{"id":194158,"date":"2020-01-14T06:19:01","date_gmt":"2020-01-13T22:19:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=194158"},"modified":"2020-01-13T21:55:15","modified_gmt":"2020-01-13T13:55:15","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%96%af%e5%9d%a6%e7%a6%8f%e5%8c%97%e5%8c%96%e5%b7%a5nature-nanotechnology%ef%bc%9a%e6%b0%ae%e6%8e%ba%e6%9d%82%e7%ba%b3%e7%b1%b3%e9%87%91%e5%88%9a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=194158","title":{"rendered":"\u65af\u5766\u798f&#038;\u5317\u5316\u5de5Nature Nanotechnology\uff1a\u6c2e\u63ba\u6742\u7eb3\u7c73\u91d1\u521a\u77f3\/Cu\u754c\u9762\u534f\u540c\u589e\u5f3a\u50ac\u5316CO2\u8fd8\u539f\u4e3aC2\u542b\u6c27\u5316\u5408\u7269"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u5728\u78b3\u5e73\u8861\u80fd\u6e90\u8f6c\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\u5bf9\u4e8e\u89e3\u51b3\u6c14\u5019\u53d8\u5316\u548c\u5168\u7403\u80fd\u6e90\u9700\u6c42\u4e0d\u65ad\u589e\u957f\u81f3\u5173\u91cd\u8981\u3002\u4e3b\u8981\u7684\u7814\u7a76\u70ed\u70b9\u4e3a\u5f00\u53d1\u7528\u4e8eCO<sub>2<\/sub>\u8fd8\u539f\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\u7684\u50ac\u5316\u5242\u3002\u5df2\u77e5\u7528\u4e8eCO<sub>2<\/sub>\u8fd8\u539f\u53cd\u5e94\u7684\u7535\u5316\u5b66\u50ac\u5316\u5242\u6709\u8d35\u91d1\u5c5e\u3001\u975e\u8d35\u91d1\u5c5e\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u91d1\u5c5e\u4e8c\u5364\u5316\u7269\u3001\u5206\u5b50\u50ac\u5316\u5242\u3001\u5171\u4ef7\u6709\u673a\u9aa8\u67b6\u548c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u50ac\u5316\u5242\u5728CO<sub>2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u4ecd\u7136\u5b58\u5728\u8bb8\u591a\u95ee\u9898\uff0c\u5982\u4f4e\u80fd\u91cf\u8f6c\u5316\u7387\u3001\u5bf9\u6240\u9700\u4ea7\u54c1\u7684\u9009\u62e9\u6027\u4f4e\u3001\u6210\u672c\u9ad8\u548c\u8f83\u5dee\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7b49\u3002\u5728\u73b0\u6709\u7684CO<sub>2<\/sub>\u7535\u50ac\u5316\u8fd8\u539f\u4e2d\uff0c\u5927\u591a\u6570\u50ac\u5316\u4ea7\u7269\u4e3a\u4e00\u6c27\u5316\u78b3\uff08CO\uff09\u6216\u7532\u9178\uff08HCOOH\uff09\u3002\u76f4\u5230\u8fd1\u51e0\u5e74\u624d\u62a5\u9053\u4e86\u5728\u4e2d\u6027\u6c34\u4ecb\u8d28\u4e2d\u4ea7\u751fC\u22652\u4ea7\u7269\u7684\u5148\u8fdb\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u51e0\u4e4e\u6240\u6709\u8fd9\u4e9b\u8fd8\u539f\u8f6c\u5316\u8fc7\u7a0b\u90fd\u9700\u8981\u975e\u5e38\u8d1f\u7684\u5de5\u4f5c\u7535\u538b\u4e0b\uff08-0.9 V RHE\uff0c\u6216\u66f4\u8d1f\uff09\uff0c\u5927\u591a\u6570\u591a\u78b3\u4ea7\u54c1\u7684\u9009\u62e9\u6027\u6bd4\u8f83\u4f4e\uff0c\u5e76\u4e14\u50ac\u5316\u5242\u5bff\u547d\u6bd4\u8f83\u77ed\u77ed\uff08\u901a\u5e38\u5c11\u4e8e40 