{"id":194486,"date":"2020-04-23T21:26:17","date_gmt":"2020-04-23T13:26:17","guid":{"rendered":"\/\/m.iemloyee.com\/?p=194486"},"modified":"2020-04-23T21:26:40","modified_gmt":"2020-04-23T13:26:40","slug":"%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e6%b2%88%e5%bf%97%e8%b1%aa%e5%92%8c%e8%8c%83%e6%98%9f%e6%b2%b3macromolecules%ef%bc%9a%e5%8c%85%e5%90%ab%e4%b8%a4%e7%a7%8d%e4%bb%8b%e6%99%b6%e5%a4%b9%e5%b1%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=194486","title":{"rendered":"\u5317\u4eac\u5927\u5b66\u6c88\u5fd7\u8c6a\u548c\u8303\u661f\u6cb3Macromolecules\uff1a\u5305\u542b\u4e24\u79cd\u4ecb\u6676\u5939\u5c42\u6db2\u6676\u805a\u5408\u7269\u7684\u6746\u68d2\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u5c42\u7ea7\u6709\u5e8f\u7ed3\u6784"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u5317\u4eac\u5927\u5b66\u6c88\u5fd7\u8c6a\u6559\u6388\u548c\u8303\u661f\u6cb3\u6559\u6388<\/strong>\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u57fa\u4e8e\u4e0a\u8ff0\u4e24\u79cd\u5177\u6709\u4e0d\u540c\u7eb3\u7c73\u7ed3\u6784\u5355\u5143\u7684MJLCP\u7684\u6746-\u68d2BCP\uff0c\u7136\u540e\u7cfb\u7edf\u5730\u7814\u7a76\u4e86BCP\u7684\u5c42\u7ea7\u6709\u5e8f\u7ed3\u6784\u3002\u5fae\u76f8\u5206\u79bb\u7684\u7ed3\u6784\u968fBCP\u7684\u603b\u805a\u5408\u5ea6\uff08N\uff09\u548c\u5176\u4e2d\u4e00\u4e2a\u5d4c\u6bb5\u7684\u4f53\u79ef\u5206\u6570\uff08f\uff09\u800c\u53d8\u5316\u3002\u540c\u65f6\uff0c\u63d0\u51fa\u4e86\u4ee3\u8868\u4e24\u4e2a\u5177\u6709POSS\u5355\u5143\u7684MJLCP\u548c\u68d2\u72b6\u4ecb\u6676\u4e4b\u95f4\u7684\u7ed3\u6784\u5dee\u5f02\u7684\u5f62\u72b6\u4e0d\u5bf9\u79f0\u6027\uff0c\u4ee5\u8bf1\u5bfc\u5f62\u6210\u4e0d\u540c\u7684LC\u7ed3\u6784\u3002SmA\u548cColh\u76f8\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u5728\u6b64\u57fa\u7840\u7814\u7a76\u4e2d\u5f15\u8d77\u4e86\u7ed3\u6784\u7684\u6f14\u53d8\uff0c\u8fd9\u53ef\u4ee5\u5e2e\u52a9\u4e86\u89e3\u66f4\u591a\u5173\u4e8e\u5fae\u7ec6\u5206\u79bb\u7ed3\u6784\u4e0e\u6746-\u68d2BCP\u4e2dLC\u76f8\u4e4b\u95f4\u5173\u7cfb\u7684\u4fe1\u606f\u3002\u8fd9\u9879\u5de5\u4f5c\u8fd8\u5728\u521a\u6027\u5747\u805a\u7269\u548c\u76f8\u5e94\u7684BCP\u4e4b\u95f4\u5efa\u7acb\u4e86\u6e05\u6670\u7684\u8054\u7cfb\uff0c\u8fd9\u53ef\u4ee5\u4e3a\u68d2-\u68d2BCP\u7684\u81ea\u7ec4\u88c5\u5f00\u8f9f\u65b0\u7684\u9014\u5f84\u3002\u6b64\u5916\uff0c\u8fd9\u9879\u7814\u7a76\u53ef\u4ee5\u8fdb\u4e00\u6b65\u5e2e\u52a9\u6307\u5bfc\u8584\u819c\u7ec4\u88c5\uff0c\u7eb3\u7c73\u56fe\u6848\u548c\u7eb3\u7c73\u6a21\u677f\u7684\u5e94\u7528\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/strong>Hierarchically Ordered Structures of Rod\u2212Rod Block Copolymers Containing Two Mesogen-Jacketed Liquid Crystalline Polymers<\/strong>\u201d<\/strong>\u53d1\u8868\u5728Macromolecules<\/strong>\u4e0a<\/strong>\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.SmPn<\/strong>\u7684\u5316\u5b66\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2.<\/strong> \u7b2c\u4e00\u6b21\u51b7\u5374\u548c\u968f\u540e\u7684\u52a0\u70ed\u8fc7\u7a0b\u4e2d<\/strong>SmPn<\/strong>\u7684<\/strong>DSC<\/strong>\u70ed\u5206\u6790\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3.PNb10PP<\/strong>\u6bb5\u7684<\/strong>LC<\/strong>\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

