{"id":200417,"date":"2020-04-30T06:30:38","date_gmt":"2020-04-29T22:30:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=200417"},"modified":"2020-04-29T23:30:22","modified_gmt":"2020-04-29T15:30:22","slug":"jacs%ef%bc%9a%e6%99%b6%e7%95%8c%e7%bb%93%e6%9e%84%e5%92%8c%e6%9f%94%e6%80%a7%e7%9a%84%e8%b7%b7%e8%b7%b7%e6%9d%bf%e6%95%88%e5%ba%94%e5%af%b9%e5%8f%8c%e9%87%91%e5%b1%9e%e8%86%9c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=200417","title":{"rendered":"JACS\uff1a\u6676\u754c\u7ed3\u6784\u548c\u67d4\u6027\u7684\u201c\u8df7\u8df7\u677f\u201d\u6548\u5e94\u5bf9\u53cc\u91d1\u5c5e\u819c\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u7684\u5f71\u54cd"},"content":{"rendered":"

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\uff08d\uff09Zn82<\/sub>Co18<\/sub>-ZIF\u819c\u7684\u52a0\u538b\u6d4b\u8bd5\u3002<\/p>\n

\u00a0<\/b><\/strong>\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u4f5c\u8005\u4f7f\u7528\u4e00\u6b65\u5feb\u901f\u7535\u6d41\u9a71\u52a8\u6cd5\uff08FCDS\uff09\u572820 min\u5185\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u53cc\u91d1\u5c5eZn(100-x)<\/sub>Cox<\/sub>-ZIF\u819c\uff0c\u5e76\u5bf9\u5f71\u54cd\u53cc\u91d1\u5c5e\u819c\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u7684\u56e0\u7d20\uff08\u67d4\u6027\u548c\u6676\u754c\u7ed3\u6784\uff09\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff0c\u53d1\u73b0\u4e86\u67d4\u6027\u548c\u6676\u754c\u7ed3\u6784\u5728\u5f71\u54cd\u819c\u6027\u80fd\u65f6\u5b58\u5728\u4e00\u4e2a\u6700\u4f73\u5e73\u8861\u70b9\uff0c\u4e14\u5f97\u5230\u4e86\u9884\u6d4b\u819c\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u7684\u7b49\u9ad8\u7ebf\u56fe\u3002\u6b64\u5916\uff0c\u6587\u4e2d\u91c7\u7528\u5b9a\u5411\u6307\u6570\uff08OI\u503c\uff09\u3001Co%\u5206\u522b\u4f5c\u4e3a\u8861\u91cf\u819c\u6676\u754c\u7ed3\u6784\u3001\u67d4\u6027\u7684\u5173\u952e\u6307\u6807\u3002\u7531\u5b9e\u9a8c\u5f97\u77e5\uff0cZn82<\/sub>Co18<\/sub>-ZIF\u819c\u4f4d\u4e8e\u6700\u4f73\u5e73\u8861\u70b9\uff0cC3<\/sub>H6<\/sub>\/C3<\/sub>H8<\/sub>\u5206\u79bb\u7cfb\u6570\u9ad8\u8fbe200\uff0c\u4e14\u8be5\u819c\u5177\u6709\u4f18\u5f02\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002<\/p>\n

\u00a0<\/b><\/strong>\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong>Balancing the Grain Boundary Structure and the Framework Flexibility through Bimetallic MOF Membranes for Gas Separation<\/b><\/u><\/strong><\/a>\u201d(<\/b><\/strong>J. Am. Chem. Soc.\uff0c<\/b><\/strong>2020\uff0c10.1021\/jacs.0c02181)<\/b><\/strong><\/p>\n

