{"id":197284,"date":"2020-03-10T06:21:00","date_gmt":"2020-03-09T22:21:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=197284"},"modified":"2020-03-09T21:21:49","modified_gmt":"2020-03-09T13:21:49","slug":"%e6%ad%a6%e5%a4%a7%e5%bc%a0%e5%85%88%e6%ad%a3%e5%9b%a2%e9%98%9f-adv-funct-mater-%ef%bc%9a%e8%87%aa%e7%9f%bf%e5%8c%96%e7%9a%84%e5%85%89%e7%83%ad%e7%bb%86%e8%8f%8c%e4%b8%8e%e9%9d%b6%e5%90%91%e7%ba%bf","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=197284","title":{"rendered":"\u6b66\u5927\u5f20\u5148\u6b63\u56e2\u961f Adv. Funct. Mater.\uff1a\u81ea\u77ff\u5316\u7684\u5149\u70ed\u7ec6\u83cc\u4e0e\u9776\u5411\u7ebf\u7c92\u4f53\u7684MOFs\u6742\u4ea4\u7528\u4e8e\u589e\u5f3a\u5149\u70ed\u80bf\u7624\u6cbb\u7597"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u5982\u4eca\uff0c\u7ec6\u83cc\u4f5c\u4e3a\u4e00\u79cd\u751f\u7269\u4f53\uff0c\u5176\u4ee3\u8c22\u4ea7\u7269\u53ef\u4ee5\u76f4\u63a5\u53d1\u6325\u91cd\u8981\u7684\u6291\u764c\u4f5c\u7528\u3002\u540c\u65f6\uff0c\u5bf9\u7ec6\u83cc\u8fdb\u884c\u57fa\u56e0\u6539\u9020\u53ef\u4ee5\u751f\u4ea7\u9776\u5411\u6027\u6297\u764c\u836f\u7269\uff0c\u4ee5\u6ee1\u8db3\u4e34\u5e8a\u9700\u6c42\u3002\u6b64\u5916\uff0c\u7ec6\u83cc\u7531\u4e8e\u5176\u8868\u9762\u4e0a\u5b58\u5728\u5927\u91cf\u5316\u5b66\u57fa\u56e2\u800c\u6613\u4e8e\u5316\u5b66\u4fee\u9970\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u7ec6\u83cc\u7684\u591a\u529f\u80fd\u80bf\u7624\u6cbb\u7597\u5e73\u53f0\u6709\u671b\u89e3\u51b3\u80bf\u7624\u6cbb\u7597\u4e2d\u7684\u91cd\u5927\u6311\u6218\u3002\u8fd1\u5e74\u6765\uff0c\u5229\u7528\u5149\u70ed\u5242\u5c06\u5149\u80fd\u8f6c\u5316\u4e3a\u70ed\u91cf\u4ee5\u6d88\u878d\u80bf\u7624\u7684\u5149\u70ed\u7597\u6cd5\uff08PTT\uff09\u53d6\u5f97\u91cd\u5927\u7a81\u7834\uff0c\u4f46\u662f\u60f0\u6027\u5149\u70ed\u5242\u7684\u9776\u5411\u80fd\u529b\u5dee\u548c\u56fa\u6709\u7684\u80bf\u7624\u8010\u70ed\u6027\u9650\u5236\u4e86\u5176\u5e94\u7528\u3002\u6240\u4ee5\uff0c\u5f00\u53d1\u57fa\u4e8e\u7ec6\u83cc\u7684PTT\u53ef\u4ee5\u63d0\u4f9b\u7279\u6b8a\u9009\u62e9\uff0c\u4ee5\u89e3\u51b3PTT\u4e2d\u80bf\u7624\u9776\u5411\u80fd\u529b\u548c\u8010\u70ed\u6027\u7684\u95ee\u9898\u3002<\/p>\n