h\uff09\u3002\u91d1\u5c5eCu\u4f5c\u4e3a\u4e00\u4e2a\u50ac\u5316\u5242\u7684\u7814\u7a76\u70ed\u70b9\uff0c\u5b83\u80fd\u591f\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aC\u22652\u7684\u4ea7\u7269\uff0c\u4f46\u5728\u7535\u5316\u5b66\u64cd\u4f5c\u6761\u4ef6\u4e0b\u4e5f\u5b58\u5728\u50ac\u5316\u5242\u8010\u4e45\u6027\u95ee\u9898\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong><b>\u65af\u5766\u798f\u5927\u5b66<\/b><\/strong><strong><b>\u5d14\u5c79\u6559\u6388\u3001\u6731\u68e3\u6587<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>\u5317\u4eac\u5316\u5de5\u5927\u5b66\u8c2d\u5929\u4f1f\u9662\u58eb<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>SLAC\u56fd\u5bb6\u52a0\u901f\u5668\u5b9e\u9a8c\u5ba4Karen Chan<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong><strong><b>\uff08<\/b><\/strong><strong><b>\u5171\u540c<\/b><\/strong><strong><b>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u8bbe\u8ba1\u539f\u7406\uff0c\u901a\u8fc7\u5408\u7406\u8c03\u6574\u6c2e\u63ba\u6742\u7eb3\u7c73\u91d1\u521a\u77f3\u548c\u94dc\u7eb3\u7c73\u9897\u7c92\u7684\u7ec4\u6210\uff0c\u521b\u5efa\u4e00\u79cd\u9ad8\u9009\u62e9\u6027\u7684\u3001\u9ad8\u7a33\u5b9a\u6027\u7684\u50ac\u5316\u754c\u9762\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aC<sub>2<\/sub>\u542b\u6c27\u5316\u7269\u3002\u5728\u4ec5-0.5V\u7684\u5de5\u4f5c\u7535\u538b\u4e0b\uff0c\u8be5\u50ac\u5316\u5242\u5bf9C2\u542b\u6c27\u5316\u5408\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a~63\uff05\u3002\u6b64\u5916\uff0c\u8be5\u50ac\u5316\u5242\u5728120 h\u5185\u8868\u73b0\u51fa\u524d\u6240\u672a\u6709\u7684\u6301\u4e45\u50ac\u5316\u6027\u80fd\uff0c\u5177\u6709\u7a33\u5b9a\u7684\u7535\u6d41\u548c\u4ec519%\u7684\u6d3b\u6027\u8870\u51cf\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cCO\u5728\u94dc\/\u7eb3\u7c73\u91d1\u521a\u77f3\u754c\u9762\u4e0a\u7684\u7ed3\u5408\u589e\u5f3a\uff0c\u964d\u4f4e\u4e86CO\u4e8c\u805a\u4f5c\u7528\u7684\u8868\u9762\u52bf\u5792\uff0c\u6291\u5236\u4e86CO\u7684\u89e3\u5438\uff0c\u8fdb\u800c\u4fc3\u8fdb\u4e86C<sub>2<\/sub>\u7684\u751f\u6210\u3002\u50ac\u5316\u5242\u7ec4\u4ef6\u7684\u56fa\u6709\u7ec4\u6210\u548c\u7535\u5b50\u53ef\u8c03\u6027\u4e3a\u50ac\u5316\u754c\u9762\u63d0\u4f9b\u4e86\u65e0\u4e0e\u4f26\u6bd4\u7684\u63a7\u5236\u7a0b\u5ea6\uff0c\u4ece\u800c\u63a7\u5236\u4e86\u53cd\u5e94\u52a8\u529b\u5b66\u548c\u52a8\u529b\u5b66\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a<strong><b>\u201c<\/b><\/strong><strong><b>Synergistic enhancement of electrocatalytic CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u00a0reduction to C<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u00a0oxygenates at nitrogen-doped nanodiamonds\/Cu interface<\/b><\/strong><strong><b>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86<strong><b>Nature Nanotech.<\/b><\/strong>\u4e0a\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u65af\u5766\u798f\u5927\u5b66\u535a\u58eb\u540e\u738b\u7ea2\u971e\u3001\u66fe\u5f66\u51ef\u548c\u7eaa\u6c38\u98de\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b> N-ND\u548cN-ND\/Cu\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u539f\u7406\u56fe<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194159\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/1-11.jpg\" alt=\"\" width=\"600\" height=\"227\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/1-11.