{"id":196397,"date":"2020-03-01T06:10:45","date_gmt":"2020-02-29T22:10:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=196397"},"modified":"2020-02-29T22:11:14","modified_gmt":"2020-02-29T14:11:14","slug":"small%ef%bc%9a%e6%96%b0%e5%9e%8b%e9%ab%98%e6%80%a7%e8%83%bd%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e6%ad%a3%e6%9e%81-%e5%a4%9a%e5%ad%94%e6%99%ae%e9%b2%81%e5%a3%ab%e8%93%9d","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=196397","title":{"rendered":"Small\uff1a\u65b0\u578b\u9ad8\u6027\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u2014\u2014\u591a\u5b54\u666e\u9c81\u58eb\u84dd\u7eb3\u7c73\u7acb\u65b9@\u805a\u591a\u5df4\u80fa\u5f02\u8d28\u7ed3\u6784"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

\u957f\u5bff\u547d\u3001\u4f4e\u6210\u672c\u3001\u73af\u5883\u53cb\u597d\u7684\u53ef\u5145\u7535\u7535\u6c60\u662f\u7535\u5316\u5b66\u50a8\u80fd\u4f53\u7cfb\u4e2d\u6700\u91cd\u8981\u7684\u5668\u4ef6\uff0c\u5c24\u5176\u662f\u5e94\u7528\u4e8e\u5927\u89c4\u6a21\u7684\u7535\u5316\u5b66\u50a8\u80fd\u4f53\u7cfb\u3002\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u673a\u5236\u548c\u9502\u79bb\u5b50\u7535\u6c60\u7c7b\u4f3c\uff0c\u4e14\u5176\u6c27\u5316\u8fd8\u539f\u70b9\u4f4d\u5408\u9002\uff0c\u5b89\u5168\u6027\u6781\u4f73\u3002\u540c\u65f6\uff0c\u7528\u4e4b\u4e0d\u7aed\u7684\u94a0\u8d44\u6e90\uff0c\u4e5f\u4f7f\u5f97\u4f4e\u6210\u672c\u94a0\u79bb\u5b50\u7535\u6c60\u5728\u50a8\u80fd\u9886\u57df\u8fdb\u884c\u5f00\u53d1\u548c\u4f7f\u7528\uff0c\u53d7\u5230\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u8fd1\u5e74\u6765\uff0c\u666e\u9c81\u58eb\u84dd\uff08PB\uff09\u53ca\u5176\u7c7b\u4f3c\u7269\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u5e94\u7528\u4f18\u52bf\u660e\u663e\u3002\u4f46\u5b83\u4eec\u7ed3\u6784\u4e2d\u5b58\u5728\u7684\u7f3a\u9677\u3001\u7a7a\u4f4d\u3001\u914d\u4f4d\u6c34\u7b49\u4f1a\u5bfc\u81f4\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6bd4\u5bb9\u91cf\u4f4e\u548c\u500d\u7387\u6027\u80fd\u5dee\u3002\u5728PB\u7684\u8868\u9762\u8fdb\u884c\u805a\u5408\u7269\u5305\u8986\u4e0d\u4ec5\u80fd\u63d0\u9ad8\u50a8\u94a0\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u63d0\u4f9b\u4e86\u67d4\u6027\u7f13\u51b2\u5c42\u6765\u7f13\u89e3\u5d4c\/\u8131\u94a0\u79bb\u5b50\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u5e94\u529b\u3002\u805a\u591a\u5df4\u80fa\uff08PDA\uff09\u7531\u4e8e\u5176\u7c98\u9644\u7279\u6027\u4f5c\u4e3a\u7535\u6781\u8868\u9762\u7684\u5305\u8986\u5c42\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u56e0\u6b64\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u9ad8\u5206\u5b50\u5305\u8986\u5c42\u4fee\u9970\u5728\u666e\u9c81\u58eb\u84dd\u7684\u8868\u9762\uff0c\u4ece\u800c\u7a33\u5b9a\u666e\u9c81\u58eb\u84dd\u5728\u94a0\u79bb\u5b50\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\uff0c\u7a33\u5b9a\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002\u540c\u65f6\uff0c\u7ed3\u5408\u5b9e\u9a8c\u7ed3\u679c\u548c\u7b2c\u4e00\u6027\u539f\u7406\uff0c\u7814\u7a76PB@PDA\u4f5c\u4e3a\u7535\u6781\uff0c\u7ed3\u6784\u4e2d\u94a0\u79bb\u5b50\u4f20\u8f93\u548c\u50a8\u5b58\u7684\u673a\u7406\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4ee5\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u5218\u9633\u526f\u6559\u6388\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u4e0a\u6d77\u5927\u5b66\u7279\u8058\u6559\u6388\u4e54\u82b8\u535a\u58eb\uff0c\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u8def\u6218\u80dc\u526f\u6559\u6388\u548c\u6fb3\u5927\u5229\u4e9a\u4f0d\u4f26\u8d21\u5927\u5b66\u4fb4\u672f\u96f7\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\uff0c\u62a5\u9053\u4e86\u7eb3\u7c73\u7acb\u65b9\u7684\u591a\u5b54PB-Nax<\/sub>FeFe(CN)6<\/sub>(NFF)\u8868\u9762\u6d82\u8986PDA\u6765\u63d0\u9ad8\u5b83\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5c06\u8868\u9762\u5305\u8986PDA\u7684NFF\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a 0.2 A g\u22121<\/sup>\u65f6\uff0c\u7ecf\u8fc7500\u6b21\u5faa\u73af\u540e\u53ef\u9006\u5bb9\u91cf\u4e3a93.8 mA h g\u22121<\/sup>\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a 5.0 A g\u22121<\/sup>\u65f6\u653e\u7535\u5bb9\u91cf\u4e3a72.6 mA h g\u22121<\/sup>\u3002\u4f5c\u8005\u901a\u8fc7\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u6765\u63ed\u793a\u8fd9\u79cd\u7535\u6781\u7684\u50a8\u94a0\u673a\u7406\u3002\u7ed3\u5408\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff0c\u8fdb\u4e00\u6b65\u4ece\u7406\u8bba\u4e0a\u89e3\u91ca\u4e86\u591a\u5df4\u80fa\u5728\u5305\u8986\u8fc7\u7a0b\u4e2d\u4e3b\u8981\u548c\u666e\u9c81\u58eb\u84dd\u4e2d\u7684\u4e8c\u4ef7\u94c1\u8fdb\u884c\u4f5c\u7528\uff0c\u94a0\u79bb\u5b50\u5728\u7535\u6781\u4e2d\u8fc1\u79fb\u4e3b\u8981\u6309\u7167S\u5f62\u8def\u5f84\u8fdb\u884c\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u8868\u9762\u5305\u8986PDA\u53ef\u4ee5\u6539\u5584\u666e\u9c81\u58eb\u84dd\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u7535\u6781\u50a8\u94a0\u6027\u80fd\u3002\u4e0a\u8ff0\u6210\u679c\u53d1\u8868\u4e8e\u56fd\u9645\u671f\u520aSmall\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1. \u591a\u5b54\u666e\u9c81\u58eb\u84dd\u7eb3\u7c73\u7acb\u65b9@\u805a\u591a\u5df4\u80fa\u5f02\u8d28\u7ed3\u6784\u5236\u5907\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

