{"id":199075,"date":"2020-04-25T06:00:03","date_gmt":"2020-04-24T22:00:03","guid":{"rendered":"\/\/m.iemloyee.com\/?p=199075"},"modified":"2020-04-24T22:13:56","modified_gmt":"2020-04-24T14:13:56","slug":"%e4%bb%8e12%e7%af%87adv-mater%e3%80%81jacs%e3%80%81nat-commun-%e6%96%87%e7%8c%ae%e4%b8%ad%e4%b8%80%e6%8e%a2%e9%87%91%e5%b1%9e%e7%ba%b3%e7%b1%b3%e5%9b%a2%e7%b0%87%e6%9c%80%e6%96%b0%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=199075","title":{"rendered":"\u4ece12\u7bc7Adv. Mater\u3001JACS\u3001Nat. Commun.\u6587\u732e\u4e2d\u4e00\u63a2\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

\u524d\u8a00<\/b><\/strong><\/p>\n

\u7531\u51e0\u4e2a\u5230\u51e0\u767e\u4e2a\u91d1\u5c5e\u539f\u5b50\u7ec4\u6210\u7684\u5355\u5c42\u914d\u4f53\u4fdd\u62a4\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\uff0c\u56e0\u4e3a\u5176\u539f\u5b50\u7ea7\u7cbe\u5ea6\u7684\u7ed3\u6784\u4fe1\u606f\uff0c\u4e0d\u8fde\u7eed\u7684\u7535\u5b50\u80fd\u7ea7\u8d4b\u4e88\u7684\u4f18\u5f02\u5149\u7535\u6027\u80fd\uff0c\u5927\u7684\u6bd4\u8868\u9762\u79ef\u7ed9\u4e88\u7684\u50ac\u5316\u9886\u57df\u5e94\u7528\u6f5c\u529b\u7b49\uff0c\u5df2\u7ecf\u6210\u4e3a\u5728\u6750\u6599\u3001\u5316\u5b66\u3001\u751f\u7269\u7b49\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u4e3a\u6b64\uff0c\u5c0f\u7f16\u6574\u7406\u4e86\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u9886\u57df\u8fdb\u51652020\u5e74\u4ee5\u6765\u7684\u6700\u65b0\u8fdb\u5c55\u3002\u5185\u5bb9\u6d89\u53ca\u5230\uff1a\u65b0\u578b\u91d1\u5c5e\u56e2\u7c07\u7684\u5236\u5907\u4e0e\u6676\u4f53\u7ed3\u6784\u89e3\u6790\u3001\u91d1\u5c5e\u56e2\u7c07\u7684\u80f6\u4f53\u52a8\u529b\u5b66\u751f\u957f\u548c\u53ef\u63a7\u5236\u5907\u3001\u9ad8\u53d1\u5149\u6027\u80fd\u7684\u91d1\u5c5e\u56e2\u7c07\u5f00\u53d1\u3001\u91d1\u5c5e\u56e2\u7c07\u57fa\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u53ca\u5176\u5728\u50ac\u5316\u9886\u57df\u7684\u5e94\u7528\u7b49\u3002<\/p>\n

Adv. Mater.: \u6df7\u6eb6\u6eb6\u5242\u8f85\u52a9\u4e24\u76f8\u5408\u6210\u4e0d\u540c\u5c3a\u5bf8\u5355\u5c42\u914d\u4f53\u4fdd\u62a4\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07<\/b><\/strong>1<\/b><\/sup><\/strong><\/p>\n

\u5c3a\u5bf8\u53ef\u8c03\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07(NCs)\u7684\u9ad8\u6548\u5408\u6210\u7b56\u7565\u662f\u7a00\u7f3a\u7684, \u56e0\u800c\u963b\u788d\u4e86\u8fd9\u7c7b\u72ec\u7279\u7eb3\u7c73\u6750\u6599\u7684\u53d1\u5c55\u3002\u6765\u81ea\u65b0\u52a0\u5761\u79d1\u6280\u7814\u7a76\u5c40\u7684Jackie Y. Ying\u6559\u6388\u8054\u5408\u9752\u5c9b\u79d1\u6280\u5927\u5b66\u7684\u8881\u52cb\u6559\u6388\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u6c34\u548c\u6709\u673a\u6eb6\u6db2\u7684\u6df7\u6eb6\u6eb6\u5242\u8f85\u52a9\u76f8\u8f6c\u79fb\u5408\u6210\u9ad8\u8d28\u91cf\u91d1\u5c5eNCs\u7684\u901a\u7528\u65b9\u6cd5\u3002\u8be5\u65b9\u6cd5\u7b80\u4fbf\u3001\u5feb\u901f(3\u5c0f\u65f6\u5185)\u3001\u53ef\u6269\u5927\u4ea7\u91cf(\u514b\u7ea7)\u3001\u901a\u7528\u6027\u5f3a\u3002\u901a\u8fc7\u7b80\u5355\u5730\u6539\u53d8\u53ef\u6df7\u6eb6\u6eb6\u5242\u7684\u6bd4\u4f8b\u548c\u7c7b\u578b\uff0c\u542b\u7852\u914d\u4f53\u548c\u786b\u9187\u914d\u4f53\u4fdd\u62a4\u7684Au-NCs\u7684\u5927\u5c0f\u53ef\u4ee5\u4eceAu10<\/sub>\u8c03\u63a7\u5230Au61<\/sub>\u3002\u8be5\u65b9\u6cd5\u5177\u6709\u76f8\u5206\u79bb\u5feb\u3001\u65e0\u9700\u7eaf\u5316\u5904\u7406\u7b49\u4f18\u70b9\uff0c\u53ef\u5b9e\u73b0\u5bf9NaBH4<\/sub>\u8fd8\u539f\u7cfb\u7edf\u4e2d\u91d1\u5c5eNCs\u751f\u957f\u7684\u5b9e\u65f6\u76d1\u6d4b\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u968f\u7740\u4ef7\u7535\u5b50\u6570\u7684\u589e\u52a0\uff0cAu-NCs\u7684\u5c3a\u5bf8\u9010\u6e10\u589e\u5927\uff0c\u5176\u673a\u5236\u4e3a2x e–<\/sup>\u751f\u957f\u673a\u5236\uff0c\u53730 e–<\/sup>\u21922 e–<\/sup>\u21924 e–<\/sup>\u21928 e–<\/sup>\u219218 e–<\/sup>\u219222 e–<\/sup>\u219232 e–<\/sup>\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/doi.org\/10.1002\/adma.201906063<\/p>\n

Sci. Adv.: \u53d1\u5149\u91cf\u5b50\u6548\u7387\u8d85\u8fc795%\u7684\u8d85\u7a33\u5b9a<\/b><\/strong>\u624b\u6027<\/b><\/strong>\u94f6<\/b><\/strong>\u56e2<\/b><\/strong>\u7c07<\/b><\/strong>2<\/b><\/sup><\/strong><\/p>\n

