{"id":196018,"date":"2020-02-20T06:42:42","date_gmt":"2020-02-19T22:42:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=196018"},"modified":"2020-02-19T21:42:53","modified_gmt":"2020-02-19T13:42:53","slug":"%e4%ba%ba%e5%b7%a5%e5%90%88%e6%88%90%e4%ba%8c%e7%bb%b4%e6%9d%90%e6%96%99%e7%9a%84%e7%99%be%e8%8a%b1%e9%bd%90%e6%94%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=196018","title":{"rendered":"\u4eba\u5de5\u5408\u6210\u4e8c\u7ef4\u6750\u6599\u7684\u767e\u82b1\u9f50\u653e"},"content":{"rendered":"

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3. \u534a\u5bfc\u4f53\u77f3\u58a8\u7094\u548c\u6c27\u5316\u8fd8\u539f\u5206\u5b50\u95f4\u7684\u7535\u5b50\u8dc3\u8fc1\u7528\u4e8e\u9009\u62e9\u6027\u7535\u50ac\u5316<\/b><\/strong>[<\/b><\/sup><\/strong>3<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u7535\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u4e0d\u4ec5\u53d6\u51b3\u4e8e\u6d3b\u6027\u4f4d\u70b9\u5bf9\u7279\u5b9a\u5e95\u7269\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fd8\u53d6\u51b3\u4e8e\u57fa\u8d28\u95f4\u8c03\u63a7\u7684\u7535\u5b50\u8026\u5408\u6548\u7387\u3002\u5728\u5bfc\u7535\u4ecb\u8d28\u4e2d\u63ba\u6742\u6709\u6548\u6d3b\u6027\u4f4d\u70b9\u867d\u7136\u53ef\u4ee5\u52a0\u901f\u6d3b\u6027\u4f4d\u70b9\u4e0e\u7535\u6781\u4e4b\u95f4\u7684\u7535\u5b50\u8fc1\u79fb\uff0c\u4f46\u662f\uff0c\u9ad8\u6d3b\u6027\u7684\u7535\u5bfc\u8868\u9762\u4e5f\u53ef\u4ee5\u6c27\u5316\u6216\u8fd8\u539f\u5177\u6709\u7535\u6d3b\u6027\u7684\u4f34\u751f\u7269\uff0c\u964d\u4f4e\u7535\u50ac\u5316\u754c\u9762\u7684\u9009\u62e9\u6027\u3002\u91c7\u53d6\u7ed3\u5408\u5177\u6709\u5f31\u5bfc\u7535\u6027\u7684\u57fa\u8d28\u4e0e\u6c27\u5316\u8fd8\u539f\u5206\u5b50\u7684\u7b56\u7565\u53ef\u4ee5\u4e3a\u76ee\u6807\u53cd\u5e94\u7269\u63d0\u4f9b\u4e00\u4e2a\u53ef\u8c03\u8282\u7684\u3001\u8fdc\u8ddd\u79bb\u7535\u5b50\u4f20\u8f93\u8def\u5f84\uff0c\u540c\u65f6\u5f15\u5165\u7a7a\u95f4\u58c1\u5792\u6765\u5f15\u5bfc\u4e0e\u5e72\u6270\u7269\u79cd\u7684\u7535\u5b50\u8026\u5408\u3002\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7684Mao Lanqun\u548cWu Fei\u7814\u7a76\u56e2\u961f\u5229\u7528\u8d85\u58f0\u5c06\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6027\u8d28\u7684\u4e9a\u7532\u57fa\u7eff\uff08MG\uff09\u5f15\u5165\u5c42\u79ef\u77f3\u58a8\u7094\uff08GDY\uff09\u4e2d\u5236\u5907\u590d\u5408\u7535\u50ac\u5316\u5242\u3002\u5229\u7528\u5149\u8c31\u5b66\u3001\u7535\u5316\u5b66\u548c\u8ba1\u7b97\u6a21\u62df\u6765\u63a2\u6d4b\u77f3\u58a8\u7094-\u63d2\u5165\u5206\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5e76\u63ed\u793a\u5176\u5bf9\u754c\u9762\u7535\u5b50\u52a8\u529b\u5b66\u548c\u7535\u50ac\u5316\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u76f8\u90bbGDY\u7247\u5c42\u4e2dMG\u4e8c\u805a\u4f53\u81ea\u4ea4\u6362\u4ea7\u751f\u7684\u7535\u5b50\u8df3\u8dc3\uff087.06 \u00d7 10\u22122<\/sup>\u00a0cm\u00b7s\u22121<\/sup>\uff09\u53ef\u4ee5\u52a0\u901fDADH\u7684\u6c27\u5316\uff0c\u800c\u7535\u5b50\u76f4\u63a5\u7a7f\u900fGDY\u7eb3\u7c73\u7247\u7684\u901f\u7387\u6162\uff086.60 \u00d7 10\u22125<\/sup>\u00a0cm\u00b7s\u22121<\/sup>\uff09\uff0c\u964d\u4f4eAA\u7684\u6c27\u5316\u3002\u5b9e\u9a8c\u7ed3\u679c\u8bc1\u660e\u4e86GDY\u5728\u7535\u50ac\u5316\u9886\u57df\u7684\u5e7f\u9614\u524d\u666f\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5176\u56fa\u6709\u7684\u7535\u5b50\u6027\u8d28\u548c\u7ed3\u6784\u7684\u72ec\u7279\u6027\u3002\u8fdb\u4e00\u6b65\u5730\uff0c\u8c03\u8282\u7535\u5b50\u8f6c\u79fb\u548c\u7535\u8377\u4f20\u8f93\u4e0d\u4ec5\u53ef\u4ee5\u63d0\u9ad8\u7535\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u800c\u4e14\u53ef\u4ee5\u589e\u5f3a\u5176\u9009\u62e9\u6027\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u5c0f\u5206\u5b50\u8c03\u8282\u534a\u5bfc\u4f53\u6216\u7edd\u7f18\u4e8c\u7ef4\u5c42\u6d41\u7247\u6216\u4e09\u7ef4\u6846\u67b6\u4e2d\u7684\u7535\u5b50\/\u7535\u8377\u52a8\u529b\u5b66\uff0c\u6709\u671b\u83b7\u5f97\u4e30\u5bcc\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u56fe3. MG\u8d85\u58f0\u63d2\u5c42\u4fee\u9970GDY\u7eb3\u7c73\u7247\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

