{"id":198276,"date":"2020-03-18T06:29:19","date_gmt":"2020-03-17T22:29:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=198276"},"modified":"2020-03-17T21:59:34","modified_gmt":"2020-03-17T13:59:34","slug":"%e6%9a%a8%e5%8d%97%e5%a4%a7%e5%ad%a6%e8%8c%83%e5%bb%ba%e4%b8%9c%e6%9d%8e%e9%97%bb%e5%93%b2adv-energy-mater-%ef%bc%9a%e9%ab%98%e6%95%88%e7%a8%b3%e5%ae%9a1d3d%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=198276","title":{"rendered":"\u66a8\u5357\u5927\u5b66\u8303\u5efa\u4e1c&\u674e\u95fb\u54f2Adv. Energy Mater.\uff1a\u9ad8\u6548\u7a33\u5b9a1D@3D\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u5728\u77ed\u77ed\u5341\u591a\u5e74\u7684\u65f6\u95f4\u91cc\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u4ece3.8%\u98de\u901f\u63d0\u9ad8\u523025.2%[1]<\/sup>\uff0c\u7136\u800c\uff0c\u5b9e\u73b0\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u4ea7\u4e1a\u5316\u7684\u6700\u5927\u74f6\u9888\u662f\u5176\u7a33\u5b9a\u6027\u95ee\u9898\uff0c\u5c24\u5176\u662f\u5728\u7d2b\u5916\u5149\u3001\u6c34\u6c27\u7b49\u654f\u611f\u6761\u4ef6\u4e0b\u7684\u957f\u671f\u7a33\u5b9a\u6027[2,3]<\/sup>\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u66a8\u5357\u5927\u5b66\u4fe1\u606f\u5b66\u9662\u65b0\u80fd\u6e90\u6280\u672f\u7814\u7a76\u9662\u8303\u5efa\u4e1c&\u674e\u95fb\u54f2\u56e2\u961f\u7684\u8bba\u6587\u201cLattice-Matching Structurally-Stable 1D@3D Perovskites toward Highly Efficient and Stable Solar Cells\u201d\u5728Advanced Energy Materials\uff08AEM\uff09\u6742\u5fd7\u4e0a\u53d1\u8868\u3002\u7855\u58eb\u751f\u5218\u9e4f\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u8303\u5efa\u4e1c\u7814\u7a76\u5458\u548c\u674e\u95fb\u54f2\u526f\u7814\u7a76\u5458\u4e3a\u6587\u7ae0\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u8be5\u7814\u7a76\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u00a0(51872126\u300151672111\u300151802120)\uff0c\u5e7f\u4e1c\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u5b66\u8005\u57fa\u91d1(2019B151502030)\uff0c\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1(2018030310181)\uff0c\u4e2d\u592e\u9ad8\u6821\u57fa\u7840\u7814\u7a76\u7ecf\u8d39(21617341\uff0c21619406)\uff0c\u73e0\u6c5f\u201c\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u201d\u9879\u76ee(2017GC010424)\u7684\u5171\u540c\u8d44\u52a9\u3002\u6b64\u5916\uff0c\u611f\u8c22\u672c\u79d1\u751f\u51bc\u4e1a\u94ed\u540c\u5b66\u5e7f\u4e1c\u7701\u5927\u5b66\u751f\u79d1\u6280\u521b\u65b0\u80fd\u529b\u57f9\u517b\u4e13\u9879\u8d44\u91d1\u8d44\u52a9(pdjh2019a0055)\u3002<\/p>\n

\u3010\u672c\u6587\u4eae\u70b9\u3011<\/b><\/strong><\/p>\n

\u672c\u8bba\u6587\u8bbe\u8ba1\u4e86\u57fa\u4e8ePbI2<\/sub>-bipyridine (II) \u6750\u6599\u76841D@3D\u7ef4\u5ea6\u6742\u5316\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\uff0c1D@3D\u9499\u949b\u77ff\u5f02\u8d28\u7ed3\u754c\u9762\u6676\u683c\u7684\u9ad8\u6548\u5339\u914d\u4e0d\u4ec5\u589e\u5f3a\u4e86\u8f7d\u6d41\u5b50\u8f93\u8fd0\u800c\u4e14\u6291\u5236\u4e86\u8d1f\u9762\u79bb\u5b50\u8fc1\u79fb\uff0c\u8fdb\u800c\u5b9e\u73b0\u4e8621.18%\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u548c\u5149\u6c27\u3001\u6c34-\u7535\u573a\u7b49\u590d\u5408\u654f\u611f\u6761\u4ef6\u4e0b\u7684\u957f\u671f\u7a33\u5b9a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1 1D@3D\u9499\u949b\u77ff\u8584\u819c\u7684\u6210\u819c\u52a8\u529b\u5b66\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