\u5355\u5c42\u4fdd\u62a4\u7684\u539f\u5b50\u7ea7\u7cbe\u5ea6\u7684\u94f6\u7eb3\u7c73\u56e2\u7c07\u5728\u901a\u5e38\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387(PLQY)\u548c\u7a33\u5b9a\u6027\uff0c\u5dee\u7684\u624b\u6027\u6d3b\u6027\u3002\u8fd1\u65e5\uff0c\u90d1\u5dde\u5927\u5b66\u81e7\u53cc\u5168\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u5728\u5ba4\u6e29\u4e0b\u7528\u624b\u6027\u914d\u4f53\u4e00\u6b65\u5408\u6210\u516b\u9762\u4f53Ag6<\/sub>\u7684\u56e2\u7c07\u5bf9\u6620\u4f53\u3002\u8fd9\u4e9b\u56e2\u7c07\u8868\u73b0\u51fa\u975e\u5e38\u9ad8\u7684PLQY(300 K)>95.0%\uff0c\u5e76\u5728\u9ad8\u8fbe150\u2103\u65f6\u4ecd\u7136\u4fdd\u6301\u597d\u7684\u7ed3\u6784\u5b8c\u6574\u6027\u548c\u4f18\u5f02\u7684\u53d1\u5149\u6027\u80fd\u3002\u539f\u5b50\u7ea7\u7cbe\u5ea6\u7ed3\u6784\u5206\u6790\uff0c\u7ed3\u5408\u5149\u7269\u7406\u548c\u8ba1\u7b97\u5206\u6790\u8868\u660e\uff0c\u7814\u7a76\u8005\u4eec\u5728\u94f6\u56e2\u7c07\u4f53\u7cfb\u4e2d\u89c2\u5bdf\u5230\u4e86\u70ed\u6d3b\u5316\u5ef6\u8fdf\u8367\u5149\uff0c\u8fd9\u4e5f\u9ad8PLQY\u7684\u4e3b\u8981\u539f\u56e0\u3002\u800c\u4e14\uff0cPLQY\u7ed3\u5408\u6fc0\u53d1\u6001\u7684\u624b\u6027\u884c\u4e3a\u53ef\u4ee5\u8868\u73b0\u51fa\u8f83\u5f3a\u7684\u5706\u504f\u632f\u53d1\u5149\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u7814\u7a76\u5355\u5c42\u4fdd\u62a4\u7684\u53d1\u5149\u94f6\u56e2\u7c07\u63d0\u51fa\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5<\/p>\n

https:\/\/advances.sciencemag.org\/content\/6\/6\/eaay0107.abstract<\/p>\n

Nat. Commun.: \u539f\u5b50\u5206\u8fa8\u7684Au<\/b><\/strong>52<\/b><\/sub><\/strong>Cu<\/b><\/strong>72<\/b><\/sub><\/strong>(SR)<\/b><\/strong>55<\/b><\/sub><\/strong>\u7eb3\u7c73\u5408\u91d1<\/b><\/strong>\u56e2\u7c07<\/b><\/strong>\u663e\u793a\u51fa\u5341\u9762\u4f53\u622a\u65ad\u548c\u5f6d\u7f57\u65af\u8d34\u7247\u7684\u75d5\u8ff9<\/b><\/strong>3<\/b><\/sup><\/strong><\/p>\n

\u91d1\u94dc\u5408\u91d1\u56e2\u7c07\u5177\u6709\u4e30\u5bcc\u7684\u5f62\u6001\u3002\u5b89\u5fbd\u5927\u5b66\u7684\u6731\u6ee1\u6d32\u6559\u6388\u8054\u5408\u7f8e\u56fd\u5361\u8010\u57fa\u6885\u9686\u5927\u5b66\u7684\u91d1\u8363\u8d85\u6559\u6388\u62a5\u9053\u4e86\u539f\u5b50\u5206\u89e3\u7684[Au52<\/sub>Cu72<\/sub>(p-MBT)55<\/sub>]+<\/sup>Cl–<\/sup>\u7eb3\u7c73\u5408\u91d1\u3002\u8fd9\u79cd\u7eb3\u7c73\u5408\u91d1\u5448\u73b0\u51fa\u4e0d\u540c\u5bfb\u5e38\u7684\u7ed3\u6784\u6a21\u5f0f\u3002\u9996\u5148\uff0c\u4e24\u4e2a\u94dc\u539f\u5b50\u4f4d\u4e8e\u5185\u90e87\u4e2a\u539f\u5b50\u5341\u9762\u4f53\u6838(M7<\/sub>\uff0cM=Au\/Cu)\u4e2d\u3002M7<\/sub>\u6838\u88ab\u7b2c\u4e8c\u5c42\u540c\u8d28\u91d1(Au47<\/sub>)\u5305\u88f9\uff0c\u5f62\u6210\u4e00\u4e2a\u4e24\u5c42\u7684M54<\/sub>(\u5373Au52<\/sub>Cu2<\/sub>)\u5168\u5341\u9762\u4f53\u3002\u5728\u7c7b\u4f3c\u5927\u5c0f\u7684\u91d1\u7eb3\u7c73\u7c92\u5b50\u4e2d\uff0c\u975e\u622a\u65adM54<\/sub>\u5341\u9762\u4f53\u4e0e\u622a\u65ad\u7684\u540c\u578b\u91d1Au49<\/sub>\u6838\u7684\u6bd4\u8f83\u9996\u6b21\u5c55\u793a\u4e86\u5341\u9762\u4f53\u622a\u65ad\u73b0\u8c61\u3002\u5176\u6b21\uff0cCu70<\/sub>(SR)55<\/sub>\u5c55\u73b0\u51fa\u7c7b\u4f3c\u4e8e3D\u5f6d\u7f57\u65af\u74f7\u7816\u7684\u4fdd\u62a4\u65b9\u5f0f\u5305\u88f9\u7740M54<\/sub>\u5185\u6838\u3002\u5bf9\u6bd4\u4f20\u7edf\u5def\u57fa\u4fdd\u62a4\u7684\u91d1\u7eb3\u7c73\u56e2\u7c07\u4e2d\u7684\u8868\u754c\u9762\u56fe\u6848\u5316\u7ed3\u6784\uff0cAu52<\/sub>Cu72<\/sub>\u7684\u8868\u9762\u5f62\u6210\u4e86\u4e00\u4e2a\u6269\u5c55\u7684\u7b3c\u72b6\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u7c92\u5b50\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4e0e\u7c92\u5b50\u7684\u5bf9\u79f0\u6027\u5bc6\u5207\u76f8\u5173\uff0c\u4f53\u7cfb\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\u201c\u56db\u9f7f\u8f6e\u5f0f\u201d\u7684\u8fde\u9501\u6a21\u5f0f\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/doi.org\/10.1038\/s41467-020-14400-2<\/p>\n

Angew. Chem. Int. Ed.: \u63ed\u793aAu(I)-\u5def\u57fa\u8868\u9762\u7ed3\u6784\u5bf9Au\u7eb3\u7c73\u56e2\u7c07\u7684\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u6027\u8d28\u7684\u5f71\u54cd<\/b><\/strong>4<\/b><\/sup><\/strong><\/p>\n

