{"id":195930,"date":"2020-02-15T06:01:42","date_gmt":"2020-02-14T22:01:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=195930"},"modified":"2020-02-14T20:02:09","modified_gmt":"2020-02-14T12:02:09","slug":"2020%e4%bc%8a%e5%a7%8b%ef%bc%8c%e9%ab%98%e6%80%a7%e8%83%bd%e6%b0%b4%e7%b3%bb%e7%94%b5%e6%b1%a0%e5%9b%9b%e5%a4%84%e5%bc%80%e8%8a%b1%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=195930","title":{"rendered":"2020\u4f0a\u59cb\uff0c\u9ad8\u6027\u80fd\u6c34\u7cfb\u7535\u6c60\u56db\u5904\u5f00\u82b1\uff01"},"content":{"rendered":"

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1<\/b><\/strong>\u00a0<\/b><\/strong>\u6c34\u7cfb\u94a0\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

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Energy & Environmental Science<\/b><\/strong>\uff1a\u8c03\u63a7\u79bb\u5b50\u4f20\u8f93\u52a8\u529b\u5b66\u548c\u754c\u9762\u7a33\u5b9a\u6027\u5236\u5907\u9ad8\u6027\u80fdZn\u91d1\u5c5e\u8d1f\u6781<\/b><\/strong><\/p>\n

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Journal of the American Chemical Society<\/b><\/strong>\uff1a\u9ad8\u6027\u80fdZn\u79bb\u5b50\u7535\u6c60\u6709\u673a\u6b63\u6781\uff1a\u4e09\u89d2\u5f62\u5927\u73af\u83f2\u918c<\/b><\/strong><\/p>\n

\u5728Zn\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\u8fc7\u7a0b\u4e2d\uff0c\u7814\u7a76\u8005\u4eec\u4e00\u76f4\u5728\u63a2\u5bfb\u9ad8\u6027\u80fd\u7684\u50a8\u950c\u6b63\u6781\u6750\u6599\u3002\u5176\u4e2d\uff0c\u918c\u7c7b\u5316\u5408\u7269\u56e0\u5177\u6709\u9ad8\u7684\u6bd4\u5bb9\u91cf\u3001\u53ef\u6301\u7eed\u6027\u548c\u4f4e\u6210\u672c\u800c\u5907\u53d7\u77a9\u76ee\u3002\u7136\u800c\uff0c\u918c\u57fa\u6b63\u6781\u6750\u6599\u5374\u5b58\u5728\u4e00\u4e2a\u4e25\u91cd\u7684\u95ee\u9898\uff0c\u5b83\u5728\u5faa\u73af\u7684\u65f6\u5019\u4f1a\u9010\u6e10\u6eb6\u89e3\uff0c\u4ece\u800c\u4e25\u91cd\u5f71\u54cd\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u6fb3\u5927\u5229\u4e9a\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\u7684<\/b><\/strong>Dong Jun Kim<\/b><\/strong>\u56e2\u961f\u548c\u7f8e\u56fd\u897f\u5317\u5927\u5b66\u7684<\/b><\/strong>J. Fraser Stoddart<\/b><\/strong>\u56e2\u961f\u8bbe\u8ba1\u5e76\u5236\u5907\u4e86\u4e00\u79cd\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u4e09\u89d2\u5f62\u5927\u73af\u83f2\u918c\uff08<\/b><\/strong>PQ-\u0394<\/b><\/strong>\uff09<\/b><\/strong>\uff0c\u5176\u5177\u6709\u72ec\u7279\u7684\u521a\u6027\u51e0\u4f55\u7ed3\u6784\u548c\u5c42\u72b6\u8d85\u7ed3\u6784[3]<\/sup>\u3002\u7814\u7a76\u8bc1\u5b9e\uff0c\u7ed3\u5408\u4e86H2<\/sub>O\u5206\u5b50\u7684Zn2<\/sup>+<\/sup>\u79bb\u5b50\u53ef\u4ee5\u63d2\u5165PQ-\u0394\u6709\u673a\u6b63\u6781\u4e2d\uff08\u56fe5\uff09\uff0c\u56e0\u6b64\uff0c\u6b63\u6781\u4e0e\u7535\u89e3\u6db2\u4e4b\u95f4\u7684\u754c\u9762\u963b\u6297\u4e5f\u5f97\u5230\u4e86\u6709\u6548\u964d\u4f4e\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u754c\u9762\u963b\u6297\u7684\u964d\u4f4e\u4e3b\u8981\u6e90\u4e8e\u6c34\u5408Zn2<\/sup>+<\/sup>\u79bb\u5b50\u53bb\u6eb6\u5242\u5316\u80fd\u7684\u964d\u4f4e\u3002\u6c34\u5408Zn2<\/sup>+<\/sup>\u79bb\u5b50\u7684\u53ef\u5d4c\u5165\u6027\u548c\u4e09\u89d2\u5f62\u7a33\u5b9a\u7684\u7ed3\u6784\u7684\u5171\u540c\u4fc3\u4f7fPQ-\u0394\u6709\u673a\u6b63\u6781\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\uff08150 mA g-1<\/sup>\uff1a210 mAh g-1<\/sup>\uff09\u548c\u4f18\u5f02\u7684\u5faa\u73af\u5bff\u547d\uff08500\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe99.9%\uff09\uff08\u56fe6\uff09\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5229\u7528\u5177\u6709\u7535\u5b50\u6d3b\u6027\u7684\u6709\u673a\u5927\u73af\u7ed3\u5408\u4e0e\u4e8c\u4ef7\u8f7d\u6d41\u5b50\u6eb6\u5242\u5316\u76f8\u5173\u7684\u4f4e\u754c\u9762\u7535\u963b\u53ef\u4ee5\u663e\u8457\u6539\u5584\u4e8c\u4ef7\u7535\u6c60\u4f53\u7cfb\u7684\u603b\u4f53\u6027\u80fd\u3002<\/p>\n