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/1-11-300x114.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>\u00a0ND\u548cN-ND\u7535\u6781\u6750\u6599\u7684\u7ed3\u6784\u3001\u6784\u578b\u548c\u7535\u5316\u5b66\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194160\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/2-10.jpg\" alt=\"\" width=\"600\" height=\"709\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/2-10.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/2-10-254x300.jpg 254w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff0c\u5408\u6210\u7684N-ND\u6750\u6599\u7684\u4f4e\u500dSEM\u56fe\u50cf\u3002\u63d2\u56fe\uff1a\u76f8\u5e94\u7684\u9ad8\u500d\u7387\u3002<\/p>\n<p>b\uff0c\u503e\u659c52\u00b0\u7684N-ND\u8584\u819c\u6a2a\u622a\u9762\u7684FIB\u56fe\u50cf\u3002<\/p>\n<p>c\uff0cN-ND\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n<p>d\uff0cN-ND\u7684\u9ad8\u5206\u8fa8\u7387N 1s XPS\u5149\u8c31\u3002<\/p>\n<p>e\uff0cN-ND\uff080.2\uff05\u6c2e\u539f\u5b50\u63ba\u6742\uff09\u7535\u6781\u5728\u4e0d\u540c\u5de5\u4f5c\u7535\u4f4d\u4e0b\u751f\u6210\u4e59\u9178\u76d0\u548c\u7532\u9178\u76d0\u79bb\u5b50\u7684\u9009\u62e9\u6027\u5206\u6790\u56fe\u3002\u8bef\u5dee\u68d2\u4ee3\u8868\u4e09\u4e2a\u72ec\u7acb\u6837\u54c1\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n<p>f\uff0cN-ND\u7535\u6781\u5728\u4e0d\u540c\u5de5\u4f5c\u7535\u4f4d\u4e0b\u751f\u6210\u4e59\u9178\u76d0\u548c\u7532\u9178\u76d0\u7684\u4ea7\u91cf\u5206\u6790\u56fe\u3002<\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u00a0N-ND\/Cu\u7535\u6781\u6750\u6599\u7684\u7ed3\u6784\u3001\u6784\u578b\u548c\u7535\u5316\u5b66\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194161\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/3-11.jpg\" alt=\"\" width=\"600\" height=\"487\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/3-11.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/3-11-300x244.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff0cN-ND\/Cu\u7684HRTEM\u56fe\u50cf\u3002HRTEM\u56fe\u50cf\u663e\u793a\u4e86\u94dc\u548c\u7eb3\u7c73\u91d1\u521a\u77f3\u7684\u5b58\u5728\uff0c\u8fd9\u662f\u7531\u663e\u5fae\u56fe\u50cf\u4e2d\u6240\u9009\u533a\u57df\u7684\u6676\u683c\u6761\u7eb9\u6240\u8bc1\u5b9e\u7684\u3002<\/p>\n<p>b\uff0cSTEM\u56fe\u50cf\uff08\u5de6\u4e0a\u65b9\uff09\u548cN-ND\/Cu\u7684\u76f8\u5e94EDX\u5149\u8c31\u5143\u7d20\u5206\u5e03\u56fe\uff08C\u3001N\u548cCu\uff09\u3002<\/p>\n<p>c\uff0cN-ND\/Cu\u819c\u7684GIWAXS 2D\u56fe\u6848\u3002\u5728q = 2.55\u00c5<sup>-1<\/sup>\u5904\u4e5f\u89c2\u5bdf\u5230\u4e86\u5fae\u5f31\u7684\u5e73\u9762\u5916\u53cd\u5c04\u7535\u5f27\uff0c\u8be5\u7535\u5f27\u662f\u7531\u4e8e\u66b4\u9732\u4e8e\u7a7a\u6c14\u800c\u4e0eCu<sub>2<\/sub>O\uff08111\uff09\u53cd\u5c04\u76f8\u5173\u7684\u3002<\/p>\n<p>d\uff0cN-ND\/Cu\u7535\u6781\u5728-0.4\u81f3-0.7 