\u738b\u6d77\u8f89\u6559\u6388<\/b><\/strong>\uff0c\u73b0\u4efb\u534e\u5357\u7406\u5de5\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u6559\u6388\uff0c\u4e3b\u8981\u4ece\u4e8b\u7684\u7814\u7a76\u65b9\u5411\u5305\u62ec\u5728\u65e0\u673a\u819c\u4e0e\u819c\u5206\u79bb\uff0c\u819c\u50ac\u5316\u4e0e\u819c\u53cd\u5e94\u5668\u3002\u738b\u6d77\u8f89\u6559\u6388\u4f5c\u4e3a\u901a\u8baf\u8054\u7cfb\u4eba\uff0c\u5728Nature Sustainability\u3001Science\u00a0Advances\u3001 Joule\u3001Journal of American Chemical Society\u3001Angewandte Chemie-International Edition\u3001Advanced Materials\u7b49\u56fd\u9645\u9876\u7ea7\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u6587\u8d85\u8fc7200\u7bc7\uff0c\u5f15\u7528\u4e07\u4f59\u6b21\uff0c\u83b7\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u522920\u9879\u3002\u738b\u6d77\u8f89\u6559\u6388\u66fe\u83b7\u5f97\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u3001\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u3001\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u548c\u4faf\u5fb7\u699c\u5316\u5de5\u79d1\u6280\u521b\u65b0\u5956\u3002\u4ed62003\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\uff0c\u540c\u5e74\u5165\u9009\u5fb7\u56fd\u6d2a\u5821\u5b66\u8005\u30022007\u5e74\u5165\u804c\u534e\u5357\u7406\u5de5\u5927\u5b66\uff0c\u540c\u5e74\u5165\u9009\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u8ba1\u5212\uff0c2011\u5e74\u5165\u9009\u5e7f\u4e1c\u7701\u73e0\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c2012\u5e74\u83b7\u5f97\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\uff0c2015\u5e74\u5165\u9009\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\uff0c2016\u5e74\u5165\u9009\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1aFellow\uff0c2017\u5e74\u83b7\u8058\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c2018\u5e74\u5165\u9009\u7b2c\u4e09\u6279\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\uff0c\u5165\u9009\u5e7f\u4e1c\u7701\u7279\u652f\u8ba1\u5212\u201c\u6770\u51fa\u4eba\u624d\u548c\u56fd\u52a1\u9662\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34\u3002<\/p>\n

\u738b\u6d77\u8f89\u6559\u6388\u56e2\u961f\u60c5\u51b5\u89c1\u8bfe\u9898\u7ec4\u7f51\u7ad9\uff1ahttp:\/\/www2.scut.edu.cn\/cee\/msem\/<\/u><\/a><\/p>\n

\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b\uff1a<\/b><\/strong><\/p>\n

\u534e\u5357\u7406\u5de5\u5927\u5b66\u738b\u6d77\u8f89\u6559\u6388\u56e2\u961f\u5f00\u8f9f\u4e86\u57fa\u4e8e\u7535\u5316\u5b66\u7b56\u7565\u5236\u5907MOF\u819c\u7684\u7cfb\u5217\u65b9\u6cd5\u3002<\/p>\n

\u8be5\u56e2\u961f\u7387\u5148\u5229\u7528\u5feb\u901f\u7535\u6c89\u79ef\u6cd5\u5728\u591a\u5b54\u4e0d\u9508\u94a2\u7f51\u57fa\u5e95\u6c89\u79ef\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u6c22\u6c27\u5316\u7269\uff0c\u5229\u7528\u5e38\u6e29\u7535\u6c89\u79ef\u6240\u5f97\u91d1\u5c5e\u524d\u9a71\u4f53\u7684\u4f18\u5f02\u6d3b\u6027\uff0c\u5b9e\u73b0\u4e86\u65e0\u9700\u9ad8\u6e29\u6d3b\u5316\u3001\u76f4\u63a5\u4e8c\u6b21\u751f\u957f\u5236\u5907\u8fde\u7eed\u65e0\u7f3a\u9677\u7684MOF\u819c\uff0c\u4e14\u5728H2<\/sub>\/CO2<\/sub>\u5206\u79bb\u65b9\u9762\u6027\u80fd\u4f18\u5f02\uff0c\u8be5\u65b9\u6cd5\u5bf9\u591a\u79cd\u91d1\u5c5e\u6e90\u7684MOF\u819c\u5177\u6709\u5f88\u597d\u7684\u666e\u9002\u6027\u3010J. Mater. Chem. A<\/i><\/b><\/em><\/strong>\u00a02017,\u00a05<\/b><\/strong>, 1948\u3011\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c \u8be5\u56e2\u961f\u53d1\u73b0\u57fa\u4e8e\u8be5\u65b9\u6cd5\u5728\u65e0\u5b54\u8f7d\u4f53\u4e0a\u5236\u5907\u7684MOF\u819c\u5177\u6709\u9ad8\u5ea6\u53d6\u5411\u6027\uff0c\u5373\u7531\u4e8e\u7535\u6c89\u79ef\u83b7\u5f97\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u524d\u9a71\u4f53\u9635\u5217\u5728\u6eb6\u89e3\u91ca\u653e\u91d1\u5c5e\u79bb\u5b50\u7684\u8fc7\u7a0b\u4e2d\u8868\u73b0\u51fa\u4e00\u5b9a\u7684\u81ea\u727a\u7272\u6a21\u677f\u4f5c\u7528\uff0c\u4f7f\u5f97\u6700\u7ec8\u83b7\u5f97\u7684MOF\u819c\u5b9a\u5411\u751f\u957f\uff1b\u4e0d\u4ec5\u5982\u6b64\uff0c\u5728\u591a\u5b54\u8f7d\u4f53\u4e0a\uff0c\u91d1\u5c5e\u524d\u9a71\u4f53\u7684\u81ea\u727a\u7272\u6a21\u677f\u4f5c\u7528\u7ed3\u5408\u91d1\u5c5e\u5f02\u6e90\u751f\u957f\u7684\u201c\u539f\u4f4d\u6676\u79cd\u6548\u5e94\u201d\u540c\u6837\u53ef\u5b9e\u73b0MOF\u819c\u7684\u9ad8\u5ea6\u5b9a\u5411\u751f\u957f\u3010Chem. Mater. <\/i><\/b><\/em><\/strong>2017, 29, 7103\u3011\u3002<\/p>\n