\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149(AIE)\u6280\u672f\u4e3a\u5236\u5907\u9ad8\u53d1\u5149\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07(NCs)\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u4f46\u5408\u7406\u63a7\u5236\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u53d1\u5c04\u80fd\u91cf\uff08\u53d1\u5149\u989c\u8272\uff09\u548c\u5f3a\u5ea6\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u8c22\u5efa\u5e73\u6559\u6388\u56e2\u961f\u4ee5\u7cfb\u5217\u6c34\u6eb6\u6027\u8c37\u80f1\u7518\u80bd(GSH)\u4fdd\u62a4\u7684Au\u914d\u5408\u7269\u548cAu\u7eb3\u7c73\u56e2\u7c07\u4e3a\u6a21\u578b(\u5373[Au10<\/sub>SR10<\/sub>]\u3001[Au15<\/sub>SR13<\/sub>]\u3001[Au18<\/sub>SR14<\/sub>]\u3001[Au25<\/sub>SR18<\/sub>]\uff0c\u5176\u4e2dSR\u8868\u793a\u786b\u9187\u914d\u4f53)\uff0c\u63ed\u793a\u4e86\u8868\u9762Au(I)-\u786b\u9187\u914d\u4f53\u5bf9Au-NCs\u7684AIE\u6027\u8d28\u7684\u5f71\u54cd\u3002\u8be6\u7ec6\u7684\u5149\u8c31\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7\u63a7\u5236NC\u8868\u9762Au(I)-SR\u6210\u5206\u7684\u957f\u5ea6\uff0cAu-NCs\u7684\u53d1\u5c04\u6ce2\u957f\u53ef\u4ee5\u5728\u53ef\u89c1\u5149\u5230\u8fd1\u7ea2\u5916II(NIR-II)\u7684\u5bbd\u5149\u8c31\u8303\u56f4\u5185\u8fdb\u884c\u8c03\u8282\u3002\u66f4\u6709\u8da3\u7684\u662f\uff0c\u7f29\u77edAu(I)-SR\u6210\u5206\u7684\u957f\u5ea6\u53ef\u4ee5\u6539\u53d8\u56e2\u7c07\u53d1\u5149\u7684\u91ca\u653e\u52a8\u529b\u5b66\u8fc7\u7a0b\uff08\u4eceAIE\u578b\u78f7\u5149\u5230Au(0)\u6838\u6001\u8367\u5149\uff09\u3002\u91cd\u8981\u7684\u662f\uff0c\u5f53Au-NCs\u5728\u6eb6\u6db2\u4e2d\u7684\u805a\u96c6\u5ea6\u589e\u52a0\u65f6\uff0c\u8fd9\u79cd\u6548\u5e94\u53d8\u5f97\u66f4\u52a0\u663e\u8457\u3002\u672c\u6587\u7684\u7814\u7a76\u7ed3\u679c\u4e0d\u4ec5\u5bf9\u91d1\u5c5eNCs\u7684\u53d1\u5c04\u673a\u7406\u63d0\u4f9b\u4e86\u6df1\u5165\u7684\u8ba4\u8bc6\uff0c\u800c\u4e14\u4e3a\u53d1\u5149\u91d1\u5c5eNCs\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u539f\u5219\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/doi.org\/10.1002\/anie.201916675<\/p>\n

J. Am. Chem. Soc.: \u542b24\u4e2a\u91d1\u539f\u5b50\u56e2\u7c07\u7684\u5185\u90e8\u7a7a\u4f4d\u5f15\u53d1\u7ed3\u6784\u5f1b\u8c6b\u589e\u5f3a\u50ac\u5316\u53cd\u5e94\u6d3b\u6027<\/b><\/strong>5<\/b><\/sup><\/strong><\/p>\n

\u63ed\u5f00\u50ac\u5316\u5242\u4e2d\u975e\u8868\u9762\u6216\u975e\u754c\u9762\u4f4d\u70b9\u5bf9\u50ac\u5316\u6027\u80fd\u7684\u8d21\u732e\u4e4b\u8c1c\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\uff0c\u56e0\u4e3a\u5f88\u96be\u7cbe\u786e\u5730\u6355\u83b7\u50ac\u5316\u5242\u4e2d\u7f16\u7801\u7684\u7ed3\u6784\u4fe1\u606f(\u8868\u9762\u52a0\u5185\u90e8)\u3002\u5317\u4eac\u79d1\u6280\u5927\u5b66\u7684\u9648\u540d\u626c\u526f\u6559\u6388\u3001\u4e0a\u6d77\u540c\u6b65\u8f90\u5c04\u88c5\u7f6e\u5f20\u6c5f\u5b9e\u9a8c\u5ba4\u7684Rui Si\u548c\u5357\u4eac\u5927\u5b66\u7684\u795d\u8273\u6559\u6388\u8054\u5408\u9610\u660e\u4e86\uff0c\u539f\u5b50\u7cbe\u5ea6\u768424\u4e2a\u539f\u5b50\u91d1\u56e2\u7c07\u5185\u7a7a\u4f4d\uff0c\u5728\u8c03\u8282CO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u50ac\u5316\u6027\u80fd\u4e2d\u7684\u5173\u952e\u4f5c\u7528\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u4e0e\u7ed3\u6784\u76f8\u4f3c\u4e14\u6ca1\u6709\u5185\u90e8\u7a7a\u4f4d\u7684Au25<\/sub>\u56e2\u7c07\u76f8\u6bd4\uff0c\u5177\u6709\u5185\u90e8\u7a7a\u4f4d\u7684Au24<\/sub>\u56e2\u7c07\u5728\u76f8\u5bf9\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u80fd\u591f\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u53e6\u5916\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0cAu24<\/sub>\u7684\u5185\u90e8\u7a7a\u4f4d\u4e3a\u56e2\u7c07\u63d0\u4f9b\u4e86\u66f4\u5927\u7684\u7ed3\u6784\u7075\u6d3b\u6027\uff0c\u8fd9\u53ef\u80fd\u5bf9\u963b\u6b62\u56e2\u7c07\u7684\u805a\u96c6\u548c\u8fdb\u4e00\u6b65\u5ef6\u7f13\u50ac\u5316\u5242\u5931\u6d3b\u8d77\u5230\u5173\u952e\u4f5c\u7528\u3002\u540c\u65f6\uff0c\u6587\u7ae0\u4e5f\u63d0\u51fa\u4e86\u53cd\u5e94\u4e2d\u95f4\u4ea7\u7269\u7684\u52a0\u6c22\u548c\u5076\u8054\u9636\u6bb5\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u4ee5\u89e3\u91ca\u7a7a\u4f4dAu24<\/sub>\u50ac\u5316\u5242\u4e0aCO2<\/sub>\u4e0eH2<\/sub>\u7684\u6f5c\u5728\u53cd\u5e94\u9014\u5f84\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.9b07761<\/p>\n

