{"id":202950,"date":"2020-06-05T06:41:25","date_gmt":"2020-06-04T22:41:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=202950"},"modified":"2020-06-04T20:42:16","modified_gmt":"2020-06-04T12:42:16","slug":"2%e7%af%87science-5%e7%af%87nature%e5%ad%90%e5%88%8a-mof%e5%a4%a7%e7%88%86%e5%8f%91%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=202950","title":{"rendered":"2\u7bc7Science 5\u7bc7Nature\u5b50\u520a&#8212;-MOF\u5927\u7206\u53d1\uff01"},"content":{"rendered":"<p>MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u4e09\u7ef4\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5728\u50ac\u5316\u3001\u50a8\u80fd\u548c\u5206\u79bb\u7b49\u7b49\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u7ee72019\u5e74\u5e95MOF\u72c2\u53d12\u7bc7Nature\u540e\uff0c2020\u5165\u5e74\u4ee5\u6765,\u5bf9\u4e8eMOF\u7684\u7814\u7a76\u53ef\u8c13\u662f\u5982\u706b\u5982\u837c\uff0c\u622a\u81f3\u76ee\u524d\uff0c\u4eca\u5e74SCI\u5df2\u68c0\u7d22\u52302000\u4f59\u7bc7MOFs\u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u3002\u4ec5\u4ec5\u8fc7\u53bb\u76845\u4e2a\u6708\u91cc\uff0c\u5c31\u5df2\u7ecf\u53d1\u8868\u4e862\u7bc7Science\uff0c3\u7bc7Nature Materials\uff0c2\u7bc7Nature Nanotechnology\u53ca\u65e0\u6570\u7bc7JACS\u3001Angew.\u3002\u4e0b\u9762\u7b14\u8005\u5e26\u5927\u5bb6\u4ecb\u7ecd\u8fd9\u4e9b\u795e\u7ea7\u7814\u7a76\u3002<\/p>\n<p><strong><b>Science\uff1a<\/b><\/strong><strong><b>\u5e73\u8861\u7528\u4e8e\u6e05\u6d01\u80fd\u6e90\u7684\u9ad8\u5ea6\u591a\u5b54\u6750\u6599\u7684\u4f53\u79ef\u548c\u91cd\u91cf\u6444\u53d6<\/b><\/strong><\/p>\n<p>\u79d1\u5b66\u5bb6\u4eec\u9762\u4e34\u7684\u4e00\u4e2a\u5de8\u5927\u6311\u6218\u662f\u5f00\u53d1\u5438\u9644\u5242\u6750\u6599\uff0c\u8fd9\u79cd\u6750\u6599\u5177\u6709\u8d85\u9ad8\u7684\u5b54\u9699\u7387\uff0c\u4f46\u8981\u4fdd\u6301\u91cd\u91cf\u548c\u4f53\u79ef\u8868\u9762\u79ef\u4e4b\u95f4\u7684\u5e73\u8861\uff0c\u4ee5\u4fbf\u50a8\u5b58\u66ff\u4ee3\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u7684\u6c22\u6c14\u548c\u7532\u70f7\u6c14\u4f53\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u897f\u5317\u5927\u5b66Omar K. Farha\u6559\u6388\u62a5\u544a\u4e86\u57fa\u4e8e\u91d1\u5c5e\u4e09\u6838\u56e2\u7c07\u7684\u8d85\u591a\u5b54\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\uff0cNU-1501-M\uff08M=Al\u6216Fe\uff09\u7684\u6a21\u62df\u5408\u6210\uff0c\u4e0e\u5176\u4ed6\u8d85\u5b54MOFs\u76f8\u6bd4\uff0cNU-1501-Al\u540c\u65f6\u5177\u67097310 m<sup>2<\/sup>\u00a0g<sup>-1<\/sup>\u7684\u9ad8\u91cd\u91cf\u6bd4\u8868\u9762\u79ef\u548c2060 m<sup>2<\/sup>\u00a0cm<sup>-3<\/sup>\u7684\u9ad8\u4f53\u79ef\u6bd4\u8868\u9762\u79ef\uff0c\u540c\u65f6\u6ee1\u8db3\u4e86\u56db\u4e2aBET\u4e00\u81f4\u6027\u6807\u51c6\u3002\u8be5MOF\u7684\u9ad8\u5b54\u9699\u7387\u548c\u8868\u9762\u79ef\u4f7f\u5176\u5177\u6709\u51fa\u8272\u7684\u6c22\u548c\u7532\u70f7\u91cd\u91cf\u548c\u4f53\u79ef\u5b58\u50a8\u6027\u80fd\uff1aNU-1501-Al\u4ee50.66 