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\uff08b\uff09\u6210\u819c\u8fc7\u7a0b\u4e2d\uff0c\u7531BPy-PbI2<\/sub>\u00a0(I)\u00a0\u5230BPy-PbI2<\/sub>\u00a0(II)\u00a0\u7684\u5f02\u6784\u5316\u8fc7\u7a0b\uff1b<\/p>\n

\uff08c\uff09\u548c\u56fe\uff08d\uff09\u5206\u522b\u4e3aBPy-PbI2<\/sub>\u00a0(I)\u00a0\u548cBPy-PbI2<\/sub>\u00a0(II)\u00a0\u6750\u6599\u7684XRD\u8c31\u56fe\u3002<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

\u901a\u8fc7\u7814\u7a761D@3D \u548c3D\u9499\u949b\u77ff\u5728\u7535\u573a\u548c\u5fae\u91cf\u6c34\u7684\u4f5c\u7528\u4e0b\u8584\u819c\u8868\u9762\u7684\u53d8\u5316\uff0c\u53ef\u4ee5\u53d1\u73b01D@3D\u9499\u949b\u77ff\u8584\u819c\u5728\u7535\u573a\u548c\u5fae\u91cf\u6c34\u7684\u6761\u4ef6\u4e0b\u5206\u89e3\u7684\u901f\u7387\u51cf\u6162\uff0c\u8868\u660e1D@3D\u9499\u949b\u77ff\u5bf9\u7535\u573a\u548c\u5fae\u91cf\u6c34\u7684\u6761\u4ef6\u6709\u8f83\u597d\u7684\u5c4f\u853d\u4f5c\u7528\u3002<\/p>\n

\uff08a\uff09\u539f\u4f4d\u4f4e\u771f\u7a7aSEM\u8868\u5f81\u539f\u7406\u56fe\uff1b<\/p>\n

\uff08b\uff09\u548c\u56fe\uff08c\uff093D\u548c1D@3D\u9499\u949b\u77ff\u8584\u819c\u7684\u754c\u9762SEM\u56fe\u548cEDS\u7ebf\u626b\u63cf\u8c31\u3002<\/p>\n

\u56fe4 \u5668\u4ef6\u6027\u80fd\u7684\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\uff08a\uff093D\u548c1D@3D\uff081mg\/mL\uff09\u9499\u949b\u77ff\u6750\u6599\u7684\u80fd\u5e26\u4f4d\u7f6e\u793a\u610f\u56fe\uff1b<\/p>\n

\u56fe\uff08b\uff091D@3D\uff081mg\/mL\uff09\u9499\u949b\u77ff\u5668\u4ef6\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

\u56fe\uff08c\uff091D@3D\uff081mg\/mL\uff09\u9499\u949b\u77ff\u5668\u4ef6\u7684EQE\u66f2\u7ebf\uff1b<\/p>\n

\u56fe\uff08d\uff091D@3D\uff081mg\/mL\uff09\u9499\u949b\u77ff\u5668\u4ef6\u7684SPO\u66f2\u7ebf\u548c\u6548\u7387\u5206\u5e03\u7edf\u8ba1\u56fe\uff1b<\/p>\n

\u56fe\uff08e\uff093D\u548c1D@3D\u9499\u949b\u77ff\u5728\u5149\u6c27\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\u56fe\uff08f\uff093D\u548c1D@3D\u9499\u949b\u77ff\u5728\u5149\u6c27\u6c34\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u3010\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

