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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

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a\uff09BP\u3001MIL-53\u548cBP@MIL-53\u7684XRD\u56fe\u8c31\u3002<\/p>\n

b\uff09BP\u3001MIL-53\u548cBP@MIL-53\u7684FT-IR\u8c31\u56fe\u3002<\/p>\n

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d\uff09BP@MIL-53\u548cBP\u7684P 2p\u5149\u8c31\u3002<\/p>\n

\u56fe4 <\/b><\/strong>BP@MIL-53\u7684<\/b><\/strong>\u504f\u5149\u663e\u5fae\u955c\u56fe\u50cf<\/b><\/strong>\"\"<\/p>\n

a\uff09BP\u3001b\uff09BP@Al3+<\/sup>\u548cc\uff09BP@MIL-53\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u66b4\u9732\u4e0d\u540c\u65f6\u95f4\u7684\u504f\u5149\u663e\u5fae\u955c\u56fe\u50cf\u3002\u63d2\u56fe\uff1a\u76f8\u5e94\u7684TEM\uff0c\u6bd4\u4f8b\u5c3a\uff1a200 nm\u3002<\/p>\n

d\uff09\u5206\u6563\u5728\u6c34\u4e2d\u4e0d\u540c\u65f6\u95f4\u7684BP\u3001BP@Al3+<\/sup>\u548cBP@MIL-53\u5728470 nm\uff08A\/A0<\/sub>\uff09\u5904\u7684\u7d2b\u5916\u5438\u6536\u53d8\u5316\u3002<\/p>\n

e\uff09BP\u3001BP@Al3+<\/sup>\u548cBP@MIL-53\u4e2dPx<\/sub>Oy<\/sub>\u542b\u91cf\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>BP@MIL-53\u7684<\/b><\/strong>\u73af\u5883\u7a33\u5b9a\u6027<\/b><\/strong>\"\"<\/p>\n

a\uff09\u901a\u8fc7MIL-53\u6d82\u5c42\u9632\u6b62Al3+<\/sup>\u4eceBP\u8868\u9762\u8131\u843d\u7684\u793a\u610f\u56fe\u3002<\/p>\n

b\uff09BP@Al3+<\/sup>\u548cBP@MIL-53\u5728\u4e0d\u540c\u65f6\u95f4\u6bb5\u5185\u5206\u6563\u5728\u6c34\u4e2d\u7684\u8131\u843dAl3+<\/sup>\u7684\u542b\u91cf\u3002<\/p>\n

c\uff09BP@Al3+<\/sup>\u548cd\uff09BP@MIL-53\u5728\u6c34\u6eb6\u6db2\u4e2d\u57f9\u517b\u4e0d\u540c\u65f6\u95f4\u540e\u7684XPS\u5149\u8c31\u3002<\/p>\n

e\uff09BP@Al3+<\/sup>\u548cBP@MIL-53\u5206\u6563\u5728EDTA\u6c34\u6eb6\u6db2\u4e2d\u4e0d\u540c\u65f6\u95f4\u8131\u843d\u7684Al3+<\/sup>\u542b\u91cf\u3002<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>\u00a0<\/b><\/strong>BP@MIL-53\u7684<\/b><\/strong>\u70ed\u7a33\u5b9a\u6027<\/b><\/strong>\"\"<\/p>\n

a\uff09BP\u548cb\uff09BP@MIL-53\u70ed\u5904\u7406\u540e\u7684\u504f\u5149\u663e\u5fae\u955c\u56fe\u50cf\u548cTEM\u56fe\u50cf\u3002\u63d2\u56fe\uff1a\u5bf9\u5e94\u7684TEM\u56fe\u50cf\uff0c\u6bd4\u4f8b\u5c3a\uff1a200 nm\u3002<\/p>\n

c\uff09\u572875\u2103\u52a0\u70ed\u524d\u540e\uff0c\u6839\u636eBP\u548cBP@MIL-53\u7684P 2p\u5149\u8c31\u8ba1\u7b97\u51fa\u7684P\u542b\u91cf\u53d8\u5316\u3002<\/p>\n

d\uff09BP\u548cBP@MIL-53\u572875\u2103\u65f6\u5206\u6563\u5728\u6c34\u4e2d\u4e0d\u540c\u65f6\u95f4\u7684470 nm\uff08A\/A0<\/sub>\uff09\u5904\u7684\u5438\u6536\u7387\u53d8\u5316\u3002<\/p>\n

e\uff09\u52a0\u70ed\u8fc7\u7a0b\u4e2dBP\u548cBP@MIL-53\u4e2a\u6837\u54c1\u7684\u70ed\u6210\u50cf\u3002<\/p>\n

f\uff09\u52a0\u70ed\u8fc7\u7a0b\u4e2dBP\u548cBP@MIL-53\u7684\u5347\u6e29\u901f\u7387\u3002<\/p>\n

