{"id":203143,"date":"2020-06-20T06:43:04","date_gmt":"2020-06-19T22:43:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=203143"},"modified":"2020-06-19T21:43:23","modified_gmt":"2020-06-19T13:43:23","slug":"%e5%af%bc%e7%94%b5mof-%e9%9b%86%e6%9c%89%e6%9c%ba%e6%97%a0%e6%9c%ba%e6%9d%90%e6%96%99%e4%bc%98%e7%82%b9%e4%ba%8e%e4%b8%80%e8%ba%ab%e7%9a%84%e6%9d%90%e6%96%99%e6%96%b0%e6%98%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=203143","title":{"rendered":"\u5bfc\u7535MOF\u2014\u2014\u96c6\u6709\u673a\u65e0\u673a\u6750\u6599\u4f18\u70b9\u4e8e\u4e00\u8eab\u7684\u6750\u6599\u65b0\u661f"},"content":{"rendered":"

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\u4e00\u3001\u5bfc\u7535MOF\u7b80\u4ecb\u53ca\u53d1\u5c55\u5386\u7a0b<\/strong><\/p>\n

\u56fe1. \u5bfc\u7535MOF\u53d1\u5c55\u5386\u7a0b\u4e2d\u91cd\u8981\u65f6\u95f4\u70b9[1]<\/sup><\/p>\n

\"\"<\/p>\n

\u91d1\u5c5e\u2014\u6709\u673a\u6846\u67b6\uff08Metal-Organic Framework, MOF\uff09\uff0c\u4e5f\u79f0\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\uff08Porous Coordination Polymer, PCP\uff09\uff0c\u5177\u6709\u4e30\u5bcc\u591a\u6837\u3001\u53ef\u8bbe\u8ba1\u526a\u88c1\u7684\u6846\u67b6\u548c\u5b54\u7ed3\u6784\uff0c\u8868\u9762\u79ef\u5927\uff0c\u529f\u80fd\u53ef\u8c03\uff0c\u53ef\u4ee5\u8bf4\u662f\u4e00\u79cd\u4ecb\u4e8e\u65e0\u673a\u6750\u6599\u548c\u6709\u673a\u6750\u6599\u4e4b\u95f4\u7684\u6742\u5316\u6750\u6599\uff0c\u5176\u7279\u6b8a\u7684\u6846\u67b6\u7ed3\u6784\u5728\u50ac\u5316\uff0c\u7535\u6c60\uff0c\u80fd\u6e90\u50a8\u5b58\u7b49\u9886\u57df\u4e2d\u6709\u7740\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u4f46\u662f\u5927\u591a\u6570MOF\u90fd\u4e0d\u5bfc\u7535\uff0c\u5176\u6781\u4f4e\u7684\u7535\u5bfc\u7387\u9650\u5236\u4e86MOF\u5728\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n