\u7136\u800c\uff0c\u4ec5\u4ec5\u589e\u5f3a\u5149\u70ed\u5242\u7684\u80bf\u7624\u9776\u5411\u80fd\u529b\uff0c\u987d\u56fa\u764c\u7ec6\u80de\u7684\u56fa\u6709\u8010\u70ed\u6027\u4ecd\u53ef\u80fd\u9650\u5236PTT\u6548\u679c\u3002\u80bf\u7624\u7684\u8010\u70ed\u6027\u4e3b\u8981\u7531\u4e8e\u70ed\u4f11\u514b\u86cb\u767d\uff08HSPs\uff09\u53ef\u4ee5\u4fdd\u62a4\u6297\u51cb\u4ea1\u548c\u4fdd\u62a4\u7ec6\u80de\u86cb\u767d\u514d\u4e8e\u53d8\u6027\uff0c\u4ece\u800c\u9632\u6b62\u7ec6\u80de\u6b7b\u4ea1\u3002\u4f17\u6240\u5468\u77e5\uff0cHSPs\u7684\u8868\u8fbe\u4f9d\u8d56\u4e8e\u6e90\u4e8e\u7ebf\u7c92\u4f53\u7684\u4e09\u78f7\u9178\u817a\u82f7\uff08ATP\uff09\u7684\u80fd\u91cf\u4f9b\u5e94\u3002\u7531\u4e8e\u7ebf\u7c92\u4f53\u7f16\u7801\u7684\u57fa\u56e0\u6709\u52a9\u4e8e\u771f\u6838\u7ec6\u80de\u8010\u70ed\u6027\u7684\u6f14\u53d8\uff0c\u56e0\u6b64\u53ef\u4ee5\u901a\u8fc7\u4ee3\u8c22\u548c\u9057\u4f20\u65b9\u5f0f\u5e72\u6270\u7ebf\u7c92\u4f53\u529f\u80fd\u4ece\u800c\u5e72\u9884\u80bf\u7624\u7ec6\u80de\u7684\u8010\u70ed\u6027\u3002\u6cb8\u77f3\u54aa\u5511\u6784\u67b690\uff08ZIF-90\uff09\u7684\u91d1\u5c5e\u6709\u673a\u6784\u67b6\uff08MOF\uff09\u53ef\u80fd\u9002\u5408\u7528\u4f5c\u9488\u5bf9\u7ebf\u7c92\u4f53\u5e72\u6270\u7684\u7ebf\u7c92\u4f53\u9776\u5411\u836f\u7269\u7684\u8f7d\u4f53\u3002\u56e0\u6b64\uff0c\u5c06\u81ea\u77ff\u5316\u7ec6\u83cc\u4e0e\u7834\u574f\u7ebf\u7c92\u4f53\u7684ZIF-90\u5c01\u88c5\u836f\u7269\u5076\u8054\u5c06\u662f\u89e3\u51b3PTT\u4e2d\u80bf\u7624\u9776\u5411\u548c\u80bf\u7624\u8010\u70ed\u6311\u6218\u7684\u6709\u6548\u7b56\u7565\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u57fa\u4e8e\u6b64\uff0c\u6b66\u6c49\u5927\u5b66\u5f20\u5148\u6b63\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u81ea\u77ff\u5316\u7684\u5149\u70ed\u7ec6\u83cc\uff08PTB\uff09\uff0c\u901a\u8fc7\u5229\u7528\u7535\u5316\u5b66\u6d3b\u6027\u7ec6\u83ccShewanella oneidensis<\/em> MR-1\uff08S. oneidensis<\/em> MR-1\uff09\u5c06\u56db\u6c2f\u5316\u94af\u9178\uff08Na2<\/sub>PdCl4<\/sub>\uff09\u8fd8\u539f\u6210\u7ec6\u83cc\u7ec6\u80de\u8868\u9762\u7684\u94af\u7eb3\u7c73\u9897\u7c92\uff08Pd NPs\uff09\u3002\u7531\u4e8e\u7ec6\u83cc\u7684\u7279\u6027\uff0cPTB\u5177\u6709\u5f88\u597d\u7684\u80bf\u7624\u9776\u5411\u80fd\u529b\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u63ba\u5165\u4e86Pd NPs\u5149\u70ed\u5242\uff0cPTB\u8fd8\u6709\u671b\u5728\u8fd1\u7ea2\u5916\uff08NIR\uff09\u533a\u57df\u5177\u6709\u4f18\u5f02\u7684\u5149\u70ed\u6027\u80fd\u3002\u4e3a\u4e86\u63d0\u9ad8PTB\u7684PTT\u6548\u7387\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u5408\u6210\u4e86\u8d1f\u8f7d\u6709\u5149\u654f\u5242\u4e9a\u7532\u57fa\u84dd\uff08MB\uff09\u7684ZIF-90\uff08ZIF-90\/MB\uff09\uff0c\u5e76\u5728PTB\u7684\u8868\u9762\u4e0a\u5171\u8f6d\uff0c\u901a\u8fc7\u9178\u654f\u611f\u4e9a\u80fa\u952e\u5236\u5907PTB@ZIF-90\/MB\u3002\u5f53PTB@ZIF-90\/MB\u5230\u8fbe\u9178\u6027\u80bf\u7624\u90e8\u4f4d\u65f6\uff0c\u7531\u4e8e\u9178\u654f\u611f\u7684\u4e9a\u80fa\u952e\u65ad\u88c2\u548cATP\u8bf1\u5bfc\u7684ZIF-90\u6846\u67b6\u964d\u89e3\uff0cZIF-90\/MB\u4f1a\u4ecePTB\u8868\u9762\u8131\u843d\u5e76\u9009\u62e9\u6027\u7684\u5728\u7ebf\u7c92\u4f53\u91ca\u653eMB\uff0c\u800cMB\u5728\u5149\u7167\u4e0b\u4f1a\u4ea7\u751f\u5355\u7ebf\u6001\u6c27\uff081<\/sup>O2<\/sub>\uff09\u3002\u56e0\u6b64\uff0c\u7ecf\u8fc7\u4fee\u9970\u7684ZIF-90\/MB\u901a\u8fc7\u7834\u574f\u7ebf\u7c92\u4f53\u6c27\u5316\u8fd8\u539f\u5e73\u8861\u800c\u5bfc\u81f4\u7ebf\u7c92\u4f53\u529f\u80fd\u969c\u788d\uff0c\u6700\u7ec8\u6291\u5236\u4ea7\u751fATP\u5e76\u4e0b\u8c03HSPs\u7684\u8868\u8fbe\u3002\u603b\u4e4b\uff0c\u57fa\u4e8ePTB\u7684PTB@ZIF-90\/MB\u5149\u70ed\u6cbb\u7597\u5e73\u53f0\u4f7f\u5f97PTT\u5177\u6709\u9009\u62e9\u6027\u9776\u5411\u80bf\u7624\u548c\u6291\u5236\u80bf\u7624\u8010\u70ed\u6027\u7684\u4f18\u70b9\uff0c\u53d6\u5f97\u4e86\u663e\u8457\u7684\u80bf\u7624\u6cbb\u7597\u6548\u679c\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cSelf-Mineralized Photothermal Bacteria Hybridizing with Mitochondria-Targeted Metal-Organic Frameworks for Augmenting Photothermal Tumor Therapy\u201d<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Funct. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001PTB\u7684\u8868\u5f81<\/strong>
\n \"\"\uff08A\uff09\u7ec6\u83cc\u548c\u6269\u5927\u7684\u7ec6\u83cc\u8868\u9762\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08B\uff09PTB\u548c\u6269\u5927\u7684PTB\u8868\u9762\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08C\uff09PTB\u8868\u9762\u4e0aPd NPs\u7684Mapping\u56fe\u50cf\uff1b<\/p>\n

