{"id":201803,"date":"2020-05-15T08:32:07","date_gmt":"2020-05-15T00:32:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=201803"},"modified":"2020-05-15T08:32:07","modified_gmt":"2020-05-15T00:32:07","slug":"%e6%9c%80%e6%96%b0science%ef%bc%9a%e5%bc%ba%e7%83%b7%e5%9f%bac-h%e9%94%ae%e7%9a%84%e6%97%a0%e5%ae%9a%e5%90%91%e7%a1%bc%e5%8c%96%e4%bd%9c%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=201803","title":{"rendered":"\u6700\u65b0Science\uff1a\u5f3a\u70f7\u57faC-H\u952e\u7684\u65e0\u5b9a\u5411\u787c\u5316\u4f5c\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5728\u6709\u673a\u5206\u5b50\u4e2d\u975e\u53cd\u5e94\u6027C-H\u952e\u7684\u4f4d\u7f6e\u4e0a\u5b89\u88c5\u5b98\u80fd\u56e2\u4e00\u76f4\u662f\u5408\u6210\u5316\u5b66\u7684\u957f\u671f\u76ee\u6807\u3002 \u5728\u6ca1\u6709\u9644\u8fd1\u5f15\u5bfc\u57fa\u56e2\u7684\u534f\u52a9\uff0c\u8fd9\u79cdC-H\u952e\u4e4b\u95f4\u7684\u53cd\u5e94\u53ef\u4ee5\u8bf4\u662f\u6700\u5927\u7684\u6311\u6218\u3002\u5df2\u77e5\u8bb8\u591a\u53cd\u5e94\uff0c\u65e0\u8bba\u662f\u50ac\u5316\u53cd\u5e94\u8fd8\u662f\u975e\u50ac\u5316\u53cd\u5e94\uff0c\u90fd\u53d1\u751f\u5728\u82c4\u57fa\u3001\u70ef\u4e19\u57fa\u3001\u4e00\u7ea7\u548c\u4e8c\u7ea7C-H\u952e\u4e0a\uff0c\u4f46\u662f\u4e00\u7ea7C-H\u952e\u7684\u65e0\u5b9a\u5411\u5b98\u80fd\u5316\u4f5c\u7528\u66f4\u5f3a\uff0c\u7535\u5b50\u542b\u91cf\u66f4\u4f4e\uff0c\u53d1\u5c55\u5f97\u66f4\u6162\u3002\u4e00\u7ea7C-H\u952e\u6bd4\u4e8c\u7ea7\u6216\u4e09\u7ea7C-H\u952e\u5f3a\uff0c\u6bd4\u4f4d\u4e8e\u03b1-\u6742\u539f\u5b50\u6216\u03b1-\u82b3\u57fa\u73af\u7684C-H\u952e\u5f3a\u5f97\u591a\u3002\u56e0\u6b64\uff0c\u4e00\u7ea7C-H\u952e\u5bf9\u8bd5\u5242\u3001\u5316\u5b66\u50ac\u5316\u5242\u6216\u9176\u7684\u6d3b\u6027\u6700\u4f4e\uff0c\u8fd9\u4e9b\u8bd5\u5242\u3001\u50ac\u5316\u5242\u6216\u9176\u80fd\u591f\u5c06\u6c22\u539f\u5b50\u6216\u6c22\u5316\u7269\u5206\u79bb\u51fa\u6765\uff0c\u751f\u6210\u70f7\u57fa\u81ea\u7531\u57fa\u6216\u78b3\u6b63\u79bb\u5b50\u4e2d\u95f4\u4f53\u3002\u7136\u800c\uff0c\u50ac\u5316\u5242\u53ef\u4ee5\u6539\u53d8\u5316\u5b66\u53cd\u5e94\u53d1\u751f\u7684\u90e8\u4f4d\u3002\u7279\u5b9a\u79cd\u7c7b\u7684\u78b3\u70ef\u7684\u63d2\u5165\u53ef\u80fd\u4f18\u5148\u53d1\u751f\u5728\u5177\u6709\u7a7a\u95f4\u4f4d\u963b\u50ac\u5316\u5242\u7684\u4e00\u7ea7C-H\u952e\u4e2d\uff0c\u800c\u4e0d\u662f\u4e8c\u7ea7C-H\u952e\u4e2d\uff0c\u4f46\u662f\u636e\u62a5\u9053\u53ea\u6709\u4e00\u7c7b\u53cd\u5e94\uff08C-H\u952e\u7684\u787c\u5316\uff09\u6ca1\u6709\u53d1\u751f\u3002\u7531\u4e8e\u70f7\u57fa\u787c\u9178\u916f\u53ef\u4ee5\u5f62\u6210\u591a\u79cd\u7c7b\u578b\u7684\u4ea7\u7269\uff0c\u56e0\u6b64\u5177\u6709\u975e\u5e38\u89c4\u7684\u9009\u62e9\u6027\u5e76\u5177\u6709\u6f5c\u5728\u7684\u5408\u6210\u4ef7\u503c\uff0c\u4f46\u4e00\u7ea7C-H\u952e\u7684\u787c\u5316\u901a\u5e38\u8981\u6c42\u5e95\u7269\u4e3a\u6eb6\u5242\u6216\u5927\u91cf\u8fc7\u91cf\uff0c\u800c\u4e14\u6ca1\u6709\u5728\u6f5c\u5728\u53cd\u5e94\u6027\u5b98\u80fd\u56e2\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u53d1\u751f\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u4eca\u65e5\uff0c\u5728\u7f8e\u56fd<\/b><\/strong>\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821John