{"id":201038,"date":"2020-05-29T06:58:56","date_gmt":"2020-05-28T22:58:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=201038"},"modified":"2020-05-28T20:59:06","modified_gmt":"2020-05-28T12:59:06","slug":"%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e8%83%bd%e5%b9%b2%e5%95%a5%ef%bc%9f%e6%9c%80%e6%96%b0%e6%88%90%e6%9e%9c%e4%bd%a0%e5%80%bc%e5%be%97%e4%ba%86%e8%a7%a3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=201038","title":{"rendered":"\u5171\u4ef7\u6709\u673a\u6846\u67b6\u80fd\u5e72\u5565\uff1f\u6700\u65b0\u6210\u679c\u4f60\u503c\u5f97\u4e86\u89e3"},"content":{"rendered":"

\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u662f\u4e00\u79cd\u65b0\u578b\u591a\u5b54\u6709\u673a\u6750\u6599\uff0c\u5b83\u901a\u8fc7\u5f3a\u5171\u4ef7\u952e\u4e0e\u6709\u673a\u6784\u5efa\u5355\u5143\u5de7\u5999\u5730\u6784\u5efa\u800c\u6210\u3002\u6676\u4f53\u591a\u5b54\u7ed3\u6784\u4ee5\u53ca\u7279\u5b9a\u7684\u529f\u80fd\u4e3aCOF\u6750\u6599\u63d0\u4f9b\u4e86\u5728\u5404\u4e2a\u9886\u57df\u663e\u793a\u51fa\u5f3a\u5927\u7684\u6f5c\u529b\u3002\u672c\u6587\u603b\u7ed3\u4e86\u6700\u8fd1COFs\u7684\u6700\u65b0\u6210\u679c\uff0c\u5bf9\u4e8e\u8ff7\u832b\u7684\u4f60\u63d0\u4f9b\u4e00\u79cd\u65b0\u7684\u601d\u8def\u548c\u89c1\u89e3\u3002<\/p>\n

Omar M. Yaghi\uff08\u52a0\u5dde\u4f2f\u514b\u5229\u5206\u6821<\/b><\/strong>\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fd\u9645\u8457\u540d\u5316\u5b66\u5bb6\uff0c\u662f\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\u3001\u6709\u673a\u5171\u4ef7\u9aa8\u67b6\u6750\u6599\u7684\u5f00\u62d3\u8005\u548c\u5960\u57fa\u4eba\u3002\u51ed\u501f\u5728\u50a8\u6c22\u6750\u6599\u9886\u57df\u7684\u79d1\u7814\u6210\u679c\uff0c\u4e8e2006\u5e74\u88ab\u5927\u4f17\u79d1\u5b66\u8bc4\u4e3a\u7f8e\u56fd\u5341\u5927\u6770\u51fa\u79d1\u5b66\u5bb6\u30022007\u5e74\uff0cYaghi\u6559\u6388\u5173\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7ed3\u6784\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\u3001\u7406\u8bba\u7814\u7a76\u4ee5\u53ca\u5b9e\u9645\u5e94\u7528\u7684\u5148\u9a71\u6027\u79d1\u7814\u6210\u679c\u4f7f\u4ed6\u6210\u4e3a\u7f8e\u56fd\u6750\u6599\u79d1\u5b66\u4f1a\u5956\u7ae0\u7684\u552f\u4e00\u83b7\u5f97\u8005\u3002\u540c\u5e74\uff0c\u83b7\u5f97\u7f8e\u56fd\u79d1\u5b66\u4fc3\u8fdb\u4f1a\u514b\u5229\u592b\u5170\u5956\u548c\u7f8e\u56fd\u80fd\u6e90\u90e8\u7279\u6b8a\u8d21\u732e\u5956\u30022009\u5e74\uff0c\u83b7\u5f97\u7f8e\u56fd\u5316\u5b66\u5b66\u4f1a\u6750\u6599\u5b66\u7279\u6b8a\u8d21\u732e\u5956\u3002Yaghi\u6559\u6388\u5df2\u5728Science\u548cNature\u7b49\u56fd\u9645\u9876\u5c16\u5b66\u672f\u671f\u520a\u53d1\u8868\u591a\u7bc7\u8bba\u6587\u3002\u66fe\u88ab\u591a\u6b21\u63d0\u540d\u4e3a\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u5019\u9009\u4eba\u30021998\u81f3\u4eca\uff0c\u8fde\u7eed\u88ab\u5217\u4e3a\u5168\u7403\u5341\u5927\u6700\u5177\u5f71\u54cd\u529b\u7684\u5316\u5b66\u5bb6\u3002<\/p>\n

1. J. Am. Chem. Soc.\u5177\u6709\u7a7a\u9699\u7684\u65b9\u683c\u62d3\u6251\u7ed3\u6784\u7684\u591a\u5b54\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7528\u4e8e\u5927\u6c14\u96c6\u6c34<\/b><\/strong><\/p>\n

