{"id":196482,"date":"2020-02-28T06:45:48","date_gmt":"2020-02-27T22:45:48","guid":{"rendered":"\/\/m.iemloyee.com\/?p=196482"},"modified":"2020-02-27T20:45:59","modified_gmt":"2020-02-27T12:45:59","slug":"%e9%80%9f%e7%9c%8b%ef%bc%81%e5%b7%a5%e4%bd%9c%e5%ad%a6%e4%b9%a0%e4%b8%a4%e4%b8%8d%e8%af%af%ef%bc%8cmofs%e8%bf%91%e6%9c%9f%e9%a1%b6%e5%88%8a%e7%a0%94%e7%a9%b6%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=196482","title":{"rendered":"\u901f\u770b\uff01\u5de5\u4f5c\u5b66\u4e60\u4e24\u4e0d\u8bef\uff0cMOFs\u8fd1\u671f\u9876\u520a\u7814\u7a76\u901f\u89c8"},"content":{"rendered":"<p>MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u4e09\u7ef4\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5728\u50ac\u5316\u3001\u50a8\u80fd\u548c\u5206\u79bb\u7b49\u7b49\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u81ea20\u4e16\u7eaa90\u5e74\u4ee3\uff0c\u7b2c\u4e00\u4ee3MOFs\u6750\u6599\u88ab\u5408\u6210\u51fa\u6765\uff0cMOFs\u5df2\u6210\u4e3a\u65e0\u673a\u5316\u5b66\u3001\u6709\u673a\u5316\u5b66\u7b49\u591a\u4e2a\u5316\u5b66\u5206\u652f\u7684\u91cd\u8981\u7814\u7a76\u65b9\u5411\u3002\u7b14\u8005\u5b9a\u671f\u68b3\u7406\u8fd1\u671f\u6750\u6599\u7c7b\u7cfb\u5217\u520a\u4e2dMOFs\u7684\u76f8\u5173\u6587\u7ae0\uff0c\u4e00\u8d77\u4e86\u89e3\u4e0b\u76f8\u5173\u7814\u7a76\uff01<\/p>\n<p><strong><b>1\u3001\u57fa\u4e8e<\/b><\/strong><strong><b>MOF\u548c\u79bb\u5b50\u6db2\u4f53<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d<\/b><\/strong><strong><b>\u5145\u653e<\/b><\/strong><strong><b>\u7535\u52a8\u529b\u5b66<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>N<\/b><\/strong><strong><b>ature<\/b><\/strong><strong><b>\u00a0Materials<\/b><\/strong><\/p>\n<p>\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u51af\u5149\u6559\u6388\u56e2\u961f\u548c\u4f26\u6566\u5e1d\u56fd\u7406\u5de5\u5b66\u9662AlexeiA. Kornyshev\u6559\u6388\u56e2\u961f\u5408\u4f5c\u91c7\u7528\u6052\u7535\u4f4d\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u65b9\u6cd5\uff0c\u5206\u6790\u4e86\u7531\u5bfc\u7535\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7535\u6781\u548c\u79bb\u5b50\u6db2\u4f53\u7ec4\u6210\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u53cc\u5c42\u7ed3\u6784\u548c\u7535\u5bb9\u6027\u80fd\u3002\u5206\u5b50\u6a21\u578b\u9610\u660e\u4e86\u79bb\u5b50\u5728\u6781\u5316\u591a\u5b54MOFs\u4e2d\u7684\u4f20\u8f93\u548c\u9a7b\u7559\u65b9\u5f0f\uff0c\u5e76\u9884\u6d4b\u4e86\u76f8\u5e94\u7684\u7535\u4f4d\u76f8\u5173\u7535\u5bb9\u7684\u7279\u5f81\u5f62\u72b6\u3002\u91c7\u7528\u4f20\u8f93\u7ebf\u6a21\u578b\u8868\u5f81\u5145\u7535\u52a8\u529b\u5b66\uff0c\u8fdb\u4e00\u6b65\u4ece\u6a21\u62df\u5f97\u5230\u7684\u7eb3\u7c73\u7ea7\u6570\u636e\u5bf9\u8be5\u7c7b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5bb9\u6027\u6027\u80fd\u8fdb\u884c\u5b8f\u89c2\u8bc4\u4ef7\u3002\u8fd9\u4e9b\u6a21\u62df\u5206\u6790\u7684\u7ed3\u679c\u5f97\u5230\u4e86\u5b8f\u89c2\u7535\u5316\u5b66\u6d4b\u91cf\u7684\u652f\u6301\u3002\u8fd9\u79cd\u4ece\u7eb3\u7c73\u7ea7\u5230\u5b8f\u89c2\u7ea7\u7684\u8054\u5408\u7814\u7a76\u8868\u660e\uff0cMOF\u8d85\u7ea7\u7535\u5bb9\u5668\u6709\u53ef\u80fd\u5b9e\u73b0\u524d\u6240\u672a\u6709\u7684\u9ad8\u5bb9\u91cf\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6\u3002\u57fa\u4e8eMOF \/ RTIL\u7684\u7535\u5bb9\u5668\u8868\u73b0\u51fa\u4f18\u4e8e\u5927\u591a\u6570\u78b3\u57fa\u8bbe\u5907\u7684\u6027\u80fd\uff0c\u8fd9\u4e3a\u8bbe\u8ba1\u5177\u6709\u9ad8\u80fd\u91cf\u548c\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u5e26\u6765\u4e86\u65b0\u7684\u5e0c\u671b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMolecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Materials\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41563-019-0598-7<\/p>\n<p>\u56fe1\u00a0\u57fa\u4e8eMOF\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5206\u5b50\u6a21\u62df\u539f\u7406\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196483 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72471-31.png\" alt=\"\" width=\"680\" height=\"448\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72471-31.