{"id":203611,"date":"2020-06-28T06:44:40","date_gmt":"2020-06-27T22:44:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=203611"},"modified":"2020-06-27T22:44:56","modified_gmt":"2020-06-27T14:44:56","slug":"%e6%b5%99%e5%a4%a7%e9%82%a2%e5%8d%8e%e6%96%8c%e6%95%99%e6%8e%88adv-mater-%e7%94%a8%e4%ba%8e%e4%b9%99%e7%82%94%e4%b8%8e%e4%b9%99%e7%83%af%e7%9a%84%e9%80%89%e6%8b%a9%e6%80%a7%e5%88%86%e7%a6%bb","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=203611","title":{"rendered":"\u6d59\u5927\u90a2\u534e\u658c\u6559\u6388Adv. Mater.:\u7528\u4e8e\u4e59\u7094\u4e0e\u4e59\u70ef\u7684\u9009\u62e9\u6027\u5206\u79bb\u7684\u79bb\u5b50\u578b\u8d85\u5fae\u5b54\u805a\u5408\u7269\u7684\u5236\u5907"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

\u4e59\u70ef\u662f\u77f3\u6cb9\u5316\u5b66\u5de5\u4e1a\u7684\u57fa\u7840\u539f\u6599\uff0c\u901a\u8fc7\u70c3\u7c7b\u7269\u8d28\u88c2\u89e3\u751f\u4ea7\u7684\u4e59\u70ef\u4e0d\u53ef\u907f\u514d\u5730\u542b\u6709\u5c11\u91cf\u4e59\u7094\uff0c\u5bfc\u81f4\u805a\u5408\u53cd\u5e94\u50ac\u5316\u5242\u7684\u5931\u6d3b\u548c\u5bf9\u805a\u4e59\u70ef\u7684\u8d28\u91cf\u4ea7\u751f\u4e0d\u5229\u7684\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u4e59\u7094\u548c\u4e59\u70ef\u7684\u5206\u79bb\u5fc5\u4e0d\u53ef\u5c11\u3002\u4f46\u662f\uff0c\u8fd9\u4f9d\u7136\u662f\u4e00\u9879\u6311\u6218\uff0c\u56e0\u4e3a\u5b83\u4eec\u7684\u5206\u5b50\u7ed3\u6784\u76f8\u4f3c\uff0c\u7269\u5316\u6027\u8d28\u76f8\u8fd1\u3002\u5b83\u4eec\u5728\u52a8\u529b\u5b66\u76f4\u5f84\u548c\u9178\u6027\u4e0a\u5b58\u5728\u7684\u5fae\u5c0f\u5dee\u5f02\uff0c\u4f7f\u5b83\u4eec\u7684\u5206\u79bb\u5177\u6709\u53ef\u80fd\u6027\u3002\u5f88\u591a\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u548c\u6c22\u952e\u6709\u673a\u9aa8\u67b6\u7528\u4e8e\u4e59\u7094\/\u4e59\u70ef\u5206\u79bb\uff0c\u5177\u6709\u4f18\u5f02\u7684\u9009\u62e9\u6027\uff0c\u7136\u800c\u8fd9\u4e9b\u6750\u6599\u5728\u957f\u671f\u7a33\u5b9a\u6027\u4e0a\u4ecd\u9762\u4e34\u6311\u6218\u3002\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u548c\u591a\u5b54\u82b3\u9999\u9aa8\u67b6\u7528\u4e8e\u4e59\u7094\/\u4e59\u70ef\u5206\u79bb\uff0c\u9009\u62e9\u6027\u4f4e\u3002\u76ee\u524d\u4e3a\u6b62\uff0c\u65e0\u5b9a\u5f62\u6709\u673a\u805a\u5408\u7269\u7528\u4e8e\u4e59\u7094\/\u4e59\u70ef\u5206\u79bb\u8fd8\u6ca1\u88ab\u62a5\u9053\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u90a2\u534e\u658c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u901a\u8fc7\u5171\u4ef7\u548c\u79bb\u5b50\u53cc\u91cd\u4ea4\u8054\u7b56\u7565\uff0c\u7528\u8d85\u652f\u5316\u4e24\u4eb2\u6027\u79bb\u5b50\u578b\u5355\u4f53\u8fdb\u884c\u7b80\u5355\u7684\u81ea\u7531\u57fa\u805a\u5408\u53cd\u5e94\uff0c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u65b0\u578b\u7684\u79bb\u5b50\u578b\u8d85\u5fae\u5b54\u805a\u5408\u7269 (IUPs) \u3002\u5171\u4ef7\u548c\u79bb\u5b50\u53cc\u91cd\u4ea4\u8054\u7b56\u7565\u8d4b\u4e88IUPs\u9ad8\u9634\u79bb\u5b50\u5bc6\u5ea6\u548c\u7a84\u5206\u5e03\u7684\u8d85\u5fae\u5b54\u9699\uff0c\u57fa\u4e8e\u9634\u79bb\u5b50\u5f3a\u6c22\u952e\u8bc6\u522b\u4f5c\u7528\u548c\u5c3a\u5bf8\u7b5b\u5206\u673a\u5236\uff0cIUPs\u5177\u6709\u51fa\u8272\u7684\u4e59\u7094\/\u4e59\u70ef\u5206\u79bb\u6027\u80fd\u3002\u5b83\u4eec\u5bf9\u4e59\u7094\/\u4e59\u70ef\u4f53\u7cfb\u5177\u6709\u521b\u5386\u53f2\u65b0\u9ad8\u7684\u9009\u62e9\u6027\u3002\u5b83\u4eec\u8868\u73b0\u51fa\u5bf9\u4e8e\u4e59\u7094\u548c\u4e59\u70ef\u7684\u6c14\u4f53\u6df7\u5408\u7269\u7684\u4f18\u5f02\u7684\u56fa\u5b9a\u5e8a\u5206\u79bb\u6027\u80fd\u3001\u51fa\u8272\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u6c34\u7a33\u5b9a\u6027\u4ee5\u53ca\u663e\u8457\u7684\u5faa\u73af\u4f7f\u7528\u6027\u80fd\u3002\u5b83\u4eec\u7684\u7ed3\u6784\u548c\u6027\u80fd\u7684\u8c03\u8282\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u5355\u4f53\u7684\u7ed3\u6784\u548c\/\u6216\u8005\u9634\u79bb\u5b50\u7684\u79cd\u7c7b\u6765\u5b9e\u73b0\u3002\u5b83\u4eec\u662f\u7b2c\u4e00\u79cd\u5bf9\u4e59\u7094\u548c\u4e59\u70ef\u5b9e\u73b0\u9ad8\u9009\u62e9\u6027\u5206\u79bb\u7684IUPs\u3002\u4e0a\u8ff0\u6210\u679c\u53d1\u8868\u4e8e\u56fd\u9645\u671f\u520aAdv. Mater.\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1.IUPs\u7684\u8868\u5f81<\/p>\n

