{"id":203967,"date":"2020-06-24T06:19:23","date_gmt":"2020-06-23T22:19:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=203967"},"modified":"2020-06-23T21:19:35","modified_gmt":"2020-06-23T13:19:35","slug":"%e6%9b%b2%e8%89%af%e4%bd%93%e6%95%99%e6%8e%88angew%ef%bc%9a%e7%a9%ba%e9%97%b4%e7%94%b5%e8%8d%b7%e5%af%86%e5%ba%a6%e6%9c%80%e5%a4%a7%e5%8c%96-%e8%b6%85%e9%ab%98%e8%83%bd%e9%87%8f%e5%af%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=203967","title":{"rendered":"\u66f2\u826f\u4f53\u6559\u6388Angew\uff1a\u7a7a\u95f4\u7535\u8377\u5bc6\u5ea6\u6700\u5927\u5316\u2014\u8d85\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7535\u5bb9\u578b\u7535\u8377\u5b58\u50a8"},"content":{"rendered":"<p>\u3010\u524d\u8a00\u3011<\/p>\n<p>\u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u5177\u6709\u529f\u7387\u5bc6\u5ea6\u9ad8\u3001\u5faa\u73af\u5bff\u547d\u957f\u3001\u5b89\u5168\u6027\u597d\u7b49\u4f18\u70b9\uff0c\u4f46\u76f8\u5bf9\u8f83\u4f4e\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e25\u91cd\u5236\u7ea6\u4e86\u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u5f52\u6839\u7ed3\u5e95\uff0c\u9650\u5236\u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u80fd\u91cf\u5bc6\u5ea6\u7684\u4e3b\u8981\u56e0\u7d20\u662f\u5176\u8f83\u4f4e\u7684\u7a7a\u95f4\u7535\u8377\u5bc6\u5ea6\uff08SCD\uff09\uff0c\u5373\u5355\u4f4d\u7a7a\u95f4\u5185\u8f7d\u6d41\u5b50\uff08\u6216\u7535\u8377\uff09\u7684\u6570\u91cf\u76f8\u5bf9\u8f83\u5c11\uff1b\u4e00\u822c\u800c\u8a00\uff0c\u7a7a\u95f4\u7535\u8377\u5bc6\u5ea6\u8d8a\u5927\uff0c\u5176\u80fd\u91cf\u5bc6\u5ea6\u5c31\u8d8a\u9ad8\u3002\u4ece\u79bb\u5b50\u8f7d\u6d41\u5b50\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u7535\u6c60\u578b\u7535\u6781\u6750\u6599\u662f\u5bf9\u5b8c\u5168\u53bb\u6eb6\u5242\u5316\u7684\u88f8\u79bb\u5b50\u7684\u81f4\u5bc6\u6709\u5e8f\u5b58\u50a8\uff0c\u56e0\u6b64\u5177\u6709\u5f88\u9ad8\u7684\u7a7a\u95f4\u7535\u8377\u5bc6\u5ea6\uff1b\u800c\u4f20\u7edf\u7535\u5bb9\u578b\u7535\u6781\u6750\u6599\u5185\u90e8\u5219\u662f\u6563\u4e71\u5206\u5e03\u7684\u5c3a\u5bf8\u5de8\u5927\u7684\u6eb6\u5242\u5316\u79bb\u5b50\uff0c\u8fd9\u5c31\u51b3\u5b9a\u4e86\u5176\u6709\u9650\u7684\u7a7a\u95f4\u7535\u8377\u5bc6\u5ea6\u3002\u53d7\u7535\u6c60\u578b\u7535\u6781\u6750\u6599\u7535\u8377\u5b58\u50a8\u673a\u5236\u7684\u542f\u53d1\uff0c\u5f00\u53d1SCD\u6700\u5927\u5316\u7b56\u7565\uff0c\u4e5f\u5c31\u662f\u5c06\u6eb6\u5242\u5316\u79bb\u5b50\u81f4\u5bc6\u6709\u5e8f\u5730\u6392\u5e03\u5728\u7535\u5bb9\u578b\u7535\u6781\u6750\u6599\u4e2d\u5c06\u6709\u671b\u5f25\u8865\u8fd9\u79cd\u4e0d\u8db3\u3002<\/p>\n<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n<p>\u6700\u8fd1\uff0c<strong>\u6e05\u534e\u5927\u5b66\u66f2\u826f\u4f53\u6559\u6388<\/strong>\u9886\u5bfc\u7684\u79d1\u7814\u56e2\u961f\u5728\u56fd\u9645\u77e5\u540d\u671f\u520a<strong>Angewandte Chemie International Edition<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a<strong>Maximization of Spatial Charge Density: An Approach to Ultrahigh Energy Density