{"id":193574,"date":"2020-04-23T21:27:12","date_gmt":"2020-04-23T13:27:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=193574"},"modified":"2020-04-23T21:27:12","modified_gmt":"2020-04-23T13:27:12","slug":"%e6%b5%99%e5%a4%a7%e9%bb%84%e9%a3%9e%e9%b9%a4adv-mater-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e8%b6%85%e5%88%86%e5%ad%90-%e5%a4%a7%e7%8e%af%e5%9f%ba%e6%9c%89%e6%9c%ba%e6%99%b6%e4%bd%93%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=193574","title":{"rendered":"\u6d59\u5927\u9ec4\u98de\u9e64Adv. Mater.\u7efc\u8ff0\uff1a\u8d85\u5206\u5b50-\u5927\u73af\u57fa\u6709\u673a\u6676\u4f53\u6750\u6599\u7814\u7a76\u8fdb\u5c55"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u51a0\u919a\u3001\u73af\u7cca\u7cbe\uff08CDs\uff09\u3001\u676f\u82b3\u70c3\u3001\u95f4\u82ef\u4e8c\u915a\u82b3\u70c3\u3001\u90bb\u82ef\u4e09\u915a\u82b3\u70c3\u3001\u846b\u82a6\u7d20\uff08CBs\uff09\u3001\u67f1\u82b3\u70c3\u3001\u7b49\u8d85\u5206\u5b50\u5927\u73af\u662f\u4e00\u7c7b\u5177\u6709\u5185\u5b54\u7684\u8d85\u5206\u5b50\u53d7\u4f53\u3002\u7531\u4e8e\u5b83\u4eec\u4e30\u5bcc\u7684\u5bbf\u4e3b\u2212\u5ba2\u4f53\u6027\u8d28\uff0c\u5176\u5728\u9ad8\u5206\u5b50\u5316\u5b66\u3001\u6750\u6599\u5316\u5b66\u3001\u7eb3\u7c73\u6280\u672f\u3001\u7b49\u9886\u57df\u4e5f\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u540c\u65f6\uff0c\u5b83\u4eec\u8fd8\u88ab\u7528\u4e8e\u901a\u8fc7\u975e\u5171\u4ef7\u5bbf\u4e3b\u2212\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\u6765\u4fee\u9970\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u7684\u8868\u9762\u6027\u8d28\uff0c\u5305\u62ec\u5b83\u4eec\u5728\u836f\u7269\u91ca\u653e\u3001\u9ad8\u7075\u654f\u5ea6\u4f20\u611f\u5668\u3001\u9009\u62e9\u6027\u50ac\u5316\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002<\/p>\n

\u9664\u4e86\u5728\u5176\u5bbf\u4e3b\u2212\u5ba2\u4f53\u5316\u5b66\u57fa\u7840\u4e0a\u7684\u5e7f\u6cdb\u5e94\u7528\u5916\uff0c\u5927\u73af\u8fd8\u88ab\u7528\u4f5c\u6784\u5efa\u56fa\u4f53\u6750\u6599\u7684\u57fa\u77f3\uff0c\u5305\u62ec\u591a\u5b54\u6709\u673a\u805a\u5408\u7269\uff08POPs\uff09\u3001\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u3001\u548c\u7ed3\u6676\u6709\u673a\u6750\u6599\uff08COMs\uff09\u3002\u7279\u522b\u662fCOMs\uff0c\u8fd9\u662f\u4e00\u7c7b\u5177\u6709\u5236\u5907\u7b80\u5355\u3001\u7ed3\u6676\u5ea6\u9ad8\u7684\u6709\u673a\u6750\u6599\u3002\u4e0e\u7531\u65e0\u673a\uff08\u91d1\u5c5e\u79bb\u5b50\uff09\u548c\u6709\u673a\u7269\u79cd\uff08\u6709\u673a\u914d\u4f53\uff09\u901a\u8fc7\u914d\u4f4d\u7ec4\u6210\u7684MOFs\u4e0d\u540c\uff0cCOMs\u662f\u4e00\u79cd\u7531\u5171\u4ef7\u952e\u6216\u975e\u5171\u4ef7\u952e\u8fde\u63a5\u7684\u7eaf\u6709\u673a\u7269\u7ec4\u6210\u7684\u7ed3\u6676\u6750\u6599\uff0c\u5176\u7ed3\u6784\u5177\u6709\u591a\u6837\u6027\u3001\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u6eb6\u6db2\u52a0\u5de5\u6027\u7b49\u3002\u5bf9\u4e8e\u975e\u5171\u4ef7\u952e\u8fde\u63a5\u7684COMs\uff0c\u5178\u578b\u7684\u6750\u6599\u662f\u5177\u6709\u8010\u4eba\u5bfb\u5473\u6027\u8d28\u7684\u6709\u673a\u5206\u5b50\u6676\u4f53\uff0c\u5982\u534a\u5bfc\u4f53\u3001\u5b54\u9699\u5ea6\u7b49\uff0c\u7531\u4e8e\u6676\u4f53\u72b6\u6001\u4e0b\u6709\u673a\u7ec4\u5757\u5806\u79ef\u6548\u7387\u4f4e\uff0c\u4e00\u4e9b\u5206\u5b50\u6676\u4f53\u8868\u73b0\u51fa\u5916\u90e8\u5b54\u9699\uff0c\u901a\u5e38\u88ab\u79f0\u4e3a\u6c22\u952e\u6709\u673a\u6846\u67b6\uff08HOFs\uff09\u6216\u8d85\u5206\u5b50\u6709\u673a\u6846\u67b6\uff08SOFs\uff09\u3002<\/p>\n