g g<sup>-1<\/sup>\u7684\u6570\u503c\u8d85\u8fc7\u7f8e\u56fd\u80fd\u6e90\u90e8\u5236\u5b9a\u76840.5 g g<sup>-1<\/sup>\u7532\u70f7\u50a8\u5b58\u91cf\uff0cNU-1501-Al\u6750\u6599\u572810 MPa\u300177 K\u6761\u4ef6\u4e0b\uff0c\u5bf9\u6c22\u6c14\u7684\u5438\u9644\u91cf\u53ef\u8fbe14.5 wt%\uff0847.9 g\/L\uff09\uff0c\u5e38\u6e29\u4e0b\u7684\u5438\u9644\u91cf\u4e5f\u53ef\u4ee5\u8fbe\u5230~2.9 wt%\uff088.4 g\/L\uff09\u3002\u5b9e\u9a8c\u4e0e\u5206\u5b50\u6a21\u62df\u76f8\u7ed3\u5408\u7684\u7ed3\u679c\u8868\u660e\uff0cNU-1501\u5728\u5b9e\u9645\u64cd\u4f5c\u6761\u4ef6\u4e0b\uff0c\u540c\u65f6\u5b9e\u73b0\u4e86\u7532\u70f7\u548c\u6c22\u6c14\u7684\u91cd\u91cf\u3001\u4f53\u79ef\u50a8\u5b58\u548c\u91ca\u653e\u80fd\u529b\uff0c\u4f7f\u8fd9\u4e9b\u6750\u6599\u6210\u4e3a\u4e00\u7c7b\u65b0\u7684\u6709\u524d\u9014\u7684MOF\u5438\u9644\u5242\uff0c\u53ef\u7528\u4e8e\u50a8\u5b58\u548c\u91ca\u653e\u7532\u70f7\u548c\u6c22\u6e05\u6d01\u80fd\u6e90\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBalancing volumetric and gravimetric uptake in highly porous materials for clean energy\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1126\/science.aaz8881<\/p>\n<p>\u56fe1\u00a0NU-1500- Al\u548cNU-1501- Al\u5bf9\u9ad8\u538b\u6c22\u6c14\u548c\u7532\u70f7\u7684\u5438\u9644\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202951 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72471-1.png\" alt=\"\" width=\"700\" height=\"853\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72471-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72471-1-246x300.png 246w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>Science<\/b><\/strong><strong><b>\uff1a\u6838\u78c1\u5171\u632f\u63ed\u793aZ<\/b><\/strong><strong><b>IF<\/b><\/strong><strong><b>\u73bb\u7483\u4e2d\u7684\u77ed\u7a0b\u65e0\u5e8f\u73b0\u8c61<\/b><\/strong><\/p>\n<p>\u7194\u878d\u6dec\u706d\u7684\u6cb8\u77f3\u54aa\u5511\u9aa8\u67b6\u73bb\u7483\u7684\u7ed3\u6784\u53ef\u4ee5\u4e3a\u7814\u7a76\u5176\u73bb\u7483\u5f62\u6210\u673a\u5236\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u3002\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u5cb3\u8fdc\u5f81\u9662\u58eb\u56e2\u961f\u4e0e\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6234\u7ef4\u65af\u5206\u6821Sabyasachi Sen\u6559\u6388\u56e2\u961f\u4f7f\u7528\u8d85\u9ad8\u573a\u768467Zn\u56fa\u6001\u6838\u78c1\u5171\u632f\u5149\u8c31\u6280\u672f\u63ed\u793a\u4e86ZIF\u73bb\u7483\u4e2d\u7684\u77ed\u7a0b\u65e0\u5e8f\u73b0\u8c61\u3002\u4e24\u4e2a\u4e0d\u540c\u7684\u950c\u4f4d\u70b9\u7684\u7279\u70b9\u662f\uff0c\u6bcd\u6676\u4f53\u8f6c\u53d8\u6210\u4e00\u4e2a\u5355\u4e00\u7684\u56db\u9762\u4f53\u4f4d\u70b9\u4e0e\u5e7f\u6cdb\u5206\u5e03\u7684\u7ed3\u6784\u53c2\u6570\u3002\u6b64\u5916\uff0cZIFs\u4