\u5927\u6c14\u6c34\u5206\u662f\u968f\u65f6\u968f\u5730\u53ef\u7528\u7684\u65e0\u5904\u4e0d\u5728\u7684\u6c34\u8d44\u6e90\uff0c\u5f00\u53d1\u7528\u4e8e\u4ece\u7a7a\u6c14\u4e2d\u6536\u96c6\u6c34\u4ee5\u89e3\u51b3\u6c34\u8d44\u6e90\u77ed\u7f3a\u5371\u673a\u7684\u6750\u6599\u5177\u6709\u91cd\u8981\u610f\u4e49 \u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u591a\u5b54\u3001\u4e8c\u7ef4\u4e9a\u80fa\u5316\u7684COF-432\uff0c\u5b83\u5177\u6709\u7a7a\u5fc3\u7684\u65b9\u683c\u62d3\u6251\u7ed3\u6784\u3002 \u4e0e\u5176\u4ed6\u5df2\u62a5\u9053\u7684COF\u4e0d\u540c\uff0c\u7531\u4e8e\u5177\u6709S\u5f62\u7684\u5438\u6c34\u7b49\u6e29\u7ebf\uff0cCOF-432\u6ee1\u8db3\u4ece\u7a7a\u6c14\u4e2d\u6536\u96c6\u6c34\u5206\u7684\u8981\u6c42\uff0c\u5728\u8f83\u4f4e\u7684\u76f8\u5bf9\u6e7f\u5ea6\u4e0b\u5177\u6709\u9661\u5ced\u7684\u5b54\u586b\u5145\u6b65\u9aa4\uff0c\u5e76\u4e14\u5728\u5438\u6536\u548c\u91ca\u653e\u6c34\u5206\u8fc7\u7a0b\u4e2d\u6ca1\u6709\u6ede\u540e\u884c\u4e3a\u3002\u6b64\u5916\uff0c\u5b83\u53ef\u4ee5\u5728\u8d85\u4f4e\u6e29\u4e0b\u518d\u751f\uff0c\u5e76\u663e\u793a\u51fa\u4f18\u5f02\u7684\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u901a\u8fc7300\u6b21\u6c34\u5438\u9644-\u89e3\u5438\u5faa\u73af\u3002\u6269\u5927\u9002\u7528\u4e8e\u5e38\u538b\u6c34\u63d0\u53d6\u7684\u6750\u6599\u7c7b\u522b\u7684\u8303\u56f4\u5c06\u5bf9\u8be5\u6280\u672f\u6709\u5f88\u5927\u7684\u63d0\u5347\uff0c\u8be5\u53d1\u73b0\u5c06\u542f\u53d1\u66f4\u591a\u5173\u4e8eCOFs\u4f5c\u4e3a\u96c6\u6c34\u6750\u6599\u7684\u672a\u6765\u7814\u7a76\u3002[1]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Porous Covalent Organic Framework with Voided Square Grid\u00a0Topology for Atmospheric Water Harvesting\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u4e00\uff1a4-c\u5355\u8282\u70b9sql\u7f51\u7edc\u548c\uff083,4,4\uff09-c\u4e09\u8282\u70b9mtf\u7f51\u7edc\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2. J. Am. Chem. Soc. \u901a\u8fc7\u4e9a\u80fa\u548c\u4e9a\u80fa\u952e\u5408\u5c06\u4e00\u7ef4\u529f\u80fd\u533a\u7f51\u72b6\u5316\u4e3a\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6<\/b><\/strong><\/p>\n

\u7531\u5927\u5206\u5b50\u751a\u81f3\u65e0\u9650\u7684\u5efa\u7b51\u5355\u5143\u8bbe\u8ba1\u548c\u5408\u62102D\u548c3D\u6676\u4f53\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5c06\u5206\u5b50\u548c1D\u5e26\u72b6\u7ed3\u6784\u8fde\u63a5\u52302D\u6676\u578b\u6846\u67b6\u7684\u7b56\u7565\u3002\u4e09\u89d2\u5f62\u7684\u4e09\uff084-\u6c28\u57fa\u82ef\u57fa\uff09\u80fa\uff08TAA\uff09\u548c\u65b9\u5f62\u76841,3,6,8-\u56db\uff08\u5bf9\u7532\u9170\u57fa\u82ef\u57fa\uff09\u82dd\uff08TFPPy\uff09\u6709\u673a\u7ed3\u6784\u5355\u5143\u901a\u8fc7\u4e9a\u80fa\u5316\u5b66\u8ba1\u91cf\u5173\u7cfb\u901a\u8fc7\u4e9a\u5316\u5b66\u952e\u8fde\u63a5\u4ee5\u751f\u6210\u4e00\u7ef4\u5e26\uff0c\u79f0\u4e3a\u5e26\u6709\u6e38\u79bb\u80fa\u7684COF-76\uff0c\u7136\u540e\u7528\u4e8e\u5c06\u5e26\u72b6\u7ed3\u6784\u8fde\u63a5\u52302D\u6846\u67b6COF-77\u548cCOF-78\u4e2d\u3002\u53e6\u5916\uff0c\u4f5c\u8005\u8fd8\u5b9e\u73b0\u4e86\u8fd9\u4e9bCOF\u7684\u539f\u4f4d\u5408\u6210\u3002\u8be5\u65b9\u6cd5\u4f9d\u8d56\u4e8e\u65e0\u4fdd\u62a4\u57fa\u56e2\u7684\u7b56\u7565\u6765\u751f\u4ea7\u5728\u4e3b\u94fe\u4e0a\u5e26\u6709\u53cd\u5e94\u6027\u529f\u80fd\u80fa\u57fa\u56e2\u7684\u4e00\u7ef4\u5e26\u72b6\u7ed3\u6784\u3002\u7136\u540e\u901a\u8fc7\u4e9a\u80fa\u548c\u9170\u4e9a\u80fa\u5316\u5b66\u5c06\u5b98\u80fd\u56e2\u7528\u4e8e\u5c06\u4e00\u7ef4\u5e26\u72b6\u7f51\u72b6\u5316\uff0c\u4ece\u800c\u83b7\u5f97\u5448bex\u62d3\u6251\u7684\u7ed3\u66762D\u9aa8\u67b6COF-77\u548cCOF-78\u3002\u8fd9\u79cd\u7b56\u7565\u80fd\u591f\u5c06\u65e0\u9650\u6784\u5efa\u57fa\u5757\uff08\u4f8b\u5982COF-76\u7684\u78b3\u5e26\uff09\u94fe\u63a5\u5230\u66f4\u9ad8\u7ef4\u5ea6\u7684COF\uff0c\u4e3a\u94fa\u5e73\u7531\u591a\u5c42\u6b21\u5316\u5b66\u7ed3\u6784\u7ec4\u6210\u7684\u5171\u4ef7\u6846\u67b6\u94fa\u5e73\u4e86\u9053\u8def\u3002[2]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cReticulating 1D Ribbons into 2D Covalent Organic Frameworks by\u00a0Imine and Imide Linkages\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u4e8c\uff1a\u9010\u6b65\u548c\u539f\u4f4d\u6cd5\u5408\u62101D COF-76\u30012D COF-77\u548cCOF-78\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3. Angew. Chem. Int. Ed. \u7fa7\u57fa\u5b98\u80fd\u5316\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7684\u9170\u80fa\u5316<\/b><\/strong>\u3001<\/b><\/strong>\u916f\u5316\u548c\u786b\u916f\u5316<\/b><\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u662f\u901a\u8fc7\u5c06\u5206\u5b50\u6784\u5efa\u5355\u5143\u7f1d\u5408\u6210\u7ed3\u6676\u7684\u591a\u5b54\u5ef6\u4f38\u7ed3\u6784\u800c\u5236\u6210\u7684\u3002\u4e3a\u4e86\u5145\u5206\u5229\u7528\u8fd9\u4e9b\u6846\u67b6\u7684\u9ad8\u5b54\u9699\u7387\u548c\u8868\u9762\u79ef\uff0c\u9700\u8981\u5c06\u7279\u5b9a\u7684\u5316\u5b66\u529f\u80fd\u5f15\u5165\u5176\u5b54\u4e2d\uff0c\u4ee5\u8c03\u6574\u4e0e\u5ba2\u4f53\u7269\u79cd\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4ee5\u5b9e\u73b0\u65b0\u7684\u5e94\u7528\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5728\u5e26\u6709\u7fa7\u57fa\u7684\u65b0\u578b\u9ad8\u5ea6\u7ed3\u6676\u7684\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6COF-616\u4e0a\u8fdb\u884c\u4fee\u9970\u9170\u80fa\u5316\u3001\u916f\u5316\u548c\u786b\u916f\u5316\u53cd\u5e94\u3002\u8be5\u7b56\u7565\u53ef\u7528\u4e8e\u5c06\u591a\u79cd\u5b98\u80fd\u56e2\u5f15\u5165COF\uff0c\u5e76\u4e14\u4fee\u9970\u53ef\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u4ee5\u9ad8\u6536\u7387\u548c\u7b80\u4fbf\u7684\u540e\u5904\u7406\u65b9\u6848\u8fdb\u884c\u3002\u5404\u79cd\u87af\u5408\u529f\u80fd\u5df2\u6210\u529f\u5730\u5408\u5e76\u5230COF-616\u4e2d\u4f5c\u4e3a\u4e00\u7c7b\u5438\u9644\u5242\uff0c\u53ef\u6709\u6548\u53bb\u9664\u6c34\u4e2d\u7684\u51e0\u79cd\u6c61\u67d3\u7269\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u6709\u6548\u5730\u5bf9COF\u7684\u6a21\u5757\u5316\u3001\u9ad8\u901a\u91cf\u548c\u5e94\u7528\u5bfc\u5411\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\u3002[3]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cAmidation, Esterification, and Thioesterification of a Carboxyl-Functionalized Covalent Organic Framework\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Angew. Chem. Int. Ed.\u3002<\/p>\n