2009\u5e74\uff0c\u65e5\u672c\u4eac\u90fd\u5927\u5b66\u7684Hiroshi Kitagawa[2]<\/sup>\u6559\u6388\u8bfe\u9898\u7ec4\u7387\u5148\u5f00\u5c55\u4e86\u5bfc\u7535MOF\u7684\u7814\u7a76\u30022012\u5e74\uff0c\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u5316\u5b66\u7cfbOmar M. Yaghi\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u901a\u8fc7\u03c0-d\u5171\u8f6d\u5bfc\u7535\u7684\u4e8c\u7ef4\u5c42\u72b6MOF[3]<\/sup>\uff1aCu-CAT\u5728\u5ba4\u6e29\u4e0b\u7535\u5bfc\u7387\u8fbe\u5230\u4e860.2 S cm-1<\/sup>\uff0c\u5bfc\u7535MOF\u5f00\u59cb\u9010\u6e10\u88ab\u5e94\u7528\u5728\u7535\u50ac\u5316\u3001\u70ed\u7535\u6548\u5e94\u3001\u6c14\u4f53\u5206\u79bb\u7b49\u9886\u57df\u30022015\u5e74\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7684\u5f90\u4f1f\u548c\u6731\u9053\u672c\u7814\u7a76\u5458\u62a5\u9053\u4e86\u5bfc\u7535MOF\u00a0Cu-BHT[4]<\/sup>\uff0c\u5176\u7535\u5bfc\u7387\u8fbe\u5230\u4e86\u8d85\u9ad8\u76841580 S\u00a0cm-1<\/sup>\uff0c\u81ea\u6b64\uff0c\u5bfc\u7535MOF\u8fce\u6765\u4e86\u4e95\u55b7\u5f0f\u7684\u53d1\u5c55\u30022018\u5e74\uff0c\u65af\u5766\u798f\u5927\u5b66\u9c8d\u54f2\u5357\u8bfe\u9898\u7ec4\u53d1\u73b0\u4e86\u4e00\u7c7b\u6027\u8d28\u7a33\u5b9a\u3001\u5408\u6210\u65b9\u6cd5\u7b80\u5355\u7684\u5bfc\u7535MOF\uff1aCu-HAB[5]<\/sup>\uff0cCo-HAB[6]<\/sup>\uff0c\u5728\u7535\u5bb9\u5668\u548c\u7535\u6c60\u65b9\u9762\u5177\u6709\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n

\u4e8c\u3001\u5bfc\u7535MOF\u7684\u5bfc\u7535\u673a\u7406<\/strong><\/p>\n

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\u56fe2. \u5bfc\u7535MOF\u4e2d\u53ef\u80fd\u7684\u5bfc\u7535\u673a\u5236<\/p>\n

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\u4e09\u3001\u5bfc\u7535MOF\u7684\u6784\u5efa\u65b9\u5f0f<\/strong><\/p>\n

a\u901a\u8fc7\u4ef7\u952e<\/strong><\/p>\n

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\u57282009\u5e74\uff0cTakaishi[2]<\/sup>\u7b49\u4eba\u62a5\u9053\u7684\u6700\u65e9\u7684\u5bfc\u7535MOF\u4e4b\u4e00Cu[Cu(pdt)2<\/sub>]\uff08pdt = 2,3-\u5421\u55ea\u4e8c\u786b\u9178\u916f\uff09\uff0c\u5c31\u662f\u901a\u8fc7\u4ef7\u952e\u7684\u65b9\u6cd5\u6784\u7b51\u5bfc\u7535MOF\u3002\u5176\u7535\u5bfc\u7387\u4e3a6\u00d710-4<\/sup>\u00a0S cm-1<\/sup>\uff08300 K\uff09\uff0c\u70ed\u6d3b\u5316\u80fd\u4e3a0.193 eV\u3002Cu(II)\u79bb\u5b50\u548cpdt\u914d\u4f53\u901a\u8fc7N\u539f\u5b50\u6865\u63a5\u5f62\u6210\u65b9\u5f62\u4e8c\u7ef4\u7247[Cu(pyrazine)]\uff0c\u8fd9\u4e9b[Cu(pyrazine)]\u7247\u53c8\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u94dc\u53cc\uff08\u4e8c\u786b\u4ee3\u70ef\uff09\u5355\u5143\u8fde\u63a5\u4ee5\u5f62\u6210\u56db\u65b9\u6676\u683c\uff08\u56fe3\uff09\u3002\u4e24\u4e2a\u5e73\u884c\u7684pdt\u914d\u4f53\u4e4b\u95f4\u7684\u6700\u77ed\u8ddd\u79bb\uff086.82\u00c5\uff09\u6bd4pdt\u914d\u4f53\u4e4b\u95f4\u7684\u8303\u5fb7\u534e\u8ddd\u79bb\u957f\u5f97\u591a\uff0c\u6392\u9664\u4e86\u901a\u8fc7\u7a7a\u95f4\u65b9\u6cd5\u5b9e\u73b0\u7535\u8377\u4f20\u8f93\u7684\u53ef\u80fd\u6027\u3002\u5177\u6709\u9ad8\u80fd\u91cf\u7684d9 Cu(II)\u7684\u9ad8\u80fd\u4e0d\u6210\u5bf9\u7535\u5b50\u901a\u8fc7\u589e\u52a0\u7535\u8377\u5bc6\u5ea6\u63d0\u9ad8\u4e86\u7535\u5bfc\u7387\uff0c\u5e76\u4e14\u7535\u8377\u8f7d\u6d41\u5b50\u66f4\u5bb9\u6613\u901a\u8fc7\u94dc\u53cc\uff08\u4e8c\u786b\u4ee3\u70ef\uff09\u5355\u5143\u7a7f\u8fc7[Cu(pyrazine)]\u8584\u7247\u4f20\u8f93\u3002<\/p>\n