\u6839\u636e\u5b83\u4eec\u7684\u7ec4\u6210\uff0c\u57fa\u4e8e\u8d85\u5206\u5b50-\u5927\u73af\u7684COMs\u53ef\u5206\u4e3a\u4e24\u5927\u7c7b\uff0c\u4e00\u7c7b\u662f\u7eaf\u7684\u5927\u73af\uff0c\u53e6\u4e00\u7c7b\u662f\u7531\u5927\u73af\u548c\u5176\u4ed6\u7b80\u5355\u7684\u6709\u673a\u6784\u4ef6\u7ec4\u6210\u7684\u3002\u7531\u4e8e\u5177\u6709\u4e00\u5b9a\u7c7b\u578b\u7684\u9884\u5236\u8154\uff0c\u4e00\u4e9b\u5927\u73afCOMs\u5728\u56fa\u6001\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u672c\u5f81\u5fae\u5b54\u9699\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7531\u4e8e\u8fd9\u4e9b\u521a\u6027\u5927\u73af\u5206\u5b50\u5728\u6676\u6001\u4e2d\u7684\u5806\u79ef\u6548\u7387\u4f4e\u4e0b\uff0c\u53ef\u80fd\u4f1a\u5f62\u6210\u4e00\u4e9b\u5927\u73af\u57fa\u5316\u5408\u7269\u7684\u5916\u90e8\u5b54\u9699\u3002\u9664\u4e86\u660e\u663e\u7684\u5b54\u9699\u5ea6\u5916\uff0c\u57fa\u4e8e\u5927\u73af\u7684COMs\u7684\u4e00\u4e2a\u7279\u70b9\u662f\u5b83\u4eec\u53ef\u80fd\u542b\u6709\u201c\u6ca1\u6709\u5b54\u201d\u7684\u591a\u5b54\u6027\u3002\u67d0\u4e9b\u57fa\u4e8e\u5927\u73af\u7684COMs\u7684\u53e6\u4e00\u4e2a\u7279\u70b9\u662f\u5b83\u4eec\u662f\u975e\u591a\u5b54\u7684\uff0c\u4f46\u5728\u7ed3\u6784\u4e0a\u662f\u81ea\u9002\u5e94\u7684\uff0c\u8fd9\u88ab\u79f0\u4e3a\u975e\u591a\u5b54\u81ea\u9002\u5e94\u6676\u4f53\uff08NACs\uff09\u3002\u5728NACs\u7684\u521d\u59cb\u72b6\u6001\u4e0b\uff0c\u7531\u4e8e\u6709\u6548\u7684\u5206\u5b50\u586b\u5145\uff0c\u4e0d\u5b58\u5728\u7a7a\u9699\u6216\u7a7a\u7a74\uff0c\u4f46\u7531\u4e8e\u8f6f\u5927\u73af\u7684\u7ed3\u6784\u9002\u5e94\u6027\uff0c\u5728\u7279\u5b9a\u5ba2\u4f53\u7684\u5438\u6536\u4e0a\u4ea7\u751f\u4e86\u4e00\u5b9a\u7684\u7a7a\u9699\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u57fa\u4e8e\u5927\u73af\u7684COMs\u8fd8\u53ef\u4ee5\u7531\u5177\u6709\u5176\u5b83\u5438\u5f15\u4eba\u7684\u6027\u8d28\u6216\u529f\u80fd\u7684\u5bbf\u4e3b\u2212\u5ba2\u4f53\u590d\u5408\u7269\u6784\u5efa\uff0c\u5982\u56fa\u6001\u5fae\u6fc0\u5149\u5668\u3002\u968f\u7740\u8d85\u5206\u5b50-\u5927\u73af\u57faCOMs\u7684\u51fa\u73b0\uff0cCOMs\u7684\u591a\u6837\u6027\u548c\u8010\u4eba\u6027\u4e0d\u65ad\u6269\u5927\uff0c\u8fd9\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4fc3\u8fdb\u4e86COMs\u7684\u53d1\u5c55\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u6d59\u6c5f\u5927\u5b66<\/strong>Kecheng Jie<\/strong>\u535a\u58eb\u548c\u9ec4\u98de\u9e64\u6559\u6388<\/strong>\u56e2\u961f\u7efc\u8ff0\u4e86\u8d85\u5206\u5b50-\u5927\u73af\u57fa\u7ed3\u6676\u6709\u673a\u6750\u6599\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u3002\u4ee5\u201cSupramolecular\u2010Macrocycle\u2010Based Crystalline Organic Materials<\/strong>\u201d\u53d1\u8868\u4e8eAdv. Mater.<\/strong>\u671f\u520a\u4e0a\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u8d85\u5206\u5b50-\u5927\u73af\u5316\u5408\u7269\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5305\u62ec\u73af\u7cca\u7cbe\u3001\u676f\u82b3\u70c3\u3001\u95f4\u82ef\u4e8c\u915a\u82b3\u70c3\u3001\u90bb\u82ef\u4e09\u915a\u82b3\u70c3\u3001\u846b\u82a6\u9187\u3001\u67f1\u82b3\u70c3\u7b49\u3002\u91cd\u70b9\u7814\u7a76\u4e86\u57fa\u4e8e\u8d85\u5206\u5b50-\u5927\u73af\u7ed3\u6784\u7684COMS\u7684\u7ed3\u6784\u53ca\u5176\u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\u3002\u6b64\u5916\uff0c\u8d85\u5206\u5b50-\u5927\u73af\u5316\u5408\u7269\u57faCOMs\u5728\u6c14\u4f53\u50a8\u5b58\u6216\u5206\u79bb\u3001\u5206\u5b50\u5206\u79bb\u3001\u56fa\u6001\u7535\u89e3\u8d28\u3001\u8d28\u5b50\u4f20\u5bfc\u3001\u7898\u6355\u83b7\u3001\u6c34\u6216\u73af\u5883\u5904\u7406\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002\u6700\u540e\uff0c\u8ba8\u8bba\u4e86\u57fa\u4e8e\u8d85\u5206\u5b50\u5927\u73afCOMs\u9886\u57df\u7684\u89c2\u70b9\u548c\u672a\u6765\u6311\u6218\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

1<\/strong>\u3001\u73af\u7cca\u7cbe\u57fa<\/strong>COMs<\/strong><\/p>\n

\u56fe\u4e00\u3001<\/strong>\u73af\u7cca\u7cbe\u57fa<\/strong>COFs<\/strong>\u3002<\/strong><\/p>\n

\"\"\uff08a\uff09\u4e0d\u540c\u53cd\u79bb\u5b50\u7684CD-COFs\u7684\u5408\u6210\uff1b<\/p>\n

\uff08b\uff09Li\u79bb\u5b50\u5728\u542b\u6709Li+<\/sup>\u7684CD-COF\u901a\u9053\u4e2d\u4f20\u8f93\u7684\u539f\u7406\u56fe\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u53cd\u79bb\u5b50\u5bf9CD-COFs\u7684CO2<\/sub>\u5438\u9644\u80fd\u529b\u3002<\/p>\n

2<\/strong>\u3001\u676f\u82b3\u70c3\u57fa\u5316\u5408\u7269<\/strong><\/p>\n

\u56fe\u4e8c\u3001\u676f<\/strong>[4]<\/strong>\u82b3\u70c3\u7684\u56db\u79cd\u7a33\u5b9a\u6784\u8c61<\/strong><\/p>\n

\"\"\u56fe\u4e09\u3001<\/strong>CMS<\/strong>\u4e2d\u676f\u82b3\u70c3\u7684\u5316\u5b66\u7ed3\u6784<\/strong><\/p>\n

\"\"2.1<\/strong>\u3001\u676f\u82b3\u70c3\u57fa\u5316\u5408\u7269<\/strong><\/p>\n

\u56fe\u56db\u3001\u676f\u82b3\u70c3<\/strong>1<\/strong>\u7684\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u6cbf\u4e09\u91cd\u8f74\u76841\u5728a\u4e2d\u7684\u4e00\u6761\u7ebf\u7684\u5927\u73af\u3001\u4e09\u91cd\u6392\u5217<\/p>\n

\uff08b\uff09\u6cbf\u4e09\u91cd\u8f74\u7684\u7a7a\u95f4\u586b\u5145\u8868\u793a<\/p>\n

\uff08c\uff09\u5782\u76f4\u4e8e\u4e09\u91cd\u8f74\u76841\u22c5CF3Br\u7a7a\u95f4\u586b\u5145\u8868\u793a<\/p>\n

