{"id":196524,"date":"2020-02-27T06:01:31","date_gmt":"2020-02-26T22:01:31","guid":{"rendered":"\/\/m.iemloyee.com\/?p=196524"},"modified":"2020-02-26T17:33:23","modified_gmt":"2020-02-26T09:33:23","slug":"%e4%b8%9c%e5%8c%97%e6%9e%97%e5%a4%a7%e5%93%88%e5%b7%a5%e5%a4%a7%e5%9b%a2%e9%98%9fadv-funct-mater-%ef%bc%9a%e7%94%a8%e4%ba%8e%e9%ab%98%e7%81%b5%e6%95%8f%e5%ba%a6%e5%92%8c%e9%ab%98%e9%80%89%e6%8b%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=196524","title":{"rendered":"\u4e1c\u5317\u6797\u5927&\u54c8\u5de5\u5927\u56e2\u961fAFM\uff1a\u7528\u4e8e\u9ad8\u7075\u654f\u5ea6\u548c\u9ad8\u9009\u62e9\u6027\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\u4f20\u611f\u5668\u9635\u5217\u7684\u6811\u679d\u72b6\u5927\u5206\u5b50\u57fa\u9ad8\u53d1\u5149\u5171\u8f6d\u5fae\u5b54\u805a\u5408\u7269\u8584\u819c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u4e1c\u5317\u6797\u4e1a\u5927\u5b66\u9a6c\u6d2a\u4f1f\u526f\u6559\u6388<\/b><\/strong>\u3001\u674e\u658c\u6559\u6388<\/b><\/strong>\u548c\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u674e\u6653\u767d\u535a\u58eb<\/b><\/strong>\uff08<\/b><\/strong>\u5171\u540c<\/b><\/strong>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u7814\u7a76\u751f\u5218\u534e\u8c26\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u6811\u679d\u72b6\u5927\u5206\u5b50\uff08TPETCz\uff09\u3002\u91c7\u7528\u5178\u578bAIE\u57fa\u56db\u82ef\u4e59\u70ef\uff08TPE\uff09\u4f5c\u4e3a\u4f20\u611f\u6838\u5fc3\uff0c\u89e3\u51b3\u4e86ACQ\u95ee\u9898\uff0c\u66f4\u597d\u5730\u54cd\u5e94VOCs\u3002\u4ee5\u5c0f\u5206\u5b50\u91cf\u3001\u6c27\u5316\u7535\u4f4d\u4f4e\u7684\u5494\u5511\u57fa\u56e2\u4e3a\u7535\u6d3b\u6027\u652f\u94fe\uff0c\u589e\u52a0\u4e86\u5408\u6210\u8584\u819c\u4e2d\u4f20\u611f\u4e2d\u5fc3\u6838\u7684\u76f8\u5bf9\u542b\u91cf\uff0c\u540c\u65f6\u5728\u7535\u5316\u5b66\u805a\u5408\uff08EP\uff09\u8fc7\u7a0b\u4e2d\u4fdd\u62a4\u4e86TPE\u4e2d\u5fc3\u6838\u4e0d\u88ab\u6c27\u5316\u3002\u6b64\u5916\uff0c\u4e8c\u805a\u5494\u5511\u9633\u79bb\u5b50\u662fEP\u8fc7\u7a0b\u4e2d\u552f\u4e00\u7684\u4e2d\u95f4\u4ea7\u7269\uff0c\u901a\u8fc7\u8c03\u8282\u7535\u5316\u5b66\u53c2\u6570\u53ef\u4ee5\u6709\u6548\u5730\u63a7\u5236\u8868\u9762\u5f62\u8c8c\u3001\u5b54\u7ed3\u6784\u548c\u8584\u819c\u539a\u5ea6\u3002\u4e3a\u4e86\u6784\u5efa\u4e00\u79cd\u7406\u60f3\u7684\u7528\u4e8eVOC\u84b8\u6c14\u4f20\u611f\u7684CMP\u8584\u819c\u5f62\u8c8c\uff0c\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08TD-DFT\uff09\u8ba1\u7b97\u4e86TPETCz\u7684\u6784\u578b\uff0c\u5e76\u5bf9\u8584\u819c\u7684\u5b54\u9699\u7ed3\u6784\u8fdb\u884c\u4e86\u4f18\u5316\u3002\u5206\u522b\u5f97\u5230\u76f4\u5f84\u4e3a1.20 nm\u548c2.45 nm\u7684\u4e24\u4e2a\u53ef\u884c\u7684\u5b54\u7ed3\u6784\uff0c\u5f97\u5230\u7684CMP\u8584\u819c\u8868\u73b0\u51fa\u5f00-\u5173\u8367\u5149\u54cd\u5e94\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u901a\u8fc7CMP\u8584\u819c\u53ca\u5176\u5355\u4f53\u7684\u65cb\u6d82\u8584\u819c\u5efa\u7acb\u4e86\u4e00\u4e2a2D\u4f20\u611f\u9635\u5217\uff0c\u5e76\u901a\u8fc7\u7ebf\u6027\u5224\u522b\u5206\u6790\uff08LDA\uff09\u5bf918\u79cdVOC\u84b8\u6c14\u8fdb\u884c\u4e86\u7cbe\u786e\u533a\u5206\u3002\u8fd9\u662f\u76ee\u524d\u6240\u62a5\u9053\u7684\u6700\u5177\u8bc6\u522b\u80fd\u529b\u7684\u4f20\u611f\u9635\u5217\u4e4b\u4e00\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/b><\/strong>Dendrimer-Based, High-Luminescence Conjugated Microporous Polymer Films for Highly Sensitive and Selective Volatile Organic Compound Sensor Arrays<\/b><\/strong>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Adv. Funct. Mater.<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1 <\/b><\/strong>TPETCz\u7684\u5316\u5b66\u7ed3\u6784\u548cEP\u5236\u5907CMP<\/b><\/strong>\u8584<\/b><\/strong>\u819c<\/b><\/strong><\/b>\"\"<\/b><\/strong><\/p>\n

