{"id":198192,"date":"2020-03-16T06:43:53","date_gmt":"2020-03-15T22:43:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=198192"},"modified":"2020-03-15T21:54:05","modified_gmt":"2020-03-15T13:54:05","slug":"%e6%b5%8e%e5%8d%97%e5%a4%a7%e5%ad%a6-nano-energy%ef%bc%9a%e5%8e%8b%e7%94%b5%e7%94%b5%e5%ad%90%e5%ad%a6%e6%95%88%e5%ba%94%e5%9c%a8%e5%85%89%e5%82%ac%e5%8c%96%e9%a2%86%e5%9f%9f%e7%9a%84%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=198192","title":{"rendered":"\u6d4e\u5357\u5927\u5b66 Nano Energy\uff1a\u538b\u7535\u7535\u5b50\u5b66\u6548\u5e94\u5728\u5149\u50ac\u5316\u9886\u57df\u7684\u5e94\u7528\u65b0\u7b56\u7565"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u8fd1\u51e0\u5341\u5e74\u6765\uff0c\u7531\u4e8e\u5149\u50ac\u5316\u6280\u672f\u5177\u6709\u76f4\u63a5\u5229\u7528\u592a\u9633\u80fd\u800c\u65e0\u4e8c\u6b21\u6c61\u67d3\u7684\u6f5c\u529b\uff0c\u56e0\u6b64\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4f46\u662f\uff0c\u57fa\u4e8e\u5149\u50ac\u5316\u7684\u6c34\u5904\u7406\u548c\u6790\u6c22\u5de5\u4e1a\u5e94\u7528\u4ecd\u7136\u5b58\u5728\u8bb8\u591a\u56f0\u96be\u3002\u4e00\u4e2a\u5173\u952e\u95ee\u9898\u662f\u5149\u751f\u8f7d\u6d41\u5b50\u5bb9\u6613\u590d\u5408\uff0c\u5bfc\u81f4\u5149\u50ac\u5316\u6548\u7387\u4f4e\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u4e3b\u8981\u901a\u8fc7\u6784\u5efa\u5f02\u8d28\u7ed3\u548c\u5185\u5efa\u7535\u573a\u7684\u65b9\u5f0f\u4fc3\u8fdb\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u5e76\u6291\u5236\u5176\u590d\u5408\u3002\u7136\u800c\uff0c\u5177\u6709\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u7c89\u4f53\u50ac\u5316\u5242\u56de\u6536\u56f0\u96be\uff0c\u56de\u6536\u4fbf\u6377\u7684\u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u5f80\u5f80\u50ac\u5316\u6d3b\u6027\u4e0d\u9ad8\u3002\u56e0\u6b64\uff0c\u50ac\u5316\u5242\u7684\u5b9e\u9645\u5e94\u7528\u4f9d\u65e7\u9762\u4e34\u5de8\u5927\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u6709\u9274\u4e8e\u6b64\uff0c\u6d4e\u5357\u5927\u5b66\u524d\u6cbf\u4ea4\u53c9\u79d1\u5b66\u7814\u7a76\u9662\u738b\u91d1\u521a\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5218\u5b8f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u538b\u7535\u7535\u5b50\u5b66\u6548\u5e94\uff0c\u901a\u8fc7\u6c34\u6d41\u