{"id":194975,"date":"2020-01-23T06:41:37","date_gmt":"2020-01-22T22:41:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=194975"},"modified":"2020-01-22T18:41:49","modified_gmt":"2020-01-22T10:41:49","slug":"%e7%94%b5%e5%ad%90%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e5%88%98%e6%98%8e%e4%be%a6%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9fnano-energy%ef%bc%9a%e9%80%9a%e8%bf%87%e6%8a%91%e5%88%b6spiro-ometad%e4%b8%ad","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=194975","title":{"rendered":"\u7535\u5b50\u79d1\u6280\u5927\u5b66\u5218\u660e\u4fa6\u6559\u6388\u56e2\u961fNano Energy\uff1a\u901a\u8fc7\u6291\u5236Spiro-OMeTAD\u4e2d\u9502\u76d0\u7684\u56e2\u805a\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387"},"content":{"rendered":"
\u5f15\u8a00<\/strong><\/p>\n 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\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u5218\u660e\u4fa6\u6559\u6388\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u4e14\u6613\u4e8e\u5b9e\u73b0\u7684\u9ad8\u6548\u7387\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u65b9\u6cd5\u3002\u5bf9\u57fa\u4e8eSpiro-OMeTAD\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\u901a\u8fc7\u4f7f\u7528\u5c11\u91cf\u7684PbI2<\/sub>\u4f5c\u4e3a\u6dfb\u52a0\u5242\u6765\u6291\u5236\u7a7a\u7a74\u4f20\u8f93\u5c42\u8584\u819c\u4e2d\u7684\u5b54\u6d1e\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5668\u4ef6\u7684\u5149\u7535\u6027\u80fd\u3002\u4f5c\u8005\u5229\u7528\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\uff0c\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u4ee5\u53ca\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08AFM\uff09\u53d1\u73b0\u52a0\u5165PbI2<\/sub>\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u8584\u819c\u5f62\u8c8c\u76f8\u6bd4\u4e8e\u5bf9\u7167\u7ec4\u6709\u660e\u663e\u7684\u6539\u5584\u3002\u8fdb\u4e00\u6b65\u5229\u7528DFT\u8ba1\u7b97\u53d1\u73b0\uff0c\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e2d\u7684\u6dfb\u52a0\u7269PbI2<\/sub>\u548cTBP\u7531\u4e8e\u5206\u5b50\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u53ef\u4ee5\u5f62\u6210\u7edc\u5408\u7269\u3002\u8fd9\u79cd\u7edc\u5408\u7269\u80fd\u591f\u6709\u6548\u963b\u788dLi-TFSI\u7684\u56e2\u805a\u548c\u4f20\u8f93\u5c42\u5b54\u6d1e\u7684\u7684\u4ea7\u751f\u3002\u4f5c\u8005\u53c8\u8fdb\u4e00\u6b65\u5206\u6790\u4e86PbI2<\/sub>\u7684\u63ba\u5165\u5bf9\u5668\u4ef6\u5149\u7535\u6027\u80fd\u7684\u5f71\u54cd\u3002\u7a7a\u95f4\u7535\u8377\u9650\u5236\u7535\u6d41\u6cd5\uff08SCLC\uff09\uff0c\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08EIS\uff09\uff0c\u8367\u5149\u5149\u8c31\uff08PL\uff09\u7b49\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\uff0cPbI2<\/sub>\u53ef\u4ee5\u63d0\u9ad8\