{"id":201665,"date":"2020-05-21T06:52:02","date_gmt":"2020-05-20T22:52:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=201665"},"modified":"2020-05-20T19:53:08","modified_gmt":"2020-05-20T11:53:08","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6afm-%e9%80%9a%e8%bf%87%e7%a6%bb%e5%ad%90%e6%8e%ba%e6%9d%82%e5%92%8c%e7%bb%93%e6%9e%84%e8%ae%be%e8%ae%a1%e5%ae%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=201665","title":{"rendered":"\u6d59\u6c5f\u5927\u5b66AFM: \u901a\u8fc7\u79bb\u5b50\u63ba\u6742\u548c\u7ed3\u6784\u8bbe\u8ba1\u5b9e\u73b0\u5177\u6709\u9ad8\u500d\u7387\u6027\u80fd\u7684Ti2Nb10O29\u8d1f\u6781\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60(LIBs)\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u6210\u529f\uff0c\u6210\u4e3a\u4e86\u76ee\u524d\u4f7f\u7528\u6700\u666e\u904d\u7684\u50a8\u80fd\u88c5\u7f6e\u3002\u7535\u6781\u6750\u6599\u4f5c\u4e3aLIBs\u7684\u5173\u952e\u7ec4\u6210\u90e8\u5206\uff0c\u5bf9\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u8d77\u7740\u51b3\u5b9a\u6027\u7684\u4f5c\u7528\u3002\u81ea2011\u5e74Goodenough\u8bfe\u9898\u7ec4\u7684\u5f00\u521b\u6027\u5de5\u4f5c\u4ee5\u6765\uff0c\u949b\u94cc\u6c27\u5316\u7269\u6750\u6599\uff08\u5982TiNb2<\/sub>O7<\/sub>\uff0cTi2<\/sub>Nb10<\/sub>O29<\/sub>\uff09\u7531\u4e8e\u5176\u7406\u8bba\u6bd4\u5bb9\u91cf\u9ad8\uff08\u63a5\u8fd1400 mAh g-1<\/sup>\uff09\u3001\u7ed3\u6784\u7a33\u5b9a\u3001\u5d4c\u9502\u7535\u4f4d\u9ad8\u4e0d\u6613\u6790\u9502\u548c\u9ad8\u5e93\u4f26\u6548\u7387\u7b49\u6210\u4e3a\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u7684\u7814\u7a76\u70ed\u70b9\u3002\u7136\u800c\uff0c\u5176\u5b9e\u7528\u5316\u4ecd\u9762\u4e34\u7740\u7535\u5b50\u7535\u5bfc\u7387\u548c\u79bb\u5b50\u7535\u5bfc\u7387\u4f4e\u7b49\u95ee\u9898\u3002\u4e3a\u4e86\u5b9e\u73b0\u9ad8\u529f\u7387\u548c\u957f\u5bff\u547d\u7279\u6027\uff0c\u589e\u5f3aTNO\u7684\u56fa\u6709\u7535\u5b50\/\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u662f\u5341\u5206\u91cd\u8981\u7684\uff0c\u540c\u65f6\u8fd8\u9700\u8981\u6539\u5584TNO\u548c\u7535\u89e3\u6db2\u754c\u9762\u7684\u79bb\u5b50\/\u7535\u5b50\u8f6c\u79fb\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u590f\u65b0\u8f89\u7814\u7a76\u5458\u3001\u738b\u79c0\u4e3d\u526f\u6559\u6388<\/strong>\u8054\u5408\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u5218\u5947\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\uff09\u62a5\u9053\u4e86\u901a\u8fc7\u7ed3\u5408\u79bb\u5b50\u63ba\u6742\u548c\u7ed3\u6784\u8bbe\u8ba1\u534f\u540c\u4f5c\u7528\u5b9e\u73b0\u9ad8\u529f\u7387\u7684TNO\u7535\u6781\u3002 \u9996\u5148\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u591a\u5b54\u5782\u76f4\u77f3\u58a8\u70ef@ TiC-C\u9635\u5217(VGTC)\u9aa8\u67b6\u4f5c\u4e3a\u5bfc\u7535\u57fa\u5e95\uff0c\u5b83\u4e0d\u4ec5\u5177\u6709\u4f18\u8d8a\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u548c\u79bb\u5b50\/\u7535\u5bfc\u7387\uff0c\u800c\u4e14\u5bf9TNO\u8d77\u5230\u4e86\u4e00\u5b9a\u7684\u7ea6\u675f\u4f5c\u7528\uff0c\u4ece\u800c\u7a33\u5b9a\u4e86\u7ed3\u6784\u3002\u7136\u540e\uff0c\u7531\u4e8eVGTC\u7684\u9650\u5236\u4f5c\u7528\uff0c\u7136\u540e\uff0c\u5728\u5bfc\u7535VGTC\u9aa8\u67b6\u4e0a\u5b9e\u73b0\u4e86Cr3+<\/sup>\u63ba\u6742\u7684TNO(Cr-TNO)\u7eb3\u7c73\u7c92\u5b50\u7684\u87ba\u65cb\u751f\u957f\uff0c\u5f62\u6210\u4e86\u5f62\u6210Cr-TNO @ VGTC\u9635\u5217\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u548c\u539f\u4f4d\u540c\u6b65\u8f90\u5c04XRD\u6280\u672f\u8868\u660eCr3+<\/sup>\u63ba\u6742\u53ef\u4ee5\u4f7f\u5f97TNO\u5177\u6709\u66f4\u5feb\u7684\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\u548c\u589e\u5f3a\u4e86\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0cCr-TNO @ VGTC\u7535\u6781\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff0c\u572840C\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5177\u6709220 mAh g-1<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\uff08\u529f\u7387\u5bc6\u5ea6\u224811kW kg-1<\/sup>\uff09\u572810 C\u4e0b500\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a91\uff05\uff0c\u8fdc\u8d85\u4e8e\u5176\u4ed6\u5de5\u4f5c\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cSynergy of Ion Doping and Spiral Array Architecture on Ti2<\/sub>Nb10<\/sub>O29<\/sub>: A New Way to Achieve High-Power Electrodes<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Functional Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/strong>Cr-TNO @ VGTC<\/strong>\u9635\u5217\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09VGTC\u9635\u5217\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\uff08c\uff09VGTC\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\uff08d-f\uff09Cr-TNO @ VGTC\u9635\u5217\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\uff08g\uff0ch\uff09Cr-TNO @ VGTC\u7684TEM-HRTEM\u56fe\u50cf\u3002<\/p>\n