e2d\u7684\u914d\u4f53\u5316\u5b66\u5bf9\u5176\u77ed\u671f\u5931\u5e8f\u4f3c\u4e4e\u6ca1\u6709\u63a7\u5236\u4f5c\u7528\uff0c\u5c3d\u7ba1\u524d\u8005\u5f71\u54cd\u4e86\u5b83\u4eec\u7684\u76f8\u53d8\u884c\u4e3a\u3002\u8fd9\u4e9b\u7ed3\u679c\u63ed\u793a\u4e86\u7ed3\u6784\u4e0e\u6027\u80fd\u7684\u5173\u7cfb\uff0c\u5bf9\u63a2\u7a76MOF\u73bb\u7483\u7684\u7279\u6b8a\u6027\u80fd\u7684\u8d77\u6e90\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\uff0c\u5bf9\u8bbe\u8ba1\u65b0\u578b\u529f\u80fdMOF\u73bb\u7483\u5177\u6709\u91cd\u8981\u6307\u5bfc\u610f\u4e49\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cUltrahigh-field 67Zn NMR reveals short-range disorder in zeolitic imidazolate framework glasses\u201d\u4f4d\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1126\/science.aaz0251<\/p>\n<p>\u56fe2\u00a0ZIFs\u7684\u76f8\u53d8\u3001\u73bb\u7483\u5f62\u6210\u548c\u73bb\u7483\u8f6c\u53d8<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202952 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72472-1.png\" alt=\"\" width=\"700\" height=\"228\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72472-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72472-1-300x98.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>Nature Nanotechnology<\/b><\/strong><strong><b>\uff1aM<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u6355\u6c34\u5668<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u6709\u6548\u5730\u89e3\u51b3\u5168\u7403\u6c34\u8d44\u6e90\u77ed\u7f3a\u5371\u673a\uff0c\u5fc5\u987b\u63d0\u51fa\u66f4\u591a\u7684\u6de1\u6c34\u751f\u4ea7\u65b9\u6cd5\u3002\u5728\u8fd9\u65b9\u9762\uff0c\u63d0\u53d6\u65e0\u5904\u4e0d\u5728\u7684\u5927\u6c14\u6c34\u5206\u662f\u4e00\u4e2a\u5f3a\u5927\u7684\u6218\u7565\uff0c\u5141\u8bb8\u5206\u6563\u83b7\u53d6\u996e\u7528\u6c34\u3002\u5982\u679c\u5c06\u9002\u5f53\u7684\u5438\u9644\u5242\u96c6\u6210\u5230\u5927\u6c14\u6c34\u53d1\u751f\u5668\u4e2d\uff0c\u8fd9\u79cd\u65b9\u6cd5\u7684\u80fd\u91cf\u9700\u6c42\u4ee5\u53ca\u65f6\u95f4\u548c\u7a7a\u95f4\u9650\u5236\u53ef\u4ee5\u5927\u5927\u51cf\u5c11\u3002\u6700\u8fd1\uff0c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u5df2\u6210\u529f\u5730\u7528\u4e8e\u4ece\u7a7a\u6c14\u4e2d\u5438\u6536\u6c34\u5206\uff0c\u4f7f\u5927\u6c14\u4e2d\u7684\u6c34\u5206\u751f\u6210\u5373\u4f7f\u5728\u6c99\u6f20\u73af\u5883\u4e2d\u4e5f\u662f\u53ef\u884c\u7684\u3002\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u6559\u6388\u7b49\u4eba\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u4ece\u7a7a\u6c14\u4e2d\u63d0\u53d6\u6c34\u5206\u7684MOFs\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u4ee5\u53ca\u91c7\u7528\u8fd9\u79cdMOFs\u7684\u5927\u6c14\u6c34\u6536\u5272\u673a\u7684\u8bbe\u8ba1\u3002\u6b64\u5916\uff0c\u8fd8\u6982\u8ff0\u4e86\u8fd9\u4e00\u65b0\u5174\u9886\u57df\u7684\u672a\u6765\u53d1\u5c55\u65b9\u5411\uff0c\u5305\u62ec\u6750\u6599\u548c\u8bbe\u5907\u7684\u6539\u8fdb\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMOF water harvesters \u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Nanotechnology\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41565-020-0673-x<\/p>\n<p>\u56fe3\u00a0\u7528\u4e8e\u5927\u6c14\u6c34\u5206\u6536\u96c6\u7684MOFs\u7684\u7f51\u72b6\u8bbe\u8ba1<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202953 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72473-1.png\" alt=\"\" width=\"700\" height=\"663\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72473-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72473-1-300x284.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>Nature Nanotechnology<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u7532\u9178\u6c27\u5316\u7528\u5355\u539f\u5b50Rh\/N\u63ba\u6742\u78b3\u7535\u50ac\u5316\u5242<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u6ee1\u8db3\u6f5c\u5728\u7684\u5e94\u7528\u9700\u6c42\uff0c\u5f00\u53d1\u5177\u6709\u8d85\u9ad8\u8d28\u91cf\u6d3b\u6027\u548c\u6297CO\u7684\u65b0\u578b\u7532\u9178\u6c27\u5316\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u3001\u738b\u5b9a\u80dc\u7b49\u4eba\u8bbe\u8ba1\u901a\u8fc7\u5bf9\u542b\u91d1\u5c5e\u7684\u950c\u57faMOF\u524d\u9a71\u4f53\u8fdb\u884c\u70ed\u89e3\uff0c\u8bbe\u8ba1\u5236\u5907\u4e86\u4e00\u79cd\u6c2e\u63ba\u6742\u78b3\u8d1f\u8f7d\u94d1\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u76f8\u5bf9\u4e8e\u94d1\u548c\u5176\u4ed6\u94c2\u65cf\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92(Pt\u548cPd)\uff0cRh\u5355\u539f\u5b50\u8868\u73b0\u51fa\u660e\u663e\u6539\u5584\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5bf9\u7532\u9178\u6c27\u5316\u8868\u73b0\u51fa\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u6c2e\u63ba\u6742\u7684\u78b3(SA-Rh\/CN)\u5bf9\u7532\u9178\u6c27\u5316\u5177\u6709\u826f\u597d\u7684\u7535\u50ac\u5316\u6027\u80fd\u3002\u5c3d\u7ba1Rh\/C\u6d3b\u6027\u8f83\u4f4e\uff0c\u4f46\u4e0e\u6700\u5148\u8fdb\u7684Pd\/C\u548cPt\/C\u76f8\u6bd4\uff0cSA-Rh\/CN\u5bf9\u7532\u9178\u6c27\u5316\u7684\u8d28\u91cf\u6d3b\u6027\u589e\u5f3a\u4e8628\u500d\u548c67\u500d\u3002\u6709\u8da3\u7684\u662f\uff0cSA-Rh\/CN\u5bf9CO\u4e2d\u6bd2\u7684\u8010\u53d7\u6027\u5927\u5927\u589e\u5f3a\uff0cSA-Rh\/CN\u4e2d\u7684Rh\u539f\u5b50\u7ecf\u8fc7\u957f\u671f\u7684\u6d4b\u8bd5\uff0c\u8010\u70e7\u7ed3\uff0c\u5177\u6709\u826f\u597d\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u7532\u9178\u76d0\u8def\u7ebf\u5bf9SA-Rh\/CN\u66f4\u6709\u5229\u3002\u6839\u636e\u8ba1\u7b97\uff0c\u4ea7\u751fCO\u7684\u9ad8\u58c1\u5792\uff0c\u52a0\u4e0a\u4e0eCO\u7684\u76f8\u5bf9\u4e0d\u5229\u7684\u7ed3\u5408\uff0c\u6709\u52a9\u4e8e\u5176CO\u8010\u53d7\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSingle-atom