\uff08d\uff09\u5782\u76f4\u4e8e\u6676\u4f53c\u8f74\u76841\u22c5CF3Br\u7684\u7a7a\u95f4\u586b\u5145\u8868\u793a<\/p>\n

\u56fe\u4e94\u3001\u676f\u82b3\u70c3<\/strong>2<\/strong>\u7684\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff092a\uff0c\u9762\u5bf9\u676f\u82b3\u70c3\u662f\u76f8\u4e92\u62b5\u6d88\u548c\u5ba2\u4f53\u5206\u5b50(\u672a\u663e\u793a)\u88ab\u90e8\u5206\u63d2\u5165\u5230\u4ed6\u4eec\u7684\u8154\uff1b<\/p>\n

\uff08b\uff092b\uff0c\u76f8\u90bb\u53cc\u5c42\u76f8\u5bf9\u4e8e2a\u6a2a\u5411\u5e73\u79fb\uff0c\u4f7f\u676f\u82b3\u70c3\u5f62\u6210\u4e8c\u805a\u4f53\u80f6\u56ca\uff1b<\/p>\n

\uff08c\uff092c\uff0c\u676f\u82b3\u70c3\u7565\u6709\u504f\u79fb\uff0c\u5f62\u6210\u504f\u659c\u7684\u7a7a\u56ca\uff1b<\/p>\n

\uff08d\uff09\u81ea\u7ec4\u88c5\u4e8c\u805a\u4f53\u7ed3\u67842d \u3002<\/p>\n

\u56fe\u516d\u3001\u4e59\u70ef\u57fa\u6eb4\u5904\u7406\u540e<\/strong><\/p>\n

\"\"\uff08a\uff092d\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff1b<\/p>\n

\uff08b\uff092e\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff1b<\/p>\n

\uff08c\uff092d\u6837\u54c1\u7684\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u5728\u5ba4\u6e29\u548c\u5927\u7ea61 atm\u521d\u59cb\u538b\u529b\u4e0b\u5438\u9644\u4e59\u7094\u548c\u4e8c\u6c27\u5316\u78b3\uff1b<\/p>\n

\uff08e\uff09\u6c27\u5316\u4e9a\u6c2e\u548c\u4e00\u6c27\u5316\u6c2e\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08f\uff09\u5728298 K\u65f6\uff0c2d\u548c3a\u5bf9\u7532\u70f7\u7684\u9ad8\u538b\u5438\u9644;<\/p>\n

\uff08g\uff09\u5728298 K\u65f6\uff0c2d\u548c3a\u5bf9\u7532\u70f7\u7684\u4f4e\u538b\u5438\u9644\uff1b<\/p>\n

\uff08h\uff092d\u548c3a\u7684\u5438\u6c22\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08i\uff094a\u7684\u5438\u6c22\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\u56fe\u4e03\u3001\u4e0d\u540c\u6761\u4ef6\u5bf9<\/strong>2d<\/strong>\u5f62\u6001\u5f71\u54cd<\/strong><\/p>\n

\"\"\uff08a\uff09\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u4e3a2d\uff0c\u70ed\u529b\u5b66\u5f62\u5f0f\u4e3a2c\u548c1\uff1a1\u7684\u5bbf\u4e3b\uff1a\u5ba2\u4f53\u914d\u5408\u7269\uff0c2e\uff0c\u9664\u53bb\u4e86\u5ba2\u4f53\u5206\u5b50\uff1b<\/p>\n

\uff08b\uff09\u5f53CO2<\/sub>\u4e3a3.5MPa\u65f6\uff0c\u6c14\u4f53\u8bf1\u5bfc2c\u54112d\u7684\u8f6c\u5316\u548c\u81a8\u80c0\uff1b<\/p>\n

\uff08c\uff09\u57283.5MPa\u6761\u4ef6\u4e0b\uff0c\u6c27\u5316\u4e9a\u6c2e\u8bf1\u5bfc2c\u54112d\u548c2e\u8f6c\u53d8\u3002<\/p>\n

\u56fe\u516b\u3001<\/strong>2<\/strong>\u6676\u4f53\u9009\u62e9\u6027\u7ed3\u5408\u7684\u793a\u610f\u56fe\u8868\u793a<\/strong><\/p>\n

\"\"\u56fe\u4e5d\u3001\u676f\u82b3\u70c3\u5206\u5b50\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u6cbf[001]\u65b9\u5411\u6295\u5f71\u76845b\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u7684\u900f\u89c6\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5206\u5b505c1<\/sub>\uff0c\u5176\u4e24\u4e2a\u88c2\u7f1d\u663e\u793a\u4e3aConnolly\u8868\u9762(\u9876\u90e8)\uff1bConnolly\u8868\u9762(\u6a59\u8272)\uff0c\u4ee3\u88685c2<\/sub>(\u5e95\u90e8)\u7684\u4e24\u4e2a\u5bf9\u79f0\u76f8\u5173\u7684\u88c2\u7f1d\uff1b<\/p>\n

\uff08c\uff095bHCl<\/sub>(\u9876\u90e8)\u548c5bHCl\u00b7H2O<\/sub>(\u5e95\u90e8)\u7ed3\u6784\u4e2d\u7684\u676f\u82b3\u70c3\u5206\u5b50\uff1b<\/p>\n

\uff08d\uff09\u6cbf[001]\u89c2\u5bdf\u676f\u82b3\u70c35b(\u9876\u90e8)\u548c5b12<\/sub> (\u5e95\u90e8)\u7684Endo\u8fde\u63a5\u9762\u548c\u5206\u5b50\u95f4\u5b54\u3002<\/p>\n

\u56fe\u5341\u3001<\/strong>6<\/strong>\u4e0e\u5421\u5576\u7684\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u7eb3\u7c73\u7ba1\u72b6\u7ec4\u88c5\u4e2d\u4e00\u4e2a\u73af\u7684\u68d2\u72b6\u8868\u5f81\uff1b<\/p>\n

\uff08b\uff09\u516d\u65b9\u586b\u5145\u7eb3\u7c73\u7ba1\u6cbfc\u8f74\u5ef6\u4f38\u7ed3\u6784\u7684\u89c6\u56fe\uff1b<\/p>\n

\uff08c\uff09\u6cbf[001]\u9762\u73af\u72b6\u7ed3\u6784\u7684\u7a7a\u95f4\u586b\u5145\u8868\u793a\uff1b<\/p>\n

\uff08d\uff09\u6cbf[100]\u9762\u73af\u72b6\u7ed3\u6784\u7684\u7a7a\u95f4\u586b\u5145\u8868\u793a\u3002<\/p>\n

\u56fe\u5341\u4e00\u3001<\/strong>8<\/strong>\u7684\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u75316\u4e2a8<\/strong>\u548c2\u4e2a\u6c34\u5206\u5b50\u6784\u6210\u7684\u8d85\u5206\u5b50\u7eb3\u7c73\u901a\u9053\uff1b<\/p>\n