\u56fe3. Cu[Cu(pdt)2<\/sub>]\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u7eff\u8272Cu\uff1b\u9ec4\u8272S\uff1b\u7070\u8272C\uff1b\u84dd\u8272N\uff1b\u7c89\u7ea2\u8272H\u3002<\/p>\n

\"\"<\/p>\n

b\u901a\u8fc7\u7a7a\u95f4<\/strong><\/p>\n

\u53d7\u5206\u5b50\u548c\u805a\u5408\u7269\u6709\u673a\u5bfc\u4f53\u548c\u534a\u5bfc\u4f53\u7684\u542f\u53d1\uff0c\u4f8b\u5982tetrathiafulvalene-tetracyanoquino-dimethane (TTF-TCNQ, TTF = tetrathiafulvalene, TCNQ = 7,7,8,8-tetracyanoquinodimethane)\uff0c\u5176\u4e2d\u03c0\u00b7\u00b7\u00b7\u03c0\u5806\u79ef\u4f53\u7cfb\u8868\u73b0\u51fa\u8d85\u5bfc\u6027\uff0c\u901a\u8fc7\u914d\u4f53-\u914d\u4f53\u03c0\u00b7\u00b7\u00b7\u03c0\u5806\u79ef\u7b56\u7565\u4e5f\u5f00\u59cb\u7528\u4e8e\u6784\u5efa\u5bfc\u7535MOF\u3002\u901a\u8fc7\u7a7a\u95f4\u7684\u65b9\u6cd5\u6784\u7b51\u5bfc\u7535MOF\u662f\u901a\u8fc7\u5177\u6709\u7535\u5316\u5b66\u6d3b\u6027\u7247\u6bb5\u4e4b\u95f4\u7684\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\uff08\u4f8b\u5982\u03c0-\u03c0\u5806\u79ef\uff09\u6784\u5efa\u7535\u8377\u4f20\u8f93\u9014\u5f84\uff0c\u56e0\u4e3a\u521a\u6027\u7684MOF\u7ed3\u6784\u53ef\u4ee5\u5f3a\u5236\u7d27\u5bc6\u5806\u79ef\u5e76\u5728\u76f8\u90bb\u914d\u4f53\u4e4b\u95f4\u5f62\u6210\u8db3\u591f\u7684\u8f68\u9053\u91cd\u53e0\u3002<\/p>\n