\u4e3a\u8fdb\u4e00\u6b65\u7b80\u5316\u5236\u819c\u8fc7\u7a0b\uff0c\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u7535\u6d41\u9a71\u52a8\u5feb\u901f\u5236\u5907ZIF-8\u819c\u7684\u65b0\u65b9\u6cd5\uff0c\u901a\u8fc7\u65bd\u52a0\u6beb\u5b89\u7ea7\u7684\u5fae\u5c0f\u7535\u6d41\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u5ba4\u6e29\u4e0bZIF-8\u819c\u5728\u591a\u5b54\u57fa\u5e95\u4e0a\u7684\u5feb\u901f\u751f\u957f\uff0c\u8017\u65f6\u4ec5\u970020\u5206\u949f\uff0c\u5236\u5907\u8fc7\u7a0b\u6781\u4e3a\u7b80\u5355\u5feb\u6377\uff0c\u5177\u6709\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\u3002\u5728\u8be5\u8fc7\u7a0b\u4e2dMOF\u819c\u7684\u8868\u73b0\u51fa\u751f\u957f\u81ea\u6291\u5236\u6027\uff08\u5373\u53ef\u83b7\u5f97\u8d85\u8584\u819c\uff09\u3001\u81ea\u4fee\u590d\u6027\uff08\u5373\u53ef\u81ea\u52a8\u4fee\u8865\u6676\u95f4\u7f3a\u9677\uff09\u3001\u6676\u683c\u539f\u4f4d\u521a\u6027\u5316\uff08\u5373\u53cd\u5e94\u4ea7\u751f\u7684\u7535\u573a\u5c06\u6676\u683c\u539f\u4f4d\u6781\u5316\u8f6c\u53d8\u4e3a\u521a\u6027\u7ed3\u6784\uff09\u7b49\u591a\u91cd\u7279\u70b9\uff0c\u5236\u5f97\u7684\u8d85\u8584\u819c\u5bf9\u4e19\u70ef\/\u4e19\u70f7\u7684\u5206\u79bb\u9009\u62e9\u6027\u9ad8\u8fbe300\u4ee5\u4e0a\uff0c\u5c55\u73b0\u51fa\u8fc4\u4eca\u4e3a\u6b62\u6700\u9ad8\u7684\u4e19\u70ef\u4e19\u70f7\u5206\u79bb\u9009\u62e9\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u5728\u4e00\u6b65\u7535\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u540c\u65f6\u89e3\u51b3\u4e86ZIF-8\u6750\u6599\u7684\u67d4\u6027\u3001\u6676\u754c\u7f3a\u9677\u3001\u819c\u5c42\u539a\u5ea6\u63a7\u5236\u7b49\u591a\u4e2a\u590d\u6742\u96be\u9898\uff0c\u4e3a\u819c\u5206\u79bb\u6280\u672f\u7684\u53d1\u5c55\u5e26\u6765\u4e86\u65b0\u7684\u601d\u8def\u3010Sci. Advances<\/i><\/b><\/em><\/strong>, 2018, 4<\/i><\/em>, eaau1393\u3011\u3002\u4e3a\u62d3\u5c55MOF\u819c\u5728\u4e0d\u540c\u6c14\u4f53\u5206\u79bb\u8fc7\u7a0b\u4e2d\u7684\u5e94\u7528\uff0c\u56e2\u961f\u5c06\u53cc\u914d\u4f53\u7b56\u7565\u4e0e\u7535\u6d41\u9a71\u52a8\u5feb\u901f\u5236\u5907\u7b56\u7565\u76f8\u7ed3\u5408\u4ee5\u7f29\u5c0f\u5b54\u5f84\uff0c\u4e00\u6b65\u5236\u5f97\u4e86\u7cfb\u5217\u53cc\u914d\u4f53\u521a\u6027MOF\u819c\uff0c\u5b9e\u73b0\u4e86CO2\/<\/sub>CH4<\/sub>\u7684\u9ad8\u6548\u5206\u79bb\u3010Angew. Chem. Int. Ed., <\/i><\/b><\/em><\/strong>2019, 58, 327\u3011\u3002<\/p>\n