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72471-31-300x198.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>2\u3001<\/b><\/strong><strong><b>\u9492<\/b><\/strong><strong><b>\u57fa<\/b><\/strong><strong><b>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7684\u9009\u62e9\u6027\u6c2e\u5438\u9644<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>N<\/b><\/strong><strong><b>ature<\/b><\/strong><strong><b>\u00a0Materials<\/b><\/strong><\/p>\n<p>\u5de5\u4e1a\u5316\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u5e38\u5e38\u4f1a\u4ea7\u751f\u5f88\u591a\u5177\u6709\u03c0-\u9178\u6027\u7684\u6c14\u4f53\uff0c\u5438\u9644\u5242\u80fd\u591f\u9009\u62e9\u6027\u5730\u4e0e\u8fd9\u4e9b\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u4f7f\u91cd\u8981\u7684\u5316\u5b66\u5206\u79bb\u6210\u4e3a\u53ef\u80fd\u3002\u751f\u7269\u4f53\u7cfb\u4e2d\u5b58\u5728\u5f88\u591a\u6613\u4e8e\u63a5\u8fd1\u7684\u8fd8\u539f\u91d1\u5c5e\u4f4d\u70b9\u80fd\u591f\u901a\u8fc7\u53cd\u9988\u03c0\u952e\u7684\u5f62\u5f0f\u4e0eN<sub>2<\/sub>\u8fd9\u4e9b\u6c14\u4f53\u7ed3\u5408\u5e76\u6fc0\u6d3b\u5176\u8f83\u5f31\u7684\u03c0\u9178\u6027\uff0c\u5982\u679c\u80fd\u591f\u5c06\u7c7b\u4f3c\u7684\u7ed3\u6784\u5f15\u5165\u5230\u591a\u5b54\u6750\u6599\u57fa\u8d28\u4e2d\u5c31\u53ef\u4ee5\u4ea7\u751f\u7c7b\u4f3c\u7684\u5438\u9644\u673a\u5236\u5bf9\u8fd9\u4e9b\u5de5\u4e1a\u5e9f\u6c14\u8fdb\u884c\u5206\u79bb\u3002\u5728\u6b64\uff0c\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Jeffrey R.Long\u6559\u6388\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u542b\u6709\u88f8\u9732\u4e8c\u4ef7\u9492\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff0c\u8fd9\u79cdV(\u2161)\u6d3b\u6027\u4e2d\u5fc3\u80fd\u591f\u4f5c\u7528\u4e8e\u03c0-\u9178\u6027\u6c14\u4f53\u63d0\u4f9b\u53cd\u9988\u7535\u5b50\u6765\u8fdb\u884c\u6c14\u4f53\u5438\u9644\u548c\u5206\u79bb\u3002\u8fd9\u79cd\u65b0\u578b\u5438\u9644\u673a\u5236\uff0c\u52a0\u4e0a\u9ad8\u6d53\u5ea6\u7684\u6709\u6548\u5438\u9644\u4f4d\u70b9\uff0c\u53ef\u4ee5\u8bb0\u5f55N<sub>2<\/sub>\u5438\u9644\u5bb9\u91cf\u548c\u4ece\u4e0eCH<sub>4<\/sub>\u7684\u6df7\u5408\u7269\u4e2d\u53bb\u9664N<sub>2<\/sub>\u7684\u9ad8\u9009\u62e9\u6027\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u5bcc\u542b\u53cd\u9988\u952e\u7684\u4f53\u7cfb\u5bf9\u4e8e\u9ad8\u6e29\u4e0b\u70ef\u70c3\u548c\u77f3\u8721\u7684\u5206\u79bb\u4e5f\u5341\u5206\u6709\u6548\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u5c06\u03c0-\u78b1\u6027\u91d1\u5c5e\u6d3b\u6027\u4e2d\u5fc3\u7ed3\u5408\u5230\u591a\u5b54\u6750\u6599\u4e2d\u7684\u65b0\u7b56\u7565\u4e3a\u5f00\u53d1\u65b0\u578b\u5438\u9644\u6750\u6599\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSelective nitrogen adsorption via backbonding in a metal\u2013organic framework with exposed vanadium sites\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Materials\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41563-019-0597-8<\/p>\n<p>\u56fe2\u00a0N<sub>2<\/sub>\/CH<sub>4<\/sub>\u9009\u62e9\u6027\u548cN<sub>2<\/sub>\u5438\u9644\u53ef\u9006\u6027\u7684\u8bc4\u4ef7<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196484 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72472-26.png\" alt=\"\" width=\"680\" height=\"199\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72472-26.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72472-26-300x88.