2012\u5e74\uff0cNarayan[7]<\/sup>\u7b49\u4eba\u9996\u5148\u62a5\u9053\u4e86\u540c\u65f6\u5177\u6709\u6c38\u4e45\u5b54\u9699\u7387\u548c\u9ad8\u7535\u8377\u8fc1\u79fb\u7387\u7684\u5bfc\u7535MOF\uff08FPTRMC\u6d4b\u5f97\u7535\u8377\u8fc1\u79fb\u7387\u4e3a0.2 cm2<\/sup>\u00a0V-1<\/sup>\u00a0s-1<\/sup>\uff09\uff0c\u901a\u8fc7\u5229\u7528\u76f8\u90bb\u7535\u6d3b\u6027\u5c0f\u5206\u5b50\u7684\u03c0\u5806\u4f5c\u4e3a\u7535\u8377\u4f20\u8f93\u9014\u5f84\u800c\u5b9e\u73b0\u5bfc\u7535\u3002\u7528\u56db\u786b\u5bcc\u74e6\u70ef-\u56db\u82ef\u7532\u9178\u916f(H4<\/sub>TTFTB)\u5408\u6210Zn2<\/sub>(TTFTB)\u00a0MOF\uff0c\u8be5MOF\u5305\u542b\u89d2\u5171\u4eab\u516b\u9762\u4f53\u914d\u4f4d\u7684Zn2+<\/sup>\u7684\u87ba\u65cb\u94fe\u548c\u7531\u56db\u786b\u5bcc\u74e6\u70ef\u548c\u82ef\u7532\u9178\u916f\u7684\u67f1\u72b6\u53e0\u5c42\u6784\u6210\u7684\u65e0\u9650\u4e00\u7ef4\u901a\u9053\uff08\u56fe4\uff09\u3002<\/p>\n

\u56fe4. Zn2<\/sub>(TTFTB)\u00a0MOF\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u968f\u540e\uff0cPark[8]<\/sup>\u7b49\u57282015\u5e74\u5408\u6210\u5e76\u7814\u7a76\u4e86\u4e00\u7cfb\u5217\u540c\u6784M2<\/sub>(TTFTB) (M = Mn, Co, Zn, and Cd)\u3002\u7ed3\u679c\u8868\u660e\uff0c\u80fd\u5e26\u7684\u5206\u6563\u5ea6\u548c\u7535\u5bfc\u7387\u4e0eS\u00b7\u00b7\u00b7S\u8ddd\u79bb\u9ad8\u5ea6\u76f8\u5173\uff0c\u800cS\u00b7\u00b7\u00b7S\u8ddd\u79bb\u4e0e\u91d1\u5c5e\u79bb\u5b50\u7684\u79bb\u5b50\u534a\u5f84\u5448\u53cd\u76f8\u5173\u3002\u5177\u6709\u8f83\u5927\u79bb\u5b50\u534a\u5f84\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u4f1a\u5ef6\u957f\u91d1\u5c5e\u7fa7\u9178\u76d0\u94fe\u7684\u957f\u5ea6\uff0c\u8fd9\u53ef\u80fd\u4f1a\u5939\u4f4fTTF\u5806\u6808\uff0c\u4ece\u800c\u5bfc\u81f4\u66f4\u77ed\u7684\u5206\u5b50\u95f4S\u00b7\u00b7\u00b7S\u8ddd\u79bb\u3002S\u00b7\u00b7\u00b7S\u8ddd\u79bb\u8d8a\u77ed\uff0c\u76f8\u90bb\u7684S\u548cC\u539f\u5b50\u7684pz\u8f68\u9053\u91cd\u53e0\u8d8a\u597d\uff0c\u5e76\u4e14\u80fd\u5e26\u5206\u6563\u5f97\u8d8a\u5bbd\u3002\u800c\u5bf9\u4e8e\u5b8c\u7f8e\u7684\u5355\u6676\uff0c\u5bbd\u7684\u80fd\u5e26\u4f1a\u4ea7\u751f\u80fd\u5e26\u4f20\u8f93\uff0c\u56e0\u6b64\u7535\u8377\u8fc1\u79fb\u7387\u8f83\u9ad8\u3002\u5728\u6b64\u7cfb\u5217\u4e2d\uff0c\u5177\u6709\u6700\u5927\u9633\u79bb\u5b50\u534a\u5f84(Cd2+<\/sup>)<\/sub>\u7684Cd2<\/sub>(TFTB)\u5177\u6709\u6700\u77ed\u7684S\u00b7\u00b7\u00b7S\u8ddd\u79bb\uff083.65\u00c5\uff09\u548c\u6700\u5927\u7684\u7535\u5bfc\u73872.86\u00d710-4<\/sup>\u00a0S cm-1<\/sup>\uff0c\u6709\u610f\u601d\u7684\u662f\u5c0f\u4e8e5%\u7684S\u00b7\u00b7\u00b7S\u8ddd\u79bb\u53d8\u5316\u80fd\u591f\u5c06\u7535\u5bfc\u7387\u63d0\u9ad8\u5c06\u8fd172\u500d(Zn2<\/sub>(TFTB):3.77\u00c5\uff0c3.95\u00d710-6<\/sup>\u00a0S cm-1<\/sup>\uff09\u3002<\/p>\n

