{"id":198980,"date":"2020-04-04T06:09:22","date_gmt":"2020-04-03T22:09:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=198980"},"modified":"2020-04-03T21:09:49","modified_gmt":"2020-04-03T13:09:49","slug":"%e9%a6%99%e6%b8%af%e5%9f%8e%e5%b8%82%e5%a4%a7%e5%ad%a6%e6%9a%a8%e5%8d%97%e5%a4%a7%e5%ad%a6adv-energy-mater-%e9%92%99%e9%92%9b%e7%9f%bf-%e6%9c%89%e6%9c%ba%e6%9f%94%e6%80%a7%e5%8f%a0%e5%b1%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=198980","title":{"rendered":"\u9999\u6e2f\u57ce\u5e02\u5927\u5b66&#038;\u66a8\u5357\u5927\u5b66Adv. Energy Mater.: \u9499\u949b\u77ff-\u6709\u673a\u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u52a9\u529b\u9ad8\u6548\u5168\u89e3\u6c34"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u53ca\u7b80\u5355\u5ec9\u4ef7\u7684\u5236\u5907\u5de5\u827a\uff0c\u5728\u5149\u4f0f\u9886\u57df\u6380\u8d77\u4e86\u65b0\u7684\u7814\u7a76\u70ed\u6f6e\u3002\u7ecf\u8fc7\u8fd1\u5341\u5e74\u7684\u7814\u7a76\u53d1\u5c55\uff0c\u5355\u7ed3\uff08single-junction\uff09\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6700\u9ad8\u5149\u7535\u8f6c\u6362\u6548\u7387\u5df2\u7ecf\u8dc3\u5347\u81f3\u6700\u65b0\u8ba4\u8bc1\u768425.2%\uff0c\u4e0e\u5546\u4e1a\u5316\u7684\u6676\u7845\u592a\u9633\u80fd\u7535\u6c60\u76f8\u5f53\u3002\u7136\u800c\u5355\u7ed3\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u53d7\u5230\u4e86Shockley-Queisser\uff08S-Q\uff09\u6781\u9650\u6548\u7387\u7684\u9650\u5236\u3002\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u662f\u7531\u591a\u4e2a\u5b50\u592a\u9633\u80fd\u7535\u6c60\u8fde\u63a5\u8d77\u6765\u7684\u4e00\u79cd\u7535\u6c60\u7ed3\u6784\uff0c\u901a\u8fc7\u5229\u7528\u5404\u5b50\u7535\u6c60\u5438\u6536\u5e26\u9699\u7684\u5dee\u5f02\u5b9e\u73b0\u66f4\u4e3a\u6709\u6548\u7684\u5149\u5b50\u5438\u6536\uff0c\u8fdb\u800c\u4f53\u73b0\u4e86\u7a81\u7834\u5355\u7ed3\u592a\u9633\u80fd\u7535\u6c60\u7684S-Q\u6781\u9650\u6548\u7387\u7684\u5de8\u5927\u6f5c\u529b\u3002\u8fd1\u51e0\u5e74\u6765\uff0c\u57fa\u4e8e\u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u7535\u6c60\u7684\u591a\u7ed3\u592a\u9633\u80fd\u7535\u6c60\uff0c\u5982\u53cc\u7ed3\u9499\u949b\u77ff\u3001\u9499\u949b\u77ff-\u7845\u3001\u9499\u949b\u77ff-\u94dc\u94df\u9553\u7852\u53e0\u5c42\u7535\u6c60\u7b49\u5df2\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u9499\u949b\u77ff-\u6709\u673a\u5149\u4f0f\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u76f8\u4f3c\u7684\u5236\u5907\u5de5\u827a\u548c\u5668\u4ef6\u7ed3\u6784\uff0c\u4e14\u4e24\u8005\u6b63\u4ea4\u7684\u6eb6\u5242\u4f53\u7cfb\u53ef\u4ee5\u6709\u6548\u907f\u514d\u540e\u7eed\u7684\u6eb6\u5242\u4fb5\u8680\uff0c\u4e5f\u9010\u6e10\u5438\u5f15\u4e86\u7814\u7a76\u8005\u7684\u5173\u6ce8\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u6731\u5b97\u9f99\u6559\u6388\u3001\u66a8\u5357\u5927\u5b66\u738b\u5b50\u9f99\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u91c7\u7528\u5bbd\u5e26\u9699\u9499\u949b\u77ff Cs<sub>0.1<\/sub>(FA<sub>0.6<\/sub>MA<sub>0.4<\/sub>)<sub>0.9<\/sub>Pb(I<sub>0.6<\/sub>Br<sub>0.4<\/sub>)<sub>3<\/sub>\uff081.74 eV\uff09\u548c\u7a84\u5e26\u9699\u6709\u673a\u6750\u6599PBDB-T:SN6IC-4F\uff081.30 eV\uff09\u5206\u522b\u4f5c\u4e3a\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684\u9876\u90e8\u548c\u5e95\u90e8\u5b50\u7535\u6c60\u7684\u6d3b\u6027\u5c42\uff0c\u5e76\u65cb\u6d82PMABr\u949d\u5316\u9499\u949b\u77ff\u5c42\u3002\u57fa\u4e8e\u949d\u5316\u540e\u7684\u9499\u949b\u77ff-\u6709\u673a\u53e0\u5c42\u5668\u4ef6\u5149\u7535\u8f6c\u6362\u6548\u7387\u9ad8\u8fbe15.13%\uff0c\u5f00\u8def\u7535\u538b\u4e3a1.85 V\uff1b\u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u6700\u9ad8\u4e3a13.61%\uff0c\u5f00\u8def\u7535\u538b\u4e3a1.80 V\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u4e5f\u642d\u5efa\u4e86\u57fa\u4e8e\u521a\u6027\u548c\u67d4\u6027\u9499\u949b\u77ff-\u6709\u673a\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u9a71\u52a8\u6c34\u5206\u89e3\u7cfb\u7edf\uff0c\u5149\u6c22\u8f6c\u6362\u6548\u7387\uff08STH\uff09\u5206\u522b\u53ef\u8fbe12.30%\u548c11.21%\uff0c\u4f53\u73b0\u4e86\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u6240\u83b7\u5f97\u7684\u9ad8\u5f00\u8def\u7535\u538b\u7684\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a<strong> \u201cHybrid Perovskite-Organic Flexible Tandem Solar Cell Enabling Highly Efficient Electrocatalysis Overall Water Splitting\u201d<\/strong> \u53d1\u8868\u5728<strong>Adv. Energy Mater.