\u56fe\u4e09\uff1a<\/b><\/strong>\u7fa7\u57fa\u5b98\u80fd\u5316\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7684\u9170\u80fa\u5316<\/b><\/strong>\u3001<\/b><\/strong>\u916f\u5316\u548c\u786b\u916f\u5316<\/b><\/strong>\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4. J. Am. Chem. Soc. \u591a\u5143\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7684\u7f51\u72b6\u5408\u6210<\/b><\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u7684\u7f51\u72b6\u5316\u5b66\u80fd\u591f\u901a\u8fc7\u8bbe\u8ba1\u6269\u5c55\u7ed3\u6784\u3002COF\u5b8c\u5168\u7531\u901a\u8fc7\u7262\u56fa\u7684\u5171\u4ef7\u952e\u7f1d\u5408\u5728\u4e00\u8d77\u7684\u6709\u673a\u7ed3\u6784\u5355\u5143\u7ec4\u6210\u30022D\u548c3D COF\u7684\u7ed3\u6784\u6839\u636e\u5176\u57fa\u7840\u62d3\u6251\u8fdb\u884c\u5206\u7c7b\uff0c\u53ef\u4ee5\u6839\u636e\u9876\u70b9\u3001\u8fb9\u7f18\u3001\u73af\u548c\u56fe\u5757\u7684\u6570\u91cf\u8fdb\u884c\u63cf\u8ff0\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u8bfe\u9898\u7ec4\u901a\u8fc7\u5c06\u516d\u65b9–\u516d\u6c28\u57fa\u82ef\u57fa\u82ef\uff0c\u56db\u65b9–\u56db\uff084-\u6c28\u57fa\u82ef\u57fa\uff09\u4e59\u70f7\u548c\u4e09\u65b9–1,3,5-\u4e09\uff08\u5bf9\u7532\u9170\u57fa\u82ef\u57fa\uff09\u82ef\u90fd\u901a\u8fc7\u4e9a\u80fa\u952e\u8fde\u63a5\u5728\u4e00\u8d77\uff0c\u5408\u6210\u65b0\u578b\u7684tth\u62d3\u6251\u7ed3\u6784\u7684\u4e8c\u7ef4\u591a\u5b54\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff0c\u79f0\u4e3aCOF -346\u3002\u4e0e\u5df2\u62a5\u9053\u76845\u79cd\u7b80\u5355COF\u73b0\u67092D\u62d3\u6251\u4e0d\u540c\uff0cCOF-346\u5177\u67093\u79cd\u9876\u70b9\u548c2\u79cd\u8fb9\u7ebf\uff0c\u5e76\u4f7f\u75283\u79cd\u8fde\u901a\u6027\u7684\u8fde\u63a5\u5355\u5143\u8fdb\u884c\u6784\u9020\uff0c\u8be5COF\u7ed3\u6784\u7684\u9ad8\u5ea6\u590d\u6742\u6027\u3002\u4f7fCOF-346\u7ed3\u6676\u7684\u6210\u529f\u662f\u57fa\u4e8e\u7cbe\u786e\u9009\u62e9\u7684\u8fde\u63a5\u5b50\u7684\u51e0\u4f55\u5f62\u72b6\u548c\u5ea6\u91cf\u4ee5\u53ca\u52a8\u6001\u4e9a\u80fa\u5f62\u6210\u63d0\u4f9b\u7684\u8bef\u5dee\u6821\u6b63\u3002\u8be5\u7814\u7a76\u8fd8\u62a5\u9053\u4e86\u53e6\u5916\u4e24\u4e2a\u76f8\u5173\u7684COF\uff1a\u4e00\u4e2a\u5177\u6709\u7f55\u89c1kgd\u62d3\u6251\u7ed3\u6784\u7684\u6676\u4f53\u591a\u5b54COF\uff0c\u79f0\u4e3aCOF-360\uff1b\u4e00\u4e2a\u88ab\u79f0\u4e3atof\u62d3\u6251\u7ed3\u6784\u7684\u7b2c\u4e00\u4e2a\u6676\u4f53\u591a\u5b54COF\uff0c\u79f0\u4e3aCOF-340\u3002[4]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cReticular Synthesis of Multinary Covalent Organic Frameworks\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u56db\uff1a2D COF\u76845\u79cd\u62d3\u6251\u7ed3\u6784\u4e0e\u5177\u67093\u9876\u70b9\u30012\u8fb9\u76846\u79cd\u62d3\u6251\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5. J. Am. Chem. Soc. \u6c28\u57fa\u7532\u9178\u916f\u8fde\u63a5\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7684\u591a\u6b65\u56fa\u6001\u6709\u673a\u5408\u6210<\/b><\/strong><\/p>\n