V\uff08vs. RHE\uff09\u7684\u7535\u52bf\u4e0b\u751f\u6210\u7532\u9178\u76d0\u3001\u7532\u9187\u3001\u4e59\u70ef\u3001\u4e59\u9178\u76d0\u548c\u4e59\u9187\u7684\u9009\u62e9\u6027\u5206\u6790\u56fe\u3002\u8bef\u5dee\u68d2\u4ee3\u8868\u4e09\u4e2a\u72ec\u7acb\u6837\u54c1\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n<p>e\uff0cN-ND\/Cu\u548cN-ND\u7535\u6781\u5728\u9971\u548cCO<sub>2<\/sub>\u00a0\u76840.5 M\u00a0KHCO<sub>3<\/sub>\uff08pH 7.3\uff09\u4e2d\u7684LSV\u5bf9\u6bd4\u56fe\uff08\u626b\u63cf\u901f\u7387\u4e3a50 mV s<sup>-1<\/sup>\uff09\u3002<\/p>\n<p>f\uff0cN-ND\/Cu\u7535\u6781\u751f\u6210\u7532\u9178\u76d0\u3001\u7532\u9187\u3001\u4e59\u70ef\u3001\u4e59\u9178\u76d0\u548c\u4e59\u9187\u7684\u901f\u7387\u3002\u00a0<\/p>\n<p>g\uff0cN-ND\/Cu\u7535\u6781\u7684\u4e59\u9178\u76d0\u548c\u4e59\u9187\u7b49\u4ea7\u7269\u7684\u7684\u8d28\u91cf\u6d3b\u6027\u5206\u6790\u56fe\uff08\u5b89\u57f9\u6bcf\u514b\u94dc\uff09\u3002<\/p>\n<p>h\uff0c\u5728\u957f\u671f\u7535\u89e3\u8fc7\u7a0b\u4e2d\uff0c\u6240\u6709CO<sub>2<\/sub>\u8fd8\u539f\u7684\u603bFEs\uff08\u7ea2\u7403\uff09\u548cN-ND\/Cu\u7535\u6781\u7684\u603b\u7535\u6d41\u5bc6\u5ea6\uff08\u7070\u7ebf\uff09\u3002\u5728-0.5 V\uff08vs. RHE\uff09\u7535\u89e324\u5c0f\u65f6\uff0c\u7535\u6d41\u5bc6\u5ea6\u548cFE\u5747\u53ea\u662f\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4 DFT\u8ba1\u7b97<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-194162\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/4-10.jpg\" alt=\"\" width=\"600\" height=\"466\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/4-10.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/01\/4-10-300x233.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a\uff0cH\uff08\u84dd\u8272\uff09\u3001\u94dc\uff08\u7ea2\u8272\uff09\u4e0e\u88f8\u9732ND\uff08111\uff09\u8868\u9762\u7684\u7ed3\u5408\u81ea\u7531\u80fd\u4e0eH\u7684\u5316\u5b66\u52bf\u7684\u0394\u03bcH\u7684\u5173\u7cfb\u3002 \u7070\u8272\u865a\u7ebf\u8868\u793a\u5728\u91d1\u521a\u77f3\u5408\u6210\u6761\u4ef6\u548cCu\u6e85\u5c04\u6761\u4ef6\u4e0b\u7684\u0394\u03bcH\u3002<\/p>\n<p>b\uff0c\u5728N-ND\uff08111\uff09\u4e0a\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aHCOOH\uff08\u7ea2\u8272\uff09\u548cCO\uff08\u84dd\u8272\uff09\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n<p>c\uff0c\u5728Cu\uff08111\uff09\u8868\u9762\uff08\u7070\u8272\uff09\u548cND\/Cu\u754c\u9762\uff08\u84dd\u8272\uff09\u4e0aCO\u8026\u5408\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n<p>d\uff0c\u8868\u89c2\u81ea\u7531\u80fd\u5792\uff08Ga\uff09\u548cCO\u5438\u9644\u80fd\uff08Eb\uff09\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u7528X\uff08\u6216X + X&#8217;\uff09\u6807\u8bb0\u7684\u6570\u636e\u70b9\u8868\u793a\u7ed3\u6784\u6a21\u578b\u4e2d\u7684\u78b3X\uff08\u6216X + X&#8217;\uff09\u88abN\u4ee3\u66ff\u3002<\/p>\n<p>\u3010<strong><b>\u5c0f\u7ed3<\/b><\/strong>\u3011<\/p>\n<p>\u672c\u6587\u63d0\u51fa\u4e86\u4e00\u79cd\u5c06\u94dc\u7eb3\u7c73\u7c92\u5b50\u63ba\u5165\u6c2e\u53c2\u6742\u7684\u7eb3\u7c73\u91d1\u521a\u77f3\u6750\u6599\u4e2d\uff0c\u751f\u6210N-ND\/Cu\u7684\u50ac\u5316\u754c\u9762\u7684\u8bbe\u8ba1\u539f\u5219\u3002\u7814\u7a76\u8868\u660e\uff0cCO<sub>2<\/sub>\u5230C<sub>2<\/sub>\u542b\u6c27\u5316\u7269\u7684\u8f6c\u5316\u786e\u5b9e\u53d1\u751f\u5728\u4e24\u79cd\u6750\u6599\u754c\u9762\u5904\uff0c\u5e76\u4e14\u53d7\u76ca\u4e8e\u4e24\u79cd\u7ec4\u5206\u7684\u534f\u540c\u4f5c\u7528\u3002\u5728N-ND\/Cu\u754c\u9762\uff0c\u53cd\u5e94\u52a8\u529b\u5b66\u6539\u53d8\uff0c\u6709\u5229\u4e8eC<sub>2+<\/sub>\u4ea7\u7269\u7684\u751f\u6210\uff0c\u4e0e\u76ee\u524d\u62a5\u9053\u7684\u5176\u4ed6\u4f53\u7cfb\u76f8\u6bd4\uff0c\u5177\u6709\u524d\u6240\u672a\u6709\u7684\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u5728\u4ec5\u65bd\u52a0-0.5 V\uff08vs. RHE\uff09\u7684\u7535\u538b\u4e0b\uff0c\u8be5\u50ac\u5316\u5242\u8868\u73b0\u51fa~63\uff05\u7684FE\uff08\u603bCO<sub>2<\/sub>\u00a0FE\u7ea6\u4e3a90\uff05\uff09\u548c\u751f\u6210C<sub>2<\/sub>\u542b\u6c27\u5316\u7269\uff08\u4e59\u9187\u548c\u4e59\u9178\u76d0\uff09~90\u03bcmoll<sup>-1<\/sup>\u00a0h<sup>-1<\/sup>\u7684\u751f\u4ea7\u901f\u7387\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u5355\u4e00\u6750\u6599\u6c2e\u63ba\u6742\u7eb3\u7c73\u91d1\u521a\u77f3\u548cCu\u7eb3\u7c73\u9897\u7c92\u5bf9C<sub>2<\/sub>\u542b\u6c27\u5316\u7269\u7684\u751f\u4ea7\u6ca1\u6709\u6d3b\u6027\u3002N-ND\/Cu\u8f83\u4e4b\u524d\u7684\u7528\u4e8eCO<sub>2<\/sub>\u8fd8\u539f\u7684CuNP\u7535\u50ac\u5316\u5242\u6709\u660e\u663e\u7684\u63d0\u9ad8\uff0c\u50ac\u5316\u5bff\u547d\u5927\u5e45\u63d0\u5347\u81f3120 h\uff0c\u7535\u6d41\u7a33\u5b9a\uff0c\u6d3b\u6027\u8870\u51cf\u4ec519%\u3002\u7814\u7a76\u56e2\u961f\u9884\u8ba1\uff0c\u8fd9\u79cd\u754c\u9762\u6750\u6599-\u6750\u6599\u5e73\u53f0\u7684\u8bbe\u8ba1\u539f\u5219\u5c06\u9002\u7528\u4e8e\u5e7f\u6cdb\u7684\u50ac\u5316\u8f6c\u5316\uff0c\u5c24\u5176\u662f\u90a3\u4e9b\u9700\u8981\u53ef\u518d\u751f\u80fd\u6e90\u8f93\u5165\u548c\u6c34\u76f8\u5bb9\u6027\u7684\u50ac\u5316\u8f6c\u5316\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><a href=\"https:\/\/www.nature.com\/articles\/s41565-019-0603-y\" target=\"_blank\" rel=\"noopener\"><u>Synergistic enhancement of electrocatalytic CO<\/u><u><sub>2<\/sub><\/u><u>\u00a0reduction to C<\/u><u><sub>2<\/sub><\/u><u>\u00a0oxygenates at nitrogen-doped nanodiamonds\/Cu interface<\/u><\/a>\uff08Nature Nanotech.\uff0c\u00a02020\uff0cDOI:10.1038\/s41565-019-0603-y\uff09<\/p>\n<p>\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/p>\n<p><strong>\u5d14\u5c79\u6559\u6388<\/strong>1998\u5e74\u5728\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u83b7\u5f97\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c2002\u5e74\u5728\u54c8\u4f5b\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c2003-2005\u5e74\u5728\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c\u73b0\u4e3a\u7f8e\u56fd\u65af\u5766\u798f\u5927\u5b66\u6750\u6599\u7cfb\u7ec8\u8eab\u6559\u6388\uff0c\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u5b66\u4f1a\u4f1a\u58eb\uff0c\u7f8e\u56fd\u6750\u6599\u5b66\u4f1a\u4f1a\u58eb\u3002\u73b0\u4efbNano