c\u901a\u8fc7\u5ba2\u4f53\u5206\u5b50\u540e\u4fee\u9970<\/strong><\/p>\n

\u9664\u4e86\u4ee5\u4e0a\u4e24\u79cd\u5e38\u89c1\u7b56\u7565\u5916\uff0c\u7531\u4e8eMOF\u7684\u591a\u5b54\u6027\uff0c\u5f15\u5165\u5ba2\u4f53\u5206\u5b50\u4e5f\u662f\u63d0\u9ad8\u7535\u5bfc\u7387\u7684\u53e6\u4e00\u79cd\u6709\u6548\u7b56\u7565\u3002\u5ba2\u4f53\u5206\u5b50\u672c\u8eab\u53ef\u4ee5\u5145\u5f53\u7535\u8377\u8f7d\u4f53\uff0c\u5bf9\u4e8e\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u5ba2\u4f53\u5206\u5b50\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5ba2\u4f53-\u6846\u67b6\u76f8\u4e92\u4f5c\u7528\u5145\u5f53\u7535\u8377\u63ba\u6742\u5242\u3002<\/p>\n

\u91d1\u5c5e\u79bb\u5b50\u548c\u6709\u673a\u914d\u4f53\u4e4b\u95f4\u7684\u8f68\u9053\u91cd\u53e0\u5dee\u901a\u5e38\u4f1a\u4f7fMOF\u6210\u4e3a\u7edd\u7f18\u4f53\u3002\u56e0\u6b64\uff0c\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u5ba2\u4f53\u5206\u5b50\u5df2\u88ab\u5e7f\u6cdb\u7528\u4e8e\u6539\u5584\u7edd\u7f18\u6846\u67b6\u7684\u7535\u5bfc\u7387\u3002I2<\/sub>\u662f\u4f7f\u7528\u6700\u5e7f\u6cdb\u7684\u63ba\u6742\u5242\uff0c\u65e9\u671f\uff0cKobayashi[9]<\/sup>\u62a5\u544a\u4e86\u4e00\u4e2a\u975e\u5e38\u5178\u578b\u7684\u4f8b\u5b50\uff0c\u572850\u2103\u4e0b\u5c06Cu[Ni(pdt)2<\/sub>]\u819c\u66b4\u9732\u4e8eI2<\/sub>\u84b8\u6c14\u4f1a\u4f7fCu[Ni(pdt)2<\/sub>]\u7684\u7535\u5bfc\u7387\u4ece1\u00d710-8<\/sup>\u00a0S cm-1<\/sup>\u589e\u5927\u52301\u00d710-4 <\/sup>S cm-1<\/sup>\uff0c\u6d3b\u5316\u80fd\u4ece0.49 eV\u4e0b\u964d\u52300.18 eV\u3002I2<\/sub>\u7684\u63ba\u6742\u91cf\u5f88\u5c0f\uff0c\u8868\u660e\u662f\u901a\u8fc7\u6846\u67b6\u800c\u4e0d\u662f\u901a\u8fc7I2<\/sub>\u5ba2\u4f53\u5206\u5b50\u53d1\u751f\u4e86\u5bfc\u7535\u884c\u4e3a\u3002<\/p>\n

