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\u5728\u524d\u9762\u7406\u8bba\u8bbe\u8ba1\u7684\u6307\u5bfc\u4e0b\uff0c\u6211\u4eec\u8bfe\u9898\u7ec4\u6210\u529f\u5236\u5907\u65b0\u578bLi6.25<\/sub>PTeS4.25<\/sub>Cl0.75<\/sub>\u786b\u94f6\u9517\u77ff\u7535\u89e3\u8d28\u3002\u5f53Te\u90e8\u5206\u53d6\u4ee3S\u540e\uff0c\u5982\u56fe3\uff08a\uff09\u6240\u793a\uff0c<\/strong>\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6709\u7740\u660e\u663e\u63d0\u9ad8\u3002Li6.25<\/sub>PTeS4.25<\/sub>Cl0.75<\/sub>\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u9ad8\u8fbe4.5 mS cm-1<\/sup>\uff0c\u4e14\u6269\u6563\u6fc0\u6d3b\u5c0f\uff0c\u4ec5\u4e3a0.160 eV\uff0c\u4fdd\u969c\u5728\u8d85\u4f4e\u6e29\u73af\u5883\u4e0b\uff08-20\u2103\uff09\uff0c\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u4ecd\u4e3a1.612 mS cm-1<\/sup>\uff0c\u5982\u56fe3\uff08b\uff09\u6240\u793a<\/strong>\u3002AIMD<\/strong>\u9884\u4f30\u7684\u79bb\u5b50\u6269\u6563\u6fc0\u6d3b\u80fd\u4e3a0.168 eV\u4e0e\u5b9e\u6d4b\u6570\u636e0.160 eV\u5b8c\u5168\u81ea\u6d3d\u3002\u5982\uff0c\u56fe3\uff08c\uff09\u6240\u793a\u3002<\/strong><\/p>\n \u53cc\u53cd\u9499\u949b\u77ff\u7535\u89e3\u8d28\u4f53\u7cfb\u7684\u7406\u8bba\u8bbe\u8ba1\u548c\u5b9e\u9a8c\u5236\u5907\uff1a<\/strong><\/p>\n \u7531\u4e8e\u73b0\u6709\u7684\u786b\u5316\u7269\u7535\u89e3\u8d28\u76f8\u5bf9\u91d1\u5c5eLi\u6216Na\u8d1f\u6781\u95f4\u5b58\u5728\u4e25\u91cd\u7684\u526f\u53cd\u5e94\uff0c\u4f1a\u88ab\u5206\u89e3\u6210Li3<\/sub>P, Li2<\/sub>S, Na3<\/sub>P, Na2<\/sub>S\u7b49\u7cdf\u7cd5\u7684\u79bb\u5b50\u5bfc\u4f53\u3002\u4e9f\u9700\u4e00\u7c7b\u4e0e\u91d1\u5c5eLi\u6216Na\u8d1f\u6781\u7684\u517c\u5bb9\u6027\u4f18\u826f\u7684\u7535\u89e3\u8d28\u4f53\u7cfb\u3002\u5df2\u77e5\u7684\u5355\u578b\u53cd\u9499\u949b\u77ff\u7535\u89e3\u8d28Li3<\/sub>OCl, Li3<\/sub>OBr,Na3<\/sub>OBr, Na4<\/sub>OI2<\/sub>\u5177\u6709\u8f83\u597d\u7684\u4e0e\u91d1\u5c5eLi\u6216Na\u8d1f\u6781\u7684\u517c\u5bb9\u6027\uff0c\u4f46\u662f\u5176\u79bb\u5b50\u7535\u5bfc\u7387\u8f83\u5dee\u3002\u56e0\u6b64\u57fa\u4e8e\u6750\u6599\u57fa\u56e0\u7ec4\u65b9\u6cd5\uff0c\u5728\u5355\u53cd\u9499\u949b\u77ff\u7ed3\u6784\u7684\u57fa\u7840\u4e0a\uff0c\u901a\u8fc7\u7ed3\u6784\u6539\u6027\uff0c\u8bbe\u8ba1\u5e76\u5236\u5907\u65b0\u578b\u53cc\u53cd\u9499\u949b\u77ff\u7535\u89e3\u8d28\u3002<\/p>\n \u56fe4<\/strong>\uff1a(a) Li3<\/sub>O0.5<\/sub>S0.5<\/sub>I\u7684\u6676\u4f53\u7ed3\u6784\u56fe\u3002(b) Li3<\/sub>O0.5<\/sub>S0.5<\/sub>I\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3002 (c) \u901a\u8fc7AIMD\u6a21\u62df\u8ba1\u7b97\u5404\u4e2a\u6210\u5206\u7684\u9502\u7684\u8f93\u8fd0\u80fd\u529b\u548c\u6269\u6563\u6fc0\u6d3b\u80fd\u3002<\/p>\n 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(d\u2019),\u660e\u663e\u51cf\u5f31\u6676\u754c\/\u6676\u7c92\u963b\u6297\u7684\u5f71\u54cd\uff0c\u79bb\u5b50\u8f93\u8fd0\u80fd\u529b\u660e\u663e\u4f18\u4e8e\u5355\u578b\u53cd\u9499\u6001\u77ff\u7535\u89e3\u8d28\u3002<\/p>\n \u56fe6\uff1a(a)<\/strong>Na3<\/sub>O0.5<\/sub>S0.5<\/sub>I\u53cc\u53cd\u9499\u949b\u77ff\u7ed3\u6784 (b) Na3<\/sub>O0.5<\/sub>S0.5<\/sub>I\u7684\u7a33\u5b9a\u7535\u538b\u7a97\u53e3 (c)\u5206\u5b50\u52a8\u529b\u5b66Na+<\/sup>\u79bb\u5b50\u8f93\u8fd0\u8f68\u8ff9\u3002<\/p>\n 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wkg-1<\/sup>\u3002\u76f8\u5173\u5b9e\u9a8c\u6b63\u5728\u5f00\u5c55\u4e2d\u3002<\/p>\n \u56fe8<\/strong>\uff1a\u4ee5Na4<\/sub>S0.5<\/sub>O0.5<\/sub>I2<\/sub>\u4e3a\u57fa\u7840\uff0c\u6784\u7b51\u4e00\u4f53\u5316\u56fa\u4f53\u7535\u6c60\u7cfb\u7edf\u3002<\/p>\n \u57fa\u4e8e\u786b\u94f6\u9517\u77ff\u578bLi6<\/sub>PA5<\/sub>X\u7535\u89e3\u8d28\u7684\u5168\u56fa\u6001\u7535\u6c60\u4e00\u4f53\u5316\u7b56\u7565\uff1a<\/strong><\/p>\n \u7535\u89e3\u8d28\u4e0e\u7535\u6781\u7684\u517c\u5bb9\u6027\uff1a<\/strong><\/p>\n 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\u79d1\u6280\u5385\uff09\u3001 \u56fd\u5bb6\u7ea7\u4f4e\u78b3\u53ca\u73af\u4fdd\u6750\u6599\u667a\u80fd\u8bbe\u8ba1\u56fd\u9645\u8054\u5408\u5b9e\u9a8c\u5ba4\uff082015\uff0c \u79d1\u6280\u90e8\uff09\u30022016\u5e74\u4e8e\u201c\u4e2d\u539f\u667a\u8c37\u201d\u521b\u5efa\u90d1\u5dde\u65b0\u4e16\u7eaa\u6750\u6599\u57fa\u56e0\u7ec4\u5de5\u7a0b\u7814\u7a76\u9662\u3002\u521b\u529e\u4e86\u56fd\u9645\u671f\u520a\u300aEnergy & Environmental Materials (EEM)\u300b\uff0c\u7531John Wiley & Sons, Inc\u51fa\u7248\u3002\u7814\u7a76\u96c6\u4e2d\u4e8e\u591a\u5c3a\u5ea6\u6750\u6599\u6a21\u62df\u53ca\u667a\u80fd\u6750\u6599\u8bbe\u8ba1\u3001\u7eb3\u7c73\u53ca\u8584\u819c\u6750\u6599\u5236\u5907\u6280\u672f\u3001\u5148\u8fdb\u6750\u6599\u8868\u5f81\u3001\u65b0\u80fd\u6e90\u53ca\u73af\u5883\u6e05\u6d01\u6750\u6599\u6280\u672f\u7b49\u3002\u53d1\u8868\u5305\u62ec\u300aNature\u300b\u5728\u5185\u7684\u56fd\u9645\u8457\u540d\u671f\u520a\u8bba\u6587200\u4f59\u7bc7\uff0c\u7533\u8bf7\u5e76\u83b7\u5f97\u56fd\u5185\u5916\u4e13\u5229\u591a\u9879\u3002<\/p>\n \u672c\u63a8\u9001\u7531\u90d1\u5dde\u5927\u5b66\u5f90\u7ea2\u6770\u535a\u58eb\u4f9b\u7a3f\u3002<\/strong><\/p>\n
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