{"id":195318,"date":"2020-05-18T06:34:36","date_gmt":"2020-05-17T22:34:36","guid":{"rendered":"\/\/m.iemloyee.com\/?p=195318"},"modified":"2020-05-17T22:34:50","modified_gmt":"2020-05-17T14:34:50","slug":"%e8%b6%85%e6%b5%93%e7%bc%a9%e7%94%b5%e8%a7%a3%e6%b6%b2%e6%88%96%e5%b0%86%e6%98%af%e4%b8%aa%e9%a3%8e%e5%90%91%e6%a0%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=195318","title":{"rendered":"\u8d85\u6d53\u7f29\u7535\u89e3\u6db2\u6216\u5c06\u662f\u4e2a\u98ce\u5411\u6807"},"content":{"rendered":"

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\u7f8e\u56fd\u6ce2\u58eb\u987f\u5b66\u9662Dunwei Wang\u6559\u6388\u7ec4\u7814\u7a76\u8868\u660e\u901a\u8fc7\u4f7f\u7528\u4e0d\u5305\u542b\u6709\u673a\u6eb6\u5242\u7684\u76d0\u5305\u6c34\u7535\u89e3\u6db2\u4f53\u7cfb\u53ef\u4ee5\u89e3\u51b3Li-O2<\/sub>\u7535\u6c60\u7cfb\u7edf\u4e2d\u7531\u4e8e\u542b\u6c27\u7269\u8d28\u7684\u9ad8\u53cd\u5e94\u6d3b\u6027\u4f7f\u5f97\u5df2\u77e5\u7684\u6709\u673a\u7535\u89e3\u6db2\u7a33\u5b9a\u6027\u5dee\u7684\u95ee\u9898\u3002[7]<\/sup>\u672c\u8d28\u4e0a\uff0c\u8be5\u7535\u89e3\u6db2\u7531\u8d85\u6d53\u7f29LiTFSI\uff08\u53cc\uff08\u4e09\u6c1f\u7532\u78fa\u9170\u57fa\uff09\u9170\u4e9a\u80fa\u9502\uff09\u7ec4\u6210\uff0c\u5176\u4e2dH2<\/sub>O\u5206\u5b50\u88ab\u9501\u5b9a\u5728\u79bb\u5b50\u4e0a\uff0c\u5e76\u4e14\u5bf9Li2<\/sub>O2<\/sub>\u6216\u5176\u4ed6\u6c27\u7269\u79cd\u7684\u53cd\u5e94\u6027\u5f88\u5c0f\u3002\u6700\u7ec8\u7ed3\u679c\u662f\u4e00\u79cd\u9ad8\u6548\u7535\u89e3\u6db2\u53ef\u5728\u9634\u6781\u4e0a\u7a33\u5b9a\u5730\u8fd0\u884c\u7684Li-O2<\/sub>\u7535\u6c60\uff0c\u5e76\u5177\u6709\u51fa\u8272\u7684\u5faa\u73af\u5bff\u547d\uff08\u5982\u56fe6\u6240\u793a\uff09\u3002\u8be5\u7814\u7a76\u4e3a\u9ad8\u6027\u80fdLi-O2<\/sub>\u7535\u6c60\u6253\u5f00\u4e86\u65b0\u7684\u5927\u95e8\u3002<\/p>\n

\u56fe6. Li-O2<\/sub>\u7535\u6c60\u5728\u76d0\u5305\u6c34\u7535\u89e3\u6db2\u4f53\u7cfb\u4e2d\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u3010<\/b><\/strong>\u94a0\u79bb\u5b50\u7535\u6c60<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

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\u56fe7. \u786c\u78b3\/Na\u534a\u7535\u6c60\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u97e9\u56fd\u9996\u5c14\u56fd\u7acb\u5927\u5b66Kisuk Kang\u6559\u6388\u56e2\u961f\u9488\u5bf9\u9ad8\u6d53\u5ea6\u7535\u89e3\u6db2\u4f53\u7cfb\u4f4e\u6210\u672c\u6eb6\u8d28\u8fdb\u884c\u4e86\u5f00\u53d1\u3002[9]<\/sup>\u7ed3\u679c\u53d1\u73b0\u5728\u6c34\u7cfb\u7535\u89e3\u6db2\u4e2d\u4f7f\u7528NaClO4<\/sub>\u6eb6\u8d28\u53ef\u901a\u8fc7\u6291\u5236\u6c34\u5206\u89e3\u6709\u6548\u5730\u62d3\u5bbd\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\uff0c\u5e76\u8bf1\u5bfc\u5f62\u6210\u7a33\u5b9a\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8\uff08SEI\uff09\u800c\u65e0\u9700\u6d89\u53ca\u76d0\u9634\u79bb\u5b50\u7684\u8fd8\u539f\u3002SEI\u5c42\u7531Na2<\/sub>CO3<\/sub>\u548c\u5305\u62ecNaOH\u7684Na-O\u5316\u5408\u7269\u7ec4\u6210\uff0c\u53ef\u786e\u4fdd\u7531Na4<\/sub>Fe3<\/sub>\uff08PO4<\/sub>\uff092<\/sub>\uff08P2<\/sub>O7<\/sub>\uff09\u9634\u6781\u548cNaTi2<\/sub>\uff08PO4<\/sub>\uff093<\/sub>\u9633\u6781\u7ec4\u6210\u7684\u5168\u7535\u6c60\u5728\u8f83\u957f\u7684\u65f6\u95f4\u5185\u5177\u6709\u51fa\u8272\u7684\u7535\u5316\u5b66\u5b58\u50a8\u7a33\u5b9a\u6027\u3002\u8fd9\u7c7b\u65b0\u7684\u7535\u89e3\u6db2\u7cfb\u7edf\u5177\u6709\u51fa\u8272\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5728200\u2103\u4e0b1C\u5faa\u73af\u65f6\u5e93\u4ed1\u6548\u7387\u8fbe\u523099\uff05\uff0c\u8fd9\u4f18\u4e8e\u57fa\u4e8eNaCF3<\/sub>SO3<\/sub>\u7684\u6700\u65b0\u8d85\u6d53\u7f29\u4f53\u7cfb\uff0c\u5982\u56fe8\u6240\u793a\u3002<\/p>\n