\uff08b\uff09\u8d85\u5206\u5b50\u7eb3\u7c73\u901a\u9053\u7684\u7a7a\u95f4\u586b\u5145\u6a21\u578b\uff0c\u663e\u793a\u6781\u6027\u660e\u6e20\u548c\u4e24\u4e2a\u758f\u6c34\u8154\uff1b<\/p>\n

\uff08c\uff09CO2<\/sub>\u5728\u591a\u5b54\u6750\u65998<\/strong>\u4e2d\u7684\u91cd\u91cf\u767e\u5206\u6bd4\u4f5c\u4e3a\u65f6\u95f4\u548c\u538b\u529b\u7684\u51fd\u6570\uff1b<\/p>\n

\uff08d\uff09CH4<\/sub>\u5728203K\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff0c\u5728\u5de6\u5782\u76f4\u8f74(\u25aa)\u548c\u5355\u4f4d\u6676\u80de\u5728\u53f3\u4fa7\u5782\u76f4\u8f74(\u25b4)\u4e0a\u7684CH4<\/sub>\u5206\u5b50\u6570(wt%)\u4e0a\u62a5\u9053\u4e86\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08e\uff09C2<\/sub>H2<\/sub>\u5728298 K\u3001278 K\u548c203 K\u5904\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08f\uff09\u5728\u8d85\u5206\u5b50\u7f51\u7edc\u7684\u771f\u7a7a\u6837\u54c1\u4e2d\uff0cAr\u7684\u5438\u9644\u7113\u548c\u5438\u9644\u6c14\u4f53\u7684\u6469\u5c14\u6570\u5206\u522b\u4e3a77k\u548c0.1bar\u3002<\/p>\n

\u56fe\u5341\u4e8c\u3001<\/strong>9<\/strong>\u7684\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u7a7a\u8154\u4e2d\u542b\u6709CHCl3<\/sub>\uff1b<\/p>\n

\uff08b\uff09\u7a7a\u8154\u542b\u6709\u4e24\u79cd\u4e0d\u540c\u7684\u5ba2\u4f53(CHCl3<\/sub>\u548c\u4e8c\u82c4\u57fa\u916e)\uff1b<\/p>\n

\uff08c\uff0910\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784<\/p>\n

\uff08d\uff09\u5bf910\u7a7a\u8154\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

2.2<\/strong>\u3001\u676f<\/strong>[5]<\/strong>\u82b3\u70c3\u57fa<\/strong>COMs<\/strong><\/p>\n

\u56fe\u5341\u4e09\u3001<\/strong>11<\/strong>\u7684\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff0911a\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff0c\u663e\u793a\u6c22\u952e\u87ba\u65cb\u8d2f\u7a7fTH\u5806\u82af\uff1b<\/p>\n

\uff08b\uff09\u6676\u4f53X\u5c04\u7ebf\u7ed3\u678411b\u7684\u68d2\u548c\u586b\u5145\u56fe\uff1b<\/p>\n

\uff08c\uff09\u57281 atm\u538b\u529b\u548c\u5ba4\u6e29\uff0cCO2<\/sub>(\u84dd\u8272)\u548cH2<\/sub>(\u7ea2\u8272)\u6761\u4ef6\u4e0b\uff0c11b\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\u56fe\u5341\u56db\u3001<\/strong> \u5bf9\u53d4\u4e01\u57fa\u676f<\/strong>[5]<\/strong>\u82b3\u70c3<\/strong>12<\/strong><\/p>\n

\u00a0\"\"<\/strong>\uff08a\uff09\u975e\u591a\u5b54\uff08\u548c\u975e\u6d3b\u6027\uff0912\u7532\u82ef\u6eb6\u5242\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u548c12\u7684\u53bb\u6eb6\u5242\/\u5347\u534e\u5f62\u5f0f\uff1b<\/p>\n

\uff08b\uff0912a\u7684\u6269\u5c55\u7ed3\u6784\u663e\u793a\u4e86\u57fa\u5bf9\u57fa\u548c\u5934\u5bf9\u7aef\u4e8c\u805a\u4f53\u7684\u6392\u5217\uff1b<\/p>\n

\uff08c\uff0912b\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u663e\u793a\u57fa\u5bf9\u57fa\u548c\u5934\u5bf9\u5934\u4e8c\u805a\u4f53\u7684\u6392\u5217\uff1b<\/p>\n

\uff08d\uff0912c\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u663e\u793a\u57fa\u5bf9\u57fa\u4e8c\u805a\u4f53\u5728\u201c\u8584\u7247\u201d\u5185\u7684\u5934\u5bf9\u5934\u7684\u6392\u5217\uff1b<\/p>\n

\uff08e\uff09\u53d7\u632b\u768412a\u5728\u5ba4\u6e29\u4e0b9\u5206\u949f\u5185\u7684\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08f\uff09\u53d7\u632b12b\u5728\u5ba4\u6e29\u548c\u538b\u529b\u4e0b9 min\u5185\u7684\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

3<\/strong>\u3001\u90bb\u82ef\u4e09\u915a\u57fa<\/strong>COMs<\/strong><\/p>\n

\u56fe\u5341\u4e94\u3001\u90bb\u82ef\u4e09\u915a<\/strong>[4]<\/strong>\u82b3\u70c3\u7684\u5316\u5b66\u7ed3\u6784<\/strong><\/p>\n

\"\"\u56fe\u5341\u516d\u3001\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u7532\u919a\u7a7a\u815413a\u7684\u7c98\u63a5\u8868\u793a\uff0c\u5c01\u95ed\u7a7a\u95f4\u4ee5\u7eff\u8272\u8868\u793a\uff0c\u6c22\u952e\u663e\u793a\u4e3a\u7834\u788e\u7684\u9ec4\u8272\u5706\u67f1\u4f53\uff1b<\/p>\n

\uff08b\uff09\u7403\u5f62\u7a7a\u8154\u7684\u7a7a\u95f4\u8868\u793a\uff1b<\/p>\n

\uff08c\uff09\u7eb3\u7c73\u7a7a\u815415a\u300116a\u548c17a\u7684\u5408\u6210\uff1b<\/p>\n

\uff08d\uff0915a\u300116a\u548c17a\u7eb3\u7c73\u7a7a\u8154\u7684\u5206\u5b50\u5305\u88c5\u56fe\uff1b<\/p>\n

\uff08e\uff0916a\u7684X\u5c04\u7ebf\u6676\u4f53\u7ed3\u6784\u56fe\uff0c\u663e\u793a\u4e86hexammer\u7ec4\u88c5(\u9876\u90e8)\u4e2d\u5206\u89e3\u7684\u8298\u788e\u7247;<\/p>\n

\u56fe\u5341\u4e03\u3001\u8298\u6216<\/strong>1-<\/strong>\u6eb4\u8298\u5904\u7406\u7684<\/strong>16<\/strong><\/p>\n

\"\"\uff08a\uff09\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u5c0616\u7ec4\u88c5\u6210\u6709\u673a\u7eb3\u7c73\u740316b\u548c\u7eb3\u7c73\u7ba116c\u7684\u6761\u4ef6\uff1b<\/p>\n