51b2\u51fb\u6539\u53d8\u805a\u504f\u6c1f\u4e59\u70ef\uff08PVDF\uff09\u81ea\u53d1\u6781\u5316\u7535\u573a\u7535\u52bf\u4fc3\u8fdb\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u7684\u8d1f\u8f7d\u578b\u5149\u50ac\u5316\u5242\u7684\u5e94\u7528\u7b56\u7565\u3002\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u4eba\u4eec\u666e\u904d\u8ba4\u4e3a\u672a\u7ecf\u4eb2\u6c34\u5904\u7406\u7684\u758f\u6c34\u6027\u9ad8\u5206\u5b50\u805a\u5408\u7269\u8868\u9762\u751f\u957f\u534a\u5bfc\u4f53\u6c27\u5316\u7269\u662f\u5f88\u56f0\u96be\u7684\uff0c\u7136\u800c\u4ed6\u4eec\u5229\u7528\u91d1\u5c5e\u79bb\u5b50\u4e0eF\u7684\u914d\u4f4d\u4f5c\u7528\uff0c\u6210\u529f\u5728\u758f\u6c34\u6027\u7684PVDF\u819c\u8868\u9762\u8d1f\u8f7d\u4e86Sn3<\/sub>O4<\/sub>\u7eb3\u7c73\u5149\u50ac\u5316\u5242\uff0c\u5c06PVDF\u81ea\u53d1\u6781\u5316\u7535\u573a\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\u7684\u5185\u5efa\u7535\u573a\u6765\u4fc3\u8fdb\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\u3002\u901a\u8fc7\u5c06Sn3<\/sub>O4<\/sub>\/PVDF\u5149\u50ac\u5316\u5242\u7f6e\u4e8e\u6c34\u6d41\u51b2\u51fb\u4e0b\uff0cPVDF\u7684\u538b\u7535\u6548\u5e94\u4f7f\u5185\u5efa\u7535\u573a\u7535\u52bf\u5904\u4e8e\u4e0d\u65ad\u53d8\u5316\u4e2d\uff0c\u5b9e\u73b0\u4e86\u6bd4\u5355\u4e00Sn3<\/sub>O4<\/sub>\u5149\u50ac\u5316\u5242\u66f4\u9ad8\u7684\u6709\u673a\u6c61\u67d3\u7269\u964d\u89e3\u6548\u7387\u3002Sn3<\/sub>O4<\/sub>\/PVDF\u5149\u50ac\u5316\u5242\u65e2\u89e3\u51b3\u4e86\u7c89\u4f53\u50ac\u5316\u5242\u56de\u6536\u56f0\u96be\u7684\u95ee\u9898\uff0c\u53c8\u5b9e\u73b0\u4e86\u8f83\u9ad8\u7684\u6709\u673a\u6c61\u67d3\u7269\u964d\u89e3\u6548\u7387\uff0c\u4e3a\u5149\u50ac\u5316\u5242\u7684\u5b9e\u9645\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cAssembling Sn3<\/sub>O4<\/sub> nanostructures on a hydrophobic PVDF film through metal-F coordination to construct a piezotronics effect-enhanced Sn3<\/sub>O4<\/sub>\/PVDF hybrid photocatalyst\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aNano Energy<\/em><\/strong>\u4e0a\u3002\u6d4e\u5357\u5927\u5b66\u7855\u58eb\u7814\u7a76\u751f\u97e9\u6811\u4f1f\u3001\u9648\u94ce\u535a\u58eb\u4ee5\u53ca\u7855\u58eb\u7814\u7a76\u751f\u738b\u5efa\u4e3a\u672c\u6587\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1<\/p>\n