<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00 \u5bbd\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5236\u5907\u4e0e\u8868\u5f81<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198981\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-1.png\" alt=\"\" width=\"600\" height=\"319\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-1-300x160.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) PMABr\u949d\u5316\u7684\u5bbd\u5e26\u9699Cs<sub>0.1<\/sub>(FA<sub>0.6<\/sub>MA<sub>0.4<\/sub>)<sub>0.9<\/sub>Pb(I<sub>0.6<\/sub>Br<sub>0.4<\/sub>)<sub>3<\/sub>\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b<br \/>\n (b-c) \u949d\u5316\u524d\u540e\u9499\u949b\u77ff\u8584\u819c\u8868\u9762SEM\uff1b<br \/>\n (d) \u949d\u5316\u524d\u540e\u9499\u949b\u77ff\u8584\u819c\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<br \/>\n (e-f) \u949d\u5316\u524d\u540e\u9499\u949b\u77ff\u8584\u819c\u7684PL\u548cTRPL\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe\u4e8c \u5bbd\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u6d4b\u8bd5<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198982\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-2.png\" alt=\"\" width=\"600\" height=\"342\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-2-300x171.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) \u5bbd\u5e26\u9699\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u80fd\u7ea7\u793a\u610f\u56fe\uff1b<br \/>\n (b) \u949d\u5316\u524d\u540e\u9499\u949b\u77ff\u7535\u6c60\u7684\u6700\u4f73J-V\u6027\u80fd\u66f2\u7ebf\uff1b<br \/>\n (c) \u949d\u5316\u524d\u540e\u9499\u949b\u77ff\u7535\u6c60\u7684EQE\u5149\u8c31\uff1b<br \/>\n (d) \u9499\u949b\u77ff\u7535\u6c60\u7684\u7a33\u6001\u5149\u7535\u6d41\u8f93\u51fa\u66f2\u7ebf\uff1b<br \/>\n (e) \u949d\u5316\u524d\u540e\u9499\u949b\u77ff\u7535\u6c60\u5f00\u8def\u7535\u538b\u7edf\u8ba1\u5206\u5e03\u56fe\uff1b<br \/>\n (f) \u5668\u4ef6\u5f00\u8def\u7535\u538b\u968f\u5149\u5f3a\u53d8\u5316\u56fe\u3002<\/p>\n<p><strong>\u56fe\u4e09 \u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u6d4b\u8bd5<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198983\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-3.png\" alt=\"\" width=\"600\" height=\"408\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-3-300x204.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) \u9499\u949b\u77ff-\u6709\u673a\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684\u80fd\u7ea7\u793a\u610f\u56fe\uff1b <br \/>\n (b) \u5bbd\u5e26\u9699\u9499\u949b\u77ff\u9876\u90e8\u7535\u6c60\u3001\u7a84\u5e26\u9699\u6709\u673a\u5e95\u90e8\u7535\u6c60\u548c\u53e0\u5c42\u7535\u6c60\u7684J-V\u6027\u80fd\u66f2\u7ebf\uff1b<br \/>\n (c) \u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684EQE\u5149\u8c31\uff1b<br \/>\n (d) \u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a33\u6001\u5149\u7535\u6d41\u8f93\u51fa\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe\u56db \u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u9a71\u52a8\u6c34\u5206\u89e3<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198984\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-4.png\" alt=\"\" width=\"600\" height=\"482\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-4-300x241.