\uff08b\uff0916\u578b\u2160\u578b\u4e8c\u805a\u4f53\u4e0e\u4ea4\u66ff\u4e8c\u805a\u4f53(\u9876)\u4e4b\u95f4\u7684\u6eb6\u5242(\u4e09\u4e2a\u7532\u9187\u5206\u5b50)\u5305\u6db5\u4f53\u7684\u4ea4\u53c9\u6b63\u9762\u548c\u53cd\u9762\u7684\u586b\u6599\u56fe\uff1b<\/p>\n

\uff08c\uff09\u5728\u6709\u548c\u4e0d\u542b\u4e8c\u6c27\u5316\u78b3\u768416\u79cd\u4e0d\u540c\u5f62\u5f0f\u4e4b\u95f4\u76f8\u4e92\u8f6c\u5316\u7684\u6d41\u7a0b\u56fe\uff1b<\/p>\n

\uff08d\uff09\u81ea\u4e0a\u800c\u4e0b\u7684PXRD\u66f2\u7ebf\uff1a\u8868\u683cI(\u6d0b\u7ea2)\u3001II(\u6d77\u519b)\u3001III(\u84dd\u8272)\u3001iv(\u68d5\u8272)\u3001v(\u7ea2\u8272)\u3001vi(\u7d2b\u8272)\u548cVII(\u6a44\u6984)\u3002<\/p>\n

\u56fe\u5341\u516b\u3001\u7ed3\u6784<\/strong>14<\/strong>\u7684\u5355\u6676\u4f53<\/strong>X<\/strong>\u5c04\u7ebf<\/strong><\/p>\n

\"\"\uff08a\uff0914\u57fa\u4e19\u916e\u5ba2\u4f53\u7684\u5206\u5b50\uff1b<\/p>\n

\uff08b\uff09\u4e24\u4e2a\u572821\u00b0\u5904\u5806\u79ef\u7684\u201c\u7eb3\u7c73\u63a2\u6d4b\u5668\u201d\u7684\u7a7a\u95f4\u586b\u5145\u56fe\uff0c\u5b83\u4eec\u76f8\u4e92\u5305\u88f9\u5728\u4e19\u916e\u4e0a\u3002<\/p>\n

\u56fe\u5341\u4e5d\u3001\u90bb\u82ef\u4e09\u915a<\/strong>[4]<\/strong>\u82b3\u70c3\u57fa<\/strong>SOFs<\/strong><\/p>\n

\"\"\uff08a\uff0918A\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff0c\u663e\u793a\u4e24\u4e2a18\u5206\u5b50\u901a\u8fc7\u4e24\u4e2aa\u5206\u5b50\u8fde\u63a5\uff1b<\/p>\n

\uff08b\uff09\u4e0e\u95f4\u9694\u5206\u5b50\u5448\u6ce2\u72b6\u6392\u5217\u768418B\uff1b<\/p>\n

\uff08c\uff0914A\u548c14B\uff0c\u95f4\u9694\u5206\u5b50\u6392\u5217\u5728\u901a\u9053\u4e2d\uff0c\u7531\u5c3e\u90e8\u5230\u5934\u90e8\u7684\u5806\u53e0\u5305\u56f4\u8d77\u6765\u6392\u521714\uff1b<\/p>\n

\uff08d\uff09\u5206\u5b50\u95f4\u6c22\u952e\u6a21\u5f0f\u768416A\uff1b<\/p>\n

\uff08e\uff0916C\uff0c\u6269\u5c55\u6c22\u952e\u89c6\u56fe\uff0c\u6cbf[001]\u6676\u4f53\u65b9\u5411\u5806\u79ef16\u5217\uff1b<\/p>\n

\uff08f\uff09\u5728298 K\u4e0b\uff0c\u6c14\u4f53\u572816C\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\u56fe\u4e8c\u5341\u3001\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u572819\u00b73 MeOH\u4e2d\u53d1\u73b0\u7684\u4e24\u5c42\u7ed3\u6784\u7684\u68d2\u72b6\u548c\u7a7a\u95f4\u586b\u5145\u8868\u793a\uff0c\u663e\u793a\u4e86\u676f\u82b3\u70c3\u6c2f\u4e01\u57fa\u94fe\u7684\u4e0d\u540c\u53d6\u5411\uff1b<\/p>\n

\uff08b\uff09\u572819\u00b71.5 MeOH\u4e2d\uff0c\u5bf9\u4e24\u5c42\u7ed3\u6784\u7684\u7c98\u7740\u548c\u7a7a\u95f4\u586b\u5145\u8868\u793a\uff0c\u663e\u793a\u4e86\u676f\u82b3\u70c3\u6c2f\u4e01\u57fa\u94fe\u7684\u4ea4\u53c9\uff1b<\/p>\n

\uff08c\uff09\u753120\u7ed3\u6784\u6c22\u952e\u7eb3\u7c73\u80f6\u675f\u7684\u7a7a\u95f4\u586b\u5145\u8868\u793a\u3002<\/p>\n

4<\/strong>\u3001\u95f4\u82ef<\/strong>\u4e8c\u915a\u57fa<\/strong>COMs<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e00\u3001\u95f4\u82ef\u4e8c\u915a<\/strong>[4]<\/strong>\u82b3\u70c3<\/strong>21-24<\/strong>\u7684\u5316\u5b66\u7ed3\u6784<\/strong><\/p>\n

\"\"\u56fe\u4e8c\u5341\u4e8c\u3001\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\"\"\uff08a\uff09\u57fa\u4e8e21\u7684\u624b\u6027\u7403\u5f62\u5206\u5b50\u7ec4\u88c5\uff1b<\/p>\n

\uff08b\uff09\u540c\u578b\u4e8c\u805a\u4f53\u7a7a\u815422a\uff1b<\/p>\n

\uff08c\uff09\u57fa\u4e8e23\u7684\u7a7a\u8154\u3002<\/p>\n

\u56fe\u4e8c\u5341\u4e09\u3001\u57fa\u4e8e<\/strong>21<\/strong>\u7684\u7a7a\u5fc3\u6676\u4f53\u7684\u5f62\u6210<\/strong><\/p>\n

\"\"5<\/strong>\u3001<\/strong>CB<\/strong>\u57fa<\/strong>COM<\/strong>s<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u56db\u3001<\/strong>CB[6]<\/strong>\u548c<\/strong>CB[8]<\/strong>\u7684\u7ed3\u6784\u3002\u989c\u8272\u4ee3\u7801\uff1a\u78b3\uff0c\u7070\u8272\uff1b\u6c2e\uff0c\u84dd\u8272\uff1b\u6c27\u6c14\uff0c\u7ea2\u8272\u3002<\/strong><\/p>\n

\"\"\u56fe\u4e8c\u5341\u4e94\u3001\u5177\u6709\u6c38\u4e45\u5b54\u9699\u7387\u548c\u9ad8\u70ed\u7a33\u5b9a\u6027\u7684<\/strong>CB[6]<\/strong>\u57fa<\/strong>COM<\/strong><\/p>\n