\"\"<\/p>\n

a) \u8d85\u652f\u5316\u4e24\u4eb2\u6027\u652f\u5316\u7684\u548c\u4e24\u4eb2\u7684\u79bb\u5b50\u578b\u5355\u4f53Ph-3MVIm-Br\u76843D\u5206\u5b50\u6a21\u578b<\/p>\n

b)\u79bb\u5b50\u578b\u8d85\u5fae\u5b54\u805a\u5408\u7269P(Ph3MVIm-Br)\u7684\u56fa\u600113<\/sup>C NMR\u8c31\u56fe<\/p>\n

c)\u6e29\u5ea6\u4e3a195 K\u4e0bP(Ph3MVIm-Br)\u7684CO2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\u548c\u6e29\u5ea6\u5206\u522b\u4e3a77 K\u548c298 K\u4e0bP(Ph3MVIm-Br)\u7684N2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n

d)P(Ph-3MVIm-Br)\u7684\u5b54\u5f84\u5206\u5e03<\/p>\n

e)P(Ph-3MVIm-Br)\u7684\u6b63\u7535\u5b50\u6e6e\u6ca1\u5bff\u547d\u8c31\uff08PALS\uff09<\/p>\n

f)P(Ph-3MVIm-Br)\u7684SEM\u56fe<\/p>\n

\u56fe2.\u7531\u5177\u6709\u4e0d\u540c\u8d85\u652f\u5316\u7ed3\u6784\u7684\u79bb\u5b50\u578b\u5355\u4f53\u5236\u5907\u5f97\u5230\u7684\u79bb\u5b50\u578b\u805a\u5408\u7269\u7684\u8868\u5f81<\/p>\n