\u56fe5<\/b><\/strong>\u00a0Zn\/PQ-\u0394<\/b><\/strong>\u4f53\u7cfb\u7684\u5316\u5b66\u7279\u6027<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe6 PQ-\u0394\u5728\u6c34\u7cfb\uff08<\/b><\/strong>3 M Zn(CF<\/b><\/strong>3<\/b><\/strong><\/sub>SO<\/b><\/strong>3<\/b><\/strong><\/sub>)<\/b><\/strong>2<\/b><\/strong><\/sub>\u6eb6\u4e8e<\/b><\/strong>H<\/b><\/strong>2<\/b><\/strong><\/sub>O<\/b><\/strong>\uff09<\/b><\/strong>\u548c\u6709\u673a\uff080.25 M Zn(CF<\/b><\/strong>3<\/b><\/sub><\/strong>SO<\/b><\/strong>3<\/b><\/sub><\/strong>)<\/b><\/strong>2<\/b><\/sub><\/strong>\u6eb6\u4e8eMeCN\uff09\u7535\u89e3\u6db2<\/b><\/strong>\u4e0b\u7684\u7535\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

A<\/b><\/strong>dvanced Energy Materials<\/b><\/strong>\uff1a\u53cc\u6eb6\u89e3\/\u6c89\u79ef\u53cd\u5e94\u5b9e\u73b0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u6c34\u7cfb\u7535\u6c60<\/b><\/strong><\/p>\n