\u63a7\u5236\u5316\u5b66\u529f\u80fd\u5728\u5171\u4ef7\u8fde\u63a5\u7684\u56fa\u4f53\u4e2d\u7684\u76f8\u5bf9\u4f4d\u7f6e\u7684\u80fd\u529b\u4ee3\u8868\u4e86\u6709\u673a\u5316\u5b66\u5411\u56fa\u6001\u7684\u6269\u5c55\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u591a\u6b65\u56fa\u6001\u6709\u673a\u5408\u6210\u4e00\u4e2a\u65b0\u7684\u4e9a\u80fa\u952e\u8fde\u63a5\u7684\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF-170\uff0c1\uff09\uff0c\u5373\u901a\u8fc7\u4e09\u4e2a\u8fde\u7eed\u7684\u540e\u5408\u6210\u4fee\u9970\u8f6c\u53d8\u4e3a\u591a\u5b54\u7684\u7ed3\u6676\u73af\u72b6\u6c28\u57fa\u7532\u9178\u916f\u548c\u786b\u4ee3\u6c28\u57fa\u7532\u9178\u916f\u3002\u8fd9\u4e9b\u5316\u5b66\u8f6c\u5316\u5728\u4e0d\u6539\u53d8\u6846\u67b6\u6574\u4f53\u8fde\u901a\u6027\u7684\u540c\u65f6\uff0c\u5728\u6bcf\u4e2a\u6b65\u9aa4\u4e2d\u5747\u5f15\u53d1\u4e86\u663e\u7740\u7684\u6784\u8c61\u548c\u7ed3\u6784\u53d8\u5316\uff0c\u7a81\u663e\u4e86\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u548c\u6784\u8c61\u7075\u6d3b\u6027\u5bf9COF\u7ed3\u6676\u5ea6\u548c\u5b54\u9699\u5ea6\u7684\u5173\u952e\u91cd\u8981\u6027\u3002\u4f7f\u752815<\/sup>N multiCP-MAS NMR\u5149\u8c31\u5bf9\u8fd9\u4e9b\u8f6c\u5316\u8fdb\u884c\u4e86\u8bc4\u4f30\uff0c\u4ece\u800c\u9996\u6b21\u5b9a\u91cf\u4e86COF\u5408\u6210\u540e\u4fee\u9970\u53cd\u5e94\u4e2d\u7684\u4ea7\u7387\u4ee5\u53ca\u4e9a\u80fa\u8fde\u63a5\u7684COF\u4e2d\u7684\u80fa\u7f3a\u9677\u4f4d\u70b9\u3002\u8fd9\u79cd\u591a\u6b65COF\u952e\u5408\u6210\u540e\u4fee\u9970\u4ee3\u8868\u4e86\u5c06\u6709\u673a\u6eb6\u6db2\u76f8\u5408\u6210\u7684\u7cbe\u786e\u5ea6\u63d0\u9ad8\u5230\u6269\u5c55\u7684\u56fa\u6001\u5316\u5408\u7269\u65b9\u9762\u7684\u91cd\u8981\u4e00\u6b65\u3002[5]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cMultistep Solid-State Organic Synthesis of Carbamate-Linked\u00a0Covalent Organic Frameworks\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u4e94\uff1a\u4e09\u6b65\u56fa\u6001\u5408\u6210\u6cd5\u5408\u6210\u73af\u72b6\u6c28\u57fa\u7532\u9178\u916f\u548c\u786b\u4ee3\u6c28\u57fa\u7532\u9178\u916f\u8fde\u63a5\u7684COF\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6c5f\u4e1c\u6797\uff08\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

1998\u5e74\u5728\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\u5e76\u5148\u540e\u5728\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u3001\u65e5\u672c\u5206\u5b50\u79d1\u5b66\u7814\u7a76\u6240\u3001\u65e5\u672c\u5317\u9646\u5148\u7aef\u79d1\u5b66\u6280\u672f\u5927\u5b66\u3001\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u4ece\u4e8b\u7814\u7a76\u5de5\u4f5c\uff0c\u66fe\u4efb\u65e5\u672c\u79d1\u5b66\u6280\u672f\u632f\u5174\u673a\u6784\u76f8\u7530\u7eb3\u7c73\u7a7a\u95f4\u9879\u76ee\u8bfe\u9898\u7ec4\u957f\u3002\u957f\u671f\u4ece\u4e8b\u6709\u673a\u591a\u5b54\u6750\u6599\u7684\u7814\u7a76\u5de5\u4f5c\uff0c\u5728\u4e8c\u7ef4\u9ad8\u5206\u5b50\u548c\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\u7684\u8bbe\u8ba1\u53ca\u5e94\u7528\u9886\u57df\u505a\u51fa\u4e86\u6770\u51fa\u8d21\u732e\u3002\u66fe\u83b7\u65e5\u672c\u9752\u5e74\u79d1\u5b66\u5bb6\u5956\u3001\u65e5\u672c\u9ad8\u5206\u5b50\u5b66\u4f1aWiley\u5956\u3001\u65e5\u672c\u5316\u5b66\u4f1a\u5b66\u672f\u5956\u7b49\u591a\u9879\u5956\u52b1\u3002<\/p>\n

6. Angew. Chem. Int. Ed.\u4e00\u7ef4\u7eb3\u7c73\u901a\u9053\u4e2d\u7684\u9ad8\u7cbe\u5ea6\u5c3a\u5bf8\u8bc6\u522b\u548c\u5206\u79bb<\/b><\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u53ef\u4ee5\u901a\u8fc7\u5408\u7406\u8bbe\u8ba1\u548c\u7cbe\u5fc3\u5408\u6210\u5b9e\u73b0\u6676\u4f53\u4e2d\u6709\u5e8f\u7684\u4e00\u7ef4\u901a\u9053\u3002\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u6c5f\u4e1c\u6797\u8bfe\u9898\u7ec4\u901a\u8fc7\u5de5\u7a0b\u901a\u9053\u5b9a\u4e49\u4e86COF\u7684\u8d85\u6676\u683c\uff0c\u8fd9\u4e9b\u901a\u9053\u5177\u6709\u6301\u4e45\u7684\u4e09\u89d2\u5f62\u5f62\u72b6\u548c\u79bb\u6563\u7684\u5b54\u5f84\u3002\u5b9e\u9a8c\u4e2d\u89c2\u5bdf\u5230\u4e86\u4e00\u79cd\u4e0d\u540c\u4e8eCOFs\u7684\u7279\u5f81\u5438\u9644\u7684\u5c3a\u5bf8\u8bc6\u522b\u673a\u5236\uff0c\u5176\u4e2d\u5b54\u7a97\u548c\u58c1\u5177\u6709\u534f\u540c\u4f5c\u7528\uff0c\u56e0\u6b64\u4e09\u89d2\u5f62\u5b54\u5bf9\u4e00\u4e2a\u539f\u5b50\u5dee\u5f02\u7684\u5206\u5b50\u8fdb\u884c\u4e86\u6392\u5e8f\uff0c\u5e76\u5728\u7eb3\u7c73\u69fd\u53e3\u4e0a\u5c06\u5b83\u4eec\u9650\u5236\u4e3a\u5355\u6392\u5206\u5b50\u94fe\u3002\u8bc6\u522b\u548c\u9650\u5236\u662f\u901a\u8fc7\u7075\u654f\u5149\u8c31\u548c\u98de\u79d2\u52a8\u6001\u6a21\u62df\u51c6\u786e\u63cf\u8ff0\u7684\u3002\u6240\u5f97\u7684COF\u53ef\u5728\u73af\u5883\u6e29\u5ea6\u548c\u538b\u529b\u4e0b\u77ac\u65f6\u5206\u79bb\u6df7\u5408\u7269\u3002\u8fd9\u9879\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u5728\u5408\u6210\u4e00\u7ef4\u901a\u9053\u4e2d\u5408\u5e76\u7cbe\u786e\u8bc6\u522b\uff0c\u9009\u62e9\u6027\u8fd0\u8f93\u548c\u5373\u65f6\u5206\u79bb\u7684\u65b9\u6cd5\u3002[6]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cHigh-Precision Size Recognition and Separation in Synthetic 1D\u00a0Nanochannels\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Angew. Chem. Int. Ed.\u3002<\/p>\n

