{"id":196826,"date":"2020-03-03T06:30:21","date_gmt":"2020-03-02T22:30:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=196826"},"modified":"2020-03-02T19:30:36","modified_gmt":"2020-03-02T11:30:36","slug":"adv-energy-mater-%ef%bc%9a%e5%a4%9a%e9%87%91%e5%b1%9e%e6%b0%94%e5%87%9d%e8%83%b6%e5%ba%94%e7%94%a8%e4%ba%8eph%e9%80%9a%e7%94%a8%e7%9a%84her%e5%92%8corr%e7%94%b5%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=196826","title":{"rendered":"Adv. Energy Mater.\uff1a\u591a\u91d1\u5c5e\u6c14\u51dd\u80f6\u5e94\u7528\u4e8epH\u901a\u7528\u7684HER\u548cORR\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u7684Jin Wei\u548cAlexander Eychm\u00fcller\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728\u524d\u671f\u5f00\u53d1\u7684\u7279\u5f02\u6027\u79bb\u5b50\u6548\u5e94\u8bf1\u5bfc\u6210\u80f6\u7684\u57fa\u7840\u4e0a\uff08Sci. Adv. 2019, 5, eaaw4590.\uff09\uff0c\u91c7\u7528\u5177\u6709\u6781\u5f3a\u76d0\u6790\u6548\u5e94\u7684\u6c1f\u5316\u94f5\u4f5c\u4e3a\u5f15\u53d1\u5242\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u5236\u5907\u7b56\u7565\uff0c\u83b7\u5f97\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u7279\u5b9a\u7ed3\u6784\u7684\u8d35\u91d1\u5c5e\u6c14\u51dd\u80f6\uff08NMAs\uff09\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7ed3\u5408\u6c14\u51dd\u80f6\u7684\u7ed3\u6784\u7279\u70b9\u53ca\u4f18\u5316\u7684\u5316\u5b66\u7ec4\u6210\uff0c\u83b7\u5f97\u4e86\u6027\u80fd\u5353\u8d8a\u7684Au-Pt\u548cAu-Rh\u6c14\u51dd\u80f6\u50ac\u5316\u5242\uff1a\u524d\u8005\u7528\u4e8e\u7535\u50ac\u5316ORR\uff0c\u540e\u8005\u7528\u4e8e\u7535\u50ac\u5316HER\u4e0e\u7535\u5316\u5b66\u6c34\u88c2\u89e3\u53cd\u5e94\uff0c\u5176\u5728\u5f88\u5bbd\u7684pH\u533a\u95f4\u5185\uff080-14\uff09\u5747\u4f18\u4e8e\u5546\u4e1a\u5316Pt\/C\u548c\u8bb8\u591a\u5176\u4ed6\u7684\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u5242\uff0c\u5728\u7535\u5316\u5b66\u5236\u6c22\u3001\u71c3\u6599\u7535\u6c60\u7b49\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u6f5c\u529b\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cEngineering Multimetallic Aerogels for pH-Universal HER and ORR Electrocatalysis<\/strong>\u201d\u53d1\u8868\u4e8e\u8457\u540d\u80fd\u6e90\u671f\u520aAdv. Energy Mater<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00 \u8d35\u91d1\u5c5e\u6c14\u51dd\u80f6\u7684\u5408\u6210\u4e0e\u8868\u5f81<\/strong><\/p>\n

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\n \uff08b-g\uff09Au-Pt\u6c14\u51dd\u80f6(b\u2013d)\u548cAu-Rh\u6c14\u51dd\u80f6(e\u2013g)\u7684SEM\u56fe\u50cf\u3001\u9ad8\u5206\u8fa8TEM\u56fe\u50cf\u548cEDX\u5143\u7d20mapping\u56fe\uff0c\u63d2\u56fe(c, f)\u8868\u793aTEM\u56fe\u50cf\u7684\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362\u5206\u6790\u6240\u5f97\u7684\u7535\u5b50\u884d\u5c04\u56fe<\/p>\n

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\"\"
\n \uff08a-c\uff09HER\u6781\u5316\u66f2\u7ebf
\n \uff08d-f\uff09Tafel\u66f2\u7ebf
\n \uff08g-i\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm-2<\/sup>\u65f6\u7684\u8fc7\u7535\u4f4d\u548c\u572850 mV\u8fc7\u7535\u4f4d\uff08\u76f8\u5bf9\u4e8eRHE\uff09\u65f6\u7684\u7535\u6d41\u5bc6\u5ea6
\n \uff08j-l\uff09\u8be5\u5de5\u4f5c\u4e0e\u53c2\u8003\u6587\u732e\u4e2d\u7684\u8fc7\u7535\u4f4d\u548cTafel\u659c\u7387\u7684\u6bd4\u8f83
\n \u8fd9\u4e9b\u6d4b\u8bd5\u5206\u522b\u57281M KOH\uff08a, d, g, j\uff09\uff0c1M PBS\uff08b, e, h, k\uff09\u548c0.5 M H2<\/sub>SO4<\/sub>\uff08c, f, i, l\uff09\u6eb6\u6db2\u4e2d\u8fdb\u884c<\/p>\n