\u672c\u8bba\u6587\u4ee5\u9499\u949b\u77ff\u6750\u6599\u672c\u8eab\u4f5c\u4e3a\u7814\u7a76\u91cd\u70b9\uff0c\u63d0\u51fa\u4e86\u7ef4\u5ea6\u6742\u5316\u9499\u949b\u77ff\u7ed3\u6784\uff0c\u63a2\u7a76\u4e86\u5149\u3001\u6c27\u3001\u6c34\u3001\u6e29\u5ea6\u548c\u7535\u573a\u7b49\u654f\u611f\u6761\u4ef6\u4e0b\u9499\u949b\u77ff\u7684\u5206\u89e3\u8fc7\u7a0b\u3002\u901a\u8fc7\u8bbe\u8ba1\u5e76\u751f\u957f\u4e86\u5177\u67091D\u7ed3\u6784\u7684BPy-PbI2<\/sub>\u9499\u949b\u77ff\u6750\u6599\uff0c\u5e76\u6210\u529f\u8bf1\u5bfc\u751f\u957f\u4e861D@3D\u9499\u949b\u77ff\u8584\u819c\uff0c1D\u9499\u949b\u77ff\u6240\u7279\u6709\u7684\u201c\u8f6f\u6676\u683c\u201d\u4e0e\u4f20\u7edf3D\u9499\u949b\u77ff\u5b9e\u73b0\u4e86\u826f\u597d\u7684\u754c\u9762\u6676\u683c\u5339\u914d\u3002\u57fa\u4e8e\u9499\u949b\u77ff\u7684\u7ef4\u5ea6\u6742\u5316\u7ed3\u6784\uff0c1D@3D\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u5206\u522b\u5728\u5149\/\u6c27\u548c\u5149\/\u6c27\/\u6c34\u6761\u4ef6\u4e0b\u8001\u5316150\u5c0f\u65f6\u548c75\u5c0f\u65f6\uff0c1D@3D\u9499\u949b\u77ff\u592a\u9633\u5668\u4ef6\u7684\u6548\u7387\u4fdd\u6301\u7387\u5747\u8d85\u8fc790%\uff0c\u800c\u4f20\u7edf3D\u9499\u949b\u77ff\u5668\u4ef6\u7684\u6548\u7387\u4fdd\u6301\u7387\u4ec5\u4e3a40%\u548c5%\uff0c\u7ef4\u5ea6\u6742\u5316\u9499\u949b\u77ff\u7535\u6c60\u8868\u73b0\u51fa\u66f4\u4f18\u5f02\u7684\u73af\u5883\u7a33\u5b9a\u6027\u3002\u672c\u7814\u7a76\u4e3a\u5236\u5907\u9ad8\u7a33\u5b9a\u6027\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u63d0\u4f9b\u4e86\u91cd\u8981\u601d\u8def\u548c\u7406\u8bba\u57fa\u7840\uff0c\u79ef\u6781\u63a8\u52a8\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u4ea7\u4e1a\u5316\u8fdb\u7a0b\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u7814\u7a76\u8fdb\u5c55\uff1a\u672c\u8bfe\u9898\u7ec4\u957f\u671f\u81f4\u529b\u4e8e\u65b0\u578b\u9499\u949b\u77ff\u6750\u6599\u53ca\u5176\u9ad8\u6027\u80fd\u5149\u7535\u5668\u4ef6\u7684\u7814\u7a76\uff0c\u8fd1\u4e24\u5e74\u8bfe\u9898\u7ec4\u5728\u9499\u949b\u77ff\u7ef4\u5ea6\u8c03\u63a7\u548c\u6742\u5316\u3001\u5168\u65e0\u673a\u9499\u949b\u77ff\u53ca\u57fa\u4e8e\u9499\u949b\u77ff\u5355\u6676\u5149\u7535\u63a2\u6d4b\u5668\u65b9\u9762\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u8fdb\u5c55\uff1a\uff081\uff09\u5728\u6709\u673a\u65e0\u673a\u6742\u5316\u7535\u6c60\u65b9\u9762\uff1a\u6211\u4eec\u57283D\u9499\u949b\u77ff\u4e2d\u63ba\u6742\u4e59\u9170\u4e19\u916e\u9553\u5b9e\u73b0\u4e86\u201c\u6838\u58f3\u201d\u7ed3\u6784\uff0c\u5668\u4ef6\u5728\u76f8\u5bf9\u6e7f\u5ea6\u4e3a50%\u6761\u4ef6\u4e0b\u8001\u5316800 h\uff0c\u6548\u7387\u4e3a\u521d\u59cb\u503c\u768485%\uff08Energy Environ. Sci.<\/i><\/b><\/em><\/strong>\u00a02018, 11, 286\uff09\u3002\uff082\uff09\u5229\u7528\u7ef4\u5ea6\u8c03\u63a7\uff0c\u6211\u4eec\u5c061-(2-\u5421\u5576\u57fa)-1H-\u5421\u5511\uff08PZPY\uff09\u4f5c\u4e3aA\u4f4d\u57fa\u56e2\uff0c1D\u9499\u949b\u77ff\u6750\u6599\u4e0e3D\u9499\u949b\u77ff\u6750\u6599\u539f\u4f4d\u751f\u957f\u5b9e\u73b01D@3D\u6742\u5316\u9499\u949b\u77ff\uff0c\u5668\u4ef6\u5728\u76f8\u5bf9\u6e7f\u5ea655%\uff0c\u73af\u5883\u6e29\u5ea685\u6761\u4ef6\u4e0b\u7ecf\u8fc75\u4e2a\u8001\u5316\u5faa\u73af\u540e\u6548\u7387\u4fdd\u6301\u7387\u572890%\u4ee5\u4e0a\uff0c\u5668\u4ef6\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u70ed\u529b\u5b66\u81ea\u4fee\u590d\u6027\u80fd\uff08Adv. Energy Mater.