\u5c3d\u7ba1\u6c34\u7cfb\u7535\u6c60\u5177\u6709\u9ad8\u5b89\u5168\u3001\u4f4e\u6210\u672c\u548c\u6613\u7ef4\u62a4\u7684\u4f18\u70b9\uff0c\u4f46\u662f\u5b83\u4e5f\u9762\u4e34\u7740\u4f4e\u5de5\u4f5c\u7535\u538b\u548c\u4f4e\u80fd\u91cf\u5bc6\u5ea6\u7684\u5de8\u5927\u6311\u6218\u3002\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u6c34\u7cfb\u7535\u89e3\u6db2\u7535\u5316\u5b66\u7a97\u53e3\u8f83\u7a84\u4ee5\u53ca\u4f20\u7edf\u63d2\u5165\u578b\u7535\u6781\u7684\u6bd4\u5bb9\u91cf\u5f88\u4f4e\u3002\u5728\u6b64\uff0c\u4e2d\u79d1\u9662\u4e0a\u6d77\u7845\u9178\u76d0\u7814\u7a76\u6240\u7684\u8fdf\u6653\u4f1f\u548c\u5218\u5b87<\/b><\/strong>\u56e2\u961f\u901a\u8fc7\u5c06\u4e00\u79cd\u65b0\u578b\u7684\u5bbd\u7535\u538b\u7a97\u53e3\uff083\u00a0V\uff09\u7684\u7535\u89e3\u6db2\u4e0e\u4e24\u4e2a\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\u7684\u7535\u6781\u76f8\u7ed3\u5408\u6784\u9020\u51fa\u4e86\u4e00\u79cd\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe1<\/b><\/strong>503 Wh kg<\/b><\/strong>-1<\/b><\/sup><\/strong>\uff08\u57fa\u4e8e\u6b63\u6781\u6d3b\u6027\u6750\u6599\u8ba1\u7b97\uff09\u7684\u6c34\u7cfb\u7535\u6c60\u4f53\u7cfb\uff08\u56fe7\uff09[4]<\/sup>\u3002\u5728\u8be5\u7cfb\u7edf\u4e2d\uff0c\u79bb\u5b50\u9009\u62e9\u6027\u8584\u819c\u5c06\u201c\u9178-\u78b1\u201d\u53cc\u7cfb\u7535\u89e3\u6db2\u5206\u9694\u5f00\uff0c\u4ece\u800c\u4f7f\u5f97\u6b63\u8d1f\u6781\u4e24\u79cd\u6eb6\u89e3\/\u6c89\u79ef\u53cd\u5e94\uff08MnO2<\/sub>\/Mn2+<\/sup>\u548cZn\/Zn(OH)4<\/sub>2-<\/sup>\uff09\u80fd\u591f\u5206\u522b\u8fdb\u884c\uff0c\u56e0\u800c\u4e5f\u8d4b\u4e88\u4e86\u6b63\u8d1f\u6781\u9ad8\u8fbe616\u548c820 mAh g-1<\/sup>\u7684\u7406\u8bba\u5bb9\u91cf\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u8be5\u65b0\u578b\u6c34\u7cfb\u7535\u6c60\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u5e93\u4f26\u6548\u7387\uff0898.4%\uff09\u548c\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u5faa\u73af1500\u5708\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u9ad8\u8fbe97.5%\uff09\uff08\u56fe8\uff09\u3002\u6b64\u5916\uff0c\u57fa\u4e8e\u8fd9\u4e24\u79cd\u6eb6\u89e3\/\u6c89\u79ef\u53cd\u5e94\u6784\u5efa\u7684\u6db2\u6d41\u7535\u6c60\u66f4\u662f\u53ef\u4ee5\u5faa\u73af\u9ad8\u8fbe6000\u6b21\u4e14\u62e5\u6709\u9ad8\u8fbe99.5%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u8be5\u5de5\u4f5c\u4e5f\u4e3a\u53d1\u5c55\u5177\u6709\u9ad8\u7535\u538b\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u65b0\u578b\u6c34\u7cfb\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u8def\u5f84\u3002<\/p>\n

\u56fe7<\/b><\/strong>\u00a0<\/b><\/strong>\u53cc\u6eb6\u89e3\/\u6c89\u79ef\u53cd\u5e94\u950c\u9530\u6c34\u7cfb\u7535\u6c60\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe8<\/b><\/strong>\u00a0<\/b><\/strong>\u950c\u9530\u6c34\u7cfb\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3 <\/b><\/strong>\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