\u56fe\u516d\uff1aCOFs\u5408\u6210\u53ca\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

7. Angew. Chem. Int. Ed.\u91cf\u8eab\u5b9a\u5236\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u79bb\u5b50\u901a\u9053\u7528\u4e8e\u4f20\u8f93\u79bb\u5b50<\/b><\/strong><\/p>\n

\u79bb\u5b50\u8fc1\u79fb\u5728\u8bb8\u591a\u751f\u7269\u548c\u7269\u7406\u8fc7\u7a0b\u4e2d\u65e0\u5904\u4e0d\u5728\u4e14\u81f3\u5173\u91cd\u8981\uff0c\u5728\u79bb\u5b50\u901a\u9053\u548c\u6280\u672f\u76f8\u5173\u8bbe\u5907\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u6c5f\u4e1c\u6797\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u57fa\u4e8e\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u7684\u8d85\u5feb\u79bb\u5b50\u8fc1\u79fb\u7b56\u7565\u6d89\u53ca\u8bbe\u8ba1\u79bb\u5b50\u754c\u9762\u4ee5\u4ecb\u5bfc\u79bb\u5b50\u8fd0\u52a8\u3002\u901a\u8fc7\u5b54\u8868\u9762\u5de5\u7a0b\u5c06\u7535\u89e3\u8d28\u94fe\u6574\u5408\u5230\u4e00\u7ef4\u901a\u9053\u7684\u58c1\u4e0a\u4ee5\u6784\u5efa\u79bb\u5b50\u9aa8\u67b6\uff0c\u4ee5\u4fbf\u53ef\u4ee5\u6309\u6240\u9700\u7684\u7ec4\u6210\u548c\u5bc6\u5ea6\u7cfb\u7edf\u5730\u8c03\u6574\u79bb\u5b50\u754c\u9762\u3002\u8be5\u7b56\u7565\u53ef\u5b9e\u73b0\u754c\u9762\u4e0e\u79bb\u5b50\u8fc1\u79fb\u4e4b\u95f4\u7684\u5b9a\u91cf\u5173\u8054\uff0c\u5e76\u63ed\u793a\u4e86\u79bb\u5b50\u754c\u9762\u4ee5\u5b9e\u73b0\u9ad8\u901f\u7387\u79bb\u5b50\u8fc1\u79fb\u7684\u5f71\u54cd\u3002\u6b64\u5916\uff0c\u754c\u9762\u5bf9\u79bb\u5b50\u4f20\u8f93\u7684\u5f71\u54cd\u4e5f\u6709\u6240\u589e\u52a0\u3002\u901a\u8fc7\u79bb\u5b50\u754c\u9762\uff0c\u79bb\u5b50\u8fc1\u79fb\u7387\u4ee5\u6307\u6570\u6a21\u5f0f\u589e\u52a0\u3002\u8be5\u7b56\u7565\u4e0d\u4ec5\u8bbe\u7f6e\u4e86\u57fa\u51c6\u7cfb\u7edf\uff0c\u800c\u4e14\u4e3a\u8bbe\u8ba1\u79bb\u5b50\u754c\u9762\u63d0\u4f9b\u4e86\u4e00\u822c\u6307\u5bfc\uff0c\u800c\u79bb\u5b50\u754c\u9762\u5bf9\u4e8e\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u7cfb\u7edf\u81f3\u5173\u91cd\u8981\u3002\u8be5\u7b56\u7565\u4e3a\u6307\u5bfc\u79bb\u5b50\u754c\u9762\u7684\u9884\u8bbe\u8ba1\u548c\u5b9a\u91cf\u5de5\u7a0b\u5f00\u8f9f\u9053\u8def\uff0c\u5e76\u4e3a\u79bb\u5b50\u754c\u9762\u5728\u8bb8\u591a\u4e0e\u6280\u672f\u76f8\u5173\u7684\u6750\u6599\u548c\u8bbe\u5907\u4e2d\u5bf9\u4e8e\u80fd\u91cf\u8f6c\u6362\u548c\u5b58\u50a8\u63d0\u4f9b\u65b0\u7684\u89c1\u89e3\u3002[7]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cDesigning Covalent Organic Frameworks with a Tailored Ionic\u00a0Interface for Ion Transport across One-Dimensional Channels\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Angew. Chem. Int. Ed.\u3002<\/p>\n

\u56fe\u4e03\uff1a\u5404\u79cd\u8bbe\u8ba1\u7684COFs\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

8. Chem\u4e8c\u7ef4sp<\/b><\/strong>2<\/b><\/sup><\/strong>\u78b3\u5171\u8f6d\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7528\u4e8e\u5149\u50ac\u5316\u5236\u6c22<\/b><\/strong><\/p>\n