Rh\/N-doped carbon electrocatalyst for formic acid oxidation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Nanotechnology\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41565-020-0665-x<\/p>\n<p>\u56fe4\u00a0\u50ac\u5316\u5242\u7684\u5408\u6210\u4e0e\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202954 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72474-1.png\" alt=\"\" width=\"700\" height=\"663\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72474-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72474-1-300x284.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>Nature Materials<\/b><\/strong><strong><b>\uff1aM<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>s<\/b><\/strong><strong><b>\u4f7f\u91d1\u5c5e\u79bb\u5b50\u5728\u4e9a\u7eb3\u7c73\u901a\u9053\u4e2d\u9ad8\u6548\u7b5b\u5206\u6210\u4e3a\u53ef\u80fd<\/b><\/strong><\/p>\n<p>\u751f\u7269\u79bb\u5b50\u901a\u9053\u5177\u6709\u663e\u8457\u7684\u79bb\u5b50\u9009\u62e9\u6027\u3001\u79bb\u5b50\u6e17\u900f\u6027\u548c\u79bb\u5b50\u6574\u6d41\u6027\uff0c\u4f46\u4eba\u5de5\u7c7b\u4f3c\u7269\u7684\u5f00\u53d1\u5177\u6709\u4e00\u5b9a\u7684\u6311\u6218\u6027\u3002\u5728\u8fd9\u91cc\uff0c\u6b66\u6c49\u79d1\u6280\u5927\u5b66\u848b\u66f4\u5e73\u6559\u6388\u8054\u5408\u6fb3\u5927\u5229\u4e9a\u83ab\u7eb3\u4ec0\u5927\u5b66\u738b\u7115\u5ead\u6559\u6388\u56e2\u961f\u62a5\u544a\u4e86\u4e00\u79cd\u57fa\u4e8e\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7684\u4e9a\u7eb3\u7c73\u901a\u9053(MOFSNC)\uff0c\u5b83\u5177\u6709\u975e\u5747\u8d28\u7ed3\u6784\u548c\u8868\u9762\u5316\u5b66\uff0c\u4ee5\u5b9e\u73b0\u8fd9\u4e9b\u7279\u6027\u3002\u975e\u5bf9\u79f0\u7ed3\u6784\u7684MOFSNC\u53ef\u4ee5\u5728\u4e9a\u7eb3\u7c73\u5230\u7eb3\u7c73\u7684\u901a\u9053\u65b9\u5411\u5feb\u901f\u4f20\u5bfcK<sup>+<\/sup>\u3001Na<sup>+<\/sup>\u548cLi+\uff0c\u5176\u5bfc\u7535\u6027\u6bd4Ca<sup>2+<\/sup>\u548cMg<sup>2+<\/sup>\u9ad8\u4e09\u4e2a\u6570\u91cf\u7ea7\uff0c\u76f8\u5f53\u4e8e\u5176\u4e00\u4ef7\/\u4e8c\u4ef7\u79bb\u5b50\u9009\u62e9\u6027\u768410<sup>3<\/sup>\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u6539\u53d8pH\u503c\u4ece3\u52308\uff0c\u79bb\u5b50\u7684\u9009\u62e9\u6027\u53ef\u4ee5\u8fdb\u4e00\u6b65\u8c03\u6574\u523010<sup>2<\/sup>\u523010<sup>4<\/sup>\u500d\u3002\u7406\u8bba\u6a21\u62df\u8868\u660e\uff0c\u79bb\u5b50\u4e0e\u7fa7\u57fa\u7684\u76f8\u4e92\u4f5c\u7528\u5927\u5927\u964d\u4f4e\u4e86\u4e00\u4ef7\u9633\u79bb\u5b50\u901a\u8fc7MOFSNC\u7684\u80fd\u91cf\u58c1\u5792\uff0c\u4ece\u800c\u5bfc\u81f4\u4e86\u8d85\u9ad8\u7684\u79bb\u5b50\u9009\u62e9\u6027\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u5f00\u53d1\u9ad8\u6548\u79bb\u5b50\u5206\u79bb\u3001\u80fd\u91cf\u50a8\u5b58\u548c\u53d1\u7535\u7684\u79bb\u5b50\u9009\u62e9\u88c5\u7f6e\u63d0\u4f9b\u4e86\u65b9\u6cd5\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cEfficient