<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/em>2018, 8, 1703421\uff09\u3002\uff083\uff09\u5728\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u65b9\u9762\uff1a\u8bfe\u9898\u7ec4\u5f00\u53d1\u4e86\u57fa\u4e8eZnO@C60\u590d\u5408\u7ed3\u6784\u7684\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u589e\u5f3a\u4e86\u7535\u8377\u63d0\u53d6\u6548\u7387\u00a0(J. Am. Chem. Soc.<\/i><\/b><\/em><\/strong>, 2018, 140, 3825)\u3002\u6b64\u5916\uff0c\u6211\u4eec\u5c06InCl3<\/sub>\u5f15\u5165\u65e0\u673aCsPbI2<\/sub>Br\u9499\u949b\u77ff\u4e2d\uff0c\u901a\u8fc7In3+<\/sup>\u548cCl–<\/sup>\u5171\u63ba\u6742\u83b7\u5f97\u4e86\u7a33\u5b9a\u7684\u03b1\u76f8\u9499\u949b\u77ff\u8584\u819c\uff0c\u901a\u8fc7\u8f90\u5c04\u52a0\u70ed\u65b9\u6cd5\u83b7\u5f9713.74%\u7684\u5668\u4ef6\u8f6c\u6362\u6548\u7387\u3002\uff08Adv. Energy Mater<\/i><\/b><\/em><\/strong>.<\/b><\/strong>\u00a02018, 1803572\uff09\u3002\uff084\uff09\u5728\u9499\u949b\u77ff\u5149\u7535\u63a2\u6d4b\u5668\u65b9\u9762\uff1a\u6211\u4eec\u901a\u8fc7\u4f7f\u7528PEABr\u539f\u4f4d\u8bf1\u5bfc\u751f\u957f\u4e86Cs2<\/sub>AgBiBr6<\/sub>\u5355\u6676\u6750\u6599\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u6676\u4f53B\u4f4d\u91d1\u5c5e\u7684\u6709\u5e8f\u6027\uff0c\u6709\u6548\u964d\u4f4e\u4e86\u5355\u6676\u7684\u7f3a\u9677\u6001\u5bc6\u5ea6\u548c\u6fc0\u5b50\u81ea\u9677\u57df\u6548\u5e94\uff0c\u5668\u4ef6\u7684\u54cd\u5e94\u65f6\u95f4\u75313190 \u00b5s \u7f29\u77ed\u523013 \u00b5s\uff0cX\u5c04\u7ebf\u63a2\u6d4b\u7075\u654f\u5ea6\u63d0\u9ad8\u5230\u4e86288.8 \u00b5C Gyair<\/sub>\u22121<\/sup>\u00a0cm\u22122<\/sup>\u00a0\uff08\u7535\u573a\u5f3a\u5ea622.7 V mm\u22121<\/sup>\uff09\uff0c\u8fbe\u5230\u4e16\u754c\u9886\u5148\u6c34\u5e73\u3002\uff08Adv. Funct. Mater. <\/i><\/b><\/em><\/strong>2019,1900234\uff09\u3002<\/p>\n

\u3010\u53c2\u8003\u6587\u732e\u3011<\/b><\/strong><\/p>\n

[1] \u00a0https:\/\/www.nrel.gov\/pv\/assets\/images\/efficiency-chart.png.<\/p>\n

[2] \u00a0Aristidou, N.; Sanchez-Molina, I.; Chotchuangchutchaval, T.; Brown, M.; Martinez, L.; Rath, T.; Haque, S. A., The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers. Angew Chem Int Ed Engl <\/i><\/em>2015, 54<\/i><\/em>\u00a0(28), 8208-12.<\/p>\n

[3] \u00a0Lira-Cant\u00fa, M., Perovskite solar cells: Stability lies at interfaces. Nature Energy <\/i><\/em>2017,<\/b><\/strong>\u00a02<\/i><\/em>\u00a0(7).<\/p>\n

Lattice\u2010Matching Structurally\u2010Stable 1D@3D Perovskites toward Highly Efficient and Stable Solar Cells<\/p>\n

https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/aenm.201903654<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

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