{"id":201735,"date":"2020-05-20T06:08:10","date_gmt":"2020-05-19T22:08:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=201735"},"modified":"2020-05-19T20:08:31","modified_gmt":"2020-05-19T12:08:31","slug":"%e8%80%b6%e9%b2%81%e5%a4%a7%e5%ad%a6angew-%e9%ab%98%e8%83%bd%e5%8f%8d%e5%ba%94%e8%af%b1%e5%af%bc%e7%9a%84%e9%ab%98%e6%95%88%e5%85%a8%e5%9b%ba%e6%80%81%e9%94%82-%e7%94%b5%e8%a7%a3%e8%b4%a8%e7%95%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=201735","title":{"rendered":"\u8036\u9c81\u5927\u5b66Angew: \u9ad8\u80fd\u53cd\u5e94\u8bf1\u5bfc\u7684\u9ad8\u6548\u5168\u56fa\u6001\u9502\/\u7535\u89e3\u8d28\u754c\u9762"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u91d1\u5c5e\u7531\u4e8e\u5176\u9ad8\u5bb9\u91cf\u548c\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4f4e\u800c\u88ab\u8ba4\u4e3a\u662f\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u7ec8\u6781\u8d1f\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u5176\u5728\u5e38\u89c4\u6db2\u6001\u7535\u89e3\u8d28\u4e2d\u5b58\u5728\u8d1f\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u5904\u7684\u526f\u53cd\u5e94\uff0cLi\u679d\u6676\u7684\u5f62\u6210\u4ee5\u53ca\u5728\u5145\u653e\u7535\u5faa\u73af\u671f\u95f4\u6b7b\u9502\u7684\u7d2f\u79ef\u7b49\u95ee\u9898\u3002\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\u6709\u671b\u7f13\u89e3\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5b89\u5168\u95ee\u9898\u3002\u5176\u4e2d\uff0c\u77f3\u69b4\u77f3\u7ed3\u6784\u7684Li7<\/sub>La3<\/sub>Zr2<\/sub>O12<\/sub>(LLZO)\u53ca\u5176\u884d\u751f\u7269\u7531\u4e8e\u5176\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u8f83\u9ad8\u7684Li+<\/sup>\u7535\u5bfc\u7387\u4e14\u5bf9\u9502\u91d1\u5c5e\u5177\u6709\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u56e0\u800c\u5177\u6709\u826f\u597d\u7684\u524d\u666f\u3002\u7136\u800c\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u4e0eLLZO\u7684\u754c\u9762\u63a5\u89e6\u4e0d\u826f\u4f1a\u5bfc\u81f4\u8f83\u5927\u7684\u754c\u9762\u963b\u6297\u3002\u5c06\u4e24\u79cd\u56fa\u4f53\u538b\u5728\u4e00\u8d77\u5f62\u6210\u7684Li\/LLZO\u754c\u9762\u53ea\u80fd\u5728\u975e\u5e38\u4f4e\u7684\u7535\u6d41\u5bc6\u5ea6(<0.2 mA\/ cm2<\/sup>\uff09\u548c\u5bb9\u91cf(<0.2 mAh\/cm2<\/sup>)\u4e0b\u5faa\u73af\u3002Li\/LLZO\u754c\u9762\u4e5f\u5bb9\u6613\u5f62\u6210\u679d\u6676\uff0c\u8be5\u679d\u6676\u6cbfLLZO\u7684\u6676\u754c\u4f20\u64ad\uff0c\u5e76\u7ecf\u5e38\u5728\u5faa\u73af\u7684\u65e9\u671f\u9636\u6bb5\u5bfc\u81f4\u7535\u6c60\u6545\u969c\u3002\u8fd1\u5e74\u6765\uff0c\u5df2\u5bfb\u6c42\u8bb8\u591a\u754c\u9762\u8bbe\u8ba1\uff0c\u5305\u62ec\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u91d1\u5c5e\u5408\u91d1\uff0c\u77f3\u58a8\uff0c\u805a\u5408\u7269\u548cLi+<\/sup>\u5bfc\u4f53\uff0c\u4ee5\u51cf\u8f7b\u8fd9\u4e9b\u95ee\u9898\u3002\u5c3d\u7ba1\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u5c55\uff0c\u4f46\u56fa\u6001\u9502\/\u77f3\u69b4\u77f3\u7535\u6781\u5728\u8fc7\u7535\u4f4d\uff0c\u5145\u653e\u7535\u5bb9\u91cf\uff0c\u5faa\u73af\u5bff\u547d\u548c\u500d\u7387\u6027\u80fd\u7b49\u65b9\u9762\u4e0e\u6db2\u6001\u7535\u89e3\u8d28\u8fd0\u884c\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u4ecd\u76f8\u5dee\u751a\u8fdc\u3002\u56