of Capacitive Charge Storage<\/strong>\u7684\u8bba\u6587\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cdSCD\u6700\u5927\u5316\u7b56\u7565\uff0c\u4ee5\u63d0\u9ad8\u7535\u5bb9\u578b\u7535\u8377\u5b58\u50a8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff1b\u5177\u4f53\u800c\u8a00\uff0c\u5c31\u662f\u5c06\u6eb6\u5242\u5316\u7684\u91d1\u5c5e\u79bb\u5b50\u81f4\u5bc6\u6709\u5e8f\u5730\u6392\u5e03\u5728\u7535\u6781\u6750\u6599\u5185\u90e8\u3002\u901a\u8fc7\u5e73\u8861\u6eb6\u5242\u5316\u79bb\u5b50\u7684\u4ef7\u6001\uff0c\u5e76\u5c06\u6eb6\u5242\u5316\u79bb\u5b50\u7684\u5c3a\u5bf8\u4e0e\u7535\u6781\u6750\u6599\u7684\u5b54\u9699\u7ed3\u6784\u8fdb\u884c\u5339\u914d\uff0c\u8be5\u5de5\u4f5c\u5b9e\u73b0\u4e86~ 550 C cm<sup>-3<\/sup>\u7684\u8d85\u9ad8SCD,\u8fd9\u4e00\u6570\u503c\u6bd4\u4f20\u7edf\u591a\u5b54\u78b3\u4f53\u7cfb\u9ad8\u51fa\u8fd1\u4e94\u500d(~ 120 C cm<sup>-3<\/sup>)\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u5229\u7528Monte Carlo\u8ba1\u7b97,\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df,\u548c\u539f\u4f4d\u7535\u5316\u5b66\u62c9\u66fc\u5149\u8c31\u6765\u8ffd\u8e2a\u5404\u79cd\u591a\u4ef7\u91d1\u5c5e\u79bb\u5b50\u5728\u7535\u5bb9\u6750\u6599\u7684\u7535\u5316\u5b66\u884c\u4e3a,\u5e76\u53d1\u73b0\u5b83\u4eec\u7684\u90e8\u5206\u8131\u6c34\u8fc7\u7a0b\u662f\u6eb6\u5242\u5316\u79bb\u5b50\u5339\u914d\u5e76\u8fdb\u5165\u4e9a\u7eb3\u7c73\u5b54\u9699\u7684\u5fc5\u8981\u6b65\u9aa4\u3002\u5728\u6b64\u57fa\u7840\u4e0a,\u4f5c\u8005\u6784\u5efa\u4e86\u950c\u79bb\u5b50\u7535\u5bb9\u5668\uff0c\u8be5\u950c\u79bb\u5b50\u7535\u5bb9\u5668\u5728150 W L<sup>-1<\/sup>\u7684\u529f\u7387\u5bc6\u5ea6\u4e0b\u8868\u73b0\u51fa165 W h L<sup>-1<\/sup>\u7684\u8d85\u9ad8\u80fd\u91cf\u5bc6\u5ea6,\u572836W L<sup>-1<\/sup>\u7684\u8d85\u9ad8\u529f\u7387\u5bc6\u5ea6\u4e0b\uff0c\u5176\u4ecd\u80fd\u4fdd\u6301120 W h L<sup>-1<\/sup>\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u8fd9\u4e9b\u4f18\u5f02\u7684\u6027\u80fd\u6709\u529b\u5730\u8bc1\u660e\u4e86\u6240\u63d0\u51fa\u7684SCD\u6700\u5927\u5316\u7b56\u7565\u63d0\u9ad8\u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u80fd\u91cf\u5bc6\u5ea6\u7684\u6709\u6548\u6027\u548c\u5408\u7406\u6027\u3002<\/p>\n<p>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n<p>\u56fe1. SCD\u6700\u5927\u5316\u7b56\u7565\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-203968 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/1-11.png\" alt=\"\" width=\"701\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/1-11.png 701w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/1-11-300x179.png 300w\" sizes=\"(max-width: 701px) 100vw, 