\uff08D\uff09\u5e72\u71e5PTB\u7684Pd 3d XPS\u5149\u8c31\uff1b<\/p>\n

\uff08E\uff09HCOONa\u3001Na2<\/sub>PdCl4<\/sub>\u3001\u7ec6\u83cc\u548cPTB\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\uff08F-G\uff09\u5728808 nm\u6fc0\u5149\u7167\u5c045 min\u4e0b\uff0c\u5bf9\u4e0d\u540c\u6d53\u5ea6\u7684PTB\u6c34\u6eb6\u6db2\u8fdb\u884c\u70ed\u6210\u50cf\u548c\u76f8\u5e94\u7684\u5347\u6e29\u66f2\u7ebf\uff1b<\/p>\n

\uff08H\uff09\u5f53\u7528\u4e0d\u540c\u7684\u6fc0\u5149\u7167\u5c04\u529f\u7387\u5f3a\u5ea6\u5904\u7406\u65f6\uff0cPTB\u7684\u6e29\u5ea6\u5347\u9ad8\u7279\u6027\uff1b<\/p>\n

\uff08I\uff09\u4e94\u4e2a\u5468\u671f\u7684PTB\u5faa\u73af\u5149\u70ed\u6d4b\u8bd5\uff1b<\/p>\n

\uff08J\uff09\u5728\u7528808 nm\u6fc0\u5149\u7167\u5c04\u7684\u4e0d\u540c\u5904\u7406\u4e2d\uff0cCT26\u7ec6\u80de\u7684\u7ec6\u80de\u6bd2\u6027\uff1b<\/p>\n

\uff08K\uff09\u5728\u7528808 nm\u6fc0\u5149\u7167\u5c04\u540e\uff0cCT26\u7ec6\u80de\u6d3b\/\u6b7b\u67d3\u8272\u3002<\/p>\n

\u56fe\u4e8c\u3001ZIF-90\u548cZIF-90\/MB\u7684\u8868\u5f81<\/strong>
\n \"\"\uff08A\uff09ZIF-90\uff08A1\uff09\u548cZIF-90\/MB\uff08A2\uff09\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08B\uff09MB\u3001ZIF-90\u548cZIF-90\/MB\u7684PXRD\u56fe\uff1b<\/p>\n