e0\u6b64\uff0c\u9700\u8981\u5f00\u53d1\u66f4\u597d\u7684\u56fa\u6001Li\/LLZO\u754c\u9762\uff0c\u4ee5\u5b9e\u73b0\u5177\u6709\u66f4\u597d\u6027\u80fd\u548c\u66f4\u5b89\u5168\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u8036\u9c81\u5927\u5b66\u738b\u6d77\u6881\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u5f00\u53d1\u4e86\u4e00\u79cd\u56fa\u6001\u9502\/\u77f3\u69b4\u77f3\u7535\u6781\uff0c\u8be5\u7535\u6781\u7684\u5bb9\u91cf\u3001\u5145\u653e\u7535\u500d\u7387\u3001\u8fc7\u7535\u4f4d\u53ef\u4e0e\u6db2\u6001\u7535\u89e3\u6db2\u4e2d\u7684\u9502\u91d1\u5c5e\u6027\u80fd\u76f8\u5ab2\u7f8e\u3002\u6b64\u5916\uff0c\u8fd8\u5177\u6709\u66f4\u957f\u7684\u5faa\u73af\u5bff\u547d\uff0c\u66f4\u9ad8\u7684\u6548\u7387\u548c\u66f4\u597d\u7684\u5b89\u5168\u6027\u3002\u5229\u7528Zn(NO3<\/sub>)2<\/sub>\u548cLi\u4e4b\u95f4\u7684\u5316\u5b66\u53cd\u5e94\u6765\u521b\u5efa\u4e00\u4e2a\u72ec\u7279\u7684\u754c\u9762\u5c42\uff0c\u8be5\u754c\u9762\u5c42\u5c06Li6.4<\/sub>La3<\/sub>Zr1.4<\/sub>Ta0.6<\/sub>O12<\/sub>(LLZTO)\u7535\u89e3\u8d28\u548cLi\u91d1\u5c5e\u710a\u63a5\u5728\u4e00\u8d77\u3002\u53cd\u5e94\u5f62\u6210\u7684Zn\u548cZnLix<\/sub>\u5408\u91d1\u662f\u826f\u597d\u7684\u7535\u5b50\u5bfc\u4f53\uff0c\u5176\u4e0eLi\u91d1\u5c5e\u9633\u6781\u5177\u6709\u5f88\u5f3a\u7684\u4eb2\u548c\u529b\u3002\u53cd\u5e94\u5f62\u6210Li3<\/sub>N\u548cLi2<\/sub>O\u7684\u662f\u826f\u597d\u7684Li+<\/sup>\u5bfc\u4f53\uff0c\u4e0e\u6c27\u5316\u7269\u7535\u89e3\u8d28\u5177\u6709\u5f88\u5f3a\u7684\u4eb2\u548c\u529b\u3002\u7531\u4e8e\u8be5\u754c\u9762\u5c42\u7684\u5b58\u5728\uff0c\u5168\u56fa\u6001Li || Li\u7535\u6c60\u53ef\u4ee5\u5728\u66f4\u9ad8\u7684\u7535\u6d41\u5bb9\u91cf\u6761\u4ef6(4 mA\/cm2<\/sup>-8 mAh\/cm2<\/sup>)\u4e0b\u5faa\u73af\uff0c\u663e\u8457\u9ad8\u4e8e\u76ee\u524d\u5176\u4ed6\u540c\u7c7b\u578b\u7535\u6c60\u3002\u8be5\u4f53\u7cfb\u51e0\u4e4e\u6ca1\u6709\u526f\u53cd\u5e94\u548c\u9502\u679d\u6676\u5f62\u6210\uff0c\u57282 mA\/cm2<\/sup>-2 mAh\/cm2<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0c\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af2400 h\uff0c\u5e76\u4e14\u5728\u8fde\u7eed\u5145\u653e\u75351000 h\u540e\uff0c\u6ca1\u6709\u89c2\u5bdf\u5230\u7535\u89e3\u8d28\u7684\u964d\u89e3\u3002\u5f53\u8584\u7684Li\u7535\u6781\u4ee580\uff05\u7684\u653e\u7535\u6df1\u5ea6\u5faa\u73af\u65f6\uff0cLi || Li\u7535\u6c60\u53ef\u7ef4\u63011000\u5c0f\u65f6\u4ee5\u4e0a\u3002\u57fa\u4e8e\u8be5\u7535\u6781\u7684\u5168\u56fa\u6001Li || LFP\u5168\u7535\u6c60\u57281 C\u7684\u500d\u7387\u4e0b\u5177\u6709150 mAh\/g\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\uff0c\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af400\u6b21\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cHighly Efficient All-Solid-State Lithium\/Electrolyte Interface Induced by an Energetic Reaction<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Angewandte Chemie-International Edition<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/strong> Z<\/strong>NR<\/strong>\u754c\u9762\u5c42\u7684\u5f62\u6210\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09Li\u4e0eZn(NO3<\/sub>)2<\/sub>\u53cd\u5e94\u7684\u7167\u7247\u5149\u5b66\u4ee5\u53ca\u5316\u5b66\u65b9\u7a0b\u5f0f\u3002<\/p>\n