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>3\u3001<\/b><\/strong><strong><b>MOF<\/b><\/strong><strong><b>\u8584\u7247\u5305\u57cb<\/b><\/strong><strong><b>\u8d85\u7ec6\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\u5b9e\u73b0\u9ad8\u6548\u7684\u7535\u50ac\u5316\u6790\u6c27<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>ACS NANO<\/b><\/strong><\/p>\n<p>\u5f00\u53d1\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\u6765\u964d\u4f4e\u8fc7\u7535\u4f4d\u5bf9\u52a0\u901f\u7f13\u6162\u7684\u6c27\u6f14\u5316\u53cd\u5e94(OER)\u8fc7\u7a0b\u81f3\u5173\u91cd\u8981\u3002\u5f00\u53d1\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\u6765\u964d\u4f4e\u8fc7\u7535\u4f4d\u5bf9\u52a0\u901f\u7f13\u6162\u7684\u6c27\u6f14\u5316\u53cd\u5e94(OER)\u8fc7\u7a0b\u81f3\u5173\u91cd\u8981\u3002\u5728\u6b64\uff0c\u5357\u6d0b\u7406\u5de5\u5927\u5b66Zhou kun\u6559\u6388\u7b49\u4eba\u8bc1\u660e\u4e86\u8d85\u8584\u5f02\u8d28\u7eb3\u7c73\u8584\u7247\u662f\u4e00\u79cd\u6709\u524d\u9014\u7684OER\u7535\u50ac\u5316\u5242\u6750\u6599\uff0c\u7531\u8d85\u7ec6CoFeO<sub>x<\/sub>\u7eb3\u7c73\u9897\u7c92\u548c\u5355\u5206\u5b50\u5c42\u7684CoN<sub>4<\/sub>\u57faMOF\u57fa\u8d28\u7ec4\u6210\u3002\u8fd9\u6837\u7684\u65e0\u673a\u7eb3\u7c73\u7c92\u5b50\u7684\u5d4c\u5165MOF\u6676\u683c\u4e2d\u5728CoFeO<sub>x<\/sub>\/MOF\u4e2d\u5f62\u6210\u4e86\u91d1\u5c5eCo\u6d3b\u6027\u4f4d\u70b9\u3002\u7ed3\u6784\u8868\u5f81\u548c\u5206\u6790\u8868\u660e\uff0c\u754c\u9762Co\u5177\u6709\u8f83\u9ad8\u7684\u4ef7\u6001\uff0c\u6539\u53d8\u4e86CoN<sub>4<\/sub>\u754c\u9762Co\u7684\u4e09\u7ef4\u7535\u5b50\u6784\u578b\u3002\u6b64\u5916\uff0c\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86OER\u7684\u754c\u9762Co\u4f4d\u70b9\u7684\u9ad8\u6d3b\u6027\u3002\u7535\u5316\u5b66\u7814\u7a76\u8bc1\u5b9e\uff0c\u6c89\u79ef\u5728\u78b3\u5e03\u4e0a\u7684\u8d85\u8584\u975e\u5747\u76f8\u7eb3\u7c73\u8584\u7247\u80fd\u591f\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA cm<sup>-2<\/sup>\u7684\u60c5\u51b5\u4e0b\uff0c\u4ee5232 mV\u7684\u4f4e\u8fc7\u7535\u4f4d\u83b7\u5f97\u4f18\u5f02\u7684\u7535\u50ac\u5316OER\u6027\u80fd\uff0c\u5177\u6709\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5f00\u53d1\u5177\u6709\u9ad8\u5ea6\u6d3b\u6027\u7684\u65e0\u673a\u5355\u5143\u548cMOFs\u754c\u9762\u7684\u8d85\u8584\u8d85\u5206\u5b50\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cEmbedding Ultrafine Metal Oxide Nanoparticles in Monolayered Metal-Organic Framework Nanosheets Enables Efficient Electrocatalytic Oxygen Evolution\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS NANO\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/acsnano.9b08458<\/p>\n<p>\u56fe3\u00a0PCB\u3001M-PCB\u53caM-PCBN\u7684\u5236\u5907\u4e0e\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196485 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-25.png\" alt=\"\" width=\"680\" height=\"742\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-25.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72473-25-275x300.png 275w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>4\u3001\u751f\u7269\u8d28<\/b><\/strong><strong><b>\u6df7\u5408\u6c34\u51dd\u80f6\u84b8\u53d1\u5668<\/b><\/strong><strong><b>\u7528\u4e8e\u9ad8\u6548\u592a\u9633\u80fd\u51c0\u6c34<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>A<\/b><\/strong><strong><b>M<\/b><\/strong><\/p>\n<p>\u592a\u9633\u80fd\u84b8\u6c7d\u53d1\u7535\u5728\u6c61\u6c34\u5904\u7406\u548c\u6d77\u6c34\u6de1\u5316\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u80fd\u91cf\u8f6c\u6362\u548c\u5229\u7528\u6548\u7387\u3002\u7136\u800c\uff0c\u5728\u5b9e\u73b0\u5feb\u901f\u84b8\u53d1\u7387\u548c\u9ad8\u8d28\u91cf\u7684\u6c34\u4ee5\u53ca\u4f4e\u6210\u672c\u90e8\u7f72\u4ee5\u63d0\u4f9b