\uff08C\uff09MB\u3001ZIF-90\u548cZIF-90\/MB\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

\uff08D\uff09\u7528ATP\u5904\u7406\u7684ZIF-90\/MB\u548cZIF-90\/MB\u7684PXRD\u56fe\uff1b<\/p>\n

\uff08E\uff09ATP\u5904\u7406\u540e\u7684ZIF-90\/MB\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08F\uff09ZIF-90\/MB\u4e0e\u7ebf\u7c92\u4f53\u57283T3\u7ec6\u80de\u548cCT26\u7ec6\u80de\u4e2d\u7684\u5171\u5b9a\u4f4d\u7814\u7a76\u4ee5\u53ca\u76f8\u5e94\u7684\u533a\u57df\u653e\u5927\u56fe\uff1b<\/p>\n

\uff08G\uff09\u5728\u4e0d\u540c\u6d53\u5ea6\u7684ZIF-90\/MB\u6c34\u6eb6\u6db2\u4e2d\uff0cSOSG\u7684\u8367\u5149\u589e\u52a0\u7279\u6027\uff1b<\/p>\n

\uff08H\uff09\u5728\u4e0d\u540c\u65f6\u95f4\u7167\u5c04\u76843T3\u7ec6\u80de\u548cCT26\u7ec6\u80de\u4e2d\u4f7f\u7528DA-DCFH\u68c0\u6d4b1O2\uff1b<\/p>\n

\uff08I-J\uff09\u57283T3\u7ec6\u80de\u548cCT26\u7ec6\u80de\u4e2d\u7528ZIF-90\/MB\u5904\u7406\u540e\uff0c\u5728\u6709\u65e0\u5149\u7167\u7684\u60c5\u51b5\u4e0b\uff0c\u4f7f\u7528JC-1\u67d3\u6599\u76d1\u6d4b\u7ebf\u7c92\u4f53\u819c\u7535\u4f4d\u548c\u76f8\u5e94\u6d41\u5f0f\u7ec6\u80de\u4eea\u68c0\u6d4b\uff1b<\/p>\n

\uff08K\uff09\u5728\u6709\u65e0\u5149\u7167\u7684\u60c5\u51b5\u4e0b\uff0cZIF-90\u6216ZIF-90\/MB\u5904\u7406\u540e\u7684\u76f8\u5bf9ATP\u91cf\uff1b<\/p>\n

\uff08L\uff09WB\u8bd5\u9a8c\u7528\u4e8e\u5728\u4e0d\u540c\u5904\u7406\u540e\u68c0\u6d4bHSP70\u548cHSP90\u7684\u8868\u8fbe\uff1b<\/p>\n

\uff08M-N\uff09ZIF-90\u6216ZIF-90\/MB\u5904\u7406\uff08\u6709\u65e0\u5149\u7167\uff09\u540e\uff0c 3T3\u7ec6\u80de\u548cCT26\u7ec6\u80de\u7684\u7ec6\u80de\u6bd2\u6027\u3002<\/p>\n

\u56fe\u4e09\u3001PTB@ZIF-90\/MB\u7684\u8868\u5f81<\/strong>
\n \"\"\uff08A\uff09\u6742\u4ea4\u7684PTB@ZIF-90\/MB\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08B\uff09PTB@ZIF-90\/MB\u4e0aPd\u548cZn\u7684\u5143\u7d20Mapping\u56fe\uff1b<\/p>\n

\uff08C\uff09PTB@ZIF-90\/MB\u7684Pd 3d XPS\u5149\u8c31\uff1b<\/p>\n

\uff08D\uff09PTB@ZIF-90\/MB\u7684Zn 2p XPS\u5149\u8c31\uff1b<\/p>\n

\uff08E\uff09\u4e0d\u540c\u5904\u7406\u540eLB\u5e73\u677f\u4e2d\u7684\u7ec6\u83cc\u83cc\u843d\u5f62\u6210\u5355\u4f4d\uff1b<\/p>\n

\uff08F\uff09\u4e0d\u540c\u5904\u7406\u540e\u7684\u76f8\u5bf9ATP\u91cf\uff1b<\/p>\n

\uff08G\uff09\u4e0d\u540c\u5904\u7406\u540eCT26\u7ec6\u80de\u7684\u7ec6\u80de\u6d3b\u529b\uff1b<\/p>\n

\uff08H\uff09\u7528\u4e8e\u5728\u4e0d\u540c\u5904\u7406\u540e\u68c0\u6d4bHSP70\u548cHSP90\u8868\u8fbe\u7684WB\u6d4b\u5b9a\uff1b<\/p>\n