\"\"<\/p>\n

\uff08a, b\uff09PVDF\u819c\u7684\u62c9\u4f38\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\uff09PVDF\u819c\u62c9\u4f38\u5904\u7406\u524d\u540e\u7684XRD\u6570\u636e\uff1b<\/p>\n

\uff08d\uff09PVDF\u819c\u7684SEM\u56fe\uff1b<\/p>\n

\uff08e\uff09PVDF\u819c\u7684\u538b\u7535\u76f8\u4f4d\u548c\u632f\u5e45\u56fe\uff1b\u00a0<\/p>\n

\uff08f\uff09\u5728\u76f8\u540c\u6fc0\u53d1\u538b\u529b\u4e0b\u62c9\u4f38\u548c\u672a\u62c9\u4f38\u5904\u7406\u7684PVDF\u819c\u7684\u6fc0\u53d1\u54cd\u5e94\u4fe1\u53f7\u56fe\u3002<\/p>\n

\u56fe2<\/p>\n

\"\"<\/p>\n

\uff08a\uff09PVDF\u548cSn2+<\/sup>-PVDF\u7684\u62c9\u66fc\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08b\uff09PVDF\u548cSn2 +<\/sup>\u00a0-PVDF\u7684XPS\u5168\u8c31\u56fe\uff0cPVDF\u548cSn2 +<\/sup>\u00a0-PVDF\u00a0F1s\u7684XPS\u5149\u8c31\u56fe\uff0cPVDF\u548cSn2 +<\/sup>\u00a0-PVDF\u00a0C1s\u7684\u00a0XPS\u5149\u8c31\u56fe\uff0cSn3d \u7684XPS\u80fd\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff09PVDF\u819c\u8868\u9762Sn\u548cF\u5143\u7d20\u7684XPS\u5143\u7d20\u56fe\uff1b<\/p>\n

\uff08d\uff09Sn2 + <\/sup>-PVDF\u819c\u8868\u9762Sn\u548cF\u5143\u7d20\u7684XPS\u5143\u7d20\u56fe\u3002<\/p>\n

\u56fe3\u00a0Sn3<\/sub>O4<\/sub>\/PVDF\u7684\u751f\u957f\u673a\u7406\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u03b2\u76f8PVDF\u7684\u6784\u8c61\u793a\u610f\u56fe\uff1b\u00a0<\/p>\n

\uff08b\uff09F\u79bb\u5b50\u4e0e\u91d1\u5c5e\u79bb\u5b50\u4e4b\u95f4\u7684\u914d\u4f4d\u4f5c\u7528\u793a\u610f\u56fe\uff1b\u00a0<\/p>\n

\uff08c\uff09PVDF\u8868\u9762\u4e0aSn3<\/sub>O4<\/sub>\u7684\u751f\u957f\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d\uff09Sn3<\/sub>O4<\/sub>\/PVDF\u6df7\u5408\u50ac\u5316\u5242\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe4<\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09Sn3<\/sub>O4<\/sub>\/PVDF\u7684SEM\u56fe\u50cf;\u00a0<\/p>\n

\uff08c\uff09Sn3<\/sub>O4<\/sub>\u7684TEM\u56fe\u50cf;<\/p>\n

\uff08d\uff09Sn3<\/sub>O4<\/sub>\u7684HRTEM\u56fe\u50cf;<\/p>\n

\uff08e\uff09Sn3<\/sub>O4<\/sub>\u7684XRD\u56fe\u8c31;<\/p>\n

\uff08f\uff09PVDF\uff0cSn3<\/sub>O4<\/sub>\u548cSn3<\/sub>O4<\/sub>\/PVDF\u7684XRD\u5bf9\u6bd4\u56fe\u3002<\/p>\n

\u56fe5<\/p>\n

\"\"<\/p>\n

\uff08a\uff0cc\uff09\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u7684\u5149\u50ac\u5316\u964d\u89e3\u5b9e\u9a8c\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff0cd\uff09\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u7684\u5149\u50ac\u5316\u964d\u89e3\u5b9e\u9a8c\u7684\u7167\u7247\uff1b<\/p>\n

\uff08e\uff09\u7d2b\u5916\u5149\u4e0b\uff0c\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u4f7f\u7528\u4e0d\u540c\u7684\u5149\u50ac\u5316\u5242\u65f6\uff0cRh B\u7684\u964d\u89e3\u66f2\u7ebf\u4e3a\uff1a\uff08\u2160\uff09\u65e0\u5149\u50ac\u5316\u5242\uff08\u7eafRh B\u6eb6\u6db2\uff09\uff0c\u6c34\u6d41\u91cf\uff1a22 mL\/min\uff1b\uff08\u2161\uff09\u65e0\u5149\u50ac\u5316\u5242\uff08\u7eafRh B\u6eb6\u6db2\uff09\uff0c\u6c34\u6d41\u901f\uff1a480 mL\/min\uff1b\uff08\u2162\uff09Sn3<\/sub>O4<\/sub>\uff0c\u6c34\u6d41\u901f\uff1a480 mL\/min;\uff08\u2163\uff09Sn3<\/sub>O4<\/sub>\uff0c\u6c34\u6d41\u901f\uff1a22 mL\/min;\uff08\u2164\uff09Sn3<\/sub>O4<\/sub>\/PVDF\uff0c\u6c34\u6d41\u901f\uff1a22 mL\/min\uff1b\uff08\u2165\uff09Sn3<\/sub>O4<\/sub>\/PVDF\uff0c\u6c34\u6d41\u901f\uff1a480 mL\/min\uff1b\uff08\u2166\uff09Sn3<\/sub>O4<\/sub>\/PTFE\uff0c\u6c34\u6d41\u901f\uff1a22 mL\/min\uff1b\uff08\u2167\uff09Sn3<\/sub>O4<\/sub>\/PTFE\uff0c\u6c34\u6d41\u901f\uff1a480 mL\/min\uff1b<\/p>\n