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\n \uff08a-c\uff09Au-Rh\u6c14\u51dd\u80f6||RuO2<\/sub>\u7535\u89e3\u69fd\u548cPt\/C|| RuO2<\/sub>\u7535\u89e3\u69fd\u7684\u6781\u5316\u66f2\u7ebf
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\n \uff08e\uff09Au-Rh\u6c14\u51dd\u80f6|| RuO2<\/sub>\u7535\u89e3\u69fd\u57281 M KOH\u6eb6\u6db2\u4e2d\u8fdb\u884c\u6c34\u88c2\u89e3\u7684\u793a\u610f\u56fe
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\n \u6240\u7528\u5b9e\u9a8c\u5747\u5728\u6307\u5b9a\u73af\u5883\u4e2d\u8fdb\u884c\uff0c\u59821 M KOH\uff0c1 M PBS\u548c0.5 M H2<\/sub>SO4<\/sub>\u7684\u6c34\u6eb6\u6db2<\/p>\n

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\"\"<\/p>\n

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\n \uff08b\uff09Au-Pt\u6c14\u51dd\u80f6\u3001Au-Pt\u7eb3\u7c73\u9897\u7c92\u548c\u5546\u7528Pt\/C\u50ac\u5316\u5242\u7684\u8d77\u59cb\u7535\u4f4d\u548c\u534a\u6ce2\u7535\u4f4d
\n \uff08c\uff09Tafel\u66f2\u7ebf
\n \uff08d\uff09H2<\/sub>O2<\/sub>\u751f\u6210\u548c\u8f6c\u79fb\u7535\u5b50\u6570
\n \uff08e, f\uff09ADT\u4e4b\u524d\u548c\u4e4b\u540e\u7684\u6781\u5316\u66f2\u7ebf
\n \u6240\u6709\u5b9e\u9a8c\u57280.1 M KOH \u62160.1 M HClO4<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u8fdb\u884c\uff0c\u5982\u56fe\u6240\u793a<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u8fde\u63a5\uff1aEngineering Multimetallic Aerogels for pH-Universal HER and ORR Electrocatalysis<\/a><\/strong>\uff08Adv. Energy Mater., 2020, DOI: 10.1002\/aenm.201903857\uff09<\/p>\n

\u672c\u6587\u7531\u6c5f\u6cb3\u5165\u6d77\u7f16\u8bd1\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip.<\/p>\n

\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b<\/p>\n

Du, R.; Hu, Y.; H\u00fcbner, R.; Joswig, J.-O.; Fan, X.; Eychm\u00fcller, A., Specific Ion Effects Directed Noble Metal Aerogels: Versatile Manipulation for Electrocatalysis and Beyond. Sci. Adv. 2019, 5, eaaw4590.<\/p>\n

Du, R.; Fan, X.; Jin, X.; H\u00fcbner, R.; Hu, Y.; Eychm\u00fcller, A., Emerging Noble Metal Aerogels: State of the Art and a Look Forward. Matter 2019, 1 (1), 39-56.<\/p>\n

Du, R.; Jin, X.; H\u00fcbner, R.; Fan, X.; Hu, Y.; Eychm\u00fcller, A., Engineering Self-Supported Noble Metal Foams Toward Electrocatalysis and Beyond. Adv. Energy Mater. 2019, 1901945.<\/p>\n

Fan, X.; Zerebecki, S.; Du, R.; H\u00fcbner, R.; Marzum, G.; Jiang, G.; Hu, Y.; Barcikowki, S.; Reichenberger, S.; Eychm\u00fcller, A., Promoting the Electrocatalytic Performance of Noble Metal Aerogels by Ligand-Directed Modulation. Angew. Chem. Int. Ed. 2020, 10.1002\/anie.201913079.<\/p>\n

Du, R.; Joswig, J.-O.; Fan, X.; H\u00fcbner, R.; Spittel, D.; Hu, Y.; Eychm\u00fcller, A., Disturbance-Promoted Unconventional and Rapid Fabrication of Self-Healable Noble Metal Gels for (Photo-)Electrocatalysis. Matter 2020, 10.1016\/j.matt.2020.01.002.<\/p>\n","protected":false},"excerpt":{"rendered":"

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