J. Am. Chem. Soc.: \u5939\u5fc3\u56e2\u7c07\u590d\u5408\u7eb3\u7c73\u50ac\u5316\u5242ZIF-8@Au<\/b><\/strong>25<\/b><\/sub><\/strong>@ZIF-6\u7684\u8bbe\u8ba1\u548c\u663e\u8457\u7684\u50ac\u5316<\/b><\/strong>\u6027\u80fd<\/b><\/strong>6<\/b><\/sup><\/strong><\/p>\n

\u5177\u6709\u7cbe\u786e\u8868\u9762\u7ed3\u6784\u548c\u754c\u9762\u7ed3\u6784\u7684\u591a\u76f8\u50ac\u5316\u5242\u5728\u83b7\u5f97\u9ad8\u6d3b\u6027\u7684\u540c\u65f6\uff0c\u5bf9\u89e3\u91ca\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb\u548c\u4fdd\u6301\u663e\u8457\u7a33\u5b9a\u6027\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5b89\u5fbd\u5927\u5b66\u7684\u6731\u6ee1\u6d32\u6559\u6388\u8054\u5408\u6cd5\u56fd\u6ce2\u5c14\u591a\u5927\u5b66Didier Astruc\u6559\u6388\u62a5\u9053\u4e86\uff0c\u901a\u8fc7\u5177\u6709\u660e\u786e\u7ed3\u6784\u548c\u754c\u9762\u7684\u534f\u540c\u8f85\u52a9\u81ea\u7ec4\u88c5\uff0c\u5b9e\u73b0\u4e86\u65b0\u578b\u5939\u5c42\u590d\u5408\u6750\u6599ZIF-8@Au25<\/sub>@ZIF-67\u548cZIF-8@Au25<\/sub>@ZIF-8\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u3002\u4e0e\u7b80\u5355\u7ec4\u5206Au25<\/sub>\/ZIF-8\u548cAu25<\/sub>@ZIF-8\u76f8\u6bd4\uff0cZIF-8@Au25<\/sub>@ZIF-67\u5728\u5ba4\u6e29\u4e0b\u5bf94-\u785d\u57fa\u82ef\u915a\u7684\u8fd8\u539f\u548c\u4e0eCO2<\/sub>\u7684\u7aef\u7094\u7fb0\u57fa\u5316\u53cd\u5e94\u5747\u6709\u660e\u663e\u7684\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u589e\u5f3a\uff0c\u7a81\u51fa\u4e86\u8d85\u8584\u58f3\u7684\u9ad8\u6548\u529f\u80fd\uff0c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u9ad8\u8fbe99%\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u590d\u5408\u5939\u5fc3\u50ac\u5316\u5242\u7684\u6027\u80fd\u53ef\u4ee5\u7531\u58f3\u7684\u539a\u5ea6\u6765\u8c03\u8282\u3002\u8fd9\u4e00\u6982\u5ff5\u548c\u6210\u679c\u5c06\u4e3a\u6709\u9488\u5bf9\u6027\u5730\u8bbe\u8ba1\u5177\u6709\u589e\u5f3a\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u7eb3\u7c73\u50ac\u5316\u5242\u5f00\u8f9f\u4e00\u6761\u65b0\u9014\u5f84\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.0c00378<\/p>\n

J. Am. Chem. Soc.: \u7094\u57fa\u4fdd\u62a4\u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u5f02\u6784\u5316<\/b><\/strong>7<\/b><\/sup><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u738b\u6cc9\u660e\u6559\u6388\u56e2\u961f\u91c7\u7528\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u548c\u57fa\u8d28\u8f85\u52a9\u6fc0\u5149\u89e3\u5438\u7535\u79bb\u98de\u884c\u65f6\u95f4\u8d28\u8c31\u8054\u7528\u6280\u672f\uff0c\u7814\u7a76\u4e86\u4e24\u79cd\u540c\u5206\u5f02\u6784\u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u63a7\u5236\u5408\u6210\u548c\u7ed3\u6784\uff0c\u5176\u7ec4\u6210\u5206\u522b\u4e3aAu23<\/sub>(C\u2261CBut<\/sup>)15 <\/sub>(\u5373: Au23<\/sub>-1\u548cAu23<\/sub>-2)\u3002\u8fd9\u662f\u9996\u6b21\u5728\u7094\u70c3\u4fdd\u62a4\u7684\u91d1\u7eb3\u7c73\u56e2\u7c07\u4e2d\u53d1\u73b0\u5f02\u6784\u73b0\u8c61\u3002\u8fd9\u4e24\u4e2a\u56e2\u7c07\u4e2d\u7684\u91d1\u5c5e\u4e0e\u914d\u4f53\u4e4b\u6bd4\u4e0d\u540c\u4e8e\u5df2\u77e5\u7684Aun<\/sub>(SR)m<\/sub>\u7cfb\u7edf\u3002\u5c3d\u7ba1\u5b83\u4eec\u5177\u6709\u76f8\u4f3c\u7684\u7ed3\u6784\u548c\u76f8\u540c\u7684\u7ec4\u5206\uff0c\u8fd9\u5bf9\u5f02\u6784\u4f53\u53ef\u4ee5\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u5149\u5b66\u6027\u8d28\u3002\u5bf9\u4e8e\u8fd9\u4e24\u4e2aAu23<\/sub>\u56e2\u7c07\uff0c\u65f6\u95f4\u4f9d\u8d56\u7684\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c HOMO-1\u3001HOMO\u548c LUMO\u4e3b\u8981\u7531Au15<\/sub>\u6838\u548cV\u5f62\u7094\u91d1\u7684\u8868\u9762\u7ed3\u6784\u6784\u6210\u3002Au23<\/sub>-1\u7684HOMO\u2192LUMO\u8dc3\u8fc1\u5728\u5149\u5b66\u4e0a\u5c5e\u7981\u6212\u8dc3\u8fc1\uff0c\u800c\u5728Au23<\/sub>-2\u4e2d\u5c5e\u5141\u8bb8\u8dc3\u8fc1\u3002\u7814\u7a76\u8fd8\u53d1\u73b0\uff0c\u5728\u81ea\u7136\u73af\u5883\u6761\u4ef6\u4e0b\uff0cAu23<\/sub>-2\u7c07\u53ef\u4ee5\u81ea\u53d1\u8f6c\u5316\u4e3aAu23<\/sub>-1\u7c07\u3002\u8fd9\u9879\u5de5\u4f5c\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u7094\u70c3\u4fdd\u62a4\u7684\u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u5408\u6210\u548c\u5f02\u6784\u6027\uff0c\u5e76\u4fc3\u8fdb\u4e86\u5bf9\u4e8e\u5f02\u6784\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u7814\u7a76\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/dx.doi.org\/10.1021\/jacs.9b11836<\/p>\n