\uff08f\uff09\u5728480 mL\/min\uff0c\u8ddd\u6ce8\u5165\u53e32 cm\u7684\u6761\u4ef6\u4e0b\uff0cSn3<\/sub>O4<\/sub>\/PVDF\u5bf9 Rh B\u6eb6\u6db2\u7684\u91cd\u590d\u964d\u89e3\u66f2\u7ebf\uff1b<\/p>\n

\uff08g\uff09\u5728\u9759\u6b62\u548c\u6405\u62cc\u6761\u4ef6\u4e0b,Sn3<\/sub>O4<\/sub>\/PVDF\u50ac\u5316\u5242\u7684\u5bf9\u82ef\u4e8c\u7532\u9178-OH\u2022\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31;<\/p>\n

\uff08h\uff09\u5728480 mL\/min\u6c34\u6d41\u901f\u548c\u7d2b\u5916\u5149\u4e0b\uff0c\u4e0d\u540c\u6761\u4ef6\u4e0b\u4f7f\u7528\u4e0d\u540c\u7684\u5149\u50ac\u5316\u5242\u65f6\uff0cRh B\u7684\u964d\u89e3\u66f2\u7ebf\u4e3a\uff1a\uff08\u2160\uff09\u65e0\u5149\u50ac\u5316\u5242\uff08\u7eafRh B\u6eb6\u6db2\uff09\uff1b\uff08\u2161\uff09Sn3<\/sub>O4<\/sub>; \uff08\u2162\uff09Sn3<\/sub>O4<\/sub>\/PVDF\uff0c\u8ddd\u6ce8\u5165\u53e32 cm\uff1b \uff08\u2163\uff09Sn3<\/sub>O4<\/sub>\/PVDF\uff0c\u8ddd\u6ce8\u5165\u53e312 cm\uff1b \uff08\u2164\uff09Sn3<\/sub>O4<\/sub>\/PTFE\uff0c\u8ddd\u6ce8\u5165\u53e32 cm\uff1b \uff08\u2165\uff09Sn3<\/sub>O4<\/sub>\/PTFE\uff0c\u8ddd\u8fdb\u6837\u53e312 cm;<\/p>\n

\uff08i\uff09\u5728480 mL\/min\u7684\u6761\u4ef6\u4e0b\uff0cSn3<\/sub>O4<\/sub>\u5bf9 Rh B\u6eb6\u6db2\u7684\u91cd\u590d\u964d\u89e3\u66f2\u7ebf\uff1b<\/p>\n

\uff08j\uff09\u5728\u9759\u6001\u548c\u6405\u62cc\u6761\u4ef6\u4e0b,PVDF\u819c\u7684\u5bf9\u82ef\u4e8c\u7532\u9178-OH\u2022\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