701px\" \/><\/p>\n<p>a\uff09\u7535\u6c60\u578b\u7535\u6781\u6750\u6599\u4e2d\u88f8\u79bb\u5b50\u7684\u6392\u5e03\uff1bb\uff09\u7535\u5bb9\u578b\u7535\u6781\u6750\u6599\u4e2d\u6eb6\u5242\u5316\u79bb\u5b50\u7684\u6392\u5e03\uff1bc\uff09\u5728HOPC\u4e2d\u81f4\u5bc6\u6709\u5e8f\u5730\u5b58\u50a8\u6eb6\u5242\u5316\u79bb\u5b50\u4ee5\u5b9e\u73b0\u8d85\u9ad8SCD\uff1bd\uff09\u5178\u578b\u7684\u6eb6\u5242\u5316\u9633\u79bb\u5b50\u7684\u7ed3\u6784\uff0c\u5706\u5f62\u4ee3\u8868\u6eb6\u5242\u5316\u58f3\uff08\u9876\u9762\u677f\uff09\uff1b\u4e0d\u540c\u534a\u5f84\u7684\u5404\u79cd\u79bb\u5b50\u7684\u793a\u610f\u56fe\uff08\u5e95\u9762\u677f\uff09\uff1b\u7535\u5316\u5b66\u6d3b\u5316\u524d\u540e\uff0c\u81f4\u5bc6HOPC\u4e2d\u4e0d\u540c\u79bb\u5b50\u7684\u6392\u5e03\uff1ae\uff09\u4e00\u4ef7\u79bb\u5b50\uff0cf\uff09\u4e8c\u4ef7\u79bb\u5b50\uff0cg\uff09\u4e09\u4ef7\u79bb\u5b50\u3002<\/p>\n<p>\u56fe2. \u4e0d\u540c\u79bb\u5b50\u5728AC\u548cHOPC\u4e2d\u7684\u7535\u5316\u5b66\u884c\u4e3a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-203969 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/2-9.png\" alt=\"\" width=\"665\" height=\"509\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/2-9.png 665w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/2-9-300x230.png 300w\" sizes=\"(max-width: 665px) 100vw, 665px\" \/><\/p>\n<p>a)\u57281 A g<sup>-1<\/sup>\u65f6AC\u548cHOPC\u7684\u8d28\u91cf\u548c\u4f53\u79ef\u6bd4\u7535\u5bb9\uff1bAC\u548cHOPC\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684\u524d10\u5708CV\u66f2\u7ebf\uff1ab)NaNO<sub>3<\/sub>, c)Zn(NO<sub>3<\/sub>)<sub>2<\/sub>, d)Al(NO<sub>3<\/sub>)<sub>3<\/sub>, e)ZnSO<sub>4<\/sub>\uff1bf) HOPC\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684\u963b\u6297\uff1bg)\u5b9e\u90e8\u963b\u6297(Z\u2019)\u5bf9\u89d2\u9891\u7387(\u03c9<sup>-1\/2<\/sup>)\u5728\u4f4e\u9891\u533a\u57df\u7684\u7ebf\u6027\u66f2\u7ebf\uff0c\u53cah\uff09\u8ba1\u7b97\u6240\u5f97\u7684\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u3002<\/p>\n<p>\u56fe3. HOPC\u7684\u79bb\u5b50\u7b5b\u6548\u5e94\u53ca\u5b54\u7ed3\u6784\u4e0e\u79bb\u5b50\u5c3a\u5bf8\u5339\u914d\u539f\u5219<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-203970 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/3-8.png\" alt=\"\" width=\"544\" height=\"571\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/3-8.png 544w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/3-8-286x300.png 286w\" sizes=\"(max-width: 544px) 100vw, 544px\" \/><\/p>\n<p>AC\u548cHOPC\u7684N<sub>2<\/sub>\u5438\/\u8131\u9644\u7b49\u6e29\u7ebfa)\u53ca\u76f8\u5e94\u7684PSD\u66f2\u7ebfb)\uff1bc)\u6eb6\u5242\u5316\u79bb\u5b50\u90e8\u5206\u8131\u6c34\u793a\u610f\u56fe\uff1bd)\u8ba1\u7b97\u6240\u5f97\u7684Zn<sup>2+<\/sup>\u79bb\u5b50\u5728\u9010\u6e10\u7f29\u5c0f\u7684\u5b54\u9699\u5185\u7684\u6784\u578b\uff1be)\u81ea\u7531\u80fd\u968f\u5b54\u9699\u534a\u5f84\u7684\u53d8\u5316\uff1bf)\u76f8\u5bf9\u81ea\u7531\u80fd\u968f\u5b54\u9699\u534a\u5f84\u7684\u53d8\u5316\uff1bg) HOPC\u5728\u7535\u5316\u5b66\u6d3b\u5316\u8fc7\u7a0b\u4e2d\u7684\u5b9e\u65f6EIS\u56fe\uff1bh) Zn<sup>2+<\/sup>\u79bb\u5b50\u5728\u81f4\u5bc6\u7684HOPC\u4e2d\u7684\u7535\u5316\u5b66\u884c\u4e3a\u5168\u56fe\uff1bi)\u6eb6\u5242\u5316\u79bb\u5b50\u90e8\u5206\u8131\u6c34\u540e\u8fdb\u5165\u5b54\u9699\u7684\u8fc7\u7a0b\uff1bj) HOPC\u5b8c\u5168\u653e\u7535\u72b6\u6001\u7684HAADF-STEM\u56fe\u50cf\uff0c\u5bc6\u96c6\u7684\u4eae\u6591\u663e\u793a\u4e86\u5b58\u50a8\u5728HOPC\u4e2d\u7684Zn<sup>2+<\/sup>\u79bb\u5b50\u3002<\/p>\n<p>\u56fe4. HOPC\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u539f\u4f4d\u7535\u5316\u5b66\u62c9\u66fc\u5149\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-203971 