4. \u5408\u7406\u8bbe\u8ba1\u4e8c\u7ef4\u8fb9\u754c\u6676\u7c92\u52a9\u529b\u6790\u6c22\u53cd\u5e94<\/b><\/strong>[<\/b><\/sup><\/strong>4<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

\u539f\u5b50\u5c42\u539a\u5ea6\u7684\u8fc7\u6e21\u91d1\u5c5e\u4e8c\u786b\u5316\u7269\uff08TMDs\uff09\u662f\u4e00\u79cd\u65b0\u578b\u7684\u7535\u50ac\u5316\u6750\u6599\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5b83\u4eec\u7684\u8fb9\u7f18\u3001\u63ba\u6742\u7684\u6742\u539f\u5b50\u548c\u7f3a\u9677\u4f5c\u4e3a\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u88c2\u89e3\u6c34\u7684\u6d3b\u6027\u4f4d\u70b9\u5df2\u88ab\u6df1\u5165\u7814\u7a76\u3002\u7136\u800c\uff0c\u4f5c\u4e3aTMDs\u4e00\u79cd\u91cd\u8981\u7f3a\u9677\u7c7b\u578b\u7684\u6676\u7c92\uff08GBs\uff09\uff0c\u7531\u4e8e\u5176\u5bc6\u5ea6\u4f4e\u3001\u7ed3\u6784\u53d8\u5316\u5927\u800c\u88ab\u5ffd\u7565\u3002\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66Liu Zheng\u7814\u7a76\u56e2\u961f\u901a\u8fc7Au-QDs\u8f85\u52a9\u6c14\u76f8\u751f\u957f\u7684\u7b56\u7565\u5236\u5907\u4e86\u6676\u7247\u7ea7\u5c3a\u5bf8\u7684\u539f\u5b50\u7ea7\u539a\u5ea6\u7684TMD\u8584\u819c\uff0c\u5e26\u6709\u8d85\u9ad8\u5bc6\u5ea6\uff08~1012<\/sup>\u00a0cm\u22122<\/sup>\uff09\u7684sub-10 nm\u7684\u6676\u7c92\u3002\u5b9e\u9a8c\u548c\u76f8\u573a\u6a21\u62df\u7ed3\u679c\u8bc1\u660eAu QDs\u8c03\u63a7TMD\u6676\u7c92\u7684\u5f62\u6210\u4e3a\u722c\u5761-\u63a8\u52a8\u7684\u751f\u957f\u673a\u7406\u3002\u7528\u56db\u7535\u6781\u5fae\u7535\u5316\u5b66\u7535\u6c60\u7814\u7a76\u4e86\u8fd9\u4e9b\u7eb3\u7c73\u9897\u7c92\u819c\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8868\u73b0\u51fa-25 mV\u7684\u8d77\u59cb\u7535\u52bf\u548c54 mV dec\u22121<\/sup>\u7684Tafel\u659c\u7387\uff0c\u8868\u660e\u5bcc\u6676\u7c922D\u754c\u9762\u5177\u6709\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002\u9664\u4e86\u7535\u50ac\u5316\uff0c\u7eb3\u7c73\u9897\u7c92\u819c\u8fd8\u53ef\u4ee5\u63d0\u4f9b\u66f4\u591a\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u5982\u5728\u7535\u963b\u5b58\u50a8\u5668\u4ef6\u3001\u67d4\u6027\u5668\u4ef6\u6216\u4f5c\u4e3a\u673a\u68b0\u8584\u819c\u548c\u5206\u5b50\u7b5b\u819c\u4f7f\u7528\u3002<\/p>\n