Talin[10]<\/sup>\u7b49\u4eba\u8bc1\u660e\u4e86\u5c06\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u5171\u8f6d\u5206\u5b50\u4f5c\u4e3a\u5ba2\u4f53\u5206\u5b50\u6e17\u900f\u5230MOFs\u9aa8\u67b6\u4e2d\u80fd\u591f\u4ea7\u751f\u6709\u6548\u7684\u7535\u5b50\u4f20\u5bfc\u9014\u5f84\u3002\u5728\u8986\u76d6\u6709SiO2<\/sub>\u7684\u7845\u7247\u4e0a\u751f\u957f\u5177\u6709\u6700\u4f73\u53d6\u5411\u7684\u591a\u6676Cu3<\/sub>(BTC)2<\/sub>\uff08BTC = 1,3,5-\u4e09\u7fa7\u9178\u76d0\uff09\u8584\u819c\uff08\u56fe5\uff09\uff0c\u8584\u819c\u7684\u7535\u5bfc\u7387\u975e\u5e38\u4f4e\uff0810-6<\/sup>\u00a0S cm-1<\/sup>\uff09\u3002\u7528TCNQ\u6e17\u900f\u540e\uff0c\u7535\u5bfc\u7387\u589e\u52a0\u4e86\u516d\u4e2a\u6570\u91cf\u7ea7\uff0c\u8fbe\u52300.07 S cm-1<\/sup>\uff0c\u6846\u67b6\u7684\u5b54\u9699\u7387\u4e5f\u4fdd\u6301\u4e0b\u6765\u4e86\u3002<\/p>\n

\u56fe5. Cu3<\/sub>(BTC)2<\/sub>\u4e2d\u63ba\u6742TCNQ\u793a\u610f\u56fe\u53caSEM\u56fe<\/p>\n

\"\"<\/p>\n

\u56db\u3001\u5bfc\u7535MOF\u7684\u5e94\u7528\u9886\u57df<\/strong><\/p>\n

a\u7535\u50ac\u5316<\/strong><\/p>\n

Huang[11]<\/sup>\u7b49\u63a2\u7d22\u4e86\u5177\u6709\u4e0d\u540c\u5f62\u6001\u7684Cu-BHT\u7684HER\u6027\u80fd\uff1a\u8584\u819c\uff0c\u7eb3\u7c73\u6676\u4f53\u548c\u65e0\u5b9a\u5f62\u7eb3\u7c73\u7c92\u5b50\u3002\u5728pH = 0\u7684\u6eb6\u6db2\u4e2d\uff0c\u8d1f\u8f7d\u5728\u73bb\u7483\u78b3\u7535\u6781\u4e0a\u7684Cu-BHT\u7eb3\u7c73\u6676\u4f53\u572810 mAcm-2<\/sup>\u4e0b\u8d85\u7535\u52bf\u4e3a760 mV\uff0c\u6bd4\u7eb3\u7c73\u9897\u7c92\uff08450 mV\uff09\u9ad8\uff0c\u8fd9\u662f\u56e0\u4e3a\u7eb3\u7c73\u9897\u7c92\u7684\u7c92\u5f84\u5c0f\u5f97\u591a\uff0c\u5e76\u4e14\u5177\u6709\u52a8\u6001\u5149\u6563\u5c04\u7684\u7ed3\u679c\u3002\u7eb3\u7c73\u7c92\u5b50Cu-BHT\uff0895 mVdec-1<\/sup>\uff09\u7684Tafel\u659c\u7387\u4e5f\u4f4e\u4e8e\u7eb3\u7c73\u6676\u4f53Cu-BHT\u7684\uff08120 mVdec-1<\/sup>\uff09\u3002\u9664HER\u5916\uff0c\u5bfc\u7535MOF\u5728\u50ac\u5316OER\u65b9\u9762\u4e5f\u5f88\u6709\u524d\u666f\u3002Li\u7b49\u5408\u6210\u4e86\u5177\u6709\u4e0d\u540c\u5f62\u6001\u7684Co-HAB MOF\uff0c\u5e76\u53d1\u73b0\u4e0e\u7eb3\u7c73\u9897\u7c92\uff0c\u539a\u7247\u548c\u5757\u72b6Co-HAB\u76f8\u6bd4\uff0c\u5177\u6709\u6700\u4f73\u7684\u7535\u6781\u52a8\u529b\u5b66\u6027\u80fd\u662f\u6700\u5177\u50ac\u5316\u6d3b\u6027\u7684\u6837\u54c1\u662f\u8d85\u8584\u7247\uff08\u5e73\u5747\u539a\u5ea6= 4.5 nm\uff09\uff08\u56fe6ab\uff09\u3002\u57281 M KOH\u4e2d\uff0c10 mA cm-2<\/sup>\u4e0b\u7684\u8fc7\u7535\u52bf\u4e3a310 mV\u3002\u540e\u6765\uff0c\u4ed6\u4eec\u62a5\u9053\u4e86\u4e00\u79cd\u5206\u5c42\u7684\u53cc\u91d1\u5c5eCoNi-HAB MOF\uff08\u56fe6c\uff09\uff0c\u4e5f\u5bf9OER\u8868\u73b0\u51fa\u51fa\u8272\u7684\u7535\u50ac\u5316\u4f5c\u7528\uff0c\u8fc7\u7535\u52bf\u4e3a219 mV\uff0cTafel\u659c\u7387\u4e3a42 mV dec-1<\/sup>\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0cNi-HAB\u4f53\u7cfb\u4e2d\u94b4\u7684\u63ba\u6742\u5bfc\u81f4OER\u7684\u56fa\u6709\u6d3b\u6027\u589e\u5f3a\u3002<\/p>\n

