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\u591a\u7ec6\u80de\u751f\u7269\u7cfb\u7edf\uff08\u4f8b\u5982\u5927\u8111\uff09\u7684\u7ed3\u6784\u548c\u529f\u80fd\u590d\u6742\u6027\u8fdc\u8fdc\u8d85\u51fa\u4e86\u4eba\u7c7b\u8bbe\u8ba1\u6216\u7ec4\u88c5\u80fd\u529b\u7684\u8303\u56f4\u3002\u5982\u679c\u5c06\u5176\u89c6\u4e3a\u7279\u5b9a\u5316\u5b66\u7684\u89e3\u5256\u5b66\u5b9a\u4e49\u7684\u533a\u5ba4\uff0c\u5e76\u5229\u7528\u751f\u7269\u5b66\u6765\u7ec4\u88c5\u590d\u6742\u7684\u529f\u80fd\u7ed3\u6784\uff0c\u5219\u53ef\u4ee5\u9009\u62e9\u6d3b\u751f\u7269\u4f53\u4e2d\u7684\u7ec6\u80de\u6765\u6784\u5efa\u5408\u6210\u8be5\u751f\u7269\u7cfb\u7edf\u3002\u8fd1\u65e5\uff0c\u7f8e\u56fd\u65af\u5766\u798f\u5927\u5b66\u9c8d\u54f2\u5357\u6559\u6388\u548cKarl Deisseroth\u6559\u6388\u8bfe\u9898\u7ec4\u7814\u7a76\u53d1\u73b0\u901a\u8fc7\u6574\u5408\u5de5\u7a0b\u9176\u9776\u5411\u6280\u672f\u548c\u9ad8\u5206\u5b50\u5316\u5b66\uff0c\u4ece\u57fa\u56e0\u6c34\u5e73\u4e0a\u6307\u5bfc\u4e86\u7528\u4e8e\u6307\u793a\u8d28\u819c\u4e0a\u7535\u529f\u80fd\uff08\u5bfc\u7535\u6216\u7edd\u7f18\uff09\u805a\u5408\u7269\u7684\u5316\u5b66\u5408\u6210\u7684\u7279\u5b9a\u6d3b\u795e\u7ecf\u5143\u3002\u7535\u751f\u7406\u548c\u884c\u4e3a\u6548\u5e94\u5206\u6790\u8bc1\u5b9e\uff0c\u529f\u80fd\u9ad8\u5206\u5b50\u7ecf\u8fc7\u5408\u7406\u8bbe\u8ba1\uff0c\u4ee5\u57fa\u56e0\u4e3a\u9776\u6807\u7684\u7ec4\u88c5\uff0c\u4e0d\u4ec5\u4fdd\u7559\u4e86\u795e\u7ecf\u5143\u7684\u751f\u5b58\u80fd\u529b\uff0c\u800c\u4e14\u8fd8\u5b9e\u73b0\u4e86\u5bf9\u81ea\u7531\u6d3b\u52a8\u52a8\u7269\u7684\u819c\u7279\u6027\u7684\u91cd\u5851\u548c\u7ec6\u80de\u7279\u5b9a\u7c7b\u578b\u884c\u4e3a\u7684\u8c03\u8282\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u65b9\u6cd5\u53ef\u4ee5\u5728\u751f\u7269\u7cfb\u7edf\u4e2d\u521b\u5efa\u5404\u79cd\u590d\u6742\u7684\u529f\u80fd\u6027\u7ed3\u6784\u548c\u6750\u6599\u3002[<\/sup>1]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cGenetically targeted chemical assembly of functional materials in living cells, tissues, and animals\u201d\uff0c\u53d1\u8868\u5728Science\u3002<\/p>\n

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\u56fe2<\/b><\/strong>\u00a0<\/b><\/strong>Ni-PACN\u7684\u5408\u6210\u673a\u7406\u4e0eS<\/b><\/strong>EM\u56fe<\/b><\/strong><\/p>\n

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\u56fe3 \u5168PSC\u7684\u5668\u4ef6\u7ed3\u6784\u4e0e\u6027\u80fd\u6d4b\u8bd5\u56fe<\/b><\/strong><\/p>\n

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\u8c22\u6bc5<\/b><\/strong><\/p>\n