\u56fe4. TMD \u7eb3\u7c73\u6676\u8584\u819c\u7684\u751f\u957f\u673a\u7406\u3002<\/p>\n

\"\"<\/p>\n

5. \u8d28\u5b50\u5728\u4e8c\u7ef4\u6676\u4f53\u4e2d\u7684\u9009\u62e9\u6027\u4f20\u8f93<\/b><\/strong>[<\/b><\/sup><\/strong>5<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

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\u56fe5. 1 M HCl\u4e2d\u7684I-V<\/i><\/em>\u66f2\u7ebf\u3002<\/p>\n

\"\"<\/p>\n

6. \u5c42\u79ef\u4e8c\u7ef4COF\u819c\u7528\u4e8e\u79bb\u5b50\u548c\u5206\u5b50\u7b5b\u5206<\/b><\/strong>[<\/b><\/sup><\/strong>6<\/b><\/sup><\/strong>]<\/b><\/sup><\/strong><\/p>\n

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\u56fe 6. COF\u7684\u793a\u610f\u56fe\u53caAA\u548cAB\u5806\u79ef\u6a21\u578b\u3002<\/p>\n

\"\"<\/p>\n

\u5c0f\u7ed3\uff1a<\/b><\/strong><\/p>\n

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\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

(1) Zhang, Z.; Yang, S.; Zhang, P.; Zhang, J.; Chen, G.; Feng, X. Mechanically Strong Mxene\/Kevlar Nanofiber Composite Membranes as High-Performance Nanofluidic Osmotic Power Generators. Nat Commun. <\/i><\/em>2019,<\/b><\/strong>\u00a010<\/i><\/em>, 2920.<\/p>\n

(2) Zhang, G.; Li, B.; Zhou, Y.; Chen, X.; Li, B.; Lu, Z. Y.; Wu, L. Processing Supramolecular Framework for Free Interconvertible Liquid Separation. Nat Commun. <\/i><\/em>2020,<\/b><\/strong>\u00a011<\/i><\/em>, 425.<\/p>\n

(3) Guo, S.; Yu, P.; Li, W.; Yi, Y.; Wu, F.; Mao, L. Electron Hopping by Interfacing Semiconducting Graphdiyne Nanosheets and Redox Molecules for Selective Electrocatalysis. J. Am. Chem. Soc. <\/i><\/em>2020,<\/b><\/strong>\u00a0142<\/i><\/em>, 2074.<\/p>\n

(4) He, Y.; Tang, P.; Hu, Z.; He, Q.; Zhu, C.; Wang, L.; Zeng, Q.; Golani, P.; Gao, G.; Fu, W.et al. Engineering Grain Boundaries at the 2d Limit for the Hydrogen Evolution Reaction. Nat Commun. <\/i><\/em>2020,<\/b><\/strong>\u00a011<\/i><\/em>, 57.<\/p>\n

(5) Mogg, L.; Zhang, S.; Hao, G. P.; Gopinadhan, K.; Barry, D.; Liu, B. L.; Cheng, H. M.; Geim, A. K.; Lozada-Hidalgo, M. Perfect Proton Selectivity in Ion Transport through Two-Dimensional Crystals. Nat Commun. <\/i><\/em>2019,<\/b><\/strong>\u00a010<\/i><\/em>, 4243.<\/p>\n

(6) Li, Y.; Wu, Q.; Guo, X.; Zhang, M.; Chen, B.; Wei, G.; Li, X.; Li, X.; Li, S.; Ma, L. Laminated Self-Standing Covalent Organic Framework Membrane with Uniformly Distributed Subnanopores for Ionic and Molecular Sieving. Nat Commun. <\/i><\/em>2020,<\/b><\/strong>\u00a011<\/i><\/em>, 599.<\/p>\n

\u672c\u6587\u7531Netlep<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

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