(a) \u591a\u5b54NFF@PDA\u7684\u5408\u6210\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n

(b) NFF\u3001PDA\u548c\u591a\u5b54NFF@PDA\u7684\u7ed3\u6784\u7684\u793a\u610f\u56fe<\/p>\n

\u56fe2. \u591a\u5b54\u666e\u9c81\u58eb\u84dd\u7eb3\u7c73\u7acb\u65b9@\u805a\u591a\u5df4\u80fa\u5f02\u8d28\u7ed3\u6784\u7684\u5fae\u7eb3\u7ed3\u6784\u8868\u5f81<\/p>\n

\"\"<\/p>\n

(a, d) \u591a\u5b54NFF (a) \u548c\u591a\u5b54NFF@PDA (d) \u7684FE-SEM\u56fe<\/p>\n

(b, e) \u591a\u5b54NFF (b) \u548c\u591a\u5b54NFF@PDA (e) \u7684TEM\u56fe<\/p>\n

(c, f) \u591a\u5b54NFF (c) \u548c\u591a\u5b54NFF@PDA (f)\u7684HRTEM\u56fe<\/p>\n

(g-i) \u591a\u5b54NFF\u548c\u591a\u5b54NFF@PDA\u7684XRD\u56fe (g)\u3001\u7ea2\u5916\u5149\u8c31\u56fe (h-i)<\/p>\n

\u56fe3. \u591a\u5b54\u666e\u9c81\u58eb\u84dd\u7eb3\u7c73\u7acb\u65b9@\u805a\u591a\u5df4\u80fa\u5f02\u8d28\u7ed3\u6784\u7535\u5316\u5b66\u7279\u6027\u53ca\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u5206\u6790<\/p>\n

\"\"<\/p>\n

(a) \u7535\u6d41\u5bc6\u5ea6\u4e3a 0.2 A g\u22121<\/sup>\u65f6\u591a\u5b54NFF@PDA\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