a\uff09TPETCz\u7684\u5316\u5b66\u7ed3\u6784\u548cEP\u5236\u5907CMP\u8584\u819c\u3002CE\uff1a\u5bf9\u7535\u6781\uff08\u949b\u677f\uff1a1.0\u00d71.5 cm\uff09\uff0cWE\uff1a\u5de5\u4f5c\u7535\u6781\uff08\u6c27\u5316\u94df\u9521\uff0cITO\uff1a1.0\u00d71.5 cm\uff09\uff0cRE\uff1a\u53c2\u6bd4\u7535\u6781\uff08Ag\/Ag+<\/sup>\uff0c0.1 M\uff09\u3002<\/p>\n

b\uff09\u901a\u8fc7TD-DFT\u8ba1\u7b97\u51faTPETCz\u7684\u6700\u4f73\u6784\u578b\u548cCMP\u7684\u5b54\u5f84\u3002<\/p>\n

\u56fe2 <\/b><\/strong>CMP\u8584\u819c<\/b><\/strong>\u7684\u5b54\u5f84\u5206\u5e03<\/b><\/strong>\"\"<\/p>\n

a\uff09CMP\u8584\u819c\u5236\u5907\u7684CV\u66f2\u7ebf\uff08\u626b\u63cf\u5468\u671f\uff1a10\u4e2a\u5468\u671f\uff1b\u626b\u63cf\u901f\u7387\uff1a50 mV s-1<\/sup>\uff1b\u626b\u63cf\u7535\u52bf\uff1a-0.7~1.04 V\uff09\u3002<\/p>\n

b\uff09CMP\u8584\u819c\u7684\u539a\u5ea6\u4e0e\u626b\u63cf\u5468\u671f\u4e4b\u95f4\u7684\u7ebf\u6027\u5173\u7cfb\u3002<\/p>\n

c\uff09CMP\u8584\u819c\u7684\u6c2e\u5438\u9644\/\u89e3\u5438\u66f2\u7ebf\u3002\u00a0<\/p>\n

d\uff09CMP\u8584\u819c\u7684\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\u3002<\/p>\n