\u56fe6<\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5185\u5efa\u7535\u573a\u7535\u52bf\u968f\u6c34\u6d41\u51b2\u51fb\u53d8\u5316\u65f6\uff0cSn3<\/sub>O4<\/sub>\u4e2d\u7a7a\u7a74\u548c\u7535\u5b50\u7684\u5206\u79bb\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff0cc\uff09\u5f53\u5185\u5efa\u7535\u573a\u5f3a\u5ea6\u968f\u5916\u529b\u53d8\u5316\u65f6\uff0c\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u91d1\u5c5e\u79bb\u5b50\u4e0eF–<\/sup>\u4e4b\u95f4\u7684\u914d\u4f4d\u4f5c\u7528\u80fd\u591f\u4f7f\u758f\u6c34\u6027\u7684PVDF\u819c\u8868\u9762\u5438\u6536\u91d1\u5c5e\u79bb\u5b50\u5e76\u5408\u6210\u534a\u5bfc\u4f53\u7eb3\u7c73\u7ed3\u6784\uff0c\u4ece\u800c\u5236\u5907\u4e86Sn3<\/sub>O4<\/sub>\/PVDF\u5149\u50ac\u5316\u5242\u3002\u7531\u4e8ePVDF\u7684\u94c1\u7535\u7279\u6027\uff0c\u5176\u81ea\u53d1\u7535\u52bf\u53ef\u4ee5\u5145\u5f53\u5185\u5efa\u7535\u573a\uff0c\u4ece\u800c\u4fc3\u8fdbSn3<\/sub>O4<\/sub>\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u6709\u6548\u5206\u79bb\u3002\u5229\u7528\u538b\u7535\u7535\u5b50\u5b66\u6548\u5e94\uff0c\u4f7f\u673a\u68b0\u4f5c\u7528\uff08\u4f8b\u5982\u6c34\u6d41\uff09\u9a71\u52a8\u7684\u5185\u5efa\u7535\u573a\u7535\u52bf\u4e0d\u65ad\u53d8\u5316\uff0c\u4ece\u800c\u5b9e\u73b0\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u6301\u7eed\u5206\u79bb\u3002\u56e0\u6b64\uff0c\u5229\u7528\u914d\u4f4d\u7406\u8bba\u80fd\u591f\u5728\u758f\u6c34\u6027PVDF\u8584\u819c\u8868\u9762\u8fdb\u884c\u534a\u5bfc\u4f53\u6c27\u5316\u7269\u7684\u8d1f\u8f7d\uff1b\u540c\u65f6\uff0c\u5229\u7528\u538b\u7535\u7535\u5b50\u5b66\u6548\u5e94\u80fd\u591f\u5b9e\u73b0\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u9ad8\u6548\u5206\u79bb\u3002\u538b\u7535\u7535\u5b50\u5b66\u548c\u914d\u4f4d\u7406\u8bba\u7684\u5f15\u5165\u4e3a\u9ad8\u6027\u80fd\u5149\u50ac\u5316\u5242\u7684\u5408\u6210\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/p>\n

https:\/\/doi.org\/10.1016\/j.nanoen.2020.104688<\/p>\n

\u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u738b\u91d1\u521a<\/strong>\uff0c\u7537\uff0c\u535a\u58eb\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u539f\u5b50\u80fd\u79d1\u5b66\u7814\u7a76\u9662\uff0c\u6d4e\u5357\u5927\u5b66\u524d\u6cbf\u4ea4\u53c9\u79d1\u5b66\u7814\u7a76\u9662\u6559\u6388\uff0c\u7855\u58eb\u751f\u5bfc\u5e08\u3002\u4e3b\u8981\u4ece\u4e8b\u7eb3\u7c73\u80fd\u6e90\u8f6c\u5316\u6750\u6599\u3001\u5149\u50ac\u5316\u6750\u6599\u4ee5\u53ca\u5e72\u7ec6\u80de\u5206\u5316\u76f8\u5173\u7684\u7814\u7a76\u3002\u4f5c\u4e3a\u9879\u76ee\u8d1f\u8d23\u4eba\u627f\u62c5\u4e86\u5305\u62ec\u5c71\u4e1c\u7701\u91cd\u5927\u521b\u65b0\u5de5\u7a0b\u9879\u76ee\u3001\u5c71\u4e1c\u7701\u91cd\u70b9\u7814\u53d1\u9879\u76ee\u3001\u5c71\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u548c\u5c71\u4e1c\u7701\u4f18\u79c0\u4e2d\u9752\u5e74\u79d1\u5b66\u5bb6\u9879\u76ee\u7b49\uff1b\u83b7\u5c71\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u5956\u4e8c\u7b49\u5956\u4e00\u9879\uff1b\u5728\u5305\u62ecAppl. Catal., B, J. Hazard. Mater.\u7b49\u91cd\u8981\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u658740\u4f59\u7bc7\u3002<\/p>\n

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