\u00a0<\/b><\/strong>\u56fe6. (a,b) Co-HAB\u00a0TEM,AFM (c)\u00a0CoNi-HAB\u5236\u5907\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

b\u70ed\u7535\u6548\u5e94<\/strong><\/p>\n

Erickson[12]<\/sup>\u7b49\u9996\u5148\u8bc1\u660e\u4e86TCNQ@Cu3<\/sub>(BTC)2<\/sub>\u8584\u819c\u4e2d\u5177\u6709\u70ed\u7535\u6548\u5e94\uff0c\u8be5\u8584\u819c\u572825\u2103\u4e0b\u7684ZT\u503c\u4e3a7\u00d710-5<\/sup>\u00a0S cm-1<\/sup>\u3002\u76f8\u5bf9\u8f83\u9ad8\u7684ZT\u503c\u5f52\u56e0\u4e8e\u5ba4\u6e29\u4e0b\u7684\u4f4e\u70ed\u5bfc\u7387(0.27 W m-1<\/sup>\u00a0K-1<\/sup>)\u548c\u8d85\u9ad8\u585e\u8d1d\u514b\u7cfb\u6570(375\u00a0\u03bcVK-1<\/sup>)\u3002\u5373\u4f7f\u5177\u6709\u8f83\u4f4e\u7684\u5bfc\u70ed\u7387\uff0cTCNQ@Cu3<\/sub>(BTC)2<\/sub>\u7684ZT\u4e5f\u53d7\u5176\u5ba4\u6e29\u5bfc\u7535\u7387\u9650\u5236\u3002<\/p>\n

c\u8d85\u7ea7\u7535\u5bb9\u5668<\/strong><\/p>\n

Sheberla[13]<\/sup>\u7b49\u9996\u5148\u5c06\u4e8c\u7ef4\u5bfc\u7535MOF Ni3<\/sub>(HITP)2<\/sub>\u5355\u72ec\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5236\u6210\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u6ca1\u6709\u5176\u4ed6\u5bfc\u7535\u6dfb\u52a0\u5242\u6216\u7c98\u5408\u5242\uff0c\u8be5\u8d85\u7ea7\u7535\u5bb9\u5668\u57280.05 A g-1<\/sup>\u7684\u653e\u7535\u901f\u7387\u4e0b\u5177\u670918\u00a0\u03bcFcm-2<\/sup>\u7684\u9ad8\u9762\u7535\u5bb9\uff0c\u5e76\u4e14\u5177\u6709\u51fa\u8272\u7684\u5bb9\u91cf\uff0c\u57282 A g-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b10,000\u4e2a\u5faa\u73af\u4e2d\u5bb9\u91cf\u4fdd\u6301\u738790\uff05\u3002<\/p>\n