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) NiFe\/\u78b3\u7eb3\u7c73\u7ba1\u6790\u6c27\u50ac\u5316\u7684J-V\u66f2\u7ebf\uff1b <br \/>\n (b) \u5546\u752820% Pt\/C\u6790\u6c22\u50ac\u5316\u7684J-V\u66f2\u7ebf\uff1b<br \/>\n (c) \u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u548c\u7528\u4e8e\u53cc\u7535\u6781\u6c34\u5206\u89e3\u4f53\u7cfb\u4e0bNiFe LDH\u7535\u6781\u7684J-V\u66f2\u7ebf\uff1b<br \/>\n (d) \u6c34\u5206\u89e3\u5668\u4ef6\u7684\u7535\u6d41\u5bc6\u5ea6\u968f\u65f6\u95f4\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe\u4e94 \u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u6d4b\u8bd5<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-198985\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-5.png\" alt=\"\" width=\"600\" height=\"253\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/03\/Figure-5-300x127.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n (a) \u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u548c\u7528\u4e8e\u53cc\u7535\u6781\u6c34\u5206\u89e3\u4f53\u7cfb\u4e0bNiFe LDH\u7535\u6781\u7684J-V\u66f2\u7ebf\uff1b<br \/>\n (c) \u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u7684EQE\u5149\u8c31\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u4f7f\u7528PMABr\u949d\u5316\u5bbd\u5e26\u9699\u9499\u949b\u77ff\u8584\u819c\uff0c\u5236\u5907\u83b7\u5f97\u7684\u9499\u949b\u77ff\u7535\u6c60\u5f00\u8def\u7535\u538b\u9ad8\u8fbe1.22 V\uff0c\u57fa\u4e8e\u949d\u5316\u540e\u7684\u9499\u949b\u77ff-\u6709\u673a\u53e0\u5c42\u521a\u6027\u548c\u67d4\u6027\u5668\u4ef6\u5149\u7535\u8f6c\u6362\u6548\u7387\u5206\u522b\u9ad8\u8fbe15.13%\u548c13.61%\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u4f5c\u8005\u5c06\u521a\u6027\u548c\u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u5e94\u7528\u5230\u592a\u9633\u80fd\u5236\u6c22\u7cfb\u7edf\u4e2d\uff0c\u83b7\u5f97\u7684\u5149\u6c22\u8f6c\u6362\u6548\u7387\u5206\u522b\u4e3a12.30%\u548c11.21%\u3002\u8be5\u7814\u7a76\u4e3a\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u9a71\u52a8\u7684\u6c34\u5206\u89e3\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\uff0c\u4e5f\u8bc1\u660e\u4e86\u9499\u949b\u77ff-\u6709\u673a\u7ed3\u6784\u5728\u67d4\u6027\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u4e0a\u7684\u72ec\u7279\u4f18\u52bf\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/aenm.202000361\" target=\"_blank\" rel=\"noopener\">Hybrid Perovskite\u2010Organic Flexible Tandem Solar Cell Enabling Highly Efficient Electrocatalysis Overall Water Splitting<\/a><\/strong>\uff08Adv. Energy Mater. 2020, DOI: 10.1002\/aenm.202000361\uff09<\/p>\n<p>\u672c\u6587\u7531\u565c\u565c\u7f16\u8bd1\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u6709\u673a-\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u9ad8\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u53ca\u7b80\u5355\u5ec9\u4ef7\u7684\u5236\u5907\u5de5\u827a\uff0c\u5728\u5149\u4f0f\u9886\u57df\u6380\u8d77\u4e86\u65b0\u7684\u7814\u7a76\u70ed\u6f6e\u3002\u7ecf\u8fc7\u8fd1\u5341\u5e74\u7684\u7814\u7a76\u53d1\u5c55\uff0c\u5355\u7ed3\uff08single-jun&#8230;<\/p>\n","protected":false},"author":9696,"featured_media":198985,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[4346,244],"class_list":["post-198980","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-4346","tag-gaitaikuang"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/198980"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/9696"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=198980"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/198980\/revisions"}],"predecessor-version":[{"id":199333,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/198980\/revisions\/199333"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/198985"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=198980"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=198980"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=198980"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}