{"id":198329,"date":"2020-04-02T06:53:25","date_gmt":"2020-04-01T22:53:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=198329"},"modified":"2020-04-01T20:53:46","modified_gmt":"2020-04-01T12:53:46","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e8%bf%87%e7%a8%8b%e6%89%80%e5%bc%a0%e9%94%81%e6%b1%9f%e9%99%a2%e5%a3%ab%e5%9b%a2%e9%98%9fadv-mater-%ef%bc%9a%e4%b8%80%e7%a7%8d%e7%94%a8%e4%ba%8e%e5%9b%ba%e6%80%81%e9%94%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=198329","title":{"rendered":"\u4e2d\u79d1\u9662\u8fc7\u7a0b\u6240\u5f20\u9501\u6c5f\u9662\u58eb\u56e2\u961fAdv. Mater.\uff1a\u4e00\u79cd\u7528\u4e8e\u56fa\u6001\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u67d4\u6027\u9676\u74f7\/\u805a\u5408\u7269\u6df7\u5408\u56fa\u4f53\u7535\u89e3\u8d28"},"content":{"rendered":"

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u8fc7\u7a0b\u5de5\u7a0b\u7814\u7a76\u6240\u5f20\u9501\u6c5f\u9662\u58eb<\/b><\/strong>\u548c\u5f20\u5170<\/b><\/strong>\u8001\u5e08<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u53d7H\u952e\u548cLi\u952e\u4e4b\u95f4\u76f8\u4f3c\u6027\u7684\u542f\u53d1\uff0c\u4e00\u79cd\u5546\u4e1a\u5316\u7684\u7845\u70f7\u5076\u8054\u5242(3-\u6c2f\u4e19\u57fa)\u4e09\u7532\u6c27\u57fa\u7845\u70f7\uff08CTMS\uff09\u4f5c\u4e3a\u52a9\u5242\uff0c\u5b9e\u73b0LGPS\u4e86\u4e0e\u805a\u4e59\u4e8c\u9187\uff08PEG\uff09\u4e4b\u95f4\u7684\u5316\u5b66\u952e\u5408\uff0c\u7136\u540e\u6dfb\u52a0PEO\u548c\u53cc(\u4e09\u6c1f\u7532\u78fa\u9170\u57fa)\u9170\u4e9a\u80fa\u9502\uff08LiTFSI\uff09\u4ee5\u5f97\u5230\u5747\u8d28\u7684HSE\u819c\u3002\u91c7\u7528PEG\u8003\u8651\u4e86\u4e09\u4e2a\u539f\u56e0\u3002\u9996\u5148\uff0c\u8be5\u6750\u6599\u63d0\u4f9b\u4e86\u66f4\u591a\u7684-OH\u57fa\u56e2\uff0c\u4ee5\u4fc3\u8fdb\u4e0eCTMS\u7684\u5316\u5b66\u7ed3\u5408\uff1b\u5176\u6b21\uff0c\u5b83\u4e0ePEO\u5177\u6709\u76f8\u540c\u7684\u5206\u5b50\u7ed3\u6784\uff0c\u56e0\u6b64PEG\u4e0ePEO\u4e4b\u95f4\u4e0d\u5b58\u5728\u76f8\u5206\u79bb\uff1b\u540c\u6837\u91cd\u8981\u7684\u662f\uff0c\u4e00\u5b9a\u5206\u5b50\u91cf\u8303\u56f4\u5185\u7684PEG\u53ef\u4ee5\u63d0\u4f9b\u6bd4PEO\u66f4\u5feb\u7684Li+<\/sup>\u8fd0\u8f93\u901f\u5ea6\u548c\u66f4\u9ad8\u7684tLi+<\/sub>\u3002\u9676\u74f7\u4e0e\u805a\u5408\u7269\u5728HSE\u819c\u4e2d\u901a\u8fc7\u5f3a\u5316\u5b66\u952e\u7ed3\u5408\uff0c\u4e3a\u9502\u79bb\u5b50\u7684\u8fd0\u8f93\u63d0\u4f9b\u4e86\u4e00\u6761\u9ad8\u901f\u901a\u9053\u3002\u4f18\u5316\u540e\u7684HSE\u819c\u7535\u5bfc\u7387\u9ad8\u3001\u6d3b\u5316\u80fd\u4f4e\u3001Li+<\/sup>\u8fc1\u79fb\u6570\u9ad8\u3001\u6291\u5236\u4e86\u9502\u679d\u6676\u7684\u751f\u957f\u3002HSE\u819c\u8868\u73b0\u4e86\u51fa\u8272\u7684\u73af\u5883\u7a33\u5b9a\u6027\uff0c\u8fd9\u4f7f\u5176\u53ef\u4ee5\u5728\u7a7a\u6c14\u4e2d\u8fdb\u884c\u5904\u7406\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/b><\/strong>A Flexible Ceramic\/Polymer Hybrid Solid Electrolyte for Solid-State Lithium Metal Batteries<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Adv. Mater.<\/b><\/strong>\u4e0a\u3002<\/p>\n