\"\"\uff08a\uff0925\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784 (\u9876\u90e8)\uff0c\u4e59\u7094\u5438\u964425 (\u5e95\u90e8)\uff1b<\/p>\n

\uff08b\uff09\u4e59\u7094\u5728196 k(\u5706)\u548c298 k(\u65b9)\u5904\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u5438\u964425\u7684CO2<\/sub>\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff1b<\/p>\n

\uff08d\uff09CO2<\/sub>(\u7ea2\u5708)\uff0cCH4(<\/sub>\u84dd\u65b9\u683c)\u548cCO(\u9ed1\u8272\u4e09\u89d2\u5f62)\u5728298 K\u4e0b\u5438\u964425\u3002<\/p>\n

\u56fe\u4e8c\u5341\u516d\u3001\u5b58\u5728\u4e8e<\/strong>CB[6]<\/strong>\u57fa<\/strong>COMS<\/strong>\u7684\u901a\u9053\u4e2d\u7684\u6c34\u548c\u9178\u5206\u5b50<\/strong><\/p>\n

\"\"\uff08a\uff09\u5728\u591a\u5b54\u6027CBs\u300125a\u300125b\u548c26a\u901a\u9053\u4e2d\u663e\u793a\u6c34\u9178\u9635\u5217\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff1b<\/p>\n

\uff08b\uff09\u572825a(\u5de6)\u300125b(\u4e2d)\u548c26a(\u53f3)\uff0c\u4e00\u7ef4\u901a\u9053\u4e2d\u7684\u6c34\u9178\u9635\u5217\uff1b<\/p>\n

\uff08c\uff09\u5728298 K\u548c98%Rh\u5355\u667625a(\u5de6)\u300125b(\u4e2d\u95f4)\u548c26a(\u53f3)\uff0cNyquist\u56fe(\u9ed1\u65b9\u683c\u56fe)\u548c\u7528\u6240\u63d0\u51fa\u7684\u591a\u5b54\u6027CBS\u7b49\u6548\u7535\u8def\u6a21\u578b(\u7ea2\u7ebf)\u62df\u5408\u7684\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728298K\u768425a(\u5de6)\u300125b(\u4e2d)\u548c26a(\u53f3)\uff0c\u591a\u5b54\u6027CBs\u9897\u7c92\u7684\u5bf9\u6570\u03c3\u4e0erh\u56fe\u3002<\/p>\n

6<\/strong>\u3001\u67f1\u82b3\u70c3\u57fa<\/strong>C<\/strong>OM<\/strong>s<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e03\u3001\u652f\u67f1<\/strong>[5]<\/strong>\u82b3\u70c3<\/strong><\/p>\n

\"\"\uff08a\uff09\u67f1[5]\u82b3\u70c3\u548c\u652f\u67f1[6]\u82b3\u70c3\u7684\u5361\u901a\u56fe\uff1b<\/p>\n

\uff08b\uff09\u67f1\u82b3\u70c3\u7684\u5316\u5b66\u7ed3\u6784\u3002<\/p>\n

\u00a0<\/strong>6.1<\/strong>\u3001\u67f1\u82b3\u70c3\u57fa<\/strong>COF<\/strong>s<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u516b\u3001<\/strong>SOP 27<\/strong><\/p>\n

\"\"\uff08a\uff0927a\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff0c\u5411\u4e0b\u770bb\u8f74(\u5de6)\uff1b\u5411\u4e0b\u770ba\u8f74(\u53f3)\uff1b<\/p>\n

\uff08b\uff0927a\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08c\uff0927b\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf;<\/p>\n

\uff08d\uff09\u5728273 K\uff0cCO2<\/sub>(\u9ed1\u8272)\u548cN2<\/sub>(\u84dd\u8272)\u572827b\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08e\uff0928a\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff1a\u6cbfc\u8f74\u89c2\u5bdf.<\/p>\n

\uff08f\uff09\u6c2e(77k\uff0c\u9ec4\u8272\u5706\u5708)\uff0cCO2(298 k\uff0c\u84dd\u65b9\u683c)\uff0c\u6b63\u4e01\u70f7(298 k\uff0c\u7d2b\u8272\u4e09\u89d2\u5f62) \uff0c\u65e0\u4e19\u916e28a\u7c89\u672b\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\uff08g\uff09\u591a\u5b5428a\u7c89\u672b\u5728298 K\u4e0b\u5bf9\u6b63\u5df1\u70f7(\u7eff\u8272\u4e09\u89d2\u5f62)\u548c\u73af\u5df1\u70f7(\u84dd\u5708)\u84b8\u6c14\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1a\u56fa\u4f53\u7b26\u53f7=\u5438\u9644\uff1b\u5f00\u7b26\u53f7=\u89e3\u5438\u3002<\/p>\n

6.2<\/strong>\u3001\u67f1\u82b3\u70c3<\/strong>\u57fa<\/strong>NAC<\/strong>s<\/strong><\/p>\n

\u56fe\u4e8c\u5341\u4e5d\u3001\u8fc7\u4e59\u57fa\u67f1<\/strong>[5]<\/strong>\u82b3\u70c3<\/strong>29<\/strong>\u6676\u4f53<\/strong><\/p>\n

\"\"\uff08a\uff0929a\u6676\u4f53\u5bf9\u5177\u6709\u5f00\u95e8\u884c\u4e3a\u7684\u7ebf\u6027\u70f7\u70c3\u548c\u652f\u94fe\u70f7\u70c3\u7684\u5438\u9644\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u9876\u90e8\uff1a\u83b7\u5f97\u542b\u70f7\u70c329\u6676\u4f53\u7684\u7a0b\u5e8f\u793a\u610f\u56fe\u3002\u5e95\u90e8\uff1aC6@29\uff0cC7@29\uff0cC8@29\u548cC16@29\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\u3002<\/p>\n

\u56fe\u4e09\u5341\u3001\u70ef\u70c3\u4f4d\u7f6e\u5f02\u6784\u4f53\u7684\u5206\u79bb<\/strong><\/p>\n

\"\"\uff08a\uff0929a\u5bf9\u7ebf\u6027\u620a\u70ef\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1a1-Pe(\u84dd\u65b9)\uff0c\u53cd\u5f0f-2-Pe (\u6d0b\u7ea2\u8272\u4e09\u89d2\u5f62)\uff0c\u987a\u5f0f-2-Pe (\u7ea2\u8272\u94bb\u77f3)\u3002\u56fa\u4f53\u7b26\u53f7=\u5438\u9644\uff1b\u5f00\u653e\u7b26\u53f7=\u89e3\u5438\uff1b<\/p>\n

\uff08b\uff09\u5ba4\u6e29\u4e0b1-Pe \/2-Pe\u6df7\u5408\u7269\u968f\u65f6\u95f4\u53d8\u5316\u768429a\u56fa\u4f53\u84b8\u6c14\u5438\u9644\u56fe\u3002<\/p>\n

\uff08c\uff09\u753129a\u54111-Pe @29\u8f6c\u53d8\u7684\u7ed3\u6784\u8868\u5f81\uff1a\u5438\u65361-Pe \/2-Pe\u6df7\u5408\u7269\u52a0\u70ed\u91ca\u653e1-Pe\u3002<\/p>\n