\u56fe3<\/b><\/strong>\u00a0<\/b><\/strong>CMP\u8584\u819c\u7684\u8367\u5149\u54cd\u5e94\u4e0eVOC\u84b8\u6c14\u6d53\u5ea6\u7684\u5173\u7cfb<\/b><\/strong>\"\"<\/p>\n

\u56fe4 <\/b><\/strong>\u5404\u79cdVOC\u84b8\u6c14\u7684<\/b><\/strong>HOMO-LUMO\u80fd\u91cf\u56fe<\/b><\/strong>\"\"<\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>\u7531CMP\u8584\u819c\u548c\u65cb\u6d82\u819c\u7ec4\u6210\u7684\u8367\u5149\u9635\u5217\u76842D LDA\u56fe<\/b><\/strong>\"\"<\/p>\n

\u7531CMP\u8584\u819c\u548c\u65cb\u6d82\u8584\u819c\u7ec4\u6210\u7684\u8367\u5149\u9635\u5217\u76842D LDA\u56fe\u7cbe\u786e\u533a\u5206\u4e8618\u79cdVOC\u84b8\u6c14\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n

\u603b\u4e4b\uff0c\u901a\u8fc7\u7b80\u5355\u6709\u6548\u7684EP\u65b9\u6cd5\u6210\u529f\u5236\u5907\u4e86\u5177\u6709AIE\u7279\u6027\u7684\u9ad8\u53d1\u5149CMP\u8584\u819c\u3002\u5229\u7528EP\u7684\u6280\u672f\u4f18\u70b9\uff0c\u901a\u8fc7\u8c03\u8282\u7535\u5316\u5b66\u53c2\u6570\u53ef\u4ee5\u7cbe\u786e\u5730\u63a7\u5236CMP\u8584\u819c\u7684\u5f62\u8c8c\u548c\u539a\u5ea6\u3002\u6240\u5f97\u7684CMP\u8584\u819c\u5177\u6709\u56fa\u6709\u7684\u5fae\u5b54\u7ed3\u6784\uff0cBET\u6bd4\u8868\u9762\u79ef\u4e3a1042.5 m2<\/sup>\u00a0g\u22121<\/sup>\u3002\u4f18\u5316\u540e\u5f97\u5230\u7684CMP\u8584\u819c\u4f5c\u4e3aVOC\u84b8\u6c14\u7684\u4f20\u611f\u5e73\u53f0\uff0c\u53d1\u73b0CMP\u8584\u819c\u5bf9VOC\u84b8\u6c14\u9ad8\u5ea6\u654f\u611f\u3002\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\uff0c\u6df1\u5165\u7814\u7a76\u4e86CMP\u8584\u819c\u5bf9\u4e0d\u540cVOC\u7684\u8367\u5149\u54cd\u5e94\u3002\u6b64\u5916\uff0c\u6839\u636eCMP\u819c\u548c\u65cb\u6d82\u8584\u819c\u5bf9VOC\u84b8\u6c14\u7684\u4e0d\u540c\u8367\u5149\u54cd\u5e94\u6784\u5efa\u4e86\u8367\u5149\u9635\u5217\u4f20\u611f\u5668\uff0c\u5e76\u901a\u8fc7LDA\u5206\u6790\u5b9e\u73b0\u4e8618\u79cdVOC\u7684\u9009\u62e9\u6027\u68c0\u6d4b\u3002\u8fd9\u662fVOC\u6325\u53d1\u6027\u5316\u5408\u7269\u7279\u5f02\u6027\u68c0\u6d4b\u7684\u6700\u4f73\u62a5\u9053\u4e4b\u4e00\uff0c\u5176\u8367\u5149\u9635\u5217\u5177\u6709\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Dendrimer<\/u>–<\/u>Based, High<\/u>–<\/u>Luminescence Conjugated Microporous Polymer Films for Highly Sensitive and Selective Volatile Organic Compound Sensor Arrays<\/u><\/a>\uff08Adv. Funct. Mater.\uff0c 2020\uff0cDOI:10.1002\/adfm.201910275\uff09<\/p>\n

\u672c\u6587\u7531\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\u3002<\/p>\n

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