\u53ef\u6301\u7eed\u7684\u592a\u9633\u80fd\u9a71\u52a8\u7684\u51c0\u6c34\u5668\u7cfb\u7edf\u65b9\u9762\uff0c\u4ecd\u7136\u5b58\u5728\u6280\u672f\u5dee\u8ddd\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u7684\u4f59\u6842\u534e\u6559\u6388\u56e2\u961f\u5c06\u4e00\u79cd\u5929\u7136\u4e30\u5bcc\u7684\u751f\u7269\u8d28\u9b54\u828b\u8461\u7518\u9732\u805a\u7cd6\uff0c\u4ee5\u53ca\u6613\u4e8e\u5236\u9020\u7684\u94c1\u57faMOF\u884d\u751f\u7684\u5149\u70ed\u7eb3\u7c73\u9897\u7c92\u5f15\u5165\u805a\u4e59\u70ef\u9187\u7f51\u7edc\uff0c\u4ee5\u4f4e\u6210\u672c\u7684\u65b9\u5f0f\u5efa\u9020\u6df7\u5408\u6c34\u51dd\u80f6\u84b8\u53d1\u5668\u3002\u6df7\u5408\u5f0f\u6c34\u51dd\u80f6\u84b8\u53d1\u5668\u5177\u6709\u8f93\u9001\u6c34\u91cf\u5145\u8db3\u3001\u6709\u6548\u6c34\u6d3b\u5316\u3001\u6297\u76d0\u57a2\u7b49\u4f18\u70b9\uff0c\u5728\u4e00\u4e2a\u9633\u5149\u4e0b\u53ef\u63d0\u4f9b\u9ad8\u8fbe3.2 kg m<sup>-2<\/sup>\u00a0h<sup>-1<\/sup>\u7684\u9ad8\u6c34\u84b8\u53d1\u7387\uff0c\u80fd\u91cf\u6548\u7387\u7ea6\u4e3a90\uff05\u3002\u66f4\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u91cd\u91d1\u5c5e\u79bb\u5b50\u901a\u8fc7\u5f62\u6210\u6c22\u952e\u5e76\u4e0e\u6c34\u51dd\u80f6\u4e2d\u8fc7\u91cf\u7684\u7f9f\u57fa\u87af\u5408\u800c\u88ab\u6709\u6548\u53bb\u9664\u3002\u9884\u8ba1\u8fd9\u9879\u7814\u7a76\u4e3a\u4e00\u79cd\u53ef\u90e8\u7f72\u7684\u3001\u5177\u6709\u6210\u672c\u6548\u76ca\u7684\u592a\u9633\u80fd\u51c0\u6c34\u5668\u7cfb\u7edf\u63d0\u4f9b\u4e86\u65b0\u7684\u53ef\u80fd\u6027\uff0c\u8be5\u51c0\u6c34\u5668\u5177\u6709\u53ef\u9760\u7684\u6c34\u8d28\uff0c\u7279\u522b\u662f\u5bf9\u7ecf\u6d4e\u538b\u529b\u5927\u7684\u793e\u533a\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBiomass-Derived Hybrid Hydrogel Evaporators for Cost-Effective Solar Water Purification\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adma.201907061<\/p>\n<p>\u56fe4\u00a0\u6df7\u5408\u5f0f\u6c34\u51dd\u80f6\u84b8\u53d1\u5668\u7684\u7814\u5236\u4e0e\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196486 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-24.png\" alt=\"\" width=\"680\" height=\"697\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-24.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72474-24-293x300.png 293w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>5\u3001<\/b><\/strong><strong><b>\u4e0a\u8f6c\u6362<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong><strong><b>\u8054\u5408\u5149\u52a8\u529b\/\u5316\u5b66<\/b><\/strong><strong><b>\/<\/b><\/strong><strong><b>\u514d\u75ab\u6cbb\u7597<\/b><\/strong><strong><b>\u7f3a<\/b><\/strong><strong><b>\u6c27\u6027\u80bf\u7624<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>J<\/b><\/strong><strong><b>ACS<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>MOFs\u4f5c\u4e3a\u7eb3\u7c73\u70ed\u654f\u5316\u5242(nPSs)\u5728\u5149\u52a8\u529b\u6cbb\u7597(PDT)\u4e2d\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u7136\u800c\uff0c\u5728PDT\u4e2d\u4f7f\u7528\u8fd9\u79cdMOFs\u53d7\u5230\u77ed\u6ce2\u957f\u5149\u7684\u7ec4\u7ec7\u7a7f\u900f\u6df1\u5ea6\u8f83\u6d45\u548c\u6c27\u4f9d\u8d56\u673a\u5236\u7684\u9650\u5236\uff0c\u4f7f\u5176\u4e0d\u9002\u7528\u4e8e\u7f3a\u6c27\u6027\u80bf\u7624\u3002\u5728\u6b64\uff0c\u4e3a\u4e86\u514b\u670d\u8fd9\u4e9b\u5c40\u9650\u6027\uff0c\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u674e\u4e50\u4e50\u6559\u6388\u7b49\u5408\u7406\u8bbe\u8ba1\u4e86\u6838-\u58f3\u4e0a\u8f6c\u6362\u7eb3\u7c73\u9897\u7c92@\u535f\u5549\u5316MOFs (UCSs)\u7528\u4e8e\u8054\u5408\u6cbb\u7597\u7f3a\u6c27\u80bf\u7624\u3002\u901a\u8fc7\u6761\u4ef6\u8868\u9762\u5de5\u7a0b\u548c\u968f\u540e\u7684\u79cd\u5b50\u4ecb\u5bfc\u751f\u957f\u7b56\u7565\uff0c\u5408\u6210\u4e86\u9ad8\u4ea7\u91cf\u7684UCSs\u3002\u8fd9\u79cd\u5f02\u8d28\u7ed3\u6784\u5141\u8bb8\u6709\u6548\u7684\u80fd\u91cf\u4eceUCNP\u5185\u6838\u8f6c\u79fb\u5230MOF\u58f3\u5c42\uff0c\u8fd9\u4f7f\u5f97\u8fd1\u7ea2\u5916(NIR)\u5149\u89e6\u53d1\u4ea7\u751f\u7ec6\u80de\u6bd2\u6027\u6d3b\u6027\u6c27\u3002\u5c06\u7f3a\u6c27\u6fc0\u6d3b\u7684\u524d\u836ftirapazamine (TPZ)\u5305\u5c01\u5728\u5f02\u7ed3\u6784MOF\u58f3\u7684\u7eb3\u7c73\u5b54\u4e2d\uff0c\u5f97\u5230\u6700\u7ec8\u7684\u7ed3\u6784TPZ\/UCSs\u3002\u7814\u7a76\u8bc1\u660eTPZ\/UCSs\u53ef\u4ee5\u901a\u8fc7\u8fd1\u7ea2\u5916\u5149\u7167\u5c04PDT\u548c\u7f3a\u6c27\u6fc0\u6d3b\u5316\u7597\u7684\u7ed3\u5408\u6765\u5b9e\u73b0\u4f53\u5185\u5916\u764c\u75c7\u6cbb\u7597\u7684\u6539\u5584\u3002\u6b64\u5916,\u00a0\u7eb3\u7c73\u5e73\u53f0\u4e0e\u6297\u7a0b\u5e8f\u6027\u6b7b\u4ea1\u914d\u4f531\u6cbb\u7597\u7684\u6574\u5408\u4fc3\u8fdb\u4e86\u901a\u8fc7\u80bf\u7624\u7ec6\u80de\u6bd2\u6027T\u7ec6\u80de\u7684\u7279\u5f02\u6027\u80bf\u7624\u6d78\u6da6\u4f5c\u7528\u6765\u5b8c\u5168\u6291\u5236\u80bf\u7624\u7684\u751f\u6210\u3002\u603b\u4e4b\uff0c\u8fd9\u9879\u5de5\u4f5c\u5f3a\u8c03\u4e86\u4e00\u4e2a\u5f3a\u5927\u7684\u7eb3\u7c73\u5e73\u53f0\uff0c\u5c06\u8fd1\u7ea2\u5916\u5149\u89e6\u53d1PDT\u548c\u7f3a\u6c27\u6fc0\u6d3b\u5316\u7597\u4e0e\u514d\u75ab\u6cbb\u7597\u7ed3\u5408\u8d77\u6765\uff0c\u4ee5\u514b\u670d\u76ee\u524d\u80bf\u7624\u6cbb\u7597\u7684\u5c40\u9650\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cEngineering of Upconverted Metal\u2013Organic Frameworks for Near-Infrared Light-Triggered CombinationalPhotodynamic\/Chemo-\/Immunotherapy against Hypoxic Tumors\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/jacs.9b12788<\/p>\n<p>\u56fe5\u00a0TPZ\/UCSs\u7684\u7ed3\u6784\u793a\u610f\u56fe\u53ca\u5176\u5728\u80bf\u7624\u6cbb\u7597\u4e2d\u7684\u5e94\u7528<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196487 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72475-23.png\" alt=\"\" width=\"680\" height=\"653\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72475-23.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72475-23-300x288.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>6\u3001<\/b><\/strong><strong><b>\u4e00\u79cd\u7528\u4e8e\u6c14\u4f53\u5206\u79bb\u7684MOF\u73bb\u7483\u8584\u819c<\/b><\/strong><strong><b>\uff5cAngew<\/b><\/strong><strong><b>.<\/b><\/strong><\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u73bb\u7483\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u819c\u5236\u9020\u6750\u6599\uff0c\u56e0\u4e3a\u5b83\u5177\u6709\u663e\u8457\u7684\u591a\u5b54\u6027\uff0c\u6613\u4e8e\u52a0\u5de5\uff0c\u6700\u91cd\u8981\u7684\u662f\uff0c\u5b83\u5177\u6709\u6d88\u9664\u591a\u6676MOF\u819c\u4e0d\u53ef\u907f\u514d\u7684\u6676\u754c\u7684\u6f5c\u529b\u3002\u5728\u6b64\uff0c\u5929\u6d25\u5927\u5b66\u59dc\u5fe0\u4e49\u3001\u6f58\u798f\u751f\u6559\u6388\u56e2\u961f\u548c\u5b81\u6ce2\u5927\u5b66\u674e\u781a\u7855\u3001\u91d1\u82b1\u6559\u6388\u5408\u4f5c\u5f00\u53d1\u4e86\u4e00\u79cdZIF-62 MOF\u73bb\u7483\u819c\uff0c\u5e76\u5229\u7528\u5176\u56fa\u6709\u7684\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u3002\u91c7\u7528\u539f\u4f4d\u6eb6\u5242\u70ed\u5408\u6210\u7684\u591a\u6676ZIF-62\u819c\u5728\u591a\u5b54\u9676\u74f7\u8f7d\u4f53\u4e0a\u8fdb\u884c\u7194\u89e3\u5904\u7406\uff0c\u5236\u5907\u4e86MOF\u73bb\u7483\u819c\u3002\u7194\u878d\u7684ZIF-62\u76f8\u6e17\u900f\u5230\u8f7d\u4f53\u7684\u7eb3\u7c73\u5b54\u4e2d\uff0c\u6d88\u9664\u4e86\u73bb\u7483\u819c\u4e2d\u6676\u95f4\u7f3a\u9677\u7684\u5f62\u6210\u3002MOF\u819c\u7684\u5206\u5b50\u7b5b\u5206\u79bb\u80fd\u529b\u7ecf\u73bb\u7483\u5316\u540e\u660e\u663e\u589e\u5f3a\uff0cMOF\u73bb\u7483\u819c\u4e2dH2\/CH4\u3001CO2\/N2\u548cCO2\/CH4\u7684\u6df7\u5408\u7269\u7684\u5206\u79bb\u56e0\u5b50\u5206\u522b\u4e3a50.7\u300134.5\u548c36.6\uff0c\u8fdc\u8fdc\u8d85\u8fc7\u4e86Robeson\u7684\u4e0a\u9650\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA MOF Glass Membrane for Gas Separation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/ange.201915807<\/p>\n<p>\u56fe6\u00a0\u00a0ZIF-62\u6676\u4f53\u7ed3\u6784\u3001MOF\u73bb\u7483\u7684\u7ed3\u6784\u793a\u610f\u56fe\u53ca\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196488 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72476-20.png\" alt=\"\" width=\"680\" height=\"817\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72476-20.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72476-20-250x300.png 250w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>7\u3001<\/b><\/strong><strong><b>\u8d85\u758f\u6c34\u6027<\/b><\/strong><strong><b>\u5f15\u5165<\/b><\/strong><strong><b>\u5230\u4ecb\u5b54<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4e2d\u7684\u5c01\u88c5\u91cd\u6392\u7b56\u7565<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>atter<\/b><\/strong><\/p>\n<p>\u8bbe\u8ba1\u5177\u6709\u8868\u9762\u8d85\u758f\u6c34\u6027\u3001\u9ad8\u8868\u9762\u79ef\u3001\u5927\u800c\u5747\u5300\u7684\u5b54\u5f84\u4ee5\u53ca\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u7684\u6750\u6599\u662f\u5408\u6210\u5316\u5b66\u5bb6\u6240\u9762\u4e34\u7684\u4e00\u4e2a\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\u7684\u9886\u57df\u3002\u5728\u6b64\uff0c\u6211\u5fb7\u514b\u8428\u65afA&amp;M\u5927\u5b66\u7684\u5468\u5b8f\u624d\u6559\u6388\u7b49\u4eba\u5c55\u793a\u4e86\u4e00\u79cd\u751f\u7269\u542f\u53d1\u7684\u5c01\u88c5\u91cd\u6392\u7b56\u7565\uff0c\u901a\u8fc7\u9009\u62e9\u6027\u5730\u4fee\u9970\u5185\u90e8\u6676\u683c\u91cd\u6392\u7684\u4ecb\u5b54\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u7684\u5916\u8868\u9762\u6765\u6784\u5efa\u8d85\u758f\u6c34\u4ecb\u5b54MOF\u3002\u7f3a\u9677\u591a\u5b54\u6750\u6599AlTz-53\u7684\u8868\u9762\u901a\u8fc7\u758f\u6c34\u70f7\u57fa\u94fe\u7684\u70b9\u51fb\u53cd\u5e94\u8fdb\u884c\u4e86\u521d\u6b65\u6539\u6027\uff0c\u968f\u540e\uff0c\u5185\u90e8\u6846\u67b6\u5728\u6eb6\u5242\u89e3\u5438\u4f5c\u7528\u4e0b\u8fdb\u884c\u6676\u683c\u91cd\u6392\uff0c\u5bfc\u81f4\u5185\u90e8\u5b54\u9699\u7387\u548c\u6750\u6599\u7ed3\u6676\u5ea6\u663e\u8457\u63d0\u9ad8\u3002\u529f\u80fd\u5316\u540e\u7684AlTz-68\u8868\u9762\u5177\u6709\u8d85\u758f\u6c34\u6027\uff0c\u6c34\u63a5\u89e6\u89d2\u4e3a173.6\u00ba\u3002AlTz-68-C18\u662f\u5728\u76ee\u524d\u6240\u6709\u62a5\u9053\u7684\u8d85\u758f\u6c34\u9aa8\u67b6\u6750\u6599\u4e2d\uff0c\u8868\u73b0\u51fa\u6700\u5927\u7684BET\u8868\u9762\u79ef\u4e4b\u4e00\u7684\u6750\u6599\u3002\u6b64\u5916\uff0c\u8bc1\u660e\u4e86\u8d85\u758f\u6c34\u7684AlTz-68-C18\u548c\u76f8\u5e94\u7684\u6539\u6027\u6d77\u7ef5\u5728\u6cb9\u6c34\u5206\u79bb\u65b9\u9762\u90fd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAn Encapsulation-Rearrangement Strategy to Integrate\u00a0Superhydrophobicity into Mesoporous Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Matter\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1016\/j.matt.2020.01.015<\/p>\n<p>\u56fe7\u00a0\u8d85\u758f\u6c34MOF\u7684\u5c01\u88c5\u91cd\u6392\u7b56\u7565<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196489 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-15.png\" alt=\"\" width=\"680\" height=\"679\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-15.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-15-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72477-15-300x300.