a21\u50a8\u80fd\u7cfb\u7edf\u5728\u8fd1\u4e9b\u5e74\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\uff0c\u5c24\u5176\u662f\u5728\u67d4\u6027\u53ef\u7a7f\u6234\u7535\u5b50\u4ea7\u54c1\u7814\u7a76\u4e2d\uff0c\u56e0\u4e3a\u4f20\u7edf\u7684\u9502\u79bb\u5b50\u7535\u6c60\u5728\u4f7f…<\/p>\n","protected":false},"author":11454,"featured_media":204423,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-204413","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/204413"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=204413"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/204413\/revisions"}],"predecessor-version":[{"id":204588,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/204413\/revisions\/204588"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/204423"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=204413"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=204413"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=204413"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}