{"id":201189,"date":"2020-05-07T06:14:51","date_gmt":"2020-05-06T22:14:51","guid":{"rendered":"\/\/m.iemloyee.com\/?p=201189"},"modified":"2020-05-06T20:15:11","modified_gmt":"2020-05-06T12:15:11","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e6%97%a5%e6%9c%ac%e4%ba%a7%e4%b8%9a%e6%8a%80%e6%9c%af%e7%bb%bc%e5%90%88%e7%a0%94%e7%a9%b6%e6%89%80am%ef%bc%9a%e4%b8%80%e7%a7%8d%e8%b6%85%e6%99%b6%e6%a0%bc","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=201189","title":{"rendered":"\u5357\u4eac\u5927\u5b66&#038;\u65e5\u672c\u4ea7\u4e1a\u6280\u672f\u7efc\u5408\u7814\u7a76\u6240AM\uff1a\u4e00\u79cd\u8d85\u6676\u683c\u7a33\u5b9a\u7684\u5c42\u72b6\u6c27\u5316\u7269\u94a0\u79bb\u5b50\u6b63\u6781\u6750\u6599"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u53ef\u518d\u751f\u80fd\u6e90\u7684\u4e0d\u65ad\u53d1\u5c55\u4ee5\u53ca\u5927\u89c4\u6a21\u7535\u529b\u5e02\u573a\u7684\u6301\u7eed\u9700\u6c42\uff0c\u5f00\u53d1\u5177\u6709\u4f4e\u6210\u672c\u548c\u9ad8\u6027\u80fd\u7684\u50a8\u80fd\u7cfb\u7edf\u8feb\u5728\u7709\u776b\u3002\u5176\u4e2d\uff0c\u57fa\u4e8e\u91d1\u5c5eNa\u8d1f\u6781\u548cAl\u96c6\u6d41\u4f53\u7684\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u7531\u4e8e\u5176\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff08-2.71 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mAh g<sup>-1<\/sup>\u7684\u653e\u7535\u5bb9\u91cf\u3002\u7279\u522b\u662f\u63d0\u51fa\u7684TM\/TM\u6709\u5e8f\u6392\u5217\u589e\u5f3a\u4e86TM\u5c42\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86Na<sup>+<\/sup>\u957f\u5faa\u73af\u7684\u5d4c\u5165\u548c\u8131\u51fa\u3002 \u901a\u8fc7\u672c\u6587\u63d0\u51fa\u7684\u65b9\u6cd5\u5f62\u6210TM\/TM\u6709\u5e8f\u7684\u8d85\u6676\u683c\u7a33\u5b9a\u7684\u5c42\u72b6\u6c27\u5316\u7269\uff0c\u53ef\u4f5c\u4e3a\u9632\u6b62\u5faa\u73af\u540e\u7ed3\u6784\u5012\u584c\u7684\u6709\u6548\u7b56\u7565\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u5f52\u56e0\u4e8e\u6709\u5e8f\u8702\u5de2\u8d85\u6676\u683c\u80fd\u591f\u901a\u8fc7\u6291\u5236\u6676\u4f53\u5e94\u529b\u6765\u7a33\u5b9a\u6676\u80de\u5e76\u6291\u5236TMs\u9633\u79bb\u5b50\u8fc1\u79fb\uff0c\u8fd9\u662f\u4f20\u7edf\u65e0\u5e8f\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\u6240\u4e0d\u5177\u5907\u7684\u7279\u70b9\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong><b>A Superlattice-Stabilized Layered Oxide Cathode for Sodium-Ion Batteries<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong><b>Adv. Mater.<\/b><\/strong>\u4e0a\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe\u4e00\u3001ONNR\u7684\u7ed3\u6784\u8868\u5f81<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-201190\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe1-2.jpg\" alt=\"\" width=\"600\" height=\"486\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe1-2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe1-2-300x243.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\uff08a\uff09Na<sub>3<\/sub>Ni<sub>2<\/sub>RuO<sub>6<\/sub>\u7684X\u5c04\u7ebf\u884d\u5c04\u56fe\u8c31\uff08XRD\uff09\u53ca\u5176Rietveld\u7cbe\u4fee\u7ed3\u679c\uff1b<\/p>\n<p>\uff08b\uff09\u6cbf[010]\u8f74\u89c2\u5bdf\u6837\u54c1\u7684SAED\u56fe\u8c31\uff1b<\/p>\n<p>\uff08c\uff09\u6cbf[310]\u8f74\u6837\u54c1\u7684HAADF\u56fe\u50cf\uff1b<\/p>\n<p>\uff08d\uff09\u6cbf[312]\u8f74\u6837\u54c1\u7684HAADF\u56fe\u50cf\uff1b<\/p>\n<p><strong><b>\u56fe\u4e8c\u3001ONNR\u548cDNNR\u6b63\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-201191\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe2-1.jpg\" alt=\"\" width=\"600\" height=\"282\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe2-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe2-1-300x141.