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>8\u3001<\/b><\/strong><strong><b>\u7528\u4e8e\u6469\u64e6\u7535\u7eb3\u7c73\u53d1\u7535\u673a\u7684<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><sub><b>S<\/b><\/sub><\/strong><strong><b>\u6210\u5458<\/b><\/strong><strong><b>\uff5cA<\/b><\/strong><strong><b>FM <\/b><\/strong><\/p>\n<p>\u6cb8\u77f3\u578b\u54aa\u5511\u9aa8\u67b6(ZIF)\u662fMOF\u4e2d\u7684\u5176\u4e2d\u4e00\u5458\uff0c\u4e0e\u5176\u4ed6MOFs\u76f8\u6bd4\uff0c\u63d0\u4f9b\u4e86\u4f18\u5f02\u7684\u5316\u5b66\u548c\u70ed\u7a33\u5b9a\u6027\u4f18\u52bf\u3002\u6469\u64e6\u7535\u7cfb\u5217\u4e3b\u8981\u7531\u5c11\u91cf\u91d1\u5c5e\u548c\u805a\u5408\u7269\u7ec4\u6210\uff0c\u4e0d\u9002\u5408\u5f00\u53d1\u9ad8\u9009\u62e9\u6027\u548c\u7279\u5f02\u6027\u7684\u4f20\u611f\u5668\u3002\u56e0\u6b64\u5f00\u53d1\u591a\u529f\u80fd\u3001\u53ef\u8c03\u8c10\u7684\u6750\u6599\u5bf9\u6269\u5c55\u6469\u64e6\u7535\u52a8\u7eb3\u7c73\u53d1\u7535\u673a(TENG)\u7684\u5e94\u7528\u81f3\u5173\u91cd\u8981\u3002\u97e9\u56fd\u6d4e\u5dde\u5927\u5b66\u7684Sang-Jae Kim\u6559\u6388\u62a5\u9053\u4e86\u57fa\u4e8eZIF\u4e9a\u79d1\u6750\u6599(ZIF-7\u3001ZIF-9\u3001ZIF-11\u3001ZIF-12)\u7684TENG\u3002\u8868\u9762\u7c97\u7cd9\u5ea6\u3001\u7ed3\u6784\u3001\u5f62\u6001\u548c\u8868\u9762\u7535\u4f4d\u5206\u6790\u63ed\u793a\u4e86ZIF\u5bb6\u65cf\u6210\u5458\u7684\u8be6\u7ec6\u7279\u5f81\u3002ZIFs\u548cKapton\u88ab\u7528\u4f5cZIF-TENG\u5236\u9020\u7684\u6469\u64e6\u7535\u5c42\u3002\u6587\u7ae0\u8be6\u7ec6\u5206\u6790\u4e86\u8bbe\u5907\u7684\u7535\u6c14\u6027\u80fd(\u7535\u538b\u3001\u7535\u6d41\u3001\u5145\u7535\u3001\u7a33\u5b9a\u6027\u3001\u8d1f\u8f7d\u5339\u914d\u5206\u6790\u3001\u7535\u5bb9\u5145\u7535)\u3002ZIF-7 TENG\u5728\u5782\u76f4\u63a5\u89e6\u5206\u79bb\u6a21\u5f0f\u4e0b\u751f\u6210\u8f93\u51fa\u6700\u9ad8\u768460 V\u7535\u538b\u548c1.1\u00b5A\u7535\u6d41\uff0c\u901a\u8fc7ZIF-7 TENG\u8f93\u51fa\u7684\u7535\u5bb9\u5145\u7535\uff0c\u53ef\u4ee5\u6210\u529f\u9a71\u52a8\u4e86\u5404\u79cd\u4f4e\u529f\u8017\u7535\u5b50\u5668\u4ef6\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cZeolitic Imidazole Framework: Metal\u2013Organic Framework Subfamily Members for Triboelectric Nanogenerator\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adfm.201910162<\/p>\n<p>\u56fe8\u00a0ZIF-TENG\u76843D\u5c42\u89c6\u56fe\u53ca\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196490 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-15.png\" alt=\"\" width=\"680\" height=\"781\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-15.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72478-15-261x300.png 261w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>9\u3001\u542b\u6709<\/b><\/strong><strong><b>\u9502\u57fa\u6db2\u4f53\u9633\u6781\u548cMOFs\u5206\u79bb\u5668<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>\u6709\u673a\u6c27\u7535\u6c60<\/b><\/strong><strong><b>\uff5cA<\/b><\/strong><strong><b>EM<\/b><\/strong><\/p>\n<p>\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u529f\u7387\u6027\u80fd\u7684\u5b89\u5168\u53ef\u5145\u7535\u7535\u6c60\u662f\u5927\u578b\u7535\u529b\u8bbe\u5907\u53d1\u5c55\u7684\u8feb\u5207\u9700\u8981\u3002\u5357\u4eac\u5927\u5b66\u5468\u8c6a\u614e\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e86\u4e00\u79cd\u9502\u57fa\u6709\u673a\u6db2\u4f53\u9633\u6781\uff0c\u5b9e\u73b0\u4e86\u4e00\u79cd\u5e26\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u819c\u5206\u79bb\u5668\u7684\u6709\u673a\u6c27\u7535\u6c60\uff0c\u8be5\u7535\u6c60\u80fd\u591f\u5bfc\u7535\u9502\u79bb\u5b50\uff0c\u5e76\u80fd\u5206\u79bb\u7cfb\u7edf\u4e2d\u7684\u5176\u4ed6\u5927\u5c3a\u5bf8\u7269\u8d28\u3002\u91c7\u7528\u53cc\u6c27\u5316\u8fd8\u539f\u4ecb\u8d28\u7b56\u7565\uff0c\u6709\u673a\u6c27\u7535\u6c60\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u901f\u7387\u6027\u80fd\uff0c\u5177\u6709\u8f83\