\u5149\u5316\u5b66\u80fd\u91cf\u8f6c\u6362\u9700\u8981\u7cfb\u7edf\u548c\u590d\u6742\u7684\u5206\u5b50\u8bbe\u8ba1\uff0c\u4ee5\u5b9e\u73b0\u8fde\u7eed\u7684\u5149\u5316\u5b66\u8fc7\u7a0b\uff0c\u5305\u62ec\u80fd\u91cf\u6536\u96c6\u3001\u6fc0\u5b50\u8fc1\u79fb\u3001\u7535\u5b50\u8f6c\u79fb\u3001\u7535\u8377\u5206\u79bb\u548c\u7535\u8377\u8f6c\u79fb\u3002\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u6c5f\u4e1c\u6797\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u4e2a\u57fa\u4e8e\u4e8c\u7ef4sp2<\/sup>\u78b3\u5171\u8f6d\u5171\u4ef7\u6709\u673a\u6846\u67b6\u5b9e\u73b0\u8fd9\u4e9b\u5149\u5316\u5b66\u8fc7\u7a0b\u7684\u65e0\u7f1d\u8854\u63a5\u3002COFs\u8bbe\u8ba1\u4e3a\u5b8c\u5168p\u5171\u8f6d\u7684\uff0c\u4ee5\u6536\u96c6\u5404\u79cd\u53ef\u89c1\u5149\u81f3\u8fd1\u7ea2\u5916\u5149\uff0c\u5e76\u6784\u6210\u7528\u4e8e\u5206\u88c2\u6fc0\u5b50\u7684\u5185\u7f6e\u4f9b\u4f53-\u53d7\u4f53\u5f02\u8d28\u7ed3\u754c\u9762\u3002COFs\u6846\u67b6\u521b\u5efa\u5bc6\u96c6\u4f46\u6709\u5e8f\u7684\u67f1\u72b6p\u9635\u5217\uff0c\u8fd9\u4e9b\u9635\u5217\u63d0\u4f9b\u4e86\u4fc3\u8fdb\u6fc0\u5b50\u8fc1\u79fb\u548c\u7535\u8377\u4f20\u8f93\u7684\u9014\u5f84\u3002\u5c06\u53cd\u5e94\u4e2d\u5fc3\u8d1f\u8f7d\u5728\u5b54\u4e2d\u6216\u8868\u9762\u4e0a\u4f1a\u7f29\u77ed\u7535\u5b50\u8f6c\u79fb\u8ddd\u79bb\uff0c\u5e76\u4fc3\u8fdb\u7535\u5b50\u5728\u53cd\u5e94\u4e2d\u5fc3\u7684\u79ef\u7d2f\u3002\u8fd9\u4e09\u79cd\u5206\u5b50\u673a\u5236\u65e0\u7f1d\u5730\u96c6\u6210\u5728COFs\u6846\u67b6\u4e2d\uff0c\u5e76\u4f7f\u7cfb\u7edf\u80fd\u591f\u6709\u6548\u4ea7\u751f\u7531\u4f4e\u80fd\u5149\u5b50\u9a71\u52a8\u7684\u6c22\u3002\u8fd9\u79cd\u673a\u68b0\u534f\u540c\u4f5c\u7528\u4f7fsp2<\/sup>\u78b3\u5171\u8f6dCOF\u80fd\u591f\u4f7f\u7528\u5404\u79cd\u53ef\u89c1\u5149\u5230\u8fd1\u7ea2\u5916\u5149\u8fde\u7eed\u6709\u6548\u5730\u4ece\u6c34\u4e2d\u751f\u4ea7\u6c22\u3002[8]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201c2D sp2<\/sup>\u00a0Carbon-Conjugated Covalent\u00a0Organic Frameworks for Photocatalytic\u00a0Hydrogen Production from Water\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Chem\u3002<\/p>\n

\u56fe\u516b\uff1a\u4ece\u6c34\u4ea7\u6c22\u7684\u4e8c\u7ef4sp<\/b><\/strong>2<\/b><\/sup><\/strong>\u78b3\u5171\u8f6dCOF\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u8d75\u65b0\uff08\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

2003\u5e747\u6708\u6bd5\u4e1a\u4e8e\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\uff0c\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5176\u540e\u5728\u7f8e\u56fd\u54c8\u4f5b\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5b66\u751f\u7269\u5b66\u7cfb\u548c\u829d\u52a0\u54e5\u5927\u5b66\u5316\u5b66\u7cfb\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u30022008\u5e745\u6708\u8d77\u5728\u4e0a\u6d77\u6709\u673a\u6240\u5efa\u7acb\u7814\u7a76\u8bfe\u9898\u7ec4\uff0c\u5386\u4efb\u521b\u65b0\u5c97\u4f4d\u526f\u7814\u7a76\u5458\u3001\u7814\u7a76\u5458\u30022015\u5e74\u83b7\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\uff08\u7b2c\u4e8c\u5b8c\u6210\u4eba\uff09\uff0c2017\u5e74\u83b7\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\uff0c2019\u5e74\u5165\u9009\u4e0a\u6d77\u5e02\u4f18\u79c0\u5b66\u672f\u5e26\u5934\u4eba\u3002<\/p>\n

9. J. Am. Chem. Soc. \u901a\u8fc7\u9009\u62e9\u6027\u5206\u89e3\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u5236\u5907\u6709\u673a\u7eb3\u7c73\u7ba1<\/b><\/strong><\/p>\n

\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u662f\u4e00\u7c7b\u65b0\u5174\u7684\u6676\u4f53\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\uff0c\u5177\u6709\u5f00\u53d1\u5177\u6709\u521b\u65b0\u5e94\u7528\u6f5c\u529b\u7684\u65b0\u578b\u6750\u6599\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u8d75\u65b0\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5c06COF\u7528\u4f5c\u5408\u6210\u660e\u786e\u7684\u7ba1\u72b6\u7eb3\u7c73\u6750\u6599\u7684\u524d\u4f53\u3002\u7814\u7a76\u63d0\u51fa\u4e86\u901a\u8fc7\u4e8c\u7ef4\u5f02\u5b54COF\u9009\u62e9\u6027\u5206\u89e3\u53ef\u63a7\u5236\u5730\u5236\u9020\u6709\u673a\u7eb3\u7c73\u7ba1\u7684\u6982\u5ff5\u9a8c\u8bc1\u7814\u7a76\u3002\u57fa\u4e8e\u6b63\u4ea4\u53cd\u5e94\u6784\u5efa\u4e86\u4e24\u4e2a\u53cc\u5b54COF\u3002\u6bcf\u4e2aCOF\u90fd\u5177\u6709\u4e24\u79cd\u4e0d\u540c\u7c7b\u578b\u7684\u5b54\uff0c\u8fd9\u4e9b\u5b54\u662f\u901a\u8fc7\u5c06\u5168hydrzaone\u952e\u5408\u7684\u7eb3\u7c73\u5b54\u4e0e\u787c\u6c27\u952e\u8fde\u63a5\u800c\u5f62\u6210\u7684\u3002 \u9009\u62e9\u6027\u6c34\u89e3COF\u4e2d\u7684\u73af\u787c\u6c27\u70f7\u73af\uff0c\u540c\u65f6\u4fdd\u6301\u952e\u4e0d\u53d7\u5f71\u54cd\uff0c\u4f1a\u4ea7\u751f\u76f4\u5f84\u548c\u5f62\u72b6\u4e0eCOF\u7eb3\u7c73\u901a\u9053\u76f8\u5bf9\u5e94\u7684\u6709\u673a\u7eb3\u7c73\u7ba1\u3002[9]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cFabricating Organic Nanotubes through Selective Disassembly of\u00a0Two-Dimensional Covalent Organic Frameworks\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u4e5d\uff1a\u901a\u8fc7\u9009\u62e9\u6027\u6c34\u89e32D\u5f02\u5b54COF\u5236\u5907\u7eb3\u7c73\u7ba1\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

