{"id":195536,"date":"2020-02-08T06:06:48","date_gmt":"2020-02-07T22:06:48","guid":{"rendered":"\/\/m.iemloyee.com\/?p=195536"},"modified":"2020-02-06T16:48:28","modified_gmt":"2020-02-06T08:48:28","slug":"%e5%a4%a9%e5%a4%a7%e5%8d%97%e5%bc%80-adv-mater-%e6%8a%a5%e9%81%93%ef%bc%9a%e5%90%88%e7%90%86%e8%ae%be%e8%ae%a1%e5%b0%96%e6%99%b6%e7%9f%b3co2vo4%ef%bc%8c%e5%ae%9e%e7%8e%b0%e4%bc%98%e5%bc%82%e7%9a%84o","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=195536","title":{"rendered":"\u5929\u5927&\u5357\u5f00 Adv. Mater.\u62a5\u9053\uff1a\u5408\u7406\u8bbe\u8ba1\u5c16\u6676\u77f3Co2VO4\uff0c\u5b9e\u73b0\u4f18\u5f02\u7684ORR\u7535\u50ac\u5316\u6027\u80fd"},"content":{"rendered":"
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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u57fa\u4e8e\u6b64\uff0c\u5929\u6d25\u5927\u5b66\u7684\u51cc\u6d9b\u6559\u6388\u3001\u5357\u5f00\u5927\u5b66\u7684\u80e1\u632f\u8283\u6559\u6388\u4ee5\u53ca\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u7684\u4e54\u4e16\u748b\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8054\u5408\u62a5\u9053\u4e86\u4e00\u79cd\u5c16\u6676\u77f3\u6c27\u5316\u7269\u2014Co2<\/sub>VO4<\/sub>\uff0c\u901a\u8fc7\u5c06\u91d1\u5c5e\u9492\u539f\u5b50\u94fe\u4e0e\u7535\u6d3b\u6027\u94b4\u9633\u79bb\u5b50\u7ed3\u5408\u6765\u5b9e\u73b0\u4f18\u5f02\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u6027\u80fd\uff0c\u4ee5\u6ee1\u8db3\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u7b49\u7684\u5173\u952e\u5de5\u827a\u7684\u9700\u6c42\u3002\u901a\u8fc7\u5b9e\u9a8c\u548c\u6a21\u62df\u7684\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\u5206\u6790\uff0c\u63ed\u793a\u4e86\u516b\u9762\u4f53\u4f4d\u70b9\u7684Co2+<\/sup>\u5448\u4f4e\u81ea\u65cb\u6001\uff0ceg<\/sub>\u4ec5\u586b\u5145\u4e00\u4e2a\u7535\u5b50\uff08t2g<\/sub>6<\/sup>eg<\/sub>1<\/sup>\uff09\uff0c\u6709\u5229\u4e8eORR\u7684\u70ed\u529b\u5b66\u3002\u5b9e\u9645\u7535\u5bfc\u7387\u7684\u6d4b\u91cf\u7ed3\u679c\u8868\u660e\uff0c\u5bf9\u6bd4\u5e38\u89c1\u94b4\u6c27\u5316\u7269CoO\u548cCo3<\/sub>O4<\/sub>\uff0cCo2<\/sub>VO4<\/sub>\u63d0\u9ad8\u4e86\u51e0\u4e2a\u6570\u91cf\u7ea7\u3002\u4f7f\u7528Co2<\/sub>VO4<\/sub>\u4f5c\u4e3aORR\u50ac\u5316\u5242\u7684\u950c-\u7a7a\u6c14\u7535\u6c60\u5177\u6709\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u5b9e\u73b0\u4e86\u521b\u7eaa\u5f55\u7684\u9ad8\u653e\u7535\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6\u2014380 mW