\u56fe\u4e09\u5341\u4e00\u3001\u57fa\u4e8e\u82b3\u70c3\u7684<\/strong>NACs<\/strong>\u4f5c\u4e3a\u5438\u9644\u5206\u79bb\u6750\u6599\u6765\u51c0\u5316\u82ef\u4e59\u70ef<\/strong><\/p>\n

\"\"\uff08a\uff09\u752830 NACs\u548c30b\u5230St@30\u4e4b\u95f4\u7684\u53ef\u9006\u53d8\u6362\u7684\u82ef\u4e59\u70ef\u51c0\u5316\u8fc7\u7a0b\u7684\u539f\u7406\u56fe\uff0c\uff1b<\/p>\n

\uff08b\uff09\u603b\u7ed3\u4e8630-\u4e8c\u7532\u82ef\u4e3b\u5ba2\u4f53\u2212\u5728\u6eb6\u6db2\u4e2d\u548c\u56fa\u6001\u4e2d\u7684\u76f8\u4e92\u8f6c\u5316\u65b9\u6848\u3002<\/p>\n

\u56fe\u4e09\u5341\u4e8c\u3001\u5206\u79bb\u8fc7\u7a0b\u548c\u673a\u7406\u7684\u8868\u793a<\/strong><\/p>\n

\"\"\uff08a\uff09\u752829a\u4eceMCH\/Tol\u6df7\u5408\u7269\u4e2d\u5206\u79bbtol\uff1b<\/p>\n

\uff08b\uff09\u752830b\u5206\u79bbMCH\/Tol\u6df7\u5408\u7269\u4e2d\u7684MCH\u3002<\/p>\n

\u56fe\u4e09\u5341\u4e09\u3001<\/strong>30b<\/strong>\u7ed3\u6784\u8f6c\u53d8\u7684\u539f\u7406\u56fe<\/strong><\/p>\n

\"\"\uff08a\uff0930b\u6676\u4f53\u4e2d\u7898\u7684\u5438\u6536\uff0cI2@30\u4e2d\u73af\u5df1\u70f7\u4e2d\u7898\u7684\u91ca\u653e\uff0cCy@30\u4e2d\u73af\u5df1\u70f7\u7684\u53bb\u9664\uff1b<\/p>\n

\uff08b\uff0932(\u9876)\u70f7\u70c3\u578b\u9009\u62e9\u6027\u6c7d\u8272\u884c\u4e3a\u7684\u793a\u610f\u56fe\u8868\u5f81\u3002\u5728\u5355\u6676\u7684X\u5c04\u7ebf\u7ed3\u6784\u4e2d\uff0cC=\u7070\u8272\uff0cO=\u7ea2\u8272\uff0cH\u539f\u5b50\u4e3a\u6e05\u6670\u7701\u7565\u3002\u7167\u7247\u663e\u793a\uff0c\u5f5320\u6beb\u514b\u768432\u6676\u4f53\u66b4\u9732\u5728\u4e0d\u540c\u7684\u8102\u80aa\u919b\u4e2d12 h(\u5e95\u90e8)\u65f6\uff0c\u989c\u8272\u4f1a\u53d1\u751f\u53d8\u5316\u3002<\/p>\n

\u56fe\u4e09\u5341\u56db\u3001\u901a\u8fc7\u6355\u83b7\u4e01\u80fa\u84b8\u6c14\u5728<\/strong>32a<\/strong>\u4e2d\u8fdb\u884c\u540e\u5408\u6210\u4fee\u9970\u7684\u539f\u7406\u56fe<\/strong><\/p>\n

\"\" \"\"6.3<\/strong>\u3001\u67f1\u82b3<\/strong>\u70c3\u57fa\u4e3b\u4f53<\/strong>–<\/strong>\u5ba2\u4f53<\/strong>COM<\/strong>s<\/strong><\/p>\n

\u56fe\u4e09\u5341\u4e94\u3001<\/strong>\u57fa\u4e8e<\/strong>33<\/strong>\u548c<\/strong>DASP<\/strong>\u7684\u8d85\u5206\u5b50\u56fa\u4f53\u5fae\u6fc0\u5149\u5668\u7684\u5f62\u6210<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

7<\/strong>\u3001\u5176\u5b83\u8d85\u5206\u5b50\u5927\u73af\u57fa<\/strong>COM<\/strong>s<\/strong><\/p>\n

7.1<\/strong>\u3001<\/strong>Noria<\/strong>\u57fa<\/strong>COM<\/strong>s<\/strong><\/p>\n

\u56fe\u4e09\u5341\u516d\u3001<\/strong>34a(<\/strong>\u53f3<\/strong>)<\/strong>\u548c<\/strong>34b(<\/strong>\u5de6<\/strong>)<\/strong>\u7684\u6269\u5c55\u6676\u4f53<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784<\/strong><\/p>\n

\u00a0\"\"<\/strong>7.2<\/strong>\u3001\u53cc\u5c3f\u7d20\u5927\u73af\u57fa<\/strong>COM<\/strong>s<\/strong><\/p>\n

\u56fe\u4e09\u5341\u4e03\u3001\u53cc\u5c3f\u7d20\u5927\u73af<\/strong>35<\/strong><\/p>\n

\"\"\uff08a\uff09\u53cc\u5c3f\u7d20\u5927\u73af35\u7684\u5355\u6676X\u5c04\u7ebf\u7ed3\u6784\uff1b<\/p>\n

\uff08b\uff09\u586b\u5145\u5bc4\u4e3b35\u22c5AcOH(\u9876\u90e8)\u7684PXRD\u56fe\u8c31\uff1b<\/p>\n

\uff08c\uff0935a\u57280\u2103\u7684CO2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\u4e3a\uff1b<\/p>\n

\uff08d\uff0935a\u5728\u221278\u00b0C\u7684CO2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\u4e3a\uff1b<\/p>\n

\uff08e\uff09\u5bf9\u5bc4\u4e3b35\u22c5\u4e8c\u7532\u82ef(\u9876\u90e8)\u3001\u4e8c\u7532\u82ef\u53bb\u9664\u540e35a(\u4e2d\u90e8)\u548c\u5bc4\u4e3b35\u22c5\u4e8c\u7532\u82ef(\u5e95\u90e8)\u8fdb\u884c\u4e86PXRD\u5206\u6790\uff1b<\/p>\n

\uff08f\uff0936\u5316\u5b66\u7ed3\u6784\uff1b<\/p>\n

\uff08g\uff09\u63cf\u8ff036\u22c5TFE\u5305\u88c5\u7684\u89c6\u56fe\uff1b<\/p>\n

\uff08h\uff09\u53bb\u9664TFE\u540e\u5bbf\u4e3b36(\u5e95\u90e8)\u3001\u5bbf\u4e3b36\u00b7TFE(\u4e2d)\u548c\u5bc4\u4e3b36\u00b7TFE(\u9876\u90e8)\u7684PXRD\u56fe\u8c31\u6bd4\u8f83\uff1b<\/p>\n