u957f\u7684\u5faa\u73af\u5bff\u547d\u548c\u8f83\u4f4e\u7684\u8fc7\u7535\u4f4d\u3002\u5728\u6709\u673a\u6db2\u4f53\u9633\u6781\u548c\u79bb\u5b50\u5bfc\u7535\u5206\u79bb\u5668\u4e4b\u95f4\u89c2\u5bdf\u5230\u201c\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\u201d\u6837\u5c42\u3002\u672c\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u9502\u57fa\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u578b\u9633\u6781\uff0c\u800c\u4e14\u4e3a\u66f4\u597d\u5730\u5e94\u7528\u8054\u82ef\u57fa\u6db2\u4f53\u9633\u6781\u63d0\u4f9b\u4e86\u57fa\u672c\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Safe Organic Oxygen Battery Built with Li-Based Liquid Anode and MOFs Separator\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728 AEM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5: DOI: 10.1002\/aenm.201903953<\/p>\n<p>\u56fe9\u00a0ZIF7\u819c\u5206\u79bb\u5668\u8054\u82ef-\u9502\u57fa\u6db2\u4f53\u9633\u6781\u7684\u793a\u610f\u56fe\u53ca\u7ed3\u6784\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-196491 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72479-14.png\" alt=\"\" width=\"680\" height=\"776\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72479-14.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/02\/\u56fe\u72479-14-263x300.png 263w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>10\u3001<\/b><\/strong><strong><b>\u8302\u91d1\u5c5e<\/b><\/strong><strong><b>\u5f15<\/b><\/strong><strong><b>\u5165<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u7528\u4e8e\u9ad8\u9009\u62e9\u6027CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u7535\u8fd8\u539f<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>NANO E<\/b><\/strong><strong><b>nergy<\/b><\/strong><\/p>\n<p>\u5177\u6709\u53ef\u8c03\u5b54\u9699\u7387\u548c\u91d1\u5c5e\u4f4d\u70b9\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u88ab\u8ba4\u4e3a\u662f\u7535\u5316\u5b66CO<sub>2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO<sub>2<\/sub>RR)\u7684\u826f\u597d\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0cMOFs\u8f83\u5dee\u7684\u7535\u5b50\u5bfc\u7535\u6027\u548c\u4f9b\u7535\u5b50\u80fd\u529b\u5236\u7ea6\u4e86\u50ac\u5316\u6548\u7387\u7684\u63d0\u9ad8\u3002\u5728\u6b64\uff0c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u7684\u5170\u4e9a\u4e7e\u6559\u6388\u7b49\u4eba\u901a\u8fc7\u7b80\u5355\u7684\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u65b9\u6cd5\u5728MOFs\u4e2d\u690d\u5165\u8302\u91d1\u5c5e\uff0c\u5f97\u5230\u7684\u50ac\u5316\u5242\u5177\u6709\u4f18\u5f02\u7684CO<sub>2<\/sub>RR\u7535\u50ac\u5316\u6027\u80fd\u3002CoCp<sub>2<\/sub>\u00a0@ MOF-555-Co\u7684FE<sub>CO<\/sub>\u5728-0.7 V\u65f6\u9ad8\u8fbe97%\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u8302\u91d1\u5c5e\u4e0e\u535f\u5549\u4e4b\u95f4\u5b58\u5728\u8f83\u5f3a\u7684\u7ed3\u5408\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u4ee5\u5927\u5e45\u5ea6\u964d\u4f4eCO<sub>2<\/sub>\u7684\u5438\u9644\u80fd\u3002\u8302\u91d1\u5c5e\u7684\u5f15\u5165\u53ef\u4ee5\u4f5c\u4e3a\u7535\u5b50\u7ed9\u4f53\u548c\u8f7d\u4f53\uff0c\u5728MOFs\u4e2d\u5f62\u6210\u8fde\u7eed\u7684\u7535\u5b50\u4f20\u9012\u901a\u9053\uff0c\u5e76\u5728CO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2d\u4e0e\u91d1\u5c5e\u535f\u5549\u53d1\u751f\u5f3a\u70c8\u7684\u7ed3\u5408\u4f5c\u7528\uff0c\u589e\u5f3aCO<sub>2<\/sub>RR\u7684\u6d3b\u6027\u3002\u8be5\u65b9\u6cd5\u5bf9\u9ad8\u9009\u62e9\u6027CO<sub>2<\/sub>RR\u7535\u50ac\u5316\u5242\u7684\u5f00\u53d1\u5177\u6709\u4e00\u5b9a\u7684\u6307\u5bfc\u610f\u4e49\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMetallocene implanted metalloporphyrin organic framework for highly selective CO2 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