{"id":202931,"date":"2020-06-06T06:26:21","date_gmt":"2020-06-05T22:26:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=202931"},"modified":"2020-06-05T21:26:32","modified_gmt":"2020-06-05T13:26:32","slug":"%e5%8c%97%e4%ba%ac%e5%b7%a5%e5%95%86%e5%a4%a7%e5%ad%a6%e6%a8%8a%e4%bf%9d%e6%b0%91%e5%9b%a2%e9%98%9f%e5%af%b9%e7%bb%84%e8%a3%85%e5%9e%8b%e7%bc%93%e8%9a%80%e5%89%82%e7%9a%84%e4%bd%9c%e7%94%a8%e6%9c%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=202931","title":{"rendered":"\u5317\u4eac\u5de5\u5546\u5927\u5b66\u6a0a\u4fdd\u6c11\u56e2\u961f\u5bf9\u7ec4\u88c5\u578b\u7f13\u8680\u5242\u7684\u4f5c\u7528\u673a\u7406\u53d6\u5f97\u7cfb\u5217\u8fdb\u5c55"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u5411\u73af\u5883\u4ecb\u8d28\u6295\u653e\u7f13\u8680\u5242\u5177\u6709\u7528\u91cf\u5c11\u3001\u6548\u7387\u9ad8\u4e14\u64cd\u4f5c\u7b80\u4fbf\u7b49\u7279\u70b9\uff0c\u662f\u6709\u6548\u51cf\u7f13\u91d1\u5c5e\u8150\u8680\u7684\u6709\u6548\u65b9\u6cd5\u4e4b\u4e00\u3002\u968f\u7740\u73af\u4fdd\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u5438\u9644\u578b\u6709\u673a\u7f13\u8680\u5242\u9010\u6e10\u6210\u4e3a\u57fa\u7840\u7814\u7a76\u4e0e\u5de5\u4e1a\u5e94\u7528\u7684\u4e3b\u6d41\u4ea7\u54c1\u3002\u7136\u800c\uff0c\u5b9e\u9645\u4f7f\u7528\u65f6\uff0c\u67d0\u4e9b\u6709\u673a\u7f13\u8680\u5242\u5e38\u51fa\u73b0\u6548\u679c\u4f18\u5f02\uff0c\u4f46\u6c34\u76f8\u6eb6\u89e3\u5206\u6563\u6027\u4e0d\u4f73\uff08\u5982\u5341\u516b\u80fa\u3001\u8089\u6842\u919b\u3001\u66f2\u5511\u916e\uff09\uff1b\u6c34\u76f8\u6eb6\u89e3\u5206\u6563\u6027\u826f\u597d\uff0c\u4f46\u91d1\u5c5e\u8868\u9762\u5438\u9644\u6027\u80fd\u5dee\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u6709\u9274\u4e8e\u6b64\uff0c<strong><b>\u5317\u4eac\u5de5\u5546\u5927\u5b66\u6a0a\u4fdd\u6c11\u526f\u6559\u6388\u56e2\u961f\u5c06\u5206\u5b50\u8bc6\u522b\u4e0e\u81ea\u7ec4\u88c5\u7406\u8bba\u5f15\u5165\u7f13<\/b><\/strong><strong><b>\u8680\u5242\u7814\u7a76<\/b><\/strong>\uff0c\u4ee5\u7f13\u8680\u6027\u80fd\u4f18\u826f\u4f46\u6c34\u6eb6\u6027\u5dee\u7684\u5341\u516b\u80fa\uff08ODA\uff09\u6216\u66f2\u5511\u916e\uff08TDO\uff09\u4e3a\u5ba2\u4f53\uff0c\u4ee5\u7b80\u5355\u73af\u7cca\u7cbe\uff08CDs\uff09\u6216\u5176\u6709\u9650\u4ea4\u8054\u7f51\u7edc\uff08CCDs\uff09\u4e3a\u4e3b\u4f53\uff0c<strong><b>\u7ecf\u53cd\u76f8\u6eb6\u5242\u8bf1\u5bfc\u6784\u7b51\u51fa\u5206\u5b50\u7ec4\u88c5\u4f53<\/b><\/strong>\uff0c\u5728\u4fdd\u7559\u5ba2\u4f53\u5316\u5408\u7269\u826f\u597d\u7f13\u8680\u6027\u80fd\u7684\u57fa\u7840\u4e0a\uff0c\u5b9e\u73b0\u96be\u6eb6\u7f13\u8680\u5242\u7684\u6c34\u76f8\u6709\u6548\u6eb6\u89e3\u5206\u6563\u3002<strong><b>\u76f8\u5173\u6210\u679c\u4f5c\u4e3a\u7cfb\u5217\u7814\u7a76\uff0c\u76f8\u7ee7\u53d1\u8868\u4e8eApplied<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Surface<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Science<\/b><\/strong><strong><b>\u00a0(2020, 514: 146086)<\/b><\/strong><strong><b>\uff0cJournal<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>of<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Molecular<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>Modeling<\/b><\/strong><strong><b>\u00a0(2020, 