Letters\u526f\u4e3b\u7f16\u3001\u7f8e\u56fd\u6e7e\u533a\u592a\u9633\u80fd\u5149\u4f0f\u8054\u76df\uff08Bay Area Photovoltaics Consortium\uff09\u4e3b\u4efb\u4ee5\u53ca\u7f8e\u56fd\u7535\u6c60500\u8054\u76df\uff08Battery500 Consortium\uff09\u4e3b\u4efb\u3002\u5d14\u5c79\u6559\u6388\u8bfe\u9898\u7ec4\u7814\u7a76\u6d3b\u8dc3\u5728\u9ad8\u80fd\u7845\u8d1f\u6781\u3001\u9ad8\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u3001\u9502\u91d1\u5c5e\u7535\u6c60\u3001\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u3001\u7535\u50ac\u5316\u6c34\u5206\u89e3\u3001\u6c27\u8fd8\u539f\u3001\u667a\u80fd\u8c03\u8282\u4eba\u4f53\u6e29\u5ea6\u7684\u9ad8\u5206\u5b50\u7ea4\u7ef4\u7ec7\u7269\u3001\u9ad8\u6548\u8fc7\u6ee4PM 2.5\u9897\u7c92\u3001\u51b7\u51bb\u7535\u955c\u7b49\u7814\u7a76\u9886\u57df\uff0c\u5df2\u53d1\u8868\u5f71\u54cd\u56e0\u5b50\u8d85\u8fc710\u7684\u8bba\u6587300\u591a\u7bc7\uff0c\u5176\u4e2dScience 8\u7bc7\uff0cNature 2\u7bc7\uff0cNature\u5b50\u520a70\u4f59\u7bc7\uff0c\u88ab\u5f15\u752816\u4e07\u4f59\u6b21\uff0cH\u56e0\u5b50\u4e3a190\uff08Google Scholar\uff09\uff0c\u6388\u6743\u56fd\u9645\u4e13\u522940\u4f59\u4ef6\uff0c\u5e76\u83b7\u5f97\u4e00\u7cfb\u5217\u5956\u9879\uff0c\u5305\u62ec2017\u5e74\u5ea6\u5e03\u62c9\u74e6\u5c3c\u514b\u9752\u5e74\u79d1\u5b66\u5bb6\u5956\u30012015\u5e74MRS Kavli Distinguished Lectureship in Nanoscience, Resonate Award for Sustainability\u30012014\u5e74Nano Energy\u5956\u30012014\u5e74Blavatnik\uff08\u5e03\u62c9\u74e6\u5c3c\u514b\uff09\u56fd\u5bb6\u5956\u5165\u56f4\u5956\u30012013\u5e74IUPCA\uff08\u56fd\u9645\u7406\u8bba\u5316\u5b66\u4e0e\u5e94\u7528\u5316\u5b66\u8054\u5408\u4f1a\uff09\u65b0\u6750\u6599\u53ca\u5408\u6210\u6770\u51fa\u5956\u30012011\u5e74\u54c8\u4f5b\u5927\u5b66\u5a01\u5c14\u900a\u5956\u30012010\u5e74\u65af\u9686\u7814\u7a76\u57fa\u91d1\u30012008\u5e74KAUST\u7814\u7a76\u5956\u30012008\u5e74ONR \u5e74\u8f7b\u53d1\u660e\u5bb6\u5956\u30012007\u5e74MDV\u521b\u65b0\u5956\u7b49\uff0c2004\u5e74\u5165\u9009\u201c\u4e16\u754c\u9876\u5c16100\u540d\u9752\u5e74\u53d1\u660e\u5bb6\u201d\u3002<\/p>\n<p>\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b<\/p>\n<ul>\n<li>Wang, Z. Liang, M. Tang, G. Chen, Y. Li, W. Chen, D. Lin, Z. Zhang, G. Zhou, J. Li, Z. Lu, K. Chan, T. Tan, and Y. Cui, &#8220;Self-Selective Catalyst Synthesis for CO<sub>2<\/sub>Reduction&#8221; Joule 3, pp 1-10 (2019)<\/li>\n<li>Zheng, Y. Ji, J. Tang, J. Wang, B. Liu, H.-G. Steinruck, K. Lim, Y. Li, M. F. Toney, K. Chan, and Y. Cui, &#8220;Theory-guided Sn\/Cu alloying for efficient CO<sub>2<\/sub>electroreduction at low overpotentials&#8221; Nature Catalysis 2, pp 55-61 (2019)<\/li>\n<li>Li, Y. Zhu, W. Chen, Z. Lu, J. Xu, A. Pei, Y. Peng, X. Zheng, Z. Zhang, S. Chu, and Y. Cui, &#8220;Breathing-Mimicking Electrocatalysis for Oxygen Evolution and Reduction&#8221; Joule 3, pp1-13 (2018)<\/li>\n<li>Li, G. Chen, Y. Zhu, Z. Liang, A. Pei, C.