cm-2<\/sup>\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u50ac\u5316\u5242\u7684\u950c-\u7a7a\u6c14\u7535\u6c60\u6027\u80fd\u4f18\u4e8ePt\/C\u50ac\u5316\u5242\uff0c\u5728\u7531\u91d1\u5c5e\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u78b3\u57fa\u50ac\u5316\u5242\u7ec4\u88c5\u800c\u6210\u7684\u950c-\u7a7a\u6c14\u7535\u6c60\u4e2d\u4e5f\u6700\u4e3a\u51fa\u8272\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3a\u9ad8\u6d3b\u6027\u548c\u9ad8\u5bfc\u7535\u6027\u6c27\u5316\u7269\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\uff0c\u53ef\u7528\u4e8eORR\u3001\u6c27\u6c14\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u548c\u6c22\u6c14\u6790\u51fa\u53cd\u5e94\uff08HER\uff09\u7b49\u591a\u79cd\u7535\u50ac\u5316\u5e94\u7528\u4e2d\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cRational Design of Spinel Cobalt Vanadate Oxide Co2<\/sub>VO4<\/sub> for Superior Electrocatalysis\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Mater.<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n \u56fe\u4e00\u3001Co2<\/sub>VO4<\/sub>\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n \u56fe\u4e8c\u3001Co2<\/sub>VO4<\/sub>\u7684\u7ed3\u6784\u8868\u5f81<\/strong> \uff08c\uff09Co2<\/sub>VO4<\/sub>\u7684\u539f\u5b50\u7ea7HAADF-STEM\u56fe\u50cf\u53ca\u5bf9\u5e94\u7684\u6676\u4f53\u7ed3\u6784\u6a21\u578b\uff1b<\/p>\n \uff08d\uff09\u5355\u4e2aCo2<\/sub>VO4<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684HAADF-STEM\u56fe\u50cf\u53ca\u5bf9\u5e94\u7684\u4f4e\u500d\u56fe\u50cf\uff1b<\/p>\n \uff08e-f\uff09Co\u548cV\u7684\u5143\u7d20\u9762\u5206\u5e03\u53caCo 2p\u548cV 2p XPS\u8c31\u56fe\u3002<\/p>\n \u56fe\u4e09\u3001Co2<\/sub>VO4<\/sub>\u7684\u7535\u5b50\u7ed3\u6784<\/strong> \uff08b\uff09\u5b9e\u9a8c\u548c\u6a21\u62df\u7684Co2<\/sub>VO4<\/sub> Co-L2,3<\/sub>\u8fb9EELS\u8c31\u56fe\u5bf9\u6bd4\uff1b<\/p>\n \uff08c\uff09\u6a21\u62df\u7684Td<\/sub>+Oh<\/sub>\uff08HS\uff09\u3001Td<\/sub>+Oh<\/sub>\uff08LS\uff09\u548c\u5b9e\u9a8c\u66f2\u7ebf\u7684\u5206\u652f\u6bd4\uff08BRs\uff09\uff1b<\/p>\n \uff08d\uff09HS\u548cLS\u72b6\u6001\u7684\u516b\u9762\u4f53\u4f4d\u70b9\uff08Oh<\/sub>\uff09\u7684Co2+<\/sup>\u7535\u5b50\u7ed3\u6784\u3002<\/p>\n \u56fe\u56db\u3001Co2<\/sub>VO4<\/sub>\u50ac\u5316\u5242\u7684ORR\u6d3b\u6027<\/strong> \uff08b\uff09Co3<\/sub>O4<\/sub>\u3001CoO\u548cCo2<\/sub>VO4<\/sub>\u7684ORR\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n \uff08c-d\uff090.85 VRHE<\/sub>\u4e0bCo3<\/sub>O4<\/sub>\u3001CoO\u548cCo2<\/sub>VO4<\/sub>\u7684\u6bd4\u6d3b\u6027\uff08is<\/sub>\uff09\u548c\u8d28\u91cf\u6d3b\u6027\uff08im<\/sub>\uff09\u3002<\/p>\n \u56fe\u4e94\u3001Co2<\/sub>VO4<\/sub>\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781ORR\u50ac\u5316\u5242\u7684\u950c-\u7a7a\u6c14\u7535\u6c60\u7684\u6027\u80fd<\/strong> \uff08c\uff09\u57fa\u4e8eCo2<\/sub>VO4<\/sub>\u7684\u950c\u7a7a\u7535\u6c60\u572820 