\uff08j\uff09Cr-TNO @ VGTC\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e8c<\/strong>\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09TNO @ VGTC\u548cCr-TNO @ VGTC\u7535\u6781\u7684CV\u66f2\u7ebf\u3002<\/p>\n

\uff08b\uff09TNO @ VGTC\u548cCr-TNO @ VGTC\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\uff08c\uff0910C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\uff08d\uff09\u5728\u7b2c\u4e00\u6b21\u5faa\u73af\u5b8c\u540e\u7684EIS\u8c31\u56fe\u3002<\/p>\n

\uff08e\uff0910C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u7684\u957f\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e09<\/strong>Cr-TNO<\/strong>\u7684\u540c\u6b65\u8f90\u5c04<\/strong>XRD<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09TNO\u548cCr-TNO\u6750\u6599\u7684\u7cbe\u4feeXRD\u3002\u3002<\/p>\n

\uff08d\uff09TNO\u6676\u80de\u7684\u6676\u683c\u53c2\u6570\u3002<\/p>\n

\uff08e\uff09\u4ece\u6807\u51c6PDF\u6570\u636e\u4e2d\u83b7\u5f97\u7684TNO\u7eb3\u7c73\u7c92\u5b50\u7684\u6676\u80de\u3002<\/p>\n

\uff08f\uff09\u57fa\u4e8eNb\/Ti\u90e8\u5206\u6709\u5e8f\u7ed3\u6784\u6a21\u578b\u7684\u7eafTNO\u7eb3\u7c73\u7c92\u5b50\u7684XRD\u7cbe\u4fee\u8c31\u56fe\u3002<\/p>\n

\uff08g\uff09\u5177\u6709Nb \/ Ti\u90e8\u5206\u6709\u5e8f\u7ed3\u6784\u7684Cr-TNO\u7eb3\u7c73\u7c92\u5b50\u7684\u6676\u80de\u3002<\/p>\n

\u56fe\u56db<\/strong>TNO<\/strong>\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e94<\/strong>Cr-TNO<\/strong>\u7684\u539f\u4f4d\u540c\u6b65\u8f90\u5c04<\/strong>XRD<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Cr-TNO\u6837\u54c1\u7684\u539f\u4f4dXRD\u8c31\u56fe\u548c\u76f8\u5e94\u7684\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\uff08b-e\uff09\u4eceCr-TNO\u6837\u54c1\u7684\u539f\u4f4dXRD\u56fe\u8bb0\u5f55\u7684\u5178\u578b\u5806\u53e0\u5cf0\u8f6e\u5ed3\u7ec4\u3002<\/p>\n