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\u8c22\u6bc5\u8bfe\u9898\u7ec4\u4e3b\u8981\u81f4\u529b\u4e8e\u57fa\u4e8e\u7535\u3001\u58f0\u8c03\u5236\u7684\u65e0\u673a\u529f\u80fd\u56fa\u4f53\u7684\u7814\u7a76\u3002\u5177\u4f53\u5185\u5bb9\u5305\u62ec\uff1a(1)\u4f4e\u7ef4\u56fa\u4f53\u7684\u8868\u5f81\u53ca\u7279\u6b8a\u7535\u5b50\u6001\u4e0e\u672c\u5f81\u7269\u6027\u7684\u6784\u6548\u5173\u7cfb\uff1b(2)\u53bb\u8026\u5408\u4f18\u5316\u70ed\u7535\u6027\u80fd\u7684\u65b0\u9014\u5f84\uff1b(3)\u57fa\u4e8e\u5149\u3001\u78c1\u3001\u7535\u3001\u70ed\u7b49\u667a\u80fd\u54cd\u5e94\u7684\u65e0\u673a\u529f\u80fd\u6750\u6599\u53ca\u5176\u673a\u654f\u7279\u6027\u63a7\u5236\uff1b(4)\u57fa\u4e8e\u7eb3\u7c73\u7ed3\u6784\u7684\u9ad8\u6548\u67d4\u6027\u80fd\u91cf\u5b58\u50a8\u4e0e\u8f6c\u6362\u5668\u4ef6\uff1b(5)\u57fa\u4e8e\u7eb3\u7c73\u7ed3\u6784\u7684CO2<\/sub>\u5bcc\u96c6\u548c\u8f6c\u6362\u7684\u5149\u3001\u7535\u50ac\u5316\u5242\u3002\u6700\u65b0\u4ee3\u8868\u6027\u7814\u7a76\u6210\u679c\u5982\u4e0b\uff1a<\/p>\n

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\u785d\u9178\u76d0\u662f\u4e00\u79cd\u751f\u4ea7\u80a5\u6599\uff0c\u706b\u836f\u548c\u70b8\u836f\u7684\u539f\u6599\u3002\u5982\u4f55\u5728\u81ea\u7136\u72b6\u6001\u4e0b\u5229\u7528\u4e30\u5bcc\u6c2e\u6c14\u7684N\u2261N\u952e\u5408\u6210\u785d\u9178\u76d0\u7684\u7814\u7a76\u5341\u5206\u91cd\u8981\u3002\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8c22\u6bc5\u6559\u6388\u8bfe\u9898\u7ec4\u4f7f\u7528\u591a\u5b54\u7684WO3<\/sub>\u50ac\u5316N\u2261N\u952e\uff0c\u5728\u5ba4\u6e29\u4e0b\u76f4\u63a5\u5408\u6210\u4e86\u785d\u9178\u76d0\u3002\u591a\u5b54\u7684\u7ed3\u6784\u4f7fWO3<\/sub>\u7eb3\u7c73\u7247\u5177\u6709\u66f4\u591a\u7684\u60ac\u7a7a\u952e\u548c\u66f4\u5bb9\u6613\u6fc0\u53d1\u7684\u9ad8\u52a8\u91cf\u7535\u5b50\uff0c\u4ece\u800c\u514b\u670d\u4e86N\u2261N\u952e\u6d3b\u5316\u8fc7\u7a0b\u4e2d\u4e24\u4e2a\u4e3b\u8981\u74f6\u9888\uff0c\u5373N2<\/sub>\u4e0e\u50ac\u5316\u6750\u6599\u7684\u7ed3\u5408\u4e0d\u826f\u4ee5\u53ca\u7531\u6b64\u4ea7\u751f\u7684\u9ad8\u80fd\u91cf\u53cd\u5e94\u3002 \u5728\u6ca1\u6709\u4efb\u4f55\u727a\u7272\u5242\u6216\u8d35\u91d1\u5c5e\u52a9\u50ac\u5316\u5242\u7684\u6761\u4ef6\u4e0b\uff0c\u785d\u9178\u76d0\u7684\u5e73\u5747\u751f\u4ea7\u901f\u5ea6\u9ad8\u8fbe1.92 mg g-1<\/sup>\u00a0h-1<\/sup>\uff0c\u8fd9\u4e00\u6210\u679c\u4e3a\u60f0\u6027\u50ac\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u7684\u65b0\u9014\u5f84\u3002[<\/sup>4]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cPothole\u2010rich Ultrathin WO3<\/sub>\u00a0Nanosheets that Trigger N\u2261N Bond Activation of Nitrogen for Direct Nitrate Photosynthesis\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Angewandte Chemie\u3002<\/p>\n