\u6700\u8fd1\uff0c\u8be5\u56e2\u961f\u4e3a\u89e3\u51b3MOF\u819c\u914d\u4f53\u65cb\u8f6c\u5e26\u6765\u201c\u547c\u5438\u6548\u5e94\u201d\u548c\u6676\u95f4\u7f3a\u9677\u5bfc\u81f4\u5206\u79bb\u9009\u62e9\u6027\u964d\u4f4e\u7684\u95ee\u9898\uff0c\u56e2\u961f\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u53cc\u91d1\u5c5eMOF\u819c\uff0c\u4e00\u65b9\u9762\u901a\u8fc7\u5f15\u5165\u7b2c\u4e8c\u7c7b\u91d1\u5c5e\u4ee5\u589e\u5f3a\u91d1\u5c5e-\u914d\u4f53\u952e\u80fd\u3001\u53e6\u4e00\u65b9\u9762\u5229\u7528\u524d\u671f\u5de5\u4f5c\u63a2\u7d22\u5f97\u5230\u7684\u91d1\u5c5e\u5f02\u6e90\u751f\u957f\u7684\u201c\u539f\u4f4d\u6676\u79cd\u6548\u5e94\u201d\uff0c\u4ee5\u5b9e\u73b0\u6676\u4f53\u5b9a\u5411\u751f\u957f\u51cf\u5c11\u6676\u95f4\u7f3a\u9677\uff0c\u5229\u7528\u53cc\u91d1\u5c5e\u7b56\u7565\u540c\u65f6\u534f\u8c03\u4e0a\u8ff0\u4e24\u65b9\u9762\u95ee\u9898\uff0c\u5236\u5f97\u7684MOF\u819c\u5728\u4e19\u70ef\/\u4e19\u70f7\u5206\u79bb\u4e2d\u8868\u73b0\u4f18\u5f02\u3010JACS <\/i><\/b><\/em><\/strong>2020, DOI: 10.1021\/jacs.0c02181\u3011\u3002<\/p>\n

\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\uff1a<\/b><\/strong><\/p>\n

JACS <\/i><\/b><\/em><\/strong>2020, DOI: 10.1021\/jacs.0c02181<\/p>\n

Angew. Chem. Int. Ed. <\/i><\/b><\/em><\/strong>2019, 58, 327<\/p>\n

Sci. Advances<\/i><\/b><\/em><\/strong>\u00a02018, 4<\/i><\/em>, eaau1393<\/p>\n

Chem. Mater. <\/i><\/b><\/em><\/strong>2017, 29, 7103<\/p>\n

Mater. Chem. A<\/i><\/b><\/em><\/strong>2017,\u00a05<\/b><\/strong>, 1948<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4ebaCYM\u7f16\u8bd1\u4f9b\u7a3f\u3002<\/p>\n

\u00a0<\/u><\/p>\n

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