\u56fe8. Na4<\/sub>Fe3<\/sub>\uff08PO4<\/sub>\uff092<\/sub>\uff08P2<\/sub>O7<\/sub>\uff09\/NaTi2<\/sub>\uff08PO4<\/sub>\uff093<\/sub>\u5168\u7535\u6c60\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u53c2\u8003\u6587\u732e\u3011<\/b><\/strong><\/p>\n

[1] Oleg Borodin, Julian Self, Kristin A. Persson, Chunsheng Wang, Kang Xu, Uncharted Waters: Super-Concentrated Electrolytes, Joule 2020, 4, 69-100.<\/p>\n

[2] Jianhui Wang, Yuki Yamada, Keitaro Sodeyama, Ching Hua Chiang, Yoshitaka Tateyama, Atsuo Yamada, Superconcentrated Electrolytes for a High-Voltage Lithium-Ion Battery, Nature Comm. 2016, 7, 1-9.<\/p>\n

[3] Chongyin Yang, Ji Chen, Tingting Qing, Xiulin Fan, Wei Sun, Arthur von Cresce, Michael S. Ding, Oleg Borodin, Jenel Vatamanu, Marshall A. Schroeder, Nico Eidson, Chunsheng Wang, Kang Xu, 4.0 V Aqueous Li-Ion Batteries, Joule 1, 122\u2013132.<\/p>\n

[4] Tohru Shiga, Chika-aki Okuda, Yuichi Kato, Hiroki Kondo, Highly Concentrated Electrolytes Containing a Phosphoric Acid Ester Amide with Self-Extinguishing Properties for Use in Lithium Batteries, J. Phys. Chem. C 2018, 122, 9738-9745.<\/p>\n

[5] Azusa Nakanishi, Kazuhide Ueno, Daiki Watanabe, Yosuke Ugata, Yoshiharu Matsumae, Jiali Liu, Morgan L. Thomas, Kaoru Dokko, Masayoshi Watanabe, Sulfolane-Based Highly Concentrated Electrolytes of Lithium Bis(trifluoromethanesulfonyl)amide: Ionic Transport, Li-Ion Coordination, and Li-S Battery Performance, J. Phys. Chem. C 2019, 123, 14229-14238.<\/p>\n

[6] Hyea Kim, Feixiang Wu, Jung Tae Lee, Naoki Nitta, Huan-Ting Lin, Martin Oschatz, Won Il Cho, Stefan Kaskel, Oleg Borodin, Gleb Yushin, In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes, Adv. Energy Mater. 2014, 1401792.<\/p>\n

[7] Qi Dong, Xiahui Yao, Yanyan Zhao, Miao Qi, Xizi Zhang, Hongyu Sun, Yumin He, Dunwei Wang, Cathodically Stable Li-O2<\/sub>Battery Operations Using Water-in-Salt Electrolyte, Chem 2018, 4, 1345-1358.<\/p>\n

[8] Koji Takada, OrcidYuki Yamada, Eriko Watanabe, OrcidJianhui Wang, Keitaro Sodeyama, Yoshitaka Tateyama, OrcidKazuhisa Hirata, Takeo Kawase, Atsuo Yamada, Unusual Passivation Ability of Superconcentrated Electrolytes toward Hard Carbon Negative Electrodes in Sodium-Ion Batteries, ACS Appl. Mater. Interfaces 2017, 9, 39, 33802-33809.<\/p>\n

[9] Myeong Hwan Lee, Sung Joo Kim, Donghee Chang, Jinsoo Kim, Sehwan Moon, Kyungbae Oh, Kyu-Young Park, Won Mo Seong, Hyeokjun Park, Giyun Kwon, Byungju Lee, Kisuk Kang, Toward a Low-Cost High-Voltage Sodium Aqueous Rechargeable Battery, Materials Today 2019, 29, 26-36.<\/p>\n

\u672c\u6587\u7531\u590f\u5929\u7684\u767d\u7f8a<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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