26: 81)<\/b><\/strong><strong><b>\uff0cJ<\/b><\/strong><strong><b>ournal of Molecular Liquids (2020, 311: 113302; 2019, 292: 111446)<\/b><\/strong>\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p>Figure 1. ODA\/CCDs\u578b\u5206\u5b50\u7ec4\u88c5\u4f53\u7684\u6784\u7b51\u8def\u5f84\u53ca\u5206\u5b50\u52a8\u529b\u5b66\u4e0e\u5bf9\u63a5\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-202933\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/1-5.png\" alt=\"\" width=\"419\" height=\"308\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/1-5.png 419w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/1-5-300x221.png 300w\" sizes=\"(max-width: 419px) 100vw, 419px\" \/><\/p>\n<p>Figure\u00a02.\u00a020#\u94a2\u5728\u542b\u4e0d\u540c\u6d53\u5ea6CDDA\u7684\u6a21\u62df\u84b8\u6c7d\u51dd\u7ed3\u6c34\u4e2d\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-202934\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/2-3.png\" alt=\"\" width=\"415\" height=\"291\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/2-3.png 415w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/2-3-300x210.png 300w\" sizes=\"(max-width: 415px) 100vw, 415px\" \/><\/p>\n<p>Figure\u00a03.\u00a0\u663e\u6027\u6eb6\u5242\u6a21\u578b\u4e0bTDO\u5206\u5b50\u7684\u5168\u5c40\u53cd\u5e94\u6027\u63cf\u8ff0\u7b26<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-202935\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/3-3.png\" alt=\"\" width=\"344\" height=\"315\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/3-3.png 344w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/3-3-300x275.png 300w\" sizes=\"(max-width: 344px) 100vw, 344px\" \/><\/p>\n<p>(a)\uff0c(e) \u4e2d\u6027\u4e0e\u8d28\u5b50\u5316TDO\u5206\u5b50\u7684\u6700\u4f18\u6784\u578b<\/p>\n<p>(b)\uff0c(f) \u4e2d\u6027\u4e0e\u8d28\u5b50\u5316TDO\u5206\u5b50\u7684\u6700\u9ad8\u5360\u636e\u8f68\u9053\u5206\u5e03<\/p>\n<p>(c)\uff0c(g) \u4e2d\u6027\u4e0e\u8d28\u5b50\u5316TDO\u5206\u5b50\u7684\u6700\u4f4e\u672a\u5360\u636e\u8f68\u9053\u5206\u5e03<\/p>\n<p>(d)\uff0c(h) \u4e2d\u6027\u4e0e\u8d28\u5b50\u5316TDO\u5206\u5b50\u7684\u9759\u7535\u52bf\u5206\u5e03<\/p>\n<p>Figure\u00a04\uff0e\u00a0\u52a8\u6001\u529b\u573a\u4e0bTDO\u57280.5 mol\/L HCl\u4e0e3.5% NaCl\u6eb6\u6db2\u4e2d\u4e8eFe (1 1 0)\u9762\u7684\u5438\u9644\u6784\u578b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-202936\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/4-2.png\" alt=\"\" width=\"373\" height=\"226\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/4-2.png 373w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/06\/4-2-300x182.png 300w\" sizes=\"(max-width: 373px) 100vw, 