(b) \u626b\u63cf\u901f\u7387\u4e3a0.2 mV s\u22121<\/sup>\u65f62.0~4.2 V\u7684NFF@PDA\u7684CV\u66f2\u7ebf<\/p>\n

(c) \u591a\u5b54NFF\u548c\u591a\u5b54NFF@PDA\u7684\u500d\u7387\u6027\u80fd<\/p>\n

(d) \u7535\u6d41\u5bc6\u5ea6\u4e0d\u540c\u65f6\u591a\u5b54NFF@PDA\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

(e) \u7535\u6d41\u5bc6\u5ea6\u4e3a 0.2 A g\u22121<\/sup>\u65f6\u591a\u5b54NFF\u548c\u591a\u5b54NFF@PDA\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

(f-g) \u9996\u6b21\u5faa\u73af\u8fc7\u7a0b\u4e2dNFF@PDA\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31 (f) \u53ca\u76f8\u5e94\u7684\u5145\u653e\u7535\u66f2\u7ebf (g)<\/p>\n

\u56fe4. \u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u673a\u5236\u5206\u6790\u56fe<\/p>\n

\"\"<\/p>\n

(a) PDA\u7684Fukui-nucleophilic\u51fd\u6570<\/p>\n

(b) PDA\u7684\u81ea\u65cb\u5bc6\u5ea6<\/p>\n

(c) PDA\u5206\u5b50\u67091\u4e2a\u94a0\u539f\u5b50\u5438\u9644\u7684\u4f18\u5316\u7ed3\u6784<\/p>\n

(d) PDA\u5206\u5b50\u67092\u4e2a\u94a0\u539f\u5b50\u5438\u9644\u7684\u4f18\u5316\u7ed3\u6784<\/p>\n

(e) \u7eafPB\u7684slab\u6a21\u578b<\/p>\n

(f) <\/em>PB\u8026\u5408PDA\u7684slab\u6a21\u578b<\/p>\n

(g, h) \u7eafPB\u7684S\u578b (f) \u548c\u7ebf\u578b (h) \u94a0\u79bb\u5b50\u8fc1\u79fb\u8def\u5f84<\/p>\n

(i, j) PB\u8026\u5408PDA\u7684S\u578b (i) \u548c\u7ebf\u578b (j) \u94a0\u79bb\u5b50\u8fc1\u79fb\u8def\u5f84\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u603b\u4e4b\uff0c\u901a\u8fc7\u5c06PDA\u548cNFF\u8fdb\u884c\u8026\u5408\u6765\u5f62\u6210\u591a\u5b54NFF@PDA\uff0c\u6709\u6548\u5730\u63d0\u9ad8PB\u6b63\u6781\u7684\u50a8\u94a0\u6027\u80fd\u3002\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u8868\u660e\u4f34\u968f\u7740\u5d4c\/\u8131\u94a0\u8fc7\u7a0b\uff0cNFF\u7684FeII<\/sup>\u88ab\u6c27\u5316\u6210FeIII<\/sup>\u7136\u540e\u88ab\u8fd8\u539f\u6210FeII<\/sup>\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0cPDA\u5bb9\u6613\u548cPB\u4e2d\u7684FeII<\/sup>\u8fdb\u884c\u8026\u5408\uff0c\u4e5f\u6709\u5229\u4e8e\u4fc3\u8fdb\u94a0\u79bb\u5b50\u5728PB\u7ed3\u6784\u4e2d\u7684\u4f20\u8f93\uff0c\u63d0\u9ad8PB\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u591a\u5b54NFF@PDA\u4e0eNFF\u76f8\u6bd4\uff0c\u7528\u4f5c\u6b63\u6781\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\u3002PDA\u4f5c\u4e3a\u8026\u5408\u5c42\u7684\u7b56\u7565\u4e5f\u80fd\u63d0\u4f9b\u7b80\u5355\u3001\u6709\u6548\u7684\u65b9\u6cd5\u6765\u6539\u5584\u53ef\u5145\u7535\u7535\u6c60\u7684PB\u6b63\u6781\u7684\u6bd4\u5bb9\u91cf\u3001\u5faa\u73af\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA Heterostructure Coupling of Bioinspired, Adhesive Polydopamine, and Porous Prussian Blue Nanocubics as Cathode for High\u2010Performance Sodium\u2010Ion Battery<\/a><\/strong>\uff08Small\uff0c2020, DOI: 10.1002\/smll.201906946\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/p>\n