Energy Storage Materials<\/b><\/strong>\uff1a\u5177\u6709\u957f\u5faa\u73af\u5bff\u547d\u7684\u67d4\u6027\u6c34\u7cfb\u94dd\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

\u968f\u7740\u67d4\u6027\u53ef\u7a7f\u6234\u7535\u5b50\u8bbe\u5907\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u5f00\u53d1\u51fa\u5177\u6709\u4f18\u5f02\u7535\u5316\u5b66\u6027\u80fd\u3001\u9ad8\u5b89\u5168\u6027\u548c\u67d4\u6027\u7684\u5148\u8fdb\u7535\u6e90\u5c31\u663e\u5f97\u5341\u5206\u7d27\u8feb\u3002\u6700\u8fd1\uff0c\u94dd\u79bb\u5b50\u7535\u6c60\uff08AIBs\uff09\u56e0\u5177\u6709\u4e30\u5bcc\u7684\u8d44\u6e90\u50a8\u91cf\u548c\u4e09\u7535\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u6709\u9650\u7684\u50a8Al3<\/sup>+<\/sup>\u7535\u6781\u6750\u6599\u548c\u73b0\u6709\u7535\u89e3\u6db2\u6781\u5dee\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e25\u91cd\u5730\u9650\u5236\u4e86AIBs\u7684\u8fdb\u6b65\u3002\u5728\u6b64\uff0c\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u7684\u9ec4\u71d5<\/b><\/strong>\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u5b89\u5168\u3001\u67d4\u6027\u4e14\u5177\u6709\u9ad8\u6027\u80fd\u7684\u94dd\u79bb\u5b50\u7535\u6c60\u7cfb\u7edf\uff0c\u5b83\u91c7\u7528\u5d4c\u5165\u578bMoO3<\/sub>\u548cVOPO4<\/sub>\u5206\u522b\u4f5c\u4e3a\u8d1f\u6781\u548c\u6b63\u6781\uff0c\u4ee5\u51dd\u80f6\u72b6\u805a\u4e19\u70ef\u9170\u80fa\u4f5c\u4e3a\u7535\u89e3\u6db2\uff08\u56fe9\uff09[5]<\/sup>\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff08\u56fe10\uff09\uff0c\u8be5AIBs\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u653e\u7535\u5bb9\u91cf\uff080.8 A g-1<\/sup>\uff1a88 mAh g-1<\/sup>\uff09\uff0c\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\uff086 A g-1<\/sup>\uff1a22 mAh g-1<\/sup>\uff09\u548c\u957f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff081 A g-1<\/sup>\u5faa\u73af2800\u6b21\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a86.2%\uff09\u3002\u6b64\u5916\uff0c\u8be5AIBs\u8fd8\u62e5\u6709\u7740\u9ad8\u7684\u5b89\u5168\u6027\u548c\u6781\u597d\u7684\u67d4\u6027\uff0c\u5373\u65f6\u7ecf\u53d7\u5f2f\u66f2\uff0c\u7a7f\u523a\u6216\u526a\u88c1\u4e5f\u80fd\u6b63\u5e38\u5de5\u4f5c\uff08\u56fe11\uff09\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8be5\u6c34\u7cfbAIBs\u8fd8\u80fd\u591f\u9a71\u52a8\u957f1\u00a0m\uff0c\u9762\u79ef\u4e3a100 cm2<\/sup>\u7684\u7535\u81f4\u53d1\u5149\u9762\u677f\uff0c\u8868\u660e\u5b83\u5177\u6709\u826f\u597d\u7684\u50a8\u94dd\u6027\u8d28\uff08\u56fe3\uff09\u3002\u9274\u4e8e\u5176\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7279\u6027\u3001\u9ad8\u7684\u7a33\u5065\u6027\u548c\u5b89\u5168\u6027\uff0c\u53ef\u4ee5\u8bf4\u5b83\u6253\u5f00\u4e86\u67d4\u6027\u53ef\u7a7f\u6234\u50a8\u80fd\u5668\u4ef6\u5f00\u53d1\u7684\u65b0\u9053\u8def\u3002<\/p>\n