\uff08c\uff09\u56fa\u6001ZNR Li\/LLZTO\u754c\u9762\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\uff08d\uff0ce\uff09Li\u6da6\u6e7fZn(NO3<\/sub>)2<\/sub>2\u6d82\u5c42\u548c\u539f\u59cbLLZTO\u7684\u5149\u5b66\u7167\u7247\u3002<\/p>\n

\uff08f\uff0cg\uff09ZNR\u754c\u9762\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c<\/strong>Z<\/strong>NR<\/strong>\u754c\u9762\u5c42\u7684\u7269\u7406\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09ZNR\u754c\u9762\u5c42\u7684SEM\u56fe\u50cf\u4ee5\u53caZn\u548cN \u7684AES\u6620\u5c04\uff0c<\/p>\n

\uff08d-f\uff09TEM\u56fe\u50cf\u548cZNR\u754c\u9762\u6a2a\u622a\u9762\u7684SAED\u3002<\/p>\n

\uff08g-i\uff09ZNR\u754c\u9762\u5c42\u7684XPS\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e09<\/strong> Li || Li<\/strong>\u534a\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6-\u5bb9\u91cf\u6761\u4ef6\u4e0b\uff0c\u5177\u6709ZNR\u754c\u9762\u7684\u56fa\u6001Li || Li\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\uff08b\uff09\u57280.3 mA\/cm2<\/sup>-0.6 mAh\/cm2<\/sup>\u6761\u4ef6\u4e0b\u672a\u4fee\u9970\u7684\u56fa\u6001Li || Li\u7535\u6c60\u7684\u5145\u653e\u7535\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff0cd\uff09\u5177\u6709ZNR\u754c\u9762\u4fee\u9970\u7684Li || Li\u7535\u6c60\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\uff08e\uff09\u4e0e\u5176\u4ed6\u540c\u7c7b\u578b\u5de5\u4f5c\u7684\u5bf9\u6bd4\u3002<\/p>\n