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e2d\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387\uff0c\u964d\u4f4e\u9499\u949b\u77ff\u548c\u7a7a\u7a74\u4f20\u8f93\u5c42\u754c\u9762\u7684\u7535\u8377\u590d\u5408\u901f\u7387\u5e76\u63d0\u9ad8\u7535\u8377\u62bd\u53d6\u901f\u7387\u3002\u56e0\u6b64\uff0c\u4fee\u9970\u540e\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u548c\u7535\u8377\u8f7d\u6d41\u5b50\u63d0\u53d6\u6548\u7387\u663e\u8457\u63d0\u9ad8\uff0c\u6700\u7ec8\u901a\u8fc7\u4f18\u5316\u540e\u7684\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\uff0c\u53ef\u4ee5\u83b7\u5f97\u8d85\u8fc720\uff05\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u63d0\u9ad8HTL\u6750\u6599\u548c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u5355\u6709\u6548\u7684\u65b9\u6cd5\u3002<\/p>\n \u76f8\u5173\u7684\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cInhibited aggregation of lithium salt in spiro-OMeTAD toward highly efficient perovskite solar cells\u201d\u53d1\u8868\u5728Elsevier\u51fa\u7248\u793e\u65d7\u4e0bNano Energy\u6742\u5fd7\u4e0a\u3002\u7535\u5b50\u79d1\u6280\u5927\u5b66\u6750\u6599\u4e0e\u80fd\u6e90\u5b66\u9662\u4e3a\u8bba\u6587\u7b2c\u4e00\u5355\u4f4d\uff0c\u5218\u6d0b\u548c\u80e1\u903e\u8d85\u535a\u58eb\u4e3a\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u5218\u660e\u4fa6\u6559\u6388\u4e3a\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n \u56fe\u6587\u7b80\u4ecb<\/strong><\/p>\n Figure 1. \u6750\u6599\u53ca\u5668\u4ef6\u5236\u5907\u793a\u610f\u56fe\u53ca\u5668\u4ef6\u5f62\u8c8c\u8868\u5f81<\/p>\n \uff08a\uff09PbI2<\/sub>\u548cTBP\u524d\u9a71\u4f53\u6eb6\u6db2\u5236\u5907\u793a\u610f\u56fe\uff0c\uff08b\uff09\u5668\u4ef6\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\uff08c-f\uff09SEM\u5f62\u8c8c\u56fe\uff0c\uff08g\uff09PbI2<\/sub>\u5bf9\u9502\u76d0\u56e2\u805a\u5f71\u54cd\u7684\u539f\u7406\u793a\u610f\u56fe\u3002<\/p>\n Figure 2. \u63ba\u5165PbI2<\/sub>\u5bf9\u7a7a\u7a74\u4f20\u8f93\u5c42\u5f62\u8c8c\u7684\u8868\u5f81\u5206\u6790<\/p>\n \u63ba\u6742PbI2<\/sub>\u524d\u540e\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u5f62\u8c8c\u8868\u5f81\u3002\uff08a\uff09\uff08c\uff09TEM\u56fe\u50cf\uff0c\uff08b\uff09\uff08d\uff09EDX\u5143\u7d20\u5206\u6790\uff0c\uff08e\uff09\uff08f\uff09AFM\u56fe\u50cf\uff0c\uff08g\uff09\uff08h\uff09AFM\u56fe\u50cf\u7684\u4e09\u7ef4\u7ed3\u6784\u3002<\/p>\n Figure 3. PbI2<\/sub>\u4e0eTBP\u5f62\u6210\u7684\u7edc\u5408\u7269\u7684\u8868\u5f81\u5206\u6790<\/p>\n \uff08a\uff09\u7d2b\u5916\u706f\u4e0b\u7684\u5149\u5b66\u7167\u7247\uff0c\uff08b\uff09TBP\uff0cPbI2<\/sub>\uff0cTBP+ PbI2<\/sub>\u7684XRD\u8c31\uff0c\uff08c\uff09DFT\u8ba1\u7b97\u7684\u5f62\u6210\u4e0d\u540c\u7edc\u5408\u7269\u7684\u76f8\u5e94\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\uff0c\uff08d\uff09\u7a00\u91ca\u540e\u6db2\u6001UV-vis\u8c31\uff0c\uff08e\uff09\u7edc\u5408\u7269\u914d\u4f4d\u7684\u7403\u68cd\u6a21\u578b\u793a\u610f\u56fe\u3002<\/p>\n