\uff08f\uff09Cr-TNO\u6837\u54c1\u7684\u6676\u683c\u6f14\u5316\u548c\u76f8\u5e94\u7684\u7535\u538b\u66f2\u7ebf\u3002 \u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u603b\u4e4b\uff0c\u4f5c\u8005\u8bbe\u8ba1\u5e76\u9a8c\u8bc1\u4e86\u79bb\u5b50\u63ba\u6742\u548c\u87ba\u65cb\u9635\u5217\u67b6\u6784\u7684\u534f\u540c\u4f5c\u7528\uff0c\u8fd9\u662f\u4e00\u79cd\u5b9e\u73b0\u9ad8\u529f\u7387\u7535\u6781\u7528\u4e8e\u7535\u5316\u5b66\u50a8\u80fd\u7684\u65b0\u65b9\u6cd5\u3002\u7eb3\u7c73\u7ea7Cr-TNO\u4ee5\u87ba\u65cb\u65b9\u5f0f\u7d27\u51d1\u5730\u751f\u957f\u5728VGTC\u9aa8\u67b6\u4e0a\uff0c\u7531\u4e8eVGTC\u7684\u9650\u5236\u4f5c\u7528\uff0c\u5f62\u6210Cr-TNO @ VGTC\u9635\u5217\u3002\u501f\u52a9DFT\u8ba1\u7b97\u548c\u539f\u4f4d\u540c\u6b65\u8f90\u5c04XRD\u6280\u672f\uff0c\u53d1\u73b0Cr3+<\/sup>\u63ba\u6742\u53ef\u4ee5\u63d0\u9ad8\u7535\u5b50\/\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u5e76\u5177\u6709\u66f4\u5f00\u653e\u7684TNO\u6676\u4f53\u7ed3\u6784\uff0c\u53ef\u4ee5\u52a0\u5feb\u9502\u79bb\u5b50\u7684\u6269\u6563\u901f\u7387\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u540c\u6b65\u8f90\u5c04\u6280\u672f\u53ef\u4ee5\u6e05\u695a\u5730\u663e\u793a\u51faCr3+<\/sup>\u7684\u63ba\u6742\u4f4d\u70b9\u3002\u8fd9\u79cd\u534f\u540c\u7b56\u7565\u8bbe\u8ba1\u4f7f\u5f97\u65b0\u578bCr-TNO @ VGTC\u9635\u5217\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5b50\/\u79bb\u5b50\u5bfc\u7535\u6027\u548c\u589e\u5f3a\u4e86\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0cCr-TNO @ VGTC\u5177\u6709\u4f18\u5f02\u7684\u9ad8\u529f\u7387\u7279\u6027\uff0c\u572840 C\u4e0b\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5177\u6709220 mAh g-1<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\uff08\u529f\u7387\u5bc6\u5ea6\u7ea6\u4e3a11 kW kg-1<\/sup>\uff09\u548c\u7a33\u5b9a\u7684\u5faa\u73af\u6027\u80fd\uff08500\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a91%\uff09\u3002\u8fd9\u79cd\u534f\u540c\u7b56\u7565\u901a\u8fc7\u6539\u5584\u56fa\u6709\u7684\u7535\u5b50\/\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u63d0\u9ad8\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u4e3a\u5927\u529f\u7387\u7535\u6781\u6750\u6599\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>Synergy of Ion Doping and Spiral Array Architecture on Ti2Nb10O29: A New Way to Achieve High-Power Electrodes<\/strong><\/a>\u201d<\/strong>(DOI: 10.1002\/adfm.202002665)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60(LIBs)\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u6210\u529f\uff0c\u6210\u4e3a\u4e86\u76ee\u524d\u4f7f\u7528\u6700\u666e\u904d\u7684\u50a8\u80fd\u88c5\u7f6e\u3002\u7535\u6781\u6750\u6599\u4f5c\u4e3aLIBs\u7684\u5173\u952e\u7ec4\u6210\u90e8\u5206\uff0c\u5bf9\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff…<\/p>\n","protected":false},"author":7084,"featured_media":201670,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1030],"class_list":["post-201665","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-1030"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201665"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=201665"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201665\/revisions"}],"predecessor-version":[{"id":202222,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/201665\/revisions\/202222"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/201670"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=201665"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=201665"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=201665"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}