\u56fe<\/b><\/strong>9 <\/b><\/strong>\u6c34\u7cfbAl\u79bb\u5b50\u7535\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u53ca\u6b63\u8d1f\u6781\u6750\u6599\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>10 <\/b><\/strong>\u56fa\u6001\u6c34\u7cfbAl\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>11 <\/b><\/strong>Al\u79bb\u5b50\u7535\u6c60\u7684\u53e0\u52a0\u53ca\u67d4\u6027\u5c55\u793a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4 <\/b><\/strong>\u6c34\u7cfb\u94f5\u79bb\u5b50\u7535\u6c60<\/b><\/strong><\/p>\n

Nano Energy<\/b><\/strong>\uff1a\u9ad8\u500d\u7387\u957f\u5faa\u73af\u7684\u67d4\u6027\u6c34\u7cfb\u94f5\u79bb\u5b50\u5168\u7535\u6c60<\/b><\/strong><\/p>\n

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\u56fe1<\/b><\/strong>2 <\/b><\/strong>\u6c34\u7cfb\u94f5\u79bb\u5b50\u5168\u7535\u6c60<\/b><\/strong>CF@PANI\/\/CF@NH<\/b><\/strong>4<\/b><\/sub><\/strong>V<\/b><\/strong>4<\/b><\/sub><\/strong>O<\/b><\/strong>10<\/b><\/sub><\/strong>\u7684\u6784\u9020\u53ca\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>13 <\/b><\/strong>\u67d4\u6027\u7ea4\u7ef4\u72b6\u6c34\u7cfb\u94f5\u79bb\u5b50\u5168\u7535\u6c60\u7684\u5c55\u793a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

[1] L. Jiang, L. Liu, J. Yue, Q. Zhang, A. Zhou, O. Borodin, L. Suo, H. Li, L. Chen, K. Xu, Y.S. Hu, High-Voltage Aqueous Na-Ion Battery Enabled by Inert-Cation-Assisted Water-in-Salt Electrolyte, Adv. Mater., 32 (2020) 1904427.<\/p>\n

[2] X. Xie, S. Liang, J. Gao, S. Guo, J. Guo, C. Wang, G. Xu, X. Wu, G. Chen, J. Zhou, Manipulating the ion-transfer kinetics and interface stability for high-performance zinc metal anodes, Energy Environ. Sci., (2020).<\/p>\n

[3] K.W. Nam, H. Kim, Y. Beldjoudi, T.W. Kwon, D.J. Kim, J.F. Stoddart, Redox-Active Phenanthrenequinone Triangles in Aqueous Rechargeable Zinc Batteries, J. Am. Chem. Soc., (2020).<\/p>\n

[4] C. Liu, X. Chi, Q. Han, Y. Liu, A High Energy Density Aqueous Battery Achieved by Dual Dissolution\/Deposition Reactions Separated in Acid\u2010Alkaline Electrolyte, Adv. Energy Mater., (2020) 1903589.<\/p>\n

[5] P. Wang, Z. Chen, H. Wang, Z. Ji, Y. Feng, J. Wang, J. Liu, M. Hu, J. Fei, W. Gan, Y. Huang, A high-performance flexible aqueous Al ion rechargeable battery with long cycle life, Energy Storage Mater., 25 (2020) 426-435.<\/p>\n

[6] H. Li, J. Yang, J. Cheng, T. He, B. Wang, Flexible aqueous ammonium-ion full cell with high rate capability and long cycle life, Nano Energy, 68 (2020) 104369.<\/p>\n

\u672c\u6587\u7531\u738b\u8001\u5e08<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

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