metal ion sieving in rectifying subnanochannels enabled by metal\u2013organic frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728\u00a0Nature Materials\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41563-020-0634-7<\/p>\n<p>\u56fe5\u00a0UiO-66-(COOH)<sub>2<\/sub>-SNC\u4e2d\u7684\u79bb\u5b50\u7b5b\u5206\u673a\u5236<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202955 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72475-1.png\" alt=\"\" width=\"700\" height=\"503\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72475-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72475-1-300x216.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>Nature Materials<\/b><\/strong><strong><b>\uff1a\u57fa\u4e8e<\/b><\/strong><strong><b>MOF\u548c\u79bb\u5b50\u6db2\u4f53<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d<\/b><\/strong><strong><b>\u5145\u653e<\/b><\/strong><strong><b>\u7535\u52a8\u529b\u5b66<\/b><\/strong><\/p>\n<p>\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u51af\u5149\u6559\u6388\u56e2\u961f\u548c\u4f26\u6566\u5e1d\u56fd\u7406\u5de5\u5b66\u9662AlexeiA. Kornyshev\u6559\u6388\u56e2\u961f\u5408\u4f5c\u91c7\u7528\u6052\u7535\u4f4d\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u65b9\u6cd5\uff0c\u5206\u6790\u4e86\u7531\u5bfc\u7535\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7535\u6781\u548c\u79bb\u5b50\u6db2\u4f53\u7ec4\u6210\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u53cc\u5c42\u7ed3\u6784\u548c\u7535\u5bb9\u6027\u80fd\u3002\u5206\u5b50\u6a21\u578b\u9610\u660e\u4e86\u79bb\u5b50\u5728\u6781\u5316\u591a\u5b54MOFs\u4e2d\u7684\u4f20\u8f93\u548c\u9a7b\u7559\u65b9\u5f0f\uff0c\u5e76\u9884\u6d4b\u4e86\u76f8\u5e94\u7684\u7535\u4f4d\u76f8\u5173\u7535\u5bb9\u7684\u7279\u5f81\u5f62\u72b6\u3002\u91c7\u7528\u4f20\u8f93\u7ebf\u6a21\u578b\u8868\u5f81\u5145\u7535\u52a8\u529b\u5b66\uff0c\u8fdb\u4e00\u6b65\u4ece\u6a21\u62df\u5f97\u5230\u7684\u7eb3\u7c73\u7ea7\u6570\u636e\u5bf9\u8be5\u7c7b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5bb9\u6027\u6027\u80fd\u8fdb\u884c\u5b8f\u89c2\u8bc4\u4ef7\u3002\u8fd9\u4e9b\u6a21\u62df\u5206\u6790\u7684\u7ed3\u679c\u5f97\u5230\u4e86\u5b8f\u89c2\u7535\u5316\u5b66\u6d4b\u91cf\u7684\u652f\u6301\u3002\u8fd9\u79cd\u4ece\u7eb3\u7c73\u7ea7\u5230\u5b8f\u89c2\u7ea7\u7684\u8054\u5408\u7814\u7a76\u8868\u660e\uff0cMOF\u8d85\u7ea7\u7535\u5bb9\u5668\u6709\u53ef\u80fd\u5b9e\u73b0\u524d\u6240\u672a\u6709\u7684\u9ad8\u5bb9\u91cf\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u3002\u57fa\u4e8eMOF \/ RTIL\u7684\u7535\u5bb9\u5668\u8868\u73b0\u51fa\u4f18\u4e8e\u5927\u591a\u6570\u78b3\u57fa\u8bbe\u5907\u7684\u6027\u80fd\uff0c\u8fd9\u4e3a\u8bbe\u8ba1\u5177\u6709\u9ad8\u80fd\u91cf\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u5e26\u6765\u4e86\u65b0\u7684\u5e0c\u671b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMolecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Materials\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41563-019-0598-7<\/p>\n<p>\u56fe6\u00a0\u57fa\u4e8eMOF\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5206\u5b50\u6a21\u62df\u539f\u7406\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202956 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72476-1.png\" alt=\"\" width=\"700\" height=\"461\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72476-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72476-1-300x198.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong><b>N<\/b><\/strong><strong><b>ature<\/b><\/strong><strong><b>\u00a0Materials<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u9492<\/b><\/strong><strong><b>\u57fa<\/b><\/strong><strong><b>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7684\u9009\u62e9\u6027\u6c2e\u5438\u9644<\/b><\/strong><\/p>\n<p>\u5de5\u4e1a\u5316\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u5e38\u5e38\u4f1a\u4ea7\u751f\u5f88\u591a\u5177\u6709\u03c0-\u9178\u6027\u7684\u6c14\u4f53\uff0c\u5438\u9644\u5242\u80fd\u591f\u9009\u62e9\u6027\u5730\u4e0e\u8fd9\u4e9b\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u4f7f\u91cd\u8981\u7684\u5316\u5b66\u5206\u79bb\u6210\u4e3a\u53ef\u80fd\u3002\u751f\u7269\u4f53\u7cfb\u4e2d\u5b58\u5728\u5f88\u591a\u6613\u4e8e\u63a5\u8fd1\u7684\u8fd8\u539f\u91d1\u5c5e\u4f4d\u70b9\u80fd\u591f\u901a\u8fc7\u53cd\u9988\u03c0\u952e\u7684\u5f62\u5f0f\u4e0eN2\u8fd9\u4e9b\u6c14\u4f53\u7ed3\u5408\u5e76\u6fc0\u6d3b\u5176\u8f83\u5f31\u7684\u03c0\u9178\u6027\uff0c\u5982\u679c\u80fd\u591f\u5c06\u7c7b\u4f3c\u7684\u7ed3\u6784\u5f15\u5165\u5230\u591a\u5b54\u6750\u6599\u57fa\u8d28\u4e2d\u5c31\u53ef\u4ee5\u4ea7\u751f\u7c7b\u4f3c\u7684\u5438\u9644\u673a\u5236\u5bf9\u8fd9\u4e9b\u5de5\u4e1a\u5e9f\u6c14\u8fdb\u884c\u5206\u79bb\u3002\u5728\u6b64\uff0c\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Jeffrey 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nitrogen adsorption via backbonding in a metal\u2013organic framework with exposed vanadium sites\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Materials\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41563-019-0597-8<\/p>\n<p>\u56fe7\u00a0N<sub>2<\/sub>\/CH<sub>4<\/sub>\u9009\u62e9\u6027\u548cN<sub>2<\/sub>\u5438\u9644\u53ef\u9006\u6027\u7684\u8bc4\u4ef7<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-202957 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72477-1.png\" alt=\"\" width=\"700\" height=\"205\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72477-1.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/\u56fe\u72477-1-300x88.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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