\u56fe5<\/b><\/strong>\u00a0<\/b><\/strong>\u5149\u50ac\u5316\u5f62\u6210\u785d\u9178\u76d0\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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\u5982\u4f55\u5229\u7528\u4f4e\u80fd\u91cf\u7ea2\u5916\u5149\u5c06\u4e8c\u6c27\u5316\u78b3\u548c\u6c34\u540c\u65f6\u8f6c\u5316\u4e3a\u78b3\u6c22\u5316\u5408\u7269\u548c\u6c27\u6c14\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8c22\u6bc5\u6559\u6388\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u4e86\u4e00\u79cd\u8d85\u8584\u5bfc\u4f53\u7cfb\u7edf\uff0c\u5176\u4e2d\u7279\u6b8a\u7684\u90e8\u5206\u5360\u636e\u80fd\u5e26\u5145\u5f53\u4ecb\u8d28\uff0c\u4ee5\u540c\u65f6\u4fdd\u8bc1\u7ea2\u5916\u5149\u7684\u91c7\u96c6\u548c\u4ee4\u4eba\u6ee1\u610f\u7684\u80fd\u5e26\u8fb9\u7f18\u4f4d\u7f6e\uff0c\u800c\u8d85\u8584\u7ed3\u6784\u5219\u6539\u5584\u4e86\u7535\u8377\u5206\u79bb\u6548\u7387\u548c\u8868\u9762\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3002\u5176\u8bfe\u9898\u7ec4\u9996\u5148\u5236\u9020\u4e86\u8d85\u8584\u7684CuS\u5c42\uff0c\u5176\u4e2d\u4e0e\u6e29\u5ea6\u6709\u5173\u7684\u7535\u963b\u7387\uff0c\u4ef7\u5e26\u8c31\u548c\u7406\u8bba\u8ba1\u7b97\u786e\u5b9a\u4e86\u5b83\u4eec\u7684\u91d1\u5c5e\u6027\u8d28\u3002\u540c\u6b65\u8f90\u5c04\u5149\u7535\u5b50\u548c\u8fd1\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u63ed\u793a\u4e86\u91d1\u5c5eCuS\u539f\u5b50\u5c42\u53ef\u4ee5\u5728IR\u5149\u7167\u5c04\u4e0b\u5b9e\u73b0\u65b0\u7684\u5e26\u5185-\u5e26\u95f4\u534f\u4f5c\u8dc3\u8fc1\uff0c\u5176\u4e2d\u4ea7\u751f\u7684\u7535\u5b50\u548c\u7a7a\u7a74\u5bf9\u5e94\u7740\u4e8c\u6c27\u5316\u78b3\u7684\u8fd8\u539f\u548c\u6c34\u7684\u6c27\u5316\u53cd\u5e94\u3002\u7ed3\u679c\u663e\u793a\uff1a\u5728\u7ea2\u5916\u5149\u7167\u5c04\u4e0b\uff0cCuS\u539f\u5b50\u5c42\u8868\u73b0\u51fa\u8fd1100\uff05\u7684CO\u9009\u62e9\u6027\uff0c\u751f\u6210\u901f\u7387\u4e3a14.5\u03bcmol g-1<\/sup>\u00a0h-1<\/sup>\uff0c\u7ecf\u8fc796 h\u6d4b\u8bd5\u540e\uff0c\u50ac\u5316\u6027\u80fd\u6ca1\u6709\u660e\u663e\u4e0b\u964d\u3002\u8fd9\u5f97\u76ca\u4e8e\u5176\u8d85\u9ad8\u7535\u5bfc\u7387\u548c\u7279\u6b8a\u7684\u90e8\u5206\u5360\u636e\u80fd\u5e26\uff0c\u4f7f\u5f97\u5bfc\u7535\u91d1\u5c5e\u786b\u5316\u7269\u548c\u91d1\u5c5e\u6c2e\u5316\u7269\u7b49\u4e30\u5bcc\u7684\u5bfc\u4f53\u6750\u6599\u4f5c\u4e3a\u6709\u6548\u7684\u7ea2\u5916\u5149\u54cd\u5e94\u578b\u5149\u50ac\u5316\u5242\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002[6]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cUltrathin Conductor Enabling Efficient IR Light CO2<\/sub>\u00a0Reduction\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Journal of the American Chemical Society\u3002<\/p>\n