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u00a0 \u00a0 \u00a0 \u00a0 \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u5c06\u91d1\u5c5e\u9492\u539f\u5b50\u94fe\u4e0e\u7535\u6d3b\u6027\u94b4\u9633\u79bb\u5b50\u76f8\u7ed3\u5408\uff0c\u6210\u529f\u5730\u5408\u6210\u5e76\u6d4b\u8bd5\u4e86\u65b0\u578b\u5c16\u6676\u77f3Co2<\/sub>VO4<\/sub>\u50ac\u5316\u5242\uff0c\u83b7\u5f97\u4e86\u9ad8\u6548\u4e14\u7a33\u5b9a\u7684ORR\u6027\u80fd\u3002\u901a\u8fc7\u5c06\u5b9e\u9a8c\u548c\u6a21\u62df\u7684\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\u5206\u6790\u4e0e\u7406\u8bba\u8ba1\u7b97\u76f8\u7ed3\u5408\uff0c\u8bc1\u660e\u4e86Co2<\/sub>VO4<\/sub>\u7684\u4f18\u5f02\u6027\u80fd\u662f\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u5176\u4e2d\u516b\u9762\u4f53\u914d\u4f4d\u7684Co2+<\/sup>\u5448\u4f4e\u81ea\u65cb\u72b6\u6001\uff0c\u5e76\u5177\u6709\u7406\u60f3\u7684eg<\/sub>\u7535\u5b50\u586b\u5145\u65701\u3002\u6b64\u5916\uff0c\u7535\u5bfc\u7387\u7684\u6d4b\u91cf\u7ed3\u679c\u8868\u660e\uff0cCo2<\/sub>VO4<\/sub>\u76f8\u6bd4CoO\u548cCo3<\/sub>O4<\/sub>\u63d0\u9ad8\u4e86\u51e0\u4e2a\u6570\u91cf\u7ea7\u3002\u4f7f\u7528Co2<\/sub>VO4<\/sub>\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781\u7684ORR\u50ac\u5316\u5242\u7684\u950c\u7a7a\u6c14\u7535\u6c60\uff0c\u5177\u6709380 mW cm-2<\/sup>\u7684\u521b\u7eaa\u5f55\u653e\u7535\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6\uff0c\u5728\u7531\u91d1\u5c5e\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u78b3\u57fa\u50ac\u5316\u5242\u7ec4\u88c5\u7684\u950c-\u7a7a\u6c14\u7535\u6c60\u4e2d\u6700\u4e3a\u51fa\u8272\u3002\u8be5\u6210\u679c\u4e3a\u8bbe\u8ba1\u7528\u4e8e\u7535\u50ac\u5316\u5e94\u7528\u7684\u9ad8\u6d3b\u6027\u548c\u9ad8\u5bfc\u7535\u6027\u6c27\u5316\u7269\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<\/p>\n
\n \uff08a-b\uff09Co2<\/sub>VO4<\/sub>\u7eb3\u7c73\u7247\u7684SEM\u56fe\u50cf\uff0c\u63d2\u56fe\u4e3aCo2<\/sub>VO4<\/sub>\u7684XRD\u56fe\u8c31\uff1b<\/p>\n
\n \uff08a\uff09\u901a\u8fc7\u56db\u70b9\u63a2\u9488\u6cd5\u6d4b\u91cf\u7684Co3<\/sub>O4<\/sub>\u3001CoO\u548cCo2<\/sub>VO4<\/sub>\u7684\u7535\u5bfc\u7387\uff1b<\/p>\n
\n \uff08a\uff091.23 VRHE<\/sub>\u4e0b\uff0cHS\u548cLS\u72b6\u6001\u7684\u516b\u9762\u4f53\u4f4dCo2+<\/sup>\u7684ORR\u81ea\u7531\u80fd\u56fe\uff1b<\/p>\n
\n \uff08a-b\uff09\u4ee5Co3<\/sub>O4<\/sub>\u3001CoO\u548cCo2<\/sub>VO4<\/sub>\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781ORR\u50ac\u5316\u5242\u7684\u950c\u7a7a\u7535\u6c60\u7684\u6781\u5316\u66f2\u7ebf\u548c\u76f8\u5e94\u7684\u529f\u7387\u5bc6\u5ea6\u56fe\uff1b<\/p>\n