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/4-6.png\" alt=\"\" width=\"689\" height=\"461\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/4-6.png 689w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/4-6-300x201.png 300w\" sizes=\"(max-width: 689px) 100vw, 689px\" \/><\/p>\n<p>\u65b0\u9c9c\u7684HOPC\u7535\u6781\uff08a-c\uff09\u548c\u6d3b\u5316\u540e\u7684HOPC\u7535\u6781\uff08d-f\uff09\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684\u539f\u4f4d\u7535\u5316\u5b66\u62c9\u66fc\u5149\u8c31\uff1aa, d)NaNO<sub>3<\/sub>, b, e)Zn(NO<sub>3<\/sub>)<sub>2<\/sub>, c, f)Al(NO<sub>3<\/sub>)<sub>3<\/sub>, \u7ea2\u8272\u548c\u84dd\u8272\u7b49\u9ad8\u7ebf\u5206\u522b\u8868\u793a\u9ad8\u62c9\u66fc\u5f3a\u5ea6\u548c\u4f4e\u62c9\u66fc\u5f3a\u5ea6\u3002<\/p>\n<p>\u56fe5. 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Chem. Int. Ed.<\/em> <strong>2020<\/strong>, DOI: 10.1002\/anie.202005270<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91luna\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u5fae\u4fe1cailiaorenvip<\/p>\n<p>&nbsp;<\/p>\n<p>\u76f8\u5173\u6587\u732e<\/p>\n<p>Hongyun Ma, Hongya Geng, Bowen Yao, Mingmao Wu, Chun Li, Miao Zhang, Fengyao Chi, and Liangti Qu\uff0cHighly Ordered Graphene Solid: An Efficient Platform for Capacitive Sodium-Ion Storage with Ultrahigh Volumetric Capacity and Superior Rate Capability\uff0c<em>ACS Nano<\/em>\u00a0<strong>2019<\/strong>, <em>13<\/em>, 9161\u20139170.<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u524d\u8a00\u3011 \u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u5177\u6709\u529f\u7387\u5bc6\u5ea6\u9ad8\u3001\u5faa\u73af\u5bff\u547d\u957f\u3001\u5b89\u5168\u6027\u597d\u7b49\u4f18\u70b9\uff0c\u4f46\u76f8\u5bf9\u8f83\u4f4e\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e25\u91cd\u5236\u7ea6\u4e86\u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u5f52\u6839\u7ed3\u5e95\uff0c\u9650\u5236\u7535\u5bb9\u578b\u50a8\u80fd\u5668\u4ef6\u80fd\u91cf\u5bc6&#8230;<\/p>\n","protected":false},"author":12975,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-203967","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/203967"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/12975"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=203967"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/203967\/revisions"}],"predecessor-version":[{"id":203978,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/203967\/revisions\/203978"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=203967"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=203967"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=203967"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}