-L. Wu, H. Wang, H. R. Lee, K. Liu, S. Chu, and Y. Cui, &#8220;Efficient electrocatalytic CO<sub>2<\/sub>reduction on a three-phase interface&#8221; Nature Catalysis 1, pp 592-600 (2018)<\/li>\n<li>Lu, G. Chen, S. Siahrostami, Z. Chen, K. Liu, J. Xie, L. Liao, T. Wu, D. Lin, Y. Liu, T. F. Jaramillo, J. K. Norskov, and Y. Cui, &#8220;High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials&#8221; Nature Catalysis 1, pp 156\u2013162 (2018)<\/li>\n<li>Lu, G. Chen, Y. Li, H. Wang, J. Xie, L. Liao, C. Liu, Y. Liu, T. Wu, Y. Li, A. C. Luntz, M. Bajdich, and Y. Cui, &#8220;Identifying the Active Surfaces of Electrochemically Tuned LiCoO<sub>2<\/sub>for Oxygen Evolution Reaction&#8221;, Journal of the American Chemical Society 139 (17), pp 6270\u20136276 (2017)<\/li>\n<li>Wang, S. Xu, C. Tsai, Y. Li, C. Liu, J. Zhao, Y. Liu, H. Yuan, F. Abild-Pederson, F. B. Prinz, J. K. Norskov, and Y. Cui, &#8220;Direct and continuous strain control of catalysts with tunable battery electrode materials&#8221;, Science 354 (6315), pp 1031-1036 (2016)<\/li>\n<li>Wang, H.-W. Lee, Y. Deng, Z. Lu, P.-C. Hsu, Y. Liu, D. Lin, and Y. Cui, &#8220;Bifunctional non-noble metal oxide nanoparticle electrocatalysts through lithium-induced conversion for overall water splitting&#8221;, Nature Communications 6, pp 7261 (2015)<\/li>\n<li>Chen, Y. Liu, Y. Li, J. Sun, Y. Qiu, C. Liu, G. Zhou, and Y. Cui, &#8220;In Situ Electrochemically Derived Nanoporous Oxides from Transition Metal Dichalcogenides for Active Oxygen Evolution Catalysts&#8221;, Nano Letters 16 (12), pp 7588\u20137596 (2016)<\/li>\n<\/ul>\n<p>\u672c\u6587\u7531<strong><b>\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5728\u78b3\u5e73\u8861\u80fd\u6e90\u8f6c\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\u5bf9\u4e8e\u89e3\u51b3\u6c14\u5019\u53d8\u5316\u548c\u5168\u7403\u80fd\u6e90\u9700\u6c42\u4e0d\u65ad\u589e\u957f\u81f3\u5173\u91cd\u8981\u3002\u4e3b\u8981\u7684\u7814\u7a76\u70ed\u70b9\u4e3a\u5f00\u53d1\u7528\u4e8eCO2\u8fd8\u539f\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\u7684\u50ac\u5316\u5242\u3002\u5df2\u77e5\u7528\u4e8e&#8230;<\/p>\n","protected":false},"author":2109,"featured_media":194159,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[293,3002,116],"class_list":["post-194158","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nature","tag-3002","tag-catalyst"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/194158"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=194158"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/194158\/revisions"}],"predecessor-version":[{"id":194487,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/194158\/revisions\/194487"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/194159"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=194158"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=194158"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=194158"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}