\uff08I-J\uff09\u4e0d\u540c\u5904\u7406\u540eCT26\u7ec6\u80de\u7684\u6d3b\/\u6b7b\u67d3\u8272\u4ee5\u53ca\u76f8\u5e94\u6d41\u5f0f\u7ec6\u80de\u4eea\u8868\u5f81\u3002<\/p>\n

\u56fe\u56db\u3001PTB@ZIF-90\/MB\u7684\u4f53\u5185\u80bf\u7624\u9776\u5411\u6d4b\u8bd5<\/strong>
\n \"\"\uff08A\uff09\u89c2\u5bdf\u5c0f\u9f20\u4f53\u5185DIR\u8367\u5149\u7814\u7a76PTB@ZIF-90\/MB\u7684\u80bf\u7624\u9776\u5411\u80fd\u529b\uff1b<\/p>\n

\uff08B\uff09\u89c2\u5bdfRhB\u8367\u5149\u7814\u7a76ZIF-90\u7684\u80bf\u7624\u9776\u5411\u80fd\u529b\u548cZIF-90\u4e0ePTB\u7684\u5171\u5b9a\u4f4d\uff1b<\/p>\n

\uff08C-D\uff09\u5c0f\u9f20\u4e2dPTB@ZIF-90\/MB\u7684\u5149\u70ed\u6027\u8d28\u7814\u7a76\u548c\u76f8\u5e94\u7684\u6e29\u5ea6\u5b9a\u91cf\u3002<\/p>\n

\u56fe\u4e94\u3001PTB@ZIF-90\/MB\u7684\u4f53\u5185\u80bf\u7624\u6cbb\u7597<\/strong>
\n \"\"\uff08A\uff09PTB@ZIF-90\/MB\u5bf9CT26\u5c0f\u9f20\u76ae\u4e0b\u80bf\u7624\u6a21\u578b\u7684\u6cbb\u7597\u8fc7\u7a0b\uff1b<\/p>\n

\uff08B\uff0917 d\u5185\u4e0d\u540c\u6cbb\u7597\u65b9\u6cd5\u7684\u80bf\u7624\u751f\u957f\u60c5\u51b5\uff1b<\/p>\n

\uff08C\uff09\u5728\u7b2c17 d\u7684\u4e0d\u540c\u6cbb\u7597\u540e\u6536\u83b7\u7684\u80bf\u7624\uff1b<\/p>\n

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\uff08I\uff09\u9759\u8109\u5185\u6ce8\u5c04PTB @ ZIF-90\/MB\u7684\u7b2c1 d\u3001\u7b2c7 d\u548c\u7b2c14 d\u540e\uff0c\u809d\u529f\u80fd\u76f8\u5173\u9176ALT\u3001AST\u548cGGT\u7684\u6d53\u5ea6\uff1b<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86PTB@ZIF-90\/MB\u7684\u751f\u7269\u6742\u4ea4\u578b\u5149\u70ed\u6cbb\u7597\u5e73\u53f0\uff0c\u8be5\u5e73\u53f0\u5177\u6709\u826f\u597d\u7684\u80bf\u7624\u9776\u5411\u80fd\u529b\u548c\u589e\u5f3a\u7684\u5149\u70ed\u80bf\u7624\u6d88\u878d\u80fd\u529b\u3002\u6b64\u5916\uff0c\u751f\u7269\u5b89\u5168\u6027\u8bc4\u4f30\u8868\u660e\uff0cPTB@ZIF-90\/MB\u4e0d\u4f1a\u5f15\u53d1\u660e\u663e\u7684\u7ec4\u7ec7\u635f\u4f24\u548c\u4e25\u91cd\u7684\u708e\u75c7\u53cd\u5e94\u3002\u8be5\u5de5\u4f5c\u5c55\u793a\u7684PTB@ZIF-90\/MB\u6cbb\u7597\u5e73\u53f0\u6709\u671b\u89e3\u51b3\u4f20\u7edf\u5149\u70ed\u5242\u80bf\u7624\u9776\u5411\u80fd\u529b\u5dee\u548c\u80bf\u7624\u8010\u70ed\u6027\u7684\u95ee\u9898\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSelf-Mineralized Photothermal Bacteria Hybridizing with Mitochondria-Targeted Metal-Organic Frameworks for Augmenting Photothermal Tumor Therapy<\/a><\/strong>. (Adv. Funct. Mater.<\/em>, 2020<\/strong>, DOI: 10.1002\/adfm.201909806)<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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