10. CCS Chem. \u5171\u4ef7\u6709\u673a\u6846\u67b6\u4e2d\u7684\u7ed3\u6784\u5f02\u6784\u7814\u7a76\uff1a\u53ef\u63a7\u5408\u6210\u3001\u8f6c\u5316\u548c\u6027\u8d28\u5dee\u5f02<\/b><\/strong><\/p>\n

\u5f02\u6784\u73b0\u8c61\u662f\u6709\u673a\u5316\u5b66\u4e2d\u5fc5\u4e0d\u53ef\u5c11\u7684\u666e\u904d\u73b0\u8c61\uff0c\u4f46\u5728\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u4e2d\u5374\u5f88\u5c11\u89c2\u5bdf\u5230\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u8d75\u65b0\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u53ef\u63a7\u5408\u6210COF\u7684\u7ed3\u6784\u5f02\u6784\u4f53\u3002\u4e24\u79cd\u5f02\u6784\u4f53\u5728\u5404\u79cd\u6eb6\u5242\u4e2d\u7684\u6c14\u4f53\/\u84b8\u6c7d\u5438\u9644\u884c\u4e3a\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u5747\u8868\u73b0\u51fa\u660e\u663e\u5dee\u5f02\u3002\u6b64\u5916\uff0c\u5b9e\u73b0\u4e86\u4ece\u4e00\u79cd\u5f02\u6784\u4f53\u5230\u53e6\u4e00\u79cd\u5f02\u6784\u4f53\u7684\u7ed3\u6784\u8f6c\u53d8\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u5408\u7406\u8bbe\u8ba1\u548c\u5408\u6210COF\u5f02\u6784\u4f53\u94fa\u5e73\u4e86\u9053\u8def\uff0c\u800c\u4e14\u4e3a\u7ed3\u6676\u591a\u5b54\u805a\u5408\u7269\u4e2d\u7ed3\u6784\u4e0e\u6027\u8d28\u4e4b\u95f4\u7684\u5173\u7cfb\u63d0\u4f9b\u4e86\u751f\u52a8\u7684\u4f8b\u8bc1\u3002\u8be5\u7814\u7a76\u9996\u6b21\u5b9e\u73b0\u4e86COF\u6784\u9020\u5f02\u6784\u4f53\u7684\u53ef\u63a7\u5408\u6210\uff0c\u5c06\u6784\u9020\u5f02\u6784\u4f53\u9009\u62e9\u6027\u5236\u5907\u62d3\u5c55\u5230COF\u9886\u57df\uff0c\u5c55\u793a\u4e0d\u540c\u5f02\u6784\u4f53\u5177\u6709\u4e0d\u4e00\u6837\u7684\u7406\u5316\u6027\u8d28\uff0c\u8fd9\u5bf9\u63ed\u793aCOFs\u7684\u5f62\u6210\u673a\u5236\u6709\u79ef\u6781\u7684\u610f\u4e49\uff0c\u4e5f\u6709\u52a9\u4e8e\u52a0\u6df1\u5bf9\u5f02\u6784\u73b0\u8c61\u7684\u7406\u89e3\u3002[10]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Study on Constitutional Isomerism\u00a0in Covalent Organic Frameworks:\u00a0Controllable Synthesis,\u00a0Transformation, and Distinct\u00a0Difference in Properties\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728CCS Chem.\u3002<\/p>\n

\u56fe\u5341\uff1aCOFs\u5f02\u6784\u4f53\u7684\u53ef\u63a7\u5408\u6210\u4ee5\u53ca\u5f02\u6784\u4f53\u8f6c\u5316\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

11. J. Am. Chem. Soc. \u4ef2\u80fa\u4e0e\u919b\u7f29\u5408\u5f62\u6210\u65b0\u578b\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n

\u65b0\u578b\u7684\u952e\u5408\u5355\u5143\u5c06\u4f7f\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u4e0d\u4ec5\u5177\u6709\u7ed3\u6784\u591a\u6837\u6027\uff0c\u800c\u4e14\u5177\u6709\u7279\u6b8a\u7684\u6027\u80fd\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u8d75\u65b0\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u4e24\u79cd\u4ef2\u80fa\u4e0e\u919b\u7f29\u5408\u5f62\u6210\u5177\u6709\u53d4\u80fa\u7ed3\u6784\u7684\u4e8c\u7ef4Aminal-COF-1\u548cAminal-COF-2\uff0c\u5e76\u53d1\u73b0\u56db\u9762\u4f53\u7684\u51e0\u4f55\u5f62\u72b6\u548c\u975e\u5171\u8f6d\u7279\u5f81\u800c\u6709\u5229\u4e8e\u4fdd\u7559\u5355\u4f53\u7684\u5149\u7269\u7406\u6027\u8d28\u3002\u8fd9\u4e24\u79cdCOFs\u5728cpi\u7f51\u7edc\u4e2d\u7ed3\u6676\u5c55\u73b0\u7684\u662f\u65b0\u62d3\u6251\u7ed3\u6784\u3002\u8fd9\u4e9b\u6c28\u919b-COF\u5728\u4e2d\u6027\u548c\u78b1\u6027\u6761\u4ef6\u4e0b\u5747\u8868\u73b0\u51fa\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u9ad8\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u9996\u6b21\u5408\u6210\u4e86\u5177\u6709\u80fa\u952e\u7684COFs\uff1aAminal\u6846\u67b6\u5728cpi\u7f51\u72b6\u7ed3\u6784\u7ed3\u6676\u662f\u65b0\u7684COFs\u62d3\u6251\u7ed3\u6784\u3002\u8be5\u7814\u7a76\u63a8\u52a8\u4e86\u80fa\u5316\u952e\u5316\u5b66\u5728COFs\u9886\u57df\u7684\u65b0\u53d1\u5c55\uff0c\u4e5f\u5c06\u8fdb\u4e00\u6b65\u62d3\u5bbd\u7f51\u72b6\u5316\u5b66\u5728\u65b0\u578b\u7684\u952e\u5408\u5355\u5143\u65b9\u9762\u7684\u5e94\u7528\u8303\u56f4\u3002[11]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cAminal-Linked Covalent Organic Frameworks through\u00a0Condensation of Secondary Amine with Aldehyde\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Am. Chem. Soc.\u3002<\/p>\n