\u56fe\u56db<\/strong> \u56fa\u6001<\/strong>Li || LFP<\/strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5168\u56fa\u6001Li || LFP\u7535\u6c60\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09SN-PPC\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\u5728\u5ba4\u6e29\u4e0b\u7684\u7167\u7247\u3002<\/p>\n

\uff08c\uff09\u5168\u56fa\u6001\u548c\u6db2\u6001Li || LFP\u7535\u6c60\u57281\/5 C\u7684\u88ab\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\uff08d\uff09\u57281\/5 C\u548c1C\u4e0b\u5168\u56fa\u6001Li || LFP\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e94<\/strong> \u5177\u6709<\/strong>ZNR<\/strong>\u754c\u9762\u7684<\/strong>LLZTO<\/strong>\u7684\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728Li | Li\u7535\u6c60\u4e2d\u4ee50.5 mA\/cm2<\/sup>-1 mAh\/cm2<\/sup>\u7684\u6761\u4ef6\u5faa\u73af1000\u5c0f\u65f6\u540e\uff0c\u5177\u6709ZNR\u754c\u9762\u7684LLZTO\u9897\u7c92\u7684\u6a2a\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n

\uff08b\uff09\u5faa\u73af\u540e\u7535\u89e3\u8d28\u9897\u7c92\u8868\u9762XPS\u5149\u8c31\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u603b\u4e4b\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u56fa\u6001Li\/LLZTO\u754c\u9762\uff0c\u53ef\u5b9e\u73b0\u4e0e\u5728\u6db2\u6001\u7535\u89e3\u8d28\u4e2d\u8fd0\u884c\u7684Li\u91d1\u5c5e\u8d1f\u6781\u76f8\u5f53\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u8fd9\u79cd\u72ec\u7279\u7684ZNR\u754c\u9762\u6e90\u81eaZn(NO3<\/sub>)2<\/sub>\u4e0eLi\u4e4b\u95f4\u7684\u9ad8\u80fd\u53cd\u5e94\uff0c\u53ef\u7262\u56fa\u5730\u952e\u5408Li\u548cLLZTO\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u5b9e\u73b0\u66f4\u5feb\u7684Li+<\/sup>\u4f20\u8f93\uff0c\u5e76\u907f\u514d\u4e86\u526f\u53cd\u5e94\u548c\u9502\u679d\u6676\u7684\u5f62\u6210\uff0c\u4ece\u800c\u5bfc\u81f4\u5168\u56fa\u6001\u7684Li || Li\u548cLi || LFP\u7535\u6c60\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>Highly Efficient All-Solid-State Lithium\/Electrolyte Interface Induced by an Energetic Reaction<\/strong><\/a>\u201d<\/strong>(DOI: 10.1002\/anie.202004477)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u9502\u91d1\u5c5e\u7531\u4e8e\u5176\u9ad8\u5bb9\u91cf\u548c\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4f4e\u800c\u88ab\u8ba4\u4e3a\u662f\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u7ec8\u6781\u8d1f\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u5176\u5728\u5e38\u89c4\u6db2\u6001\u7535\u89e3\u8d28\u4e2d\u5b58\u5728\u8d1f\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u5904\u7684\u526f\u53cd\u5e94\uff0cLi\u679d\u6676\u7684\u5f62\u6210\u4ee5\u53ca…<\/p>\n","protected":false},"author":7084,"featured_media":201736,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[129],"class_list":["post-201735","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201735"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=201735"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201735\/revisions"}],"predecessor-version":[{"id":202189,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201735\/revisions\/202189"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/201736"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=201735"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=201735"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=201735"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}