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C\uff09LFP|PEO\/PEG-3LGPS|Li\u7535\u6c60\u5206\u522b\u57280.05 C\u30010.1 C\u548c0.5 C\u65f6\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

D\uff09LFP|PEO\/PEG-3LGPS|Li\u7535\u6c6060\u2103\u4e0b\u5206\u522b\u57280.05 C\uff0c0.1 C\u548c0.5 C\u65f6\u7684\u5145\u653e\u7535\u7279\u5f81\u66f2\u7ebf\u3002<\/p>\n

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\u603b\u4e4b\uff0c\u501f\u52a9\u4e8eCTMS\uff0c\u901a\u8fc7\u539f\u4f4d\u5076\u8054\u53cd\u5e94\u5236\u5907\u4e86\u5177\u6709\u4e0d\u540cLGPS\u542b\u91cf\u7684\u67d4\u6027\u9676\u74f7\/\u805a\u5408\u7269HSE\u819c\u3002\u53d1\u73b0\u5316\u5b66\u952e\u5408\u5f62\u6210\u7684\u72ec\u7279\u7684HSE\u819c\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u548cLi+<\/sup>\u8fc1\u79fb\u6570\u3002\u5728\u8fd9\u4e9bHSE\u4e2d\uff0cPEO\/PEG-3LGPS\u7684\u7535\u5bfc\u7387\u6700\u9ad8\uff08\u5ba4\u6e29\u4e0b\u4e3a9.83\u00d710-4<\/sup>\u00a0S cm-1<\/sup>\uff0c\u572850\u2103\u65f6\u4e3a1.72\u00d710-3<\/sup>\u00a0S cm-1<\/sup>\uff09\uff0c\u6d3b\u5316\u80fd\u6700\u4f4e\uff080.26 eV\uff09\uff0cLi+<\/sup>\u8fc1\u79fb\u7387\u6570\u503c\u4e5f\u8f83\u9ad8\uff080.68\uff09\u3002\u800c\u9502\u679d\u6676\u7684\u751f\u957f\u53d7\u5230\u6291\u5236\uff0c\u8fd9\u5728\u9502\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u4e2d\u5f97\u5230\u4e86\u8bc1\u660e\uff0c\u5728\u5ba4\u6e29\u4e0b\u7ecf\u8fc76700 h\u6ca1\u6709\u4efb\u4f55\u4e2d\u65ad\u3002\u6700\u540e\uff0cPEO\/PEG-3LGPS HSE\u7684\u5168\u56fa\u6001LTO|Li\u7535\u6c60\u548cLFP|Li\u7535\u6c60\u8868\u73b0\u51fa\u51fa\u8272\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5177\u6709\u9ad8\u5bb9\u91cf\u4fdd\u6301\u80fd\u529b\u548c\u7a33\u5b9a\u7684\u5e93\u4ed1\u6548\u7387\u3002\u56e2\u961f\u7684\u5de5\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u9896\u53ef\u9760\u7684\u5236\u5907\u9676\u74f7\/\u805a\u5408\u7269HSE\u819c\u7684\u65b9\u6cd5\uff0c\u53ef\u7528\u4e8e\u5168\u56fa\u6001\u9502\u7535\u6c60\uff0c\u4e5f\u53ef\u7528\u4e8e\u5176\u4ed6\u9676\u74f7\u548c\u805a\u5408\u7269\u7cfb\u7edf\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>A Flexible Ceramic\/Polymer Hybrid Solid Electrolyte for Solid<\/u>–<\/u>State Lithium Metal Batteries<\/u><\/a>\uff08Adv. Mater.\uff0c 2020\uff0cDOI:10.1002\/adma.202000399\uff09<\/p>\n

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