J. Am. Chem. Soc.: <\/b><\/strong>\u4e00\u79cd\u8d4b\u4e88\u91d1\u7eb3\u7c73\u56e2\u7c07\u5177\u6709\u50ac\u5316\u6d3b\u6027\u548c\u6c34\u6eb6\u6027\u53cc<\/b><\/strong>\u529f<\/b><\/strong>\u80fd\u7684\u7b56\u7565<\/b><\/strong>8<\/b><\/sup><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u91d1\u7eb3\u7c73\u56e2\u7c07\u7531\u4e8e\u5176\u8d85\u5c0f\u7684\u5c3a\u5bf8\u3001\u660e\u786e\u7684\u7ec4\u6210\u548c\u7ed3\u6784\uff0c\u5728\u50ac\u5316\u9886\u57df\u5f15\u8d77\u4e86\u79d1\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5174\u8da3\u3002\u7136\u800c\uff0c\u5728\u8fd9\u4e00\u65b0\u5174\u9886\u57df\u4e2d\u81f3\u5c11\u5b58\u5728\u4e24\u4e2a\u6311\u6218\u3002\u9996\u5148\uff0c\u914d\u4f53\u7684\u7a7a\u95f4\u4f4d\u963b\u6291\u5236\u4e86\u50ac\u5316\u6d3b\u6027\uff1b\u5176\u6b21\uff0c\u5229\u7528\u91d1\u7eb3\u7c73\u56e2\u7c07\u8fdb\u884c\u6c34\u76f8\u50ac\u5316\u7684\u673a\u7406\u5f80\u5f80\u4e0d\u660e\u786e\u3002\u4e2d\u79d1\u9662\u56fa\u4f53\u7269\u7406\u7814\u7a76\u6240\u7684\u4f0d\u5fd7\u9cb2\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u201c\u4e00\u77f3\u4e8c\u9e1f\u201d\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u4f7f\u7528\u4e3b\u5ba2\u4f53\u5316\u5b66\u6765\u89e3\u51b3\u8fd9\u4e24\u4e2a\u6311\u6218\u3002\u4f5c\u8005\u4eec\u9996\u5148\u5408\u6210\u4e86\u91d1\u521a\u70f7\u786b\u9187\u4fdd\u62a4\u7684Au40<\/sub>(S-Adm)22<\/sub>\u7eb3\u7c73\u56e2\u7c07\uff0c\u5e76\u4e0e\u03b3-CD-MOF\u7ed3\u5408\uff0c\u7136\u540e\u8f6c\u79fb\u5230HRP\u53cd\u5e94\u4f53\u7cfb\u4e2d\u3002\u6240\u5f97\u50ac\u5316\u5242\u5177\u6709\u4f18\u5f02\u7684\u6c34\u6eb6\u6027\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u4e0e\u539f\u59cbAu40<\/sub>(S-Adm)22<\/sub>\u7eb3\u7c73\u56e2\u7c07\u5b8c\u5168\u4e0d\u540c\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u4eec\u63d0\u51fa\u4e86HRP\u50ac\u5316\u673a\u7406\uff0c\u5e76\u901a\u8fc7DFT\u8ba1\u7b97\u8fdb\u884c\u4e86\u9a8c\u8bc1\u3002\u53e6\u4e00\u4e2a\u6709\u8da3\u7684\u53d1\u73b0\u662fAu40<\/sub>(S-Adm)22<\/sub>\u7684\u72ec\u7279\u7ed3\u6784\uff0c\u5b83\u53ef\u4ee5\u88ab\u89c6\u4e3aAu13<\/sub>\u4e8c\u5341\u9762\u4f53\u5355\u5143\u884d\u751f\u7ed3\u6784\uff0c\u4f46\u4e0d\u540c\u4e8e\u5e7f\u6cdb\u62a5\u9053\u7684Au13<\/sub>\u4e8c\u5341\u9762\u4f53\u4e3a\u4e2d\u5fc3\u7684\u7eb3\u7c73\u56e2\u7c07\u3002\u8fd9\u4e9b\u65b0\u9896\u6709\u8da3\u7684\u7814\u7a76\u7ed3\u679c\u5bf9\u672a\u6765\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u6027\u80fd\u8c03\u6574\u548c\u5b9e\u9645\u5e94\u7528\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u610f\u4e49\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b11017<\/p>\n

Angew. Chem. Int. Ed.: \u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u8868\u9762<\/b><\/strong>\u6539\u6027\u63d0\u9ad8\u5176\u56fa\u6001\u8367\u5149\u6027\u80fd<\/b><\/strong>9<\/b><\/sup><\/strong><\/p>\n

\u80fd\u591f\u7cbe\u786e\u5730\u8bbe\u8ba1\u51fa\u6240\u9700\u7684\u7535\u5b50\u548c\u5149\u5b66\u6027\u8d28\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7ed3\u6784\uff0c\u5bf9\u4e8e\u5145\u5206\u53d1\u6325\u5176\u5728\u5149\u7535\u548c\u751f\u7269\u533b\u5b66\u5e94\u7528\u4e2d\u7684\u6f5c\u529b\u81f3\u5173\u91cd\u8981\u3002\u6765\u81ea\u6df1\u5733\u5927\u5b66\u82cf\u9648\u826f\u6559\u6388\u7b49\u4eba\u63d0\u51fa\u901a\u8fc7\u914d\u4f53\u8bf1\u5bfc\u7684\u8868\u9762\u91cd\u7ec4\u548c\u6742\u539f\u5b50\u63ba\u6742\u6765\u7cbe\u786e\u5730\u4fee\u9970\u5178\u578b\u7684[Au25<\/sub>(SR1<\/sup>)18<\/sub>]–<\/sup>\u00a0\u7c07(1)\u7684\u8868\u9762\uff0c\u540c\u65f6\u4fdd\u6301\u5176\u4e8c\u5341\u9762\u4f53Au13<\/sub>\u6838\uff0c\u4ee5\u5408\u6210\u65b0\u7684\u5408\u91d1\u56e2\u7c07[Au19<\/sub>Cd3<\/sub>(SR2<\/sup>)18<\/sub>]–<\/sup>\u00a0(2)\u3002\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u7814\u7a76\u8868\u660e\uff0c\u56e2\u7c071\u7684Au13<\/sub>\u6838\u4e0a\u7684\u516d\u4e2a\u4e8c\u9f7fAu2<\/sub>(SR1<\/sup>)3<\/sub>\u8868\u9762\u7ed3\u6784\u88ab\u4e09\u4e2a\u56db\u9f7fAu2<\/sub>Cd(SR2<\/sup>)6<\/sub>\u8868\u9762\u7ed3\u6784\u6240\u53d6\u4ee3\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7ed3\u679c\u90fd\u8868\u660e\u8868\u9762\u7ed3\u6784Au2<\/sub>Cd(SR2<\/sup>)6<\/sub>\u4e0eAu13<\/sub>\u6838\u4e4b\u95f4\u5b58\u5728\u8f83\u5f3a\u7684\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u8fd9\u662f\u7531\u4e8eAu2<\/sub>Cd(SR2<\/sup>)6<\/sub>\u5177\u6709\u66f4\u7d27\u5bc6\u7684\u56e2\u7c07\u7ed3\u6784\u548c\u66f4\u5927\u7684\u80fd\u9699\u3002\u8fd9\u4e9b\u56e0\u7d20\u663e\u8457\u63d0\u9ad8\u4e86\u56e2\u7c072\u6676\u4f53\u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u6548\u7387\u548c\u5bff\u547d\u3002\u6b64\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u4e00\u7cfb\u5217\u5177\u6709\u4f18\u5f02\u5149\u7535\u6027\u80fd\u548c\u529f\u80fd\u7684\u5408\u91d1\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

http:\/\/dx.doi.org\/10.1002\/anie.202001034<\/p>\n

Angew. Chem. Int. Ed.: \u8d85\u5c0f\u91d1\u56e2\u7c07<\/b><\/strong>\u5d4c\u5165<\/b><\/strong>\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u5b54<\/b><\/strong>\u9053<\/b><\/strong>\u4e2d\u4ee5\u63d0\u9ad8\u5149\u7a33\u5b9a\u6027\u548c\u5149\u50ac\u5316\u6027\u80fd<\/b><\/strong>10<\/b><\/sup><\/strong><\/p>\n