Hartwig<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u7b49\u4eba<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u75312-\u7532\u57fa\u83f2\u7f57\u5549\u8fde\u63a5\u7684\u94f1\u50ac\u5316\u5242\uff0c\u5177\u6709\u4ee5\u5e95\u7269\u4e3a\u9650\u5236\u5242\u7684\u6d3b\u6027\uff0c\u53ef\u4ee5\u4f7f\u4e00\u7ea7C-H\u952e\u65e0\u5b9a\u5411\u787c\u5316\uff0c\u5e76\u4e14\u5f53\u4e00\u7ea7C-H\u952e\u4e0d\u5b58\u5728\u6216\u53d7\u963b\u65f6\uff0c\u53ef\u4f7f\u4e8c\u7ea7C-H\u952e\u7684\u787c\u5316\u4f5c\u7528\u3002\u5728\u751f\u6210\u7684\u78b3-\u787c\u952e\u4e0a\u7684\u53cd\u5e94\u89e3\u91ca\u4e86\uff0c\u8fd9\u4e9b\u787c\u5316\u4f5c\u7528\u5982\u4f55\u5bfc\u81f4\u5728\u6709\u673a\u5206\u5b50\u4ee5\u524d\u65e0\u6cd5\u8fbe\u5230\u7684\u4f4d\u7f6e\u4e0a\u5b89\u88c5\u5927\u91cf\u7684\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/b><\/strong>Diverse functionalization of strong alkyl C<\/b><\/strong>–<\/b><\/strong>H bonds by undirected borylation<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Science<\/b><\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1<\/b><\/strong>\u00a0<\/b><\/strong>\u4e0d\u540c\u53d6\u4ee3\u83f2\u7f57\u5549\u914d\u4f53\u7684B2pin2\u4e0e\u56db\u6c22\u544b\u5583\u548c\u4e8c\u4e01\u57fa\u919a\u7684<\/b><\/strong>Ir<\/b><\/strong>\u50ac\u5316\u53cd\u5e94<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>2 \u70f7\u57fa\u7684\u4e00\u7ea7C-H\u952e\u548c\u73af\u72b6\u5316\u5408\u7269\u7684\u4e8c\u7ea7C-H\u952e\u7684\u787c\u5316\u4f5c\u7528<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>3 <\/b><\/strong>\u70f7\u57faC-H\u952e\u5904\u7684C-H\u787c\u5316\u4ea7\u7269\u7684\u884d\u751f\u5316<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>4 <\/b><\/strong>N-Boc 3-\u787c\u57fa\u5421\u54af\u70f7\u7684B<\/b><\/strong>–<\/b><\/strong>C\u952e\u7684\u884d\u751f\u5316<\/b><\/strong>\"\"<\/p>\n

\u56fe<\/b><\/strong>5 <\/b><\/strong>\u8131\u6c22\u677e\u9999\u9178\u53d4\u4e01\u916f\u7684\u787c\u5316\u548c\u884d\u751f\u5316<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Diverse functionalization of strong alkyl C<\/u>–<\/u>H bonds by undirected borylation<\/u><\/a>\uff08Science\uff0c2020\uff0cDOI:10.1126\/science.aba6146\uff09<\/p>\n

\u672c\u6587\u7531\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5728\u6709\u673a\u5206\u5b50\u4e2d\u975e\u53cd\u5e94\u6027C-H\u952e\u7684\u4f4d\u7f6e\u4e0a\u5b89\u88c5\u5b98\u80fd\u56e2\u4e00\u76f4\u662f\u5408\u6210\u5316\u5b66\u7684\u957f\u671f\u76ee\u6807\u3002 \u5728\u6ca1\u6709\u9644\u8fd1\u5f15\u5bfc\u57fa\u56e2\u7684\u534f\u52a9\uff0c\u8fd9\u79cdC-H\u952e\u4e4b\u95f4\u7684\u53cd\u5e94\u53ef\u4ee5\u8bf4\u662f\u6700\u5927\u7684\u6311\u6218\u3002\u5df2\u77e5\u8bb8\u591a…<\/p>\n","protected":false},"author":2109,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[67],"tags":[155,116],"class_list":["post-201803","post","type-post","status-publish","format-standard","hentry","category-zhoubao","tag-science","tag-catalyst"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201803"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=201803"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201803\/revisions"}],"predecessor-version":[{"id":201814,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201803\/revisions\/201814"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=201803"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=201803"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=201803"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}