S10P30\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u4e00\u7ef4WAXD\u66f2\u7ebf\uff08a\uff09\u548cPNb10PP\u6bb5\u7684SmA\u76f8\u793a\u610f\u56fe\uff08b\uff09<\/p>\n

\u56fe<\/strong>4.PNb12POSS<\/strong>\u7247\u6bb5\u7684<\/strong>LC<\/strong>\u548c\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

S30P30\u5728\u52a0\u70ed\uff08a\uff09\u548c\u51b7\u5374\uff08b\uff09\u8fc7\u7a0b\u4e2d\u7684\u4e00\u7ef4WAXD\u8f6e\u5ed3\u4ee5\u53caPNb12POSS\u6bb5\u7684Colh\u76f8\u793a\u610f\u56fe\uff08c\uff09<\/p>\n

\u56fe<\/strong>5.S10P30<\/strong>\uff0c<\/strong>S20P30<\/strong>\u548c<\/strong>S30P30<\/strong>\u7684<\/strong>SAXS<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6.S10P30<\/strong>\u7684<\/strong>TEM<\/strong>\u663e\u5fae\u7167\u7247\uff08<\/strong>a,b<\/strong>\uff09\u548c\u5206\u5c42\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff08<\/strong>c<\/strong>\uff09<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>7.TEM<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>8.<\/strong> S30P120<\/strong>\u548c<\/strong>S80P120<\/strong>\u7684<\/strong>TEM<\/strong>\u663e\u5fae\u7167\u7247<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>9.SmPn<\/strong>\u7684\u8868\u89c2\u76f8\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7ROMP\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u57fa\u4e8eMJLCP\u7684\u68d2-\u68d2BCP SmPn\uff0c\u8be5MJLCP\u5177\u6709\u805a\u964d\u51b0\u7247\u70ef\u9aa8\u67b6\u548c\u4e24\u4e2a\u4e0d\u540c\u7684\u7eb3\u7c73\u7ed3\u6784\u5355\u5143\u3002\u7eb3\u7c73\u7ed3\u6784\u5355\u5143\u7684\u5f62\u72b6\uff0cDP\u548c\u4e24\u6bb5\u4e4b\u95f4\u7684\u4e0d\u5bf9\u79f0\u6027\u5bf9SmPn\u7684\u5c42\u7ea7\u6709\u5e8f\u7ed3\u6784\u5f71\u54cd\u5f88\u5927\u3002\u968f\u7740fPNb12POSS<\/sub>\u7684\u589e\u52a0\uff0cSmPn\u7684\u5fae\u76f8\u5206\u79bb\u7ed3\u6784\u4eceLAM\u53d8\u4e3aHEX\u3002\u9ad8\u5206\u5b50\u91cf\u7684SmPn\u6837\u54c1\u5f88\u96be\u5f62\u6210\u6709\u5e8f\u7ed3\u6784\uff0c\u8fd9\u4e3b\u8981\u662f\u56e0\u4e3a\u5176\u52a8\u529b\u5b66\u8f83\u6162\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5236\u9020\u5c42\u6b21\u7ed3\u6784\u7684\u901a\u7528\u65b9\u6cd5\u3002\u8fd9\u4e9bSmPn BCP\u53ef\u80fd\u5728\u7eb3\u7c73\u6a21\u677f\u4e2d\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aHierarchically Ordered Structures of Rod\u2212Rod Block Copolymers Containing Two Mesogen-Jacketed Liquid Crystalline Polymers<\/a>. Macromolecules, <\/em>2019<\/strong>, DOI: 10.1021\/acs.macromol.9b01759<\/p>\n

\u672c\u6587\u7531tt\u4f9b\u7a3f\u3002\u00a0<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

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