Figure 4. \u63ba\u5165PbI2<\/sub>\u540e\u5bf9\u5668\u4ef6\u7535\u5b66\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n \uff08a-c\uff09\u7a7a\u7a74\u4f20\u8f93\u5c42\u63ba\u6742\u524d\u540e\u7535\u5316\u5b66\u963b\u6297\u8c31\u6d4b\u8bd5\uff0c\uff08d\uff09\u7d2b\u5916\u5149\u7535\u5b50\u80fd\u8c31\uff0c\uff08e\uff09\u7a33\u6001\u8367\u5149\u53d1\u5c04\u8c31\uff0c\uff08f\uff09\u65f6\u95f4\u5206\u8fa8\u8367\u5149\u5149\u8c31\u3002<\/p>\n Figure 5. \u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u4f0f\u6027\u80fd\u6d4b\u8bd5<\/p>\n \uff08a\uff09\u4e0d\u540cPbI2<\/sub>\u63ba\u6742\u91cf\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u6548\u7387\u5206\u5e03\u7edf\u8ba1\u56fe\uff0c\uff08b\uff09\u4fee\u9970\u524d\u540e\u6700\u4f73\u5668\u4ef6\u7684J-V\u66f2\u7ebf\uff0c\uff08c\uff09\u6700\u9ad8\u6548\u7387\u5668\u4ef6\u5728\u6700\u5927\u529f\u7387\u70b9\u7684\u7a33\u6001\u8f93\u51fa\uff0c\uff08d\uff09\u6700\u4f73\u5668\u4ef6\u7684\u5149\u54cd\u5e94\u6d4b\u8bd5\u3002<\/p>\n \u5c0f\u7ed3<\/strong><\/p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u6df1\u5165\u900f\u5f7b\u5730\u5206\u6790\u4e86PbI2<\/sub>\u4f5c\u4e3a\u6dfb\u52a0\u7269\u5bf9\u7a7a\u7a74\u4f20\u8f93\u5c42\u5f62\u8c8c\u548c\u8f7d\u6d41\u5b50\u884c\u4e3a\u7684\u5f71\u54cd\u3002\u8bd5\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u901a\u8fc7\u6291\u5236Li-TFSI\u7684\u805a\u96c6\uff0c\u4fee\u9970\u540eHTL\u7684\u5f62\u8c8c\u6709\u4e86\u660e\u663e\u7684\u63d0\u5347\uff0c\u540c\u65f6\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u548c\u7535\u8377\u8f7d\u6d41\u5b50\u62bd\u53d6\u6548\u7387\uff0c\u83b7\u5f97\u4e86\u8d85\u8fc720%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u800c\u4e14\u4fee\u9970\u540e\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u8868\u73b0\u51fa\u5feb\u901f\u7684\u77ac\u6001\u54cd\u5e94\uff08<1s\uff09\u4ee5\u8fbe\u5230\u7a33\u6001\uff0c\u8fd9\u4e00\u7ed3\u679c\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u8d85\u8fc7\u65e0PbI2<\/sub>\u6dfb\u52a0\u7269\u7684\u5668\u4ef6\u3002\u8fd9\u4e00\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7b56\u7565\u6765\u5236\u5907\u65e0\u7a7a\u6d1e\u7684HTL\uff0c\u4ee5\u589e\u5f3a\u7535\u8377\u8f7d\u6d41\u5b50\u7684\u4f20\u8f93\uff0c\u5c06\u6709\u52a9\u4e8ePSC\u6027\u80fd\u7684\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002<\/p>\n \u8bba\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.nanoen.2020.104483<\/a><\/p>\n Inhibited aggregation of lithium salt in spiro-OMeTAD toward highly efficient perovskite solar cells (Nano Energy, 2019, accepted)<\/p>\n
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