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\uff08a\uff09ONNR\u6b63\u6781\u57280.05C\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08b\uff09DNNR\u6b63\u6781\u57280.05C\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08c\uff09ONNR\u57280.05C\u65f6\u7684dQ\/dV\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08d\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bONNR\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n<p>\uff08e\uff09ONNR\u548cDNNR\u6b63\u6781\u57281C\u65f6\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\u3002<\/p>\n<p><strong><b>\u56fe\u4e09\u3001ONNR\u6b63\u6781\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-201192\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe3-1.jpg\" alt=\"\" width=\"600\" height=\"494\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe3-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe3-1-300x247.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09ONNR\u6b63\u6781\u7684\u539f\u4f4dXRD\u56fe\u8c31\uff1b<\/p>\n<p>\uff08b\uff09\u6cbf[111<sup>&#8211;<\/sup>]\u8f74\u4e0d\u540c\u72b6\u6001\u4e0b\u7684ONNR\u6b63\u6781\u76f8\u5e94\u7684SAED\u56fe\u8c31\uff1b<\/p>\n<p><strong><b>\u56fe\u56db\u3001ONNR\u548cDNNR\u6b63\u6781\u5faa\u73af\u6027\u80fd\u7684\u6bd4\u8f83<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-201193\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe4-1.jpg\" alt=\"\" width=\"600\" height=\"404\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe4-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/05\/\u56fe4-1-300x202.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\uff08a\uff09\u6709\u5e8f\u539f\u59cb\u6b63\u6781\u3001\u6709\u5e8f\u6b63\u6781\u548c\u65e0\u5e8f\u6b63\u6781\u5faa\u73af1000\u6b21\u4e4b\u540e\u7684XRD\u56fe\u8c31\uff1b<\/p>\n<p>\uff08b\uff09\u6709\u5e8f\u6b63\u6781HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08c\uff09\u6709\u5e8f\u6b63\u6781STEM\u56fe\u50cf\u7684\u7ebf\u6761\u8f6e\u5ed3\uff1b<\/p>\n<p>\uff08d\uff09\u65e0\u5e8f\u6b63\u6781\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n<p>\uff08e\uff09\u65e0\u5e8f\u6b63\u6781STEM\u56fe\u50cf\u7684\u7ebf\u8f6e\u5ed3\uff1b<\/p>\n<p>\uff08f\uff09\u4e0e\u65e0\u5e8f\u6392\u5217\u76f8\u6bd4\uff0c\u8fc7\u6e21\u91d1\u5c5e\uff08TM\uff09\u5728\u5c42\u72b6\u6c27\u5316\u7269\u4e2d\u7684\u6709\u5e8f\u6392\u5217\u53ef\u4ee5\u4e3aNa<sup>+<\/sup>\u7684\u957f\u671f\u63d2\u5c42\/\u8131\u5d4c\u63d0\u4f9b\u66f4\u7a33\u5b9a\u7684\u7ed3\u6784\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong><b>\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n<p>\u603b\u4e4b\uff0c\u672c\u6587\u4ee5\u8fc7\u6e21\u91d1\u5c5e\uff08TM\uff09\u5c42\u72b6\u91d1\u5c5e\u6c27\u5316\u7269\u4e3a\u4f8b\uff0c\u901a\u8fc7\u6784\u9020TMs\u7684\u6709\u5e8f\u6392\u5217\u6765\u5b9e\u73b0\u76f8\u5bf9\u7a33\u5b9a\u7684\u7535\u6781\u6750\u6599\u3002 \u901a\u8fc7\u6bd4\u8f83ONNR\u548cDNNR\u6b63\u6781\uff0c\u7814\u7a76\u4e86TMs\u6392\u5217\u7684\u5173\u952e\u4f5c\u7528\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cONNR\u6b63\u6781\u88ab\u8bbe\u8ba1\u6210\u6709\u5e8f\u7684\u8d85\u6676\u683c\u7ed3\u6784\uff0c\u5177\u6709130 mAh g<sup>-1<\/sup>\u7684\u9ad8\u5bb9\u91cf\u3001\u8d85\u957f\u7535\u538b\u5e73\u53f0\u548c\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u3002\u4e0eDNNR\u7ed3\u6784\u7684\u65e0\u5e8f\u6392\u5217\u4e0d\u540c\uff0cONNR\u4e2dTMs\u7684\u6392\u5217\u5c55\u73b0\u4e86\u4e00\u79cd\u7262\u56fa\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u4f7f\u5f97\u6301\u7eed\u7684Na<sup>+<\/sup>\u63d2\u5c42\/\u8131\u5d4c\u5f97\u4ee5\u957f\u65f6\u95f4\u4fdd\u6301\u3002\u56e0\u6b64\uff0c\u6709\u5e8f\u6b63\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u53ef\u4e3a\u5728\u5e7f\u6cdb\u7684\u7535\u529b\u5e02\u573a\u63a8\u5e7f\u5148\u8fdb\u7684SIBs\u63d0\u4f9b\u6709\u524d\u9014\u7684\u601d\u8def\uff0c\u4ee5\u53ca\u4fc3\u8fdb\u5176\u4ed6\u7528\u4e8e\u9ad8\u7a33\u5b9a\u548c\u5927\u89c4\u6a21\u7684\u80fd\u91cf\u50a8\u5b58\u7535\u6781\u6750\u6599\u7684\u5f00\u53d1\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong><\/p>\n<p><a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.201907936#accessDenialLayout\"><strong><u><b>A Superlattice-Stabilized Layered Oxide Cathode \u00a0<\/b><\/u><\/strong><strong><u><b>for Sodium-Ion Batteries<\/b><\/u><\/strong><\/a><b><\/b><u><b><\/b><\/u><u><b><\/b><\/u><strong><b>\u201d(Adv. 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