\"\"<\/p>\n

a)\u6e29\u5ea6\u4e3a195 K\u4e0bP(Ph-6MVIm-Br)\u3001P(Ph-3MVIm-Br)\u3001P(Ph-2MVIm-Br)\u3001P(C2-2MVIm-Br)\u3001P(EVIm-Br)\u548cPh-3MVIm-Br\u7684CO2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n

b)P(Ph-6MVIm-Br)\u3001P(Ph-3MVIm-Br)\u3001P(Ph-2MVIm-Br)\u548cP(C2-2MVIm-Br)\u7684\u5b54\u5f84\u5206\u5e03<\/p>\n

c,d)Ph-6MVIm-Br (c)\u548cPh-2MVIm-Br (d)\u7684\u5206\u5b50\u7ed3\u6784<\/p>\n

\u56fe3.\u79bb\u5b50\u578b\u805a\u5408\u7269\u7684\u4f4e\u78b3\u70c3\u5206\u79bb\u6027\u80fd<\/p>\n

\"\"<\/p>\n

a,b)\u6e29\u5ea6\u4e3a298 K\u4e0bP(Ph-3MVIm-Cl)(a)\u548cP(Ph-3MVIm-SiF6<\/sub>) (b)\u7684\u4e59\u7094\u548c\u4e59\u70ef\u7684\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n

c)\u6e29\u5ea6\u4e3a298 K\u548c\u538b\u529b\u4e3a1 bar\u7684\u6761\u4ef6\u4e0b\uff0c P(Ph-3MVIm-Cl)\u3001P(Ph-3MVIm-SiF6<\/sub>)\u3001CTF-PO71\u3001 PAF-110\u3001SIFSIX-2-Cu-i\u3001SIFSIX-1-Cu\u3001M\u2019MOF-3a\u3001NOTT-300\u548cFeMOF-74\u5bf9\u4e59\u7094\/\u4e59\u70ef\u7684IAST\u5206\u79bb\u9009\u62e9\u6027\u968f\u4e59\u7094\u7ec4\u6210\u53d8\u5316\u7684\u5bf9\u6bd4\u56fe<\/p>\n

d)\u4e59\u7094\u548c\u4e59\u70ef\u7684\u7b49\u91cf\u5438\u9644\u70ed\u66f2\u7ebf\u5bf9\u6bd4\u56fe\uff08Qst<\/sub>\uff09<\/p>\n

e)\u6e29\u5ea6\u4e3a298 K\u4e0bP(Ph-6MVIm-Br)\u3001P(Ph-3MVIm-Br)\u3001P(Ph-2MVIm-Br)\u548cP(EVIm-Br)\u7684\u4e59\u7094\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n

f)\u6e29\u5ea6\u4e3a298 K\u4e0bP(Ph-3MVIm-Cl)\u3001P(Ph-3MVIm-SiF6<\/sub>)\u3001P(Ph-3MVIm-Br)\u3001P(Ph-3MVImBF4<\/sub>)\u548cP(Ph-3MVIm-Tf2<\/sub>N)\u7684\u4e59\u7094\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n

\u56fe4.P(Ph-3MVIm-Br)\u7684\u5206\u5b50\u6a21\u62df\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

a,b) P(Ph-3MVIm-Br) \u5206\u5b50\u6a21\u578b\u5b54\u9699\u8d2f\u901a\u6027\u7684\u53ef\u89c6\u5316\u5bf9\u6bd4\u56fe\uff0c\u534a\u5f84\u5927\u5c0f1.20 \u00c5\uff08a\uff09\u548c 1.55 \u00c5\uff08b\uff09\u4f5c\u4e3a\u63a2\u9488\u5206\u5b50\uff0c\u7eff\u8272\u548c\u7ea2\u8272\u5206\u522b\u4ee3\u8868\u8d2f\u901a\u548c\u4e0d\u8d2f\u901a\u7684\u5b54\u9699<\/p>\n

c) \u5b54\u5f84\u5206\u5e03\u989c\u8272\u56fe\uff0c\u5b54\u76f4\u5f84\u7684\u8303\u56f480-9.10 \u00c5<\/p>\n

d) \u6e29\u5ea6\u4e3a298 K\u4e0b\uff0c\u4e59\u7094\u4e59\u70ef\u6a21\u62df\u548c\u5b9e\u9a8c\u5438\u9644\u7b49\u6e29\u7ebf\u5bf9\u6bd4\u56fe<\/p>\n

e)P(Ph-3MVIm-Br)\u7684\u5b54\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u5305\u62ec\u79bb\u5b50\u7b3c\uff08\u6de1\u9ec4\u8272\uff09\u548c\u5b54\u901a\u9053\uff08\u6de1\u84dd\u8272\uff09<\/p>\n

f)\u5171\u4ef7\u548c\u79bb\u5b50\u53cc\u91cd\u4ea4\u8054\u7b56\u7565\u7684\u793a\u610f\u56fe<\/p>\n

g)P(Ph-3MVIm-Br)\u7684\u4e59\u7094\u5438\u9644\u6a21\u62df\u793a\u610f\u56fe<\/p>\n