\u91d1\u56e2\u7c07(Au-NCs)\u8d1f\u8f7d\u4e8e\u5404\u79cd\u8f7d\u4f53\u4e0a\u5e7f\u6cdb\u5e94\u7528\u4e8e\u80fd\u6e90\u548c\u751f\u7269\u9886\u57df\u3002\u7136\u800c\uff0c\u5728\u957f\u65f6\u95f4\u7684\u5149\u7167\u4e0b\uff0cAu-NCs\u5728\u8f7d\u4f53\u754c\u9762\u4e0a\u7684\u5149\u7a33\u5b9a\u6027\u5dee\uff0c\u5f80\u5f80\u4f1a\u5bfc\u81f4\u50ac\u5316\u6027\u80fd\u7684\u4e0b\u964d\u3002\u5177\u6709\u5468\u671f\u6027\u548c\u8d85\u5c0f\u5b54\u7ed3\u6784\u7684\u5171\u4ef7\u6709\u673a\u9aa8\u67b6(COFs)\u662f\u5206\u6563\u548c\u7a33\u5b9aAu-NCs\u7684\u7406\u60f3\u8f7d\u4f53\uff0c\u4f46\u5f88\u96be\u5c06Au-NCs\u5305\u8986\u5230\u8d85\u5c0f\u5b54\u7ed3\u6784\u4e2d\u3002\u5929\u6d25\u5927\u5b66\u7684\u5362\u5c0f\u6cc9\u6559\u6388\u56e2\u961f\u5236\u5907\u4e86\u4e00\u79cd\u5728\u5176\u5b54\u4e2d\u7528\u5def\u57fa\u94fe(-SH)\u4fee\u9970\u7684\u4e8c\u7ef4COF\u3002\u4ee5-SH\u4e3a\u6210\u6838\u70b9\uff0cAu-NCs\u53ef\u4ee5\u5728COF\u4e2d\u539f\u4f4d\u751f\u957f\u3002COF\u7684\u8d85\u5c0f\u5b54\u7ed3\u6784\u548cS-Au\u7684\u5f3a\u7ed3\u5408\u80fd\u4e3a\u63d0\u9ad8Au-NCs\u5728\u957f\u65f6\u95f4\u5149\u7167\u6761\u4ef6\u4e0b\u7684\u5206\u6563\u6027\u63d0\u4f9b\u4e86\u53cc\u91cd\u4fdd\u8bc1\u3002\u6709\u8da3\u7684\u662f\uff0c\u7531\u4e8eAu-S-COF\u952e\u5408\u6865\u7684\u5f62\u6210\uff0c\u4eba\u5de5Z\u578b\u5149\u50ac\u5316\u4f53\u7cfb\u88ab\u8ba4\u4e3a\u662f\u63d0\u9ad8\u7535\u8377\u5206\u79bb\u6548\u7387\u7684\u7406\u60f3\u9014\u5f84\u3002\u8fd9\u4e00\u65b0\u7b56\u7565\u4e3a\u5408\u7406\u8bbe\u8ba1\u5177\u6709\u53ef\u63a7\u6d3b\u6027\u548c\u9ad8\u7a33\u5b9a\u6027\u7684COF\u8f7d\u4f53\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u6709\u6548\u53c2\u8003\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

http:\/\/dx.doi.org\/10.1002\/anie.201916154<\/p>\n

Angew. Chem. Int. Ed.: \u901a\u8fc7\u7535\u8377\u8f6c\u79fb\u7814\u7a76\u7eb3\u7c73\u56e2\u7c07\u5728\u5149\u50ac\u5316\u7cfb\u7edf\u4e2d\u7684<\/b><\/strong>\u89d2\u8272<\/b><\/strong>11<\/b><\/sup><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5fb7\u56fd\u67cf\u6797\u6d2a\u5821\u5927\u5b66Nicola Pinna\u6559\u6388\u7b49\u4eba\u5efa\u7acb\u4e86\u4e00\u4e2a\u56e2\u7c07\/\u534a\u5bfc\u4f53\u6a21\u578b\u6765\u63a2\u7d22\u8d35\u91d1\u5c5e\u56e2\u7c07\u5728\u5149\u50ac\u5316\u4f53\u7cfb\u4e2d\u7684\u4f5c\u7528\u3002\u5c06\u539f\u5b50\u7ea7\u7cbe\u786e\u7684\u7eb3\u7c73\u56e2\u7c07Ag44<\/sub>(SR)30<\/sub>\u5f15\u5165\u5230\u8f83\u5927\u7981\u5e26\u5bbd\u5ea6\u7684\u534a\u5bfc\u4f53TiO2<\/sub>\u4e0a\uff0c\u53ef\u4ee5\u83b7\u5f97\u6e05\u6670\u7684\u754c\u9762\u5e76\u68c0\u6d4b\u5230\u754c\u9762\u5904\u7684\u7535\u8377\u8f6c\u79fb\u3002\u8be5\u590d\u5408\u6750\u6599\u7528\u4e8e\u5149\u50ac\u5316\u5236\u6c22(H2<\/sub>)\u3002\u7ecf\u7814\u7a76\u53d1\u73b0\uff0c\u5c06\u5149\u6e90\u7531\u53ef\u89c1\u5149\u6539\u4e3a\u6a21\u62df\u592a\u9633\u5149\uff0c\u53ef\u4f7f\u5176\u5149\u50ac\u5316\u6027\u80fd\u589e\u52a0\u4e09\u4e2a\u6570\u91cf\u7ea7\u3002H2<\/sub>\u4ea7\u7387\u8fbe\u52307.4mmol\/h\/g\uff0c\u662fAg\u7eb3\u7c73\u7c92\u5b50\u6539\u6027TiO2<\/sub>\u6750\u6599\u6027\u80fd\u76845\u500d\uff0c\u751a\u81f3\u53ef\u4ee5\u4e0e\u7c7b\u4f3c\u6761\u4ef6\u4e0b\u7684Pt\u7eb3\u7c73\u7c92\u5b50\u6539\u6027TiO2<\/sub>\u76f8\u6bd4\u3002\u80fd\u5e26\u6392\u5217\u548c\u77ac\u6001\u5438\u6536\u5149\u8c31\u4ee5\u53ca\u5176\u4ed6\u7814\u7a76\u8868\u660e\uff0c\u91d1\u5c5e\u56e2\u7c07\u7684\u4f5c\u7528\u4e0d\u540c\u4e8e\u91d1\u5c5e\u6709\u673a\u914d\u5408\u7269\u548c\u7b49\u79bb\u5b50\u4f53\u7eb3\u7c73\u9897\u7c92\u3002\u5728\u7d2b\u5916\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0c\u5b9e\u73b0\u4e86\u4e00\u79cd\u4ee5\u56e2\u7c07\u4e3a\u5c0f\u7981\u5e26\u534a\u5bfc\u4f53\u7684\u2161\u578b\u5f02\u8d28\u7ed3\u7535\u8377\u8f6c\u79fb\u8def\u7ebf\u3002II\u578b\u5149\u7cfb\u7edf\u5177\u6709\u66f4\u9ad8\u6548\u7684\u7535\u8377\u5206\u79bb\u80fd\u529b\uff0c\u8fd9\u5bf9\u63d0\u9ad8\u50ac\u5316\u6027\u80fd\u6709\u91cd\u8981\u8d21\u732e\u3002\u8fd9\u4e00\u53d1\u73b0\u4f7f\u8fd9\u4e9b\u56e2\u7c07\u4e0d\u4ec5\u4ec5\u4f5c\u4e3a\u5149\u654f\u5242\u540c\u65f6\u4e5f\u4e3a\u5728\u5149\u80fd\u8f6c\u6362\u7684\u5e94\u7528\u4e2d\u63d0\u4f9b\u4e86\u4e00\u4e2a\u66f4\u52a0\u5e7f\u9614\u7684\u5e73\u53f0\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