d\u6676\u4f53\u7ba1<\/strong><\/p>\n

2015\u5e74\uff0cZhu[4]<\/sup>\u7b49\u4eba\u57fa\u4e8e\u03c0-d\u5171\u8f6dMOF Cu-BHT\u8584\u819c\u5236\u9020\u4e86\u4e00\u79cdFET\u5668\u4ef6\uff0c\u8be5\u5668\u4ef6\u8868\u73b0\u51fa\u53cc\u6781\u6027\u884c\u4e3a\u3002\u4f46\u662f\u7531\u4e8e\u8584\u819c\u7684\u591a\u6676\u6027\u8d28\uff0c\u4e0d\u80fd\u51c6\u786e\u5730\u5c55\u73b0\u51fa\u56fa\u6709\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\u884c\u4e3a\uff0c\u56e0\u6b64\u9700\u8981\u9ad8\u8d28\u91cf\u7684\u6676\u4f53\u6216\u5927\u5c3a\u5bf8\u7684\u5355\u5c42\u6750\u6599\u3002Lahiri[14]<\/sup>\u7b49\u901a\u8fc7\u6db2-\u6db2\u754c\u9762\u6cd5\u6216\u6c14-\u6db2\u754c\u9762\u6cd5\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u57fa\u4e8eHAB\u7684\u5bfc\u7535MOF\u819c\uff0cM3<\/sub>HAB2<\/sub>\uff08M = Co\uff0cNi\u548cCu\uff09\u3002Ni-HAB\u8584\u819c\u7528\u4e8e\u5236\u9020FET\u5668\u4ef6\u663e\u793a\uff0c\u7531\u4e8e\u6676\u4f53\u7f3a\u9677\u548c\u5b58\u5728\u7684\u5927\u91cf\u6676\u754c\uff0c\u8be5\u5668\u4ef6\u7535\u5bfc\u7387\u53ca\u548c\u80cc\u6805\u76f8\u5173\u7535\u5bfc\u7387\u8f83\u4f4e\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

[1]Wen-Hua Li, Wei-Hua Deng, Guan- E. Wang, Gang Xu, Conductive MOFs, EnergyChem, 2020 (2) 100029.<\/p>\n

[2]Shinya Takaishi, Miyuki Hosoda, Takashi Kajiwara, Hitoshi Miyasaka, Hiroshi Kitagawa, Electroconductive Porous Coordination Polymer Cu[Cu(pdt)2<\/sub>] Composed of Donor and Acceptor Building Units, Inorganic Chemistry, 2009 (48) 9048-9050.<\/p>\n

[3]Mohamad Hmadeh, Zheng Lu, Zheng Liu, Felipe G\u00e1ndara, Hiroyasu Furukawa, Shun Wan, Veronica Augustyn, Rui Chang, Lei Liao, Fei Zhou, Emilie Perre, Vidvuds Ozolins, Kazu Suenaga, Xiangfeng Duan, Bruce Dunn, Yasuaki Yamamto, Osamu Terasaki, Omar M. Yaghi, New Porous Crystals of Extended Metal-Catecholates, Chemistry of Materials, 2012 (24) 3511-3513.<\/p>\n

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[7]Tarun C. Narayan, Tomoyo Miyakai, Shu Seki, Mircea Dinc\u0103, High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal\u2013Organic Framework, Journal of the American Chemical Society, 2012 (134) 12932-12935.<\/p>\n

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