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\"\"<\/p>\n

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\u9ad8\u50ac\u5316\u6d3b\u6027\u7684\u5bcc\u94dd\u4ecb\u5b54<\/b><\/strong>ZSM-5\u7eb3\u7c73\u76d2<\/b><\/strong>\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

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\u56fe7 <\/b><\/strong>ZSM-5-P\u7eb3\u7c73\u76d2\u5408\u6210\u673a\u7406\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

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\u56fe8<\/b><\/strong>\u00a0<\/b><\/strong>\u5355\u539f\u5b50\u50ac\u5316\u5242\u5f62\u6001\u4e0e\u6027\u80fd\u6d4b\u8bd5\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\u5bf9\u4e8e\u805a\u4e73\u9178\uff08PLA\uff09\u5de5\u4e1a\u53ef\u6301\u7eed\u53d1\u5c55\u6765\u8bf4\uff0c\u57fa\u4e8e\u03b2\u6cb8\u77f3\u50ac\u5316\u5242\u7684\u9ad8\u6d53\u5ea6\u4e73\u9178\uff08LA\uff09\u6709\u6548\u751f\u4ea7\u4e19\u4ea4\u916f\uff08LT\uff09\u662f\u5f88\u6709\u5fc5\u8981\u7684\u3002\u50cf\u4efb\u4f55\u6cb8\u77f3\u4e00\u6837\uff0c\u7eb3\u7c73\u03b2\u6cb8\u77f3\u7684Si \/ Al\u9700\u8981\u8fdb\u884c\u8c03\u6574\u4ee5\u9002\u5e94\u4e0d\u540c\u5de5\u4e1a\u50ac\u5316\u7684\u8981\u6c42\u3002\u7136\u800c\uff0c\u6539\u53d8\u5176Si \/ Al\u6bd4\u5728\u5927\u4e8e100\u6216\u4f4e\u4e8e20\u540c\u65f6\u5c06\u6676\u4f53\u5c3a\u5bf8\u4fdd\u6301\u5728100nm\u4ee5\u5185\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u8fd1\u65e5\uff0c\u5409\u6797\u5927\u5b66\u4e8e\u5409\u7ea2\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u6d53\u7f29\u51dd\u80f6\u7cfb\u7edf\u4e2d\u7684L-\u8d56\u6c28\u9178\u8f85\u52a9\u4e24\u6b65\u7ed3\u6676\u6210\u529f\u5236\u5907\u4e86\u5177\u6709\u5bbdSi \/ Al\u6bd4\uff086-300\uff09\u7684\u7eb3\u7c73\u03b2\u6cb8\u77f3\uff0810-106 nm\uff09\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u6240\u5236\u5907\u7684\u5177\u6709\u6700\u4f4eSi \/ Al\u6bd4\u548c\u6700\u5c0f\u7c92\u5f84\u7684\u03b2-15-10\u50ac\u5316\u5242\uff08Si \/ Al = 15.5\uff0c\u5c3a\u5bf8= 10.1 nm\uff09\uff0c\u5728\u9ad8\u6d53\u5ea6LA\u7684\u8f6c\u5316\u7387\uff08105 wt\uff05\uff09\u4e2d\u663e\u793a\u51fa\u6700\u9ad8\u7684LnA\u8f6c\u5316\u7387\uff08n = 1-3\uff09\u548cLT\u4ea7\u7387\uff0874\uff05\uff09\u3002\u91cd\u8981\u7684\u662f\uff0c\u9ad8\u6d53\u5ea6LA\u4e2d\u4e0d\u4ec5\u5b58\u5728LA \/ L2<\/sub>A\uff0c\u800c\u4e14\u5b58\u5728L3<\/sub>A\u8f6c\u5316\u4e3aLT\u3002\u8fd9\u662f\u7531\u4e8eBr\u00f8nsted\u9178\u4f4d\u70b9\u5bc6\u5ea6\u589e\u52a0\u53ca\u5176\u5feb\u901f\u6269\u6563\u51fa\u7eb3\u7c73\u7ea7\u6676\u4f53\u800c\u200b\u200b\u907f\u514d\u4e86\u6b21\u7ea7\u53cd\u5e94\uff08\u5373\u8131\u73af\u548c\u4f4e\u805a\uff09\u800c\u4fc3\u8fdb\u7684\u5feb\u901fLT\u751f\u4ea7\u7684\u7ed3\u679c\u3002\u540c\u65f6\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u9610\u660e\u4e86\u4eceL3A \/ L2A\u5230LT\u7684\u53cd\u5e94\u9014\u5f84\u3002[<\/sup>9]<\/sup>\u76f8\u5173\u7814\u7a76\u4ee5\u201cBreaking the Si\/Al limit of nanosized Beta zeolites: promoting catalytic production of lactide\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Chemistry of Materials\u3002<\/p>\n