http:\/\/dx.doi.org\/10.1002\/anie.201915074<\/p>\n

J. Am. Chem. Soc.: \u542b\u56db\u9762\u4f53[Cu<\/b><\/strong>4<\/b><\/sub><\/strong>]<\/b><\/strong>0<\/b><\/sup><\/strong>\u6838\u7684\u539f\u5b50\u7cbe\u786eCu<\/b><\/strong>23<\/b><\/sub><\/strong>\u7eb3\u7c73\u56e2\u7c07\u7684\u591a\u6001\u6027<\/b><\/strong>12<\/b><\/sup><\/strong><\/p>\n

\u7531\u4e8e\u94dc\u7eb3\u7c73\u56e2\u7c07\u5177\u6709\u5178\u578b\u4e0d\u7a33\u5b9a\u6027\uff0c\u8fd9\u4e9b\u7eb3\u7c73\u56e2\u7c07\u7684\u539f\u5b50\u7cbe\u786e\u7ed3\u6784\u4e00\u76f4\u662f\u4e2a\u8c1c\u3002\u5c71\u4e1c\u5927\u5b66\u5b59\u9814\u6559\u6388\u4e0e\u582a\u8428\u65af\u5dde\u7acb\u5927\u5b66Christine M. Aikens\u6559\u6388\u7b49\u5408\u4f5c\u62a5\u9053\u4e86\u4e00\u4e2a\u4eceCu(CF3<\/sub>COO)2<\/sub>\u3001t<\/sup>BuC\u2261CH\u3001\u94dc\u7c89\u548cPh2<\/sub>SiH2<\/sub>\u53cd\u5e94\u4e2d\u5206\u79bb\u51fa\u6765\u7684\uff0c\u5177\u6709\u7a7a\u6c14\u548c\u6c34\u7a33\u5b9a\u6027\u7684\u94dc\u7eb3\u7c73\u56e2\u7c07(SD\/Cu23a\u6216SD\/Cu23b)\uff0c\u5b83\u91c7\u7528\u68af\u5ea6\u8fd8\u539f\u6cd5(CuII<\/sup>\u2192CuI<\/sup>\u2192Cu0<\/sup>)\uff0c\u63a7\u5236\u8fd8\u539f\u53cd\u5e94\u7684\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u907f\u514d\u4e86\u7eafCuI<\/sup>\u7edc\u5408\u7269\u6216\u5927\u7684Cu0<\/sup>\u7eb3\u7c73\u7c92\u5b50\u7684\u5f62\u6210\u3002Cu23<\/sub>\u7eb3\u7c73\u56e2\u7c07\u7684\u56fa\u6001\u7ed3\u6784\u5177\u6709\u4e00\u4e2a\u7f55\u89c1\u7684[Cu4<\/sub>]0<\/sup>\u56db\u9762\u4f53\u6838\uff0c\u7531\u5916\u90e8Cu19<\/sub>\u58f3\u5305\u88f9\u4ee5\u53cat<\/sup>BuC\u2261C–<\/sup>\u548cCF3<\/sub>COO–<\/sup>\u914d\u4f53\u4fdd\u62a4\u3002Cu23<\/sub>\u7eb3\u7c73\u56e2\u7c07\u662f\u4e00\u79cd\u7a00\u6709\u7684\u56db\u7535\u5b50\u8d85\u539f\u5b50\uff0c\u5177\u67091S2<\/sup>1P2<\/sup>\u7535\u5b50\u58f3\u5c42\u5c01\u95ed\u7ed3\u6784\uff0c\u6839\u636e\u6240\u7528\u6eb6\u5242\u7684\u4e0d\u540c\uff0c\u53ef\u7ed3\u6676\u6210\u4e24\u79cd\u7a7a\u95f4\u7fa4(R3c\u548cR3\u0305 )\u3002R3c\u7a7a\u95f4\u7fa4\u4e2dSD\/Cu23a\u7684\u7ed3\u6676\u4e3b\u8981\u53d7\u8303\u5fb7\u534e\u529b\u548cC-H\u00b7\u00b7\u00b7F\u76f8\u4e92\u4f5c\u7528\u7684\u63a7\u5236\uff0c\u800cR3\u0305\u7a7a\u95f4\u7fa4\u7684SD\/Cu23b\u7684\u53d7C-H\u00b7\u00b7\u00b7\u00b7Cl\u76f8\u4e92\u4f5c\u7528\u652f\u914d\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u5c55\u793a\u4e86\u5408\u6210\u94dc\u7eb3\u7c73\u56e2\u7c07\u7684\u68af\u5ea6\u8fd8\u539f\u7b56\u7565\u7684\u72ec\u521b\u6027\uff0c\u800c\u4e14\u5bf9\u4e8e\u5982\u4f55\u83b7\u5f97\u7cbe\u786e\u53ef\u8c03\u7684\u591a\u6001\u94dc\u7eb3\u7c73\u56e2\u7c07\u63d0\u4f9b\u4e86\u53c2\u8003\u4ef7\u503c\u3002<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/p>\n