\u56fe5.\u56fa\u5b9a\u5e8a\u7a7f\u900f\u5b9e\u9a8c\u548c\u7a33\u5b9a\u6027\u5b9e\u9a8c\u7684\u7ed3\u679c<\/p>\n

\"\"<\/p>\n

a)P(Ph3MVIm-Br)\u5728 298 K \u548c 1 bar \u5bf9\u4e59\u7094\/\u4e59\u70ef\u6df7\u5408\u6c14\u4f53\uff081% C2<\/sub>H2<\/sub> 99% C2<\/sub>H4<\/sub>\uff09\u56fa\u5b9a\u5e8a\u7a7f\u900f\u66f2\u7ebf<\/p>\n

b) \u5bf9\u4e59\u7094\/\u4e59\u70ef\u6df7\u5408\u6c14\u4f53\uff081\/99\uff09\u56fa\u5b9a\u5e8a\u7a7f\u900f\u5faa\u73af\u5b9e\u9a8c<\/p>\n

c)\u7a33\u5b9a\u6027\u5b9e\u9a8c<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u7814\u7a76\u56e2\u961f\u7528\u5171\u4ef7\u548c\u79bb\u5b50\u53cc\u91cd\u4ea4\u8054\u7b56\u7565\u5236\u5907\u4e86\u65b0\u578b\u7684IUPs\u3002\u5b83\u4eec\u5177\u6709\u9ad8\u5bc6\u5ea6\u7684\u65e0\u673a\u9634\u79bb\u5b50\u548c\u7a84\u5206\u5e03\u7684\u8d85\u5fae\u5b54\u9699\u3002\u5b83\u4eec\u5c55\u73b0\u51fa\u5bf9\u4e59\u7094\/\u4e59\u70ef\u4f53\u7cfb\u5177\u6709\u4f18\u5f02\u7684\u5206\u79bb\u9009\u62e9\u6027\u4ee5\u53ca\u51fa\u8272\u7684\u6c34\u70ed\u7a33\u5b9a\u6027\u548c\u5faa\u73af\u4f7f\u7528\u6027\u80fd\u3002\u8fd9\u9879\u7814\u7a76\u7ed9\u7528\u4e8e\u5176\u5b83\u6df7\u5408\u6c14\u4f53\u7684\u5206\u79bb\u7684\u5176\u5b83\u8d85\u5fae\u5b54\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSynthesis of Ionic Ultramicroporous Polymers for Selective Separation of Acetylene from Ethylene<\/a><\/strong>\uff08Adv. Mater. 2020,DOI: 10.1002\/adma.201907601\uff09<\/p>\n

\u56e2\u961f\u4ecb\u7ecd\u5982\u4e0b\uff1a\u6d59\u6c5f\u5927\u5b66\u5316\u5b66\u5de5\u7a0b\u4e0e\u751f\u7269\u5de5\u7a0b\u5b66\u9662\u4f4e\u78b3\u70c3\u4e0e\u836f\u7269\u5206\u79bb\u8bfe\u9898\u7ec4\u957f\u671f\u4ece\u4e8b\u5148\u8fdb\u5206\u79bb\u6750\u6599\u4e0e\u5206\u79bb\u5de5\u7a0b\u3001\u9ad8\u7eaf\u5316\u5b66\u54c1\u5236\u9020\u7b49\u7684\u7814\u7a76\uff0c\u8fd1\u5e74\u6765\u5728Science<\/span><\/i>\uff0c<\/i>Science Advances<\/span><\/i>\u7b49\u671f\u520a\u4e0a\u53d1\u8868\u5b66\u672f\u8bba\u6587150<\/span>\u4f59\u7bc7\uff0c\u66fe\u83b7\u56fd\u5bb6\u6280\u672f\u53d1\u660e\u4e8c\u7b49\u5956\u3001\u4e2d\u56fd\u767e\u7bc7\u6700\u5177\u5f71\u54cd\u529b\u5b66\u672f\u8bba\u6587\u3001\u6d59\u6c5f\u7701\u79d1\u6280\u8fdb\u6b65\u4e00\u7b49\u5956\u3001\u4e2d\u56fd\u77f3\u5316\u8054\u5408\u4f1a\u9752\u5e74\u79d1\u6280\u7a81\u51fa\u8d21\u732e\u5956\u7b49\u5956\u52b1\u3002<\/div>\n

\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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