\u56fe\u5341\u4e00\uff1a<\/b><\/strong>Aminal<\/b><\/strong>\u8fde\u63a5\u7684COF\u7684\u6a21\u578b\u53cd\u5e94\u4e0e\u5408\u6210\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

12. Nat. Commun.\u9ad8\u5ea6\u590d\u6742\u62d3\u6251\u7ed3\u6784\u7684\u6676\u6001\u4e8c\u7ef4\u6846\u67b6\u7684\u5408\u7406\u8bbe\u8ba1<\/b><\/strong><\/p>\n

\u901a\u8fc7\u5408\u6210\u5316\u5b66\u6784\u9020\u5177\u6709\u590d\u6742\u9576\u5d4c\u56fe\u6848\u7684\u4e8c\u7ef4\uff082D\uff09\u805a\u5408\u7269\uff0c\u4e0d\u4ec5\u5bf9\u4e86\u89e3\u751f\u7269\u4f53\u4e2d\u590d\u6742\u7684\u5c42\u6b21\u7cfb\u7edf\u7684\u51fa\u73b0\u505a\u51fa\u4e86\u91cd\u5927\u8d21\u732e\uff0c\u800c\u4e14\u5bf9\u5148\u8fdb\u7684\u5c42\u6b21\u6750\u6599\u7684\u5236\u9020\u4e5f\u505a\u51fa\u4e86\u91cd\u5927\u8d21\u732e\u3002\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u8d75\u65b0\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u4e09\u79cd\u6216\u56db\u79cd\u51e0\u4f55\u5f62\u72b6\/\u5c3a\u5bf8\u6765\u7ec6\u52062D\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\uff08COF\uff09\u7684\u7b80\u4fbf\u4e14\u901a\u7528\u7684\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u53ef\u63d0\u4f9b\u5e26\u6709\u4e09\u79cd\u6216\u56db\u79cd\u4e0d\u540c\u7c7b\u578b\u5b54\u76842D COF\uff0c\u5e76\u589e\u52a02D\u805a\u5408\u7269\u7684\u9576\u5d4c\u4e2d\u7684\u7ed3\u6784\u590d\u6742\u6027\u3002\u901a\u8fc7\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\u7814\u7a76\uff0c\u7406\u8bba\u6a21\u62df\u548c\u9ad8\u5206\u8fa8\u7387TEM\u9610\u660e\u4e86COF\u7684\u590d\u6742\u9576\u5d4c\u56fe\u6848\u3002\u7531\u4e8e\u5c06\u5177\u6709\u4e0d\u540c\u51e0\u4f55\u5f62\u72b6\u76842D COF\u7ec6\u5206\u63d0\u4f9b\u4e86\u5bf9\u6846\u67b6\u7684\u4e0d\u540c\u90e8\u5206\u8fdb\u884c\u9ad8\u7cbe\u5ea6\u7684\u72ec\u7acb\u7ed3\u6784\u4fee\u6539\u548c\u529f\u80fd\u5316\u7684\u9014\u5f84\uff0c\u8be5\u7b56\u7565\u5f00\u8f9f\u4e86\u4e00\u79cd\u6709\u524d\u9014\u7684\u65b9\u5f0f\u5408\u6210\u53ef\u4ee5\u9ad8\u5ea6\u96c6\u6210\u5404\u79cd\u529f\u80fd\u7684\u9ad8\u7ea7\u6750\u6599\u3002[12]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cRational design of crystalline two-dimensional\u00a0frameworks with highly complicated\u00a0topological structures\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nat. Commun.\u3002<\/p>\n

\u56fe\u5341\u4e8c\uff1a\u8bbe\u4e09\u5b54\u548c\u56db\u5b54COF\u7684\u8bbe\u8ba1\u7b56\u7565\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

    \n
  1. Nguyen H.L., Hanikel N.,Lyle S.J., Zhu C., Proserpio D.M.,Yaghi O.M., A Porous Covalent Organic Framework with Voided Square Grid\u00a0Topology for Atmospheric Water Harvesting. [J] J. Am. Chem. Soc. 2020, 142, 2218-2221.<\/li>\n
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  3. Guo L., Jia S., Diercks C.S., Yang X., Alshmimri S.A., Yaghi O.M., Amidation, Esterification, and Thioesterification of a Carboxyl-Functionalized Covalent Organic Framework. [J] Angew. Chem. Int. Ed.2020, 132, 2039-2043.<\/li>\n
  4. ZhangB.,Mao\u00a0H.,\u00a0Matheu\u00a0R.,\u00a0Reimer\u00a0J.A.,\u00a0Alshmimri\u00a0S.A.,\u00a0Alshihri\u00a0S.,\u00a0Yaghi O.\u00a0M., Reticular Synthesis of Multinary Covalent Organic Frameworks. [J] J. Am. Chem. Soc. 2019, 141, 11420-11424.<\/li>\n
  5. Lyle S.J., Osborn Popp T.M., Waller P.J., Pei X., Reimer J.A.,Yaghi O.M.,\u00a0Multistep Solid-State Organic Synthesis of Carbamate-Linked\u00a0Covalent Organic Frameworks. [J] J. Am. Chem. Soc. 2019, 141, 11253\u221211258.<\/li>\n
  6. Wang P., Chen X., Jiang Q., Addicoat M., Huang N., Dalapati S.,Heine T., Huo F., Jiang D., High-Precision Size Recognition and Separation in Synthetic 1DNanochannels. [J] Angew. Chem. Int. Ed. 2019, 58, 15922-15927.<\/li>\n
  7. Xu Q., Tao S., Jiang Q., Jiang D., Designing Covalent Organic Frameworks with a Tailored IonicInterface for Ion Transport across One-Dimensional Channels. [J] Angew. Chem. Int. Ed. 2020, 59, 4557-4563.<\/li>\n
  8. Jin E., Lan Z., Jiang Q., Geng K., Li G.,Wang X., Jiang D.,2D sp2<\/sup>\u00a0Carbon-Conjugated Covalent Organic\u00a0Frameworks for Photocatalytic Hydrogen\u00a0Production from Water. [J] Chem 2019, 5, 1632-1647.<\/li>\n
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