373px\" \/><\/p>\n<p><strong><b>\u3010\u603b\u7ed3\u3011<\/b><\/strong><\/p>\n<p>\u4ee5CCDs\u4e0eODA\u95f4\u5f62\u6210\u7684\u5206\u5b50\u7ec4\u88c5\u4f53CDDA\u4e3a\u4f8b\uff0c\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u7ed3\u679c\u663e\u793a\u4ea4\u8054\u4e3b\u4f53\uff0cCDs\u57fa\u5143\u95f4\u4ee5\u7a84\u7aef\u53e3\u76f8\u5bf9\u6392\u5217\u6784\u578b\u7684\u975e\u952e\u80fd\u6700\u5927\uff0c\u4e3a\u7a33\u5b9a\u6784\u50cf\uff1b\u540c\u65f6\uff0c\u5206\u5b50\u5bf9\u63a5\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u5ba2\u4f53ODA\u503e\u5411\u4e8e\u4f9d\u9760CDs\u5185\u58c1\u4e00\u4fa7\u5f62\u6210\u6c22\u952e\uff0c\u7ed3\u5408\u80fd\u4e3a-36.8<sup>\u00a0<\/sup>kJ\/mol\u3002\u91c7\u7528\u52a8\u7535\u4f4d\u6781\u5316\u4e0e\u7535\u5316\u5b66\u963b\u6297\u8c31\u8bc4\u4ef7CDDA\u5bf920#\u94a2\u5728\u6a21\u62df\u84b8\u6c7d\u51dd\u7ed3\u6c34\u73af\u5883\u4e2d\u7684\u7f13\u8680\u6548\u679c\uff0c<strong><b>\u5f53\u6dfb\u52a0\u6d53\u5ea6\u4e3a1<\/b><\/strong><strong><sup><b>\u00a0<\/b><\/sup><\/strong><strong><b>mmol<\/b><\/strong><strong><b>\/L<\/b><\/strong><strong><b>\u65f6\uff0c\u7f13\u8680\u7387\u53ef\u8fbe93.7%<\/b><\/strong>\uff0c\u6709\u6548\u51cf\u7f13\u8150\u8680\u3002\u5bf9\u7ecfCDDA\u5904\u7406\u540e\u7684\u78b3\u94a2\u8fdb\u884c\u8868\u9762\u5206\u6790\u53d1\u73b0\uff0c\u8868\u9762\u4ec5\u63a2\u6d4b\u5230\u5ba2\u4f53ODA\u7684\u5316\u5b66\u4fe1\u606f\uff0c\u8bf4\u660e\u5ba2\u4f53\u7ecf\u5206\u5b50\u7ec4\u88c5\u540e\uff0c\u6709\u6548\u6eb6\u89e3\u5206\u6563\u4e8e\u6c34\u4e2d\uff0c\u8f93\u8fd0\u81f3\u91d1\u5c5e\u8868\u9762\u540e\u88ab\u91ca\u653e\u3002\u4ee5\u7b80\u4fbf\u65b9\u6cd5\u5408\u6210\u591a\u6d3b\u6027\u4f4d\u70b9\u7684\u66f2\u5511\u916e\u5316\u5408\u7269\uff08TDO\uff09\uff0c\u5e76\u4ee5\u6b64\u4e3a\u5ba2\u4f53\u5b8c\u6210\u7ec4\u88c5\u5f62\u6210\u7ec4\u88c5\u4f53\u3002\u5bf9\u5e94\u7ec4\u88c5\u4f53\u53ef\u540c\u65f6\u51cf\u7f13\u78b3\u94a2\u5728\u4e2d\u6027\uff083.5% NaCl\u6eb6\u6db2\uff09\u4e0e\u9178\u6027\uff080.5<sup>\u00a0<\/sup>mol\/L HCl\u6eb6\u6db2\uff09\u4ecb\u8d28\u4e2d\u7684\u8150\u8680\uff0c<strong><b>\u7f13\u8680\u7387\u53ef\u5206\u522b\u8fbe93.1%\u4e0e90.6%<\/b><\/strong>\uff0c\u9178\u6027\u6eb6\u6db2\u4f7f\u5ba2\u4f53\u8d28\u5b50\u5316\u7684\u5f71\u54cd\u4e0d\u5927\uff0c\u5177\u6709\u8f83\u5f3a\u666e\u9002\u6027\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u539f\u5b50\u7ed3\u5408\u7535\u5b50\u591a\u5c3a\u5ea6\u65b9\u6cd5\uff0c<strong><b>\u6784\u5efa\u5ba2\u4f53\u7684\u663e\u6027\u6eb6\u5242\u6a21\u578b\uff0c\u7ecf\u5bc6\u5ea6\u6cdb\u51fd\u8ba1\u7b97\u83b7\u53d6\u53cd\u5e94\u6027\u53c2\u6570\uff0c\u6700\u5927\u9650\u5ea6\u5730\u63a5\u8fd1\u771f\u5b9e\u60c5\u51b5<\/b><\/strong>\uff1b\u9274\u4e8e\u7f13\u8680\u5242\u5728\u91d1\u5c5e\/\u7535\u89e3\u8d28\u754c\u9762\u7684\u5438\u9644\u8fc7\u7a0b\uff0c\u540c\u65f6\u5305\u62ec\u7269\u7406\u3001\u5316\u5b66\u4f5c\u7528\uff0c\u8be5\u56e2\u961f<strong><b>\u57fa\u4e8eperl\u8bed\u8a00\uff0c\u81ea\u5efa\u5305\u62ec\u53cd\u5e94\u6027\u529b\u573a\u4e0e\u975e\u53cd\u5e94\u6027\u529b\u573a\u7684\u52a8\u6001\u7acb\u573a<\/b><\/strong>\uff0c\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u63ed\u793a\u5ba2\u4f53\u5728\u78b3\u94a2\u8868\u9762\u7684\u4f5c\u7528\u884c\u4e3a\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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