\u56fe9<\/b><\/strong>\u00a0LA<\/b><\/strong>\u3001<\/b><\/strong>L<\/b><\/strong>2<\/b><\/sub><\/strong>A<\/b><\/strong>\u548c<\/b><\/strong>L<\/b><\/strong>3<\/b><\/sub><\/strong>A<\/b><\/strong>\u8f6c\u5316\u4e3a<\/b><\/strong>LT<\/b><\/strong>\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u6587\u7ae0\u7bc7\u5e45\u6709\u9650\uff0c\u591a\u6709\u4e0d\u5168\u4e4b\u5904\uff0c\u6b22\u8fce\u6279\u8bc4\u6307\u6b63\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

1. Liu, Jia, et al. “Genetically targeted chemical assembly of functional materials in living cells, tissues, and animals.”\u00a0Science6484 (2020): 1372-1376.<\/p>\n

2. Koshy, David, et al. “Understanding the Origin of Highly Selective CO2<\/sub>Electroreduction to CO on Ni, N\u2010doped Carbon Catalysts.”\u00a0Angewandte Chemie\u00a0(2020).<\/p>\n

3. Wu, Yilei, et al. “Fine-Tuning Semiconducting Polymer Self-Aggregation and Crystallinity Enables Optimal Morphology and High-Performance Printed All-Polymer Solar Cells.”\u00a0Journal of the American Chemical Society\u00a0(2019).<\/p>\n

4. Chen, Shichuan, et al. “Oxygen vacancy associated single-electron transfer for photofixation of CO2<\/sub>to long-chain chemicals.”\u00a0Nature communications1 (2019): 1-8.<\/p>\n

5. Liu, Youwen, et al. “Pothole\u2010rich Ultrathin WO3<\/sub>Nanosheets that Trigger N\u2261N Bond Activation of Nitrogen for Direct Nitrate Photosynthesis.”\u00a0Angewandte Chemie International Edition3 (2019): 731-735.<\/p>\n

6. Li, Xiaodong, et al. “Ultrathin Conductor Enabling Efficient IR Light CO2<\/sub>”\u00a0Journal of the American Chemical Society\u00a0141.1 (2018): 423-430.<\/p>\n

7. Jiao, Yilai, et al. “Creation of Al\u2010Enriched Mesoporous ZSM\u20105 Nanoboxes with High Catalytic Activity: Converting Tetrahedral Extra\u2010Framework Al into Framework Sites via Post Treatment.”\u00a0Angewandte Chemie International Edition(2020).<\/p>\n

8. Hou, Chun-Chao, et al. “Single\u2010Atom Iron Catalysts on Overhang\u2010Eave Carbon Cages for High\u2010Performance Oxygen Reduction Reaction.” Angewandte Chemie(2020).<\/p>\n

9. Zhang Q, Xiang S, Zhang Q, et al. Breaking the Si\/Al limit of nanosized Beta zeolites: promoting catalytic production of lactide[J]. Chemistry of Materials, 2020.<\/p>\n

\u672c\u6587\u7531Leo<\/b><\/strong>\u00a0W<\/b><\/strong>u<\/b><\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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