\u56fe<\/b><\/strong>7<\/b><\/strong>\u00a0<\/b><\/strong>BP@MIL<\/b><\/strong>–<\/b><\/strong>53<\/b><\/strong>\u4f20\u611f\u5668\u7684\u54cd\u5e94\u6027<\/b><\/strong>\"\"<\/p>\n

a\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0bBP@MIL-53\u4f20\u611f\u5668\u5bf9NO2<\/sub>\uff081.0 ppm\uff09\u7684\u54cd\u5e94\u65f6\u95f4\u548c\u6062\u590d\u65f6\u95f4\u7684\u53d8\u5316\u3002\u63d2\u56fe\uff1a\u76f8\u5e94\u7684\u54cd\u5e94\u66f2\u7ebf\u3002<\/p>\n

b\uff09BP@MIL-53\u4f20\u611f\u5668\u572870\u2103\u4e0b\u5bf9NO2<\/sub>\u6c14\u4f53\uff080.25-20 ppm\uff09\u7684\u52a8\u6001\u54cd\u5e94\u66f2\u7ebf\u3002<\/p>\n

c\uff09BP@MIL-53\u4f20\u611f\u5668\u572870\u2103\u4e0b\u5bf91 ppm\u30012 ppm\u548c5 ppm NO2<\/sub>\u7684\u54cd\u5e94\u91cd\u590d\u6027\u3002<\/p>\n

d\uff09\u572870\u2103\u5b58\u5728\u5e72\u6270\u6c14\u4f53\u7684\u60c5\u51b5\u4e0b\uff0cBP@MIL-53\u4f20\u611f\u5668\u7684\u9009\u62e9\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0cBP\u7684Al\u79bb\u5b50\u96c6\u6210\u529f\u80fd\u5316\u662f\u901a\u8fc7MIL-53\u5728BP\u8868\u9762\u7684\u539f\u4f4d\u751f\u957f\u548c\u5305\u8986\u6765\u5b9e\u73b0\u7684\u3002Al\u79bb\u5b50\u4e0eBP\u7684\u5b64\u5bf9\u7535\u5b50\u7ed3\u5408\u964d\u4f4e\u4e86\u8868\u9762\u7535\u5b50\u5bc6\u5ea6\uff0c\u8fdb\u800c\u964d\u4f4e\u4e86BP\u7684\u53cd\u5e94\u6d3b\u6027\uff08\u751f\u6210H2<\/sub>O\u548cO2<\/sub>\uff09\u3002MOF\u7684\u751f\u957f\u4f7fAl\u79bb\u5b50\u53d1\u751f\u4ea4\u8054\uff0c\u9650\u5236\u4e86\u5355\u4e2aAl\u79bb\u5b50\u5728BP\u8868\u9762\u7684\u5206\u79bb\u3002BP-Al\u7684\u975e\u5171\u4ef7\u952e\u548cMIL-53\u7684\u9ad8\u5b54\u9699\u7ed3\u6784\u6700\u5927\u9650\u5ea6\u5730\u4fdd\u6301\u4e86BP\u7684\u7269\u7406\/\u5316\u5b66\u6027\u8d28\uff0c\u540c\u65f6\u63d0\u9ad8\u4e86BP\u7684\u70ed\u7a33\u5b9a\u6027\u3002BP@MIL-53\u88ab\u8fdb\u4e00\u6b65\u7528\u4f5c\u9ad8\u5de5\u4f5c\u6e29\u5ea6\u4e0b\u7684NO2<\/sub>\u6c14\u4f53\u4f20\u611f\u5668\u3002\u4e0e\u88f8BP\u4f20\u611f\u5668\u76f8\u6bd4\uff0cBP@MIL-53\u4f20\u611f\u5668\u5177\u6709\u9ad8\u54cd\u5e94\u3001\u9ad8\u9009\u62e9\u6027\u3001\u826f\u597d\u7684\u6062\u590d\u52a8\u6001\u8fc7\u7a0b\u3002\u672c\u7814\u7a76\u4e3a\u91d1\u5c5e\u79bb\u5b50\u5728BP\u4e0a\u7684\u96c6\u6210\u529f\u80fd\u5316\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b56\u7565\uff0c\u53ef\u63a8\u5e7f\u5230\u5176\u4ed62D\u6750\u6599\uff0c\u62d3\u5bbd\u5176\u5e94\u7528\u8303\u56f4\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>The Art of Integrated Functionalization: Super Stable Black Phosphorus Achieved through Metal-Organic Framework Coating<\/u><\/a>\uff08Adv. Funct. Mater.\uff0c\u00a02019\uff0cDOI:10.1002\/adfm.202002232\uff09<\/p>\n

\u672c\u6587\u7531\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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