\u4e54\u82b8\u535a\u58eb\u957f\u671f\u4ece\u4e8b\u65b0\u80fd\u6e90\u7535\u6781\u6750\u6599\u7684\u5feb\u901f\u5236\u5907\u53ca\u5e94\u7528\u7814\u7a76\uff0c\u8fd1\u5e74\u6765\u53d6\u5f97\u4e00\u7cfb\u5217\u539f\u521b\u6027\u7684\u6210\u679c\u3002\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u65b9\u9762\uff0c\u5236\u5907\u4e86\u591a\u79cd\u590d\u5408\u7ed3\u6784\u7684\u666e\u9c81\u58eb\u84dd\u6b63\u6781\u6750\u6599\uff0c\u5728\u8d1f\u6781\u65b9\u9762\u5236\u5907\u4e00\u7cfb\u5217\u5f02\u8d28\u539f\u5b50\u63ba\u6742\u7535\u6781\uff0c\u540c\u65f6\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\u5bf9\u5176\u50a8\u94a0\u673a\u5236\u8fdb\u884c\u4e86\u6df1\u5165\u7684\u5206\u6790\u548c\u7814\u7a76\u3002\u5728\u7a7a\u6c14\u7535\u6c60\u65b9\u9762\uff0c\u5c06\u78b3\u57fa\u7535\u6781\u6750\u6599\u4f5c\u4e3a\u57fa\u4f53\u62c5\u8f7d\u4e0d\u540c\u7684\u50ac\u5316\u5242\u6765\u63d0\u9ad8\u9502-\u4e8c\u6c27\u5316\u78b3\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u3002\u8def\u6218\u80dc\u535a\u58eb\u4e3b\u8981\u4ece\u4e8b\u7406\u8bba\u8ba1\u7b97\u7684\u5728\u6750\u6599\u4e2d\u7684\u6a21\u62df\u4e0e\u8bbe\u8ba1\u7814\u7a76\uff0c\u8fd1\u5e74\u6765\u4e0e\u4e54\u82b8\u535a\u58eb\u5408\u4f5c\u5728\u7535\u6781\u6750\u6599\u673a\u7406\u8ba1\u7b97\u65b9\u9762\u53d6\u5f97\u4e00\u7cfb\u5217\u539f\u521b\u6027\u6210\u679c\u3002\u4fb4\u672f\u96f7\u6559\u6388\u4e3b\u8981\u4ece\u4e8b\u65b0\u80fd\u6e90\u6750\u6599\u7684\u7814\u53d1\u548c\u5e94\u7528\u5de5\u4f5c\uff0c\u5e76\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7684\u7814\u7a76\u6210\u679c\uff0c\u83b7\u5f97\u4e86\u8f83\u591a\u7684\u5173\u6ce8\uff0c\u793e\u4f1a\u5f71\u54cd\u529b\u8f83\u5927\uff0c\u5c24\u5176\u662f\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u65b9\u9762\uff0c\u5c06\u666e\u9c81\u58eb\u84dd\u6750\u6599\u4f5c\u4e3a\u6b63\u6781\uff0c\u5df2\u7ecf\u8fdb\u884c\u5230\u5e94\u7528\u5f00\u53d1\u4e2d\u8bd5\u9636\u6bb5\u3002<\/p>\n

\u3010\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350<\/strong>\u3011<\/p>\n

\u94a0\u79bb\u5b50\u7535\u6c60\u78b3\u8d1f\u6781\uff1aSodium storage mechanism of N, S co-doped nanoporous carbon: Experimental design and theoretical evaluation (Energy Storage Mater. 2018, DOI: 10.1016\/j.ensm.2017.09.003)<\/p>\n

\u9502-\u4e8c\u6c27\u5316\u78b3\u7535\u6c60\u7535\u6781\uff1aSynergistic effect of bifunctional catalytic sites and defect engineering for high-performance Li-CO2<\/sub> batteries. (Energy Storage Mater. 2020, DOI: 10.1016\/j.ensm.2020.01.021)<\/p>\n

\u8d85\u5feb\u901f\u5236\u5907\u9502-\u4e8c\u6c27\u5316\u78b3\u7535\u6c60\u7535\u6781\uff1aTransient, in situ Synthesis of Ultrafine Ruthenium Nanoparticles for a High-rate Li-CO2<\/sub> Battery. (Energy Environ. Sci. 2019, DOI: 10.1039\/C8EE03506G)<\/p>\n

3D\u6253\u5370\u539a\u7535\u6781\uff1a3D-Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li-CO2<\/sub> Batteries. (Adv. Funct. Mater. 2018, DOI: 10.1002\/adfm.201805899)<\/p>\n

\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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