https:\/\/dx.doi.org\/10.1021\/jacs.0c01053<\/p>\n

\u7ed3\u8bed<\/b><\/strong><\/p>\n

\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u9886\u57df\u662f\u5f53\u4e0b\u6750\u6599\u3001\u5316\u5b66\u548c\u751f\u7269\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u548c\u91cd\u70b9\u3002\u5177\u6709\u539f\u5b50\u7ea7\u7cbe\u5ea6\u7684\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u80f6\u4f53\u52a8\u529b\u751f\u957f\u7814\u7a76\u662f\u5f00\u53d1\u666e\u9002\u6027\u3001\u9ad8\u53ef\u63a7\u6027\u7684\u5236\u5907\u65b0\u7b56\u7565\u7684\u5173\u952e\u6b65\u9aa4\u3002\u63ed\u793a\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u53d1\u5149\u673a\u7406\u3001\u8c03\u63a7\u5176\u53d1\u5149\u6027\u80fd\uff08\u5305\u62ec\u53d1\u5149\u5f3a\u5ea6\uff0c\u53d1\u5149\u80fd\u91cf\u548c\u7a33\u5b9a\u6027\u7b49\uff09\u662f\u63a8\u8fdb\u5176\u4f5c\u4e3a\u65b0\u578b\u53d1\u5149\u6750\u6599\u7684\u91cd\u70b9\u5185\u5bb9\u3002\u57fa\u4e8e\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u590d\u5408\u6750\u6599\u5236\u5907\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5bf9\u4e8e\u63d0\u9ad8\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u5404\u65b9\u9762\u6027\u80fd\u5e2e\u52a9\u663e\u8457\u3002\u4ee5\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u4f5c\u4e3a\u50ac\u5316\u5242\u6a21\u578b\u662f\u7406\u89e3\u5f02\u76f8\u50ac\u5316\u4f53\u7cfb\u4e2d\u50ac\u5316\u5242\u8868\u754c\u9762\u50ac\u5316\u52a8\u529b\u5b66\u7684\u6709\u6548\u7b56\u7565\u3002\u53ef\u4ee5\u9884\u89c1\uff0c\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u9886\u57df\u5c06\u4f1a\u662f\u4e00\u4e2a\u56fd\u9645\u524d\u6cbf\u7814\u7a76\u70ed\u70b9\uff0c\u8ba9\u6211\u4eec\u5171\u540c\u671f\u5f85\u8be5\u9886\u57df\u66f4\u591a\u65b0\u6210\u679c\u7684\u5230\u6765\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

1. Xun Yuan, Leng Leng Chng, Jinhua Yang, Jackie Y. Ying, Miscible-Solvent-Assisted Two-Phase Synthesis of Monolayer-Ligand-Protected Metal Nanoclusters with Various Sizes. Adv. Mater. 2020, 1906063.<\/p>\n

2. Zhen Han, Xi-Yan Dong, Peng Luo, Si Li, Zhao-Yang Wang, Shuang-Quan Zang, Thomas C. W. Mak, Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency. Sci. Adv. 2020; 6 : eaay0107.<\/p>\n

3. Yongbo Song, Yingwei Li, Hao Li1, Feng Ke, Ji Xiang, Chuanjun Zhou, Peng Li, Manzhou Zhu, Rongchao Jin,Atomically resolved Au52<\/sub>Cu72<\/sub>(SR)55<\/sub>\u00a0nanoalloy reveals Marks decahedron truncation and Penrose tiling surface. Nat. Commun. 2020, 11, 478.<\/p>\n

4. Zhennan Wu, Qiaofeng Yao, Osburg Jin Huang Chai, Nan Ding, Wen Xu, Jianping Xie, Shuangquan Zang, Unraveling the Impact of Gold(I)-Thiolate Motifs on the Aggregation-Induced Emission of Gold Nanoclusters. Angew. Chem. Int. Ed. DOI:10.1002\/anie.201916675<\/p>\n

5. Xiao Cai, Weigang Hu, Shun Xu, Dan Yang, Mingyang Chen, Miao Shu, Rui Si, Weiping Ding, Yan Zhu, Structural Relaxation Enabled by Internal Vacancy Available in a 24-atom Gold Cluster Reinforces Catalytic Reactivity. J. Am. Chem. Soc. 2020, 142, 9, 4141-4153.<\/p>\n

6. Yapei Yun, Hongting Sheng, Kang Bao, Li Xu, Yu Zhang, Didier Astruc, Manzhou Zhu, Design and Remarkable Efficiency of the Robust Sandwich Cluster Composite Nanocatalysts ZIF-8@Au25@ZIF-67. J. Am. Chem. Soc. 2020, 142, 9, 4126-4130.<\/p>\n

7. Zong-Jie Guan, Feng Hu, Jiao-Jiao Li, Zhao-Rui Wen, Yu-Mei Lin, Quan-Ming Wang, Isomerization in Alkynyl-Protected Gold Nanoclusters. J. Am. Chem. Soc. 2020, 142, 2995\u22123001.<\/p>\n

8. Yan Zhao, Shengli Zhuang, Lingwen Liao, Chengming Wang, Nan Xia, Zibao Gan, Wanmiao Gu, Jin Li, Haiteng Deng, Zhikun Wu, A Dual Purpose Strategy to Endow Gold Nanoclusters with Both Catalysis Activity and Water Solubility. J. Am. Chem. Soc. 2020, 142, 973\u2212977.<\/p>\n

9. Jiong Lu, Chuanhao Yao, Cong-Qiao Xu, In-Hyeok Park, Meng Zhao, Ziyu Zhu, Jing Li, Xiao Hai, Hanyan Fang, Yong Zhang, Gennevieve Macam, Jinghua Teng, Lin Li, Qing-Hua Xu, Feng-Chuan Chuang, JunPeng Lu, Chenliang Su, Jun Li, Giant emission enhancement of solid-state gold nanoclusters via surface engineering. Angew. Chem. Int. Ed. DOI:10.1002\/anie.202001034<\/p>\n

10. Yang Deng, Zhen Zhang, Peiyao Du, Xingming Ning, Yue Wang, Dongxu Zhang, Jia Liu, Shouting Zhang, Xiaoquan Lu, Bridging Ultrasmall Au Clusters into the Pores of a Covalent Organic Framework for Enhanced Photostability and Photocatalytic Performance. Angew. Chem. Int. Ed. DOI:10.1002\/anie.201916154.<\/p>\n

11. Yu Wang, Xiao-He Liu, Qiankun Wang, Martin Quick, Sergey Kovalenko, Qing-Yun Chen, Norbert Koch, Nicola Pinna, Insights into charge transfer at the atomically precise nanocluster\/ semiconductor interface for in-depth understanding the role of nanocluster in photocatalytic system. Angew. Chem. Int. Ed. DOI:10.1002\/anie.201915074.<\/p>\n

12. Bao-Liang Han, Zhen Liu, Lei Feng, Zhi Wang, Rakesh Kumar Gupta, Christine M. Aikens, Chen-Ho Tung, Di Sun, Polymorphism in Atomically Precise Cu23<\/sub>Nanocluster Incorporating Tetrahedral [Cu4<\/sub>]0<\/sup> J. Am. Chem. Soc. 2020, 142, 12, 5834-5841.<\/p>\n

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