\uff08i\uff09\u5728273 K\u5904\u5bf9\u5bc4\u4e3b36\u7684\u4e8c\u6c27\u5316\u78b3\u5438\u9644\u7b49\u6e29\u7ebf(\u84dd\u8272\u3001\u5e72\u6e7f\u5438\u9644)\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u603b\u4e4b\uff0c\u4f5c\u8005\u7efc\u8ff0\u4e86\u57fa\u4e8e\u8d85\u5206\u5b50-\u5927\u73af\u7684COMs\u7684\u6700\u65b0\u8fdb\u5c55\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u5927\u73af\u5728COMs\u4e2d\u7684\u5e94\u7528\u5df2\u7ecf\u5f88\u6210\u719f\uff0c\u4e0e\u4f20\u7edfCOMs\u76f8\u6bd4\u5177\u6709\u5982\u4e0b\u4f18\u70b9\uff1a1) \u5927\u591a\u6570\u5927\u73af\u57faCOMs\u5728\u521a\u6027\u7ed3\u6784\u4e2d\u5b58\u5728\u6c38\u4e45\u6027\u7684\u5b54\/\u901a\u9053\uff0c\u6216\u5728\u52a8\u6001\u6216\u81ea\u9002\u5e94\u7ed3\u6784\u4e2d\u5b58\u5728\u7531\u5ba2\u4f53\u8bf1\u5bfc\u7684\u65b0\u7a7a\u9699\/\u901a\u9053\uff0c\u4ece\u800c\u4f7f\u5176\u5177\u6709\u5438\u6536\u5ba2\u4f53\u7684\u7279\u6027\uff1b(2)\u591a\u4e2a\u529f\u80fd\u7531\u4e8e\u5176\u7ed3\u6784\u591a\u6837\u6027\u800c\u88ab\u8d4b\u4e88\u5355\u4e00\u7684COM\uff1b3)\u591a\u4e2a\u7ed3\u5408\u4f4d\u70b9\u6709\u52a9\u4e8e\u7ed3\u6784\u7684\u9ad8\u7a33\u5b9a\u6027\u3002<\/p>\n

\u7136\u800c\uff0c\u4f5c\u8005\u8ba4\u4e3a\u5c3d\u7ba1\u5176\u56fa\u6709\u7684\u4f18\u70b9\u548c\u5e7f\u6cdb\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u4ecd\u6709\u6539\u8fdb\u7684\u4f59\u5730\u3002\u867d\u7136\u7531\u5206\u5b50\u95f4\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5236\u5907\u7684\u57fa\u4e8e\u5927\u73af\u7684COMs\u5df2\u7ecf\u88ab\u5e7f\u6cdb\u62a5\u9053\uff0c\u4f46\u662f\u5229\u7528\u5171\u4ef7\u952e\u6765\u6784\u5efa\u57fa\u4e8e\u5927\u73afCOMs\u7684\u6784\u5efa\u662f\u76f8\u5f53\u6709\u9650\u7684\u3002\u4e14\u5176\u5728\u4e8e\u51e0\u4e2a\u65b9\u9762\u5b58\u5728\u5236\u5907\u56f0\u96be\uff1a1)\u4e00\u4e9b\u5927\u73af\u5982\u80cd\u7c7b\u5f88\u96be\u529f\u80fd\u5316\uff0c\u56e0\u6b64\u65e0\u6cd5\u4e0e\u5176\u4ed6\u7b80\u5355\u7684\u6709\u673a\u8fde\u63a5\u53cd\u5e94\u6765\u63d0\u4f9b\u6846\u67b6\uff1b2)\u4e00\u4e9b\u5bb9\u6613\u88ab\u5b98\u80fd\u56e2\u4fee\u6539\u7684\u5927\u73af\u592a\u8fc7\u4e8e\u67d4\u6027\uff0c\u65e0\u6cd5\u6784\u5efa\u5728\u53bb\u6eb6\u5242\u5316\u65f6\u4ecd\u80fd\u4fdd\u6301\u5176\u6846\u67b6\u7684\u521a\u6027\uff1b(3)\u5c06\u5927\u7684\u5927\u73af\u52a0\u5165COFs\u53ef\u80fd\u4f1a\u589e\u52a0\u7ed3\u6784\u7684\u590d\u6742\u6027\uff0c\u800c\u8fd9\u53ef\u80fd\u4f1a\u7834\u574f\u7ed3\u6676\u5ea6\u5e76\u751f\u6210\u65e0\u5b9a\u5f62\u7684\u6846\u67b6\u3002\u7136\u800c\uff0c\u8003\u8651\u5230\u57fa\u4e8e\u5927\u73af\u7684MOF\u53d6\u5f97\u7684\u5de8\u5927\u8fdb\u5c55\uff0c\u901a\u8fc7\u514b\u670d\u8fd9\u4e9b\u969c\u788d\uff0c\u5c06\u5728\u4e0d\u4e45\u7684\u5c06\u6765\u5b9e\u73b0\u57fa\u4e8e\u5927\u73af\u7684COFs\u7684\u6539\u8fdb\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u8d85\u5206\u5b50\u5316\u5b66\u548c\u5bc4\u4e3b\u2212\u5ba2\u4f53\u7684\u53d1\u5c55\u3002\u8d8a\u6765\u8d8a\u591a\u7684\u5927\u73af\u53d7\u4f53\u88ab\u5408\u6210\u6216\u53d1\u73b0\u3002\u8fd9\u4e3a\u4ece\u65b0\u7684\u5927\u73af\u6784\u5efa\u57fa\u4e8e\u5927\u73afCOMs\u5e76\u63a2\u7d22\u5176\u6f5c\u5728\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002<\/p>\n

\u6b64\u5916\uff0c\u8fd1\u5e74\u6765\u8ba1\u7b97\u673a\u79d1\u5b66\u7684\u5de8\u5927\u8fdb\u6b65\u4f7f\u8ba1\u7b97\u548c\u6a21\u62df\u6210\u4e3a\u5316\u5b66\u548c\u6750\u6599\u79d1\u5b66\u9886\u57df\u7684\u5f3a\u6709\u529b\u7684\u7814\u7a76\u5de5\u5177\uff0c\u8fd9\u5c06\u6709\u52a9\u4e8e\u57fa\u4e8e\u65e7\u5927\u73af\u7684\u65b0COMs\u7684\u53d1\u73b0\u3002\u540c\u65f6\uff0c\u5206\u5b50\u6a21\u62df\u8fd8\u53ef\u80fd\u6709\u52a9\u4e8e\u66f4\u597d\u5730\u7406\u89e3\u57fa\u4e8e\u5927\u73af\u7684COMs\u4e2d\u7684\u7ed3\u6784-\u529f\u80fd\u5173\u7cfb\uff0c\u5e76\u4e3a\u7279\u5b9a\u4efb\u52a1\u7684\u5e94\u7528\u63d0\u4f9b\u7ed3\u6784\u8bbe\u8ba1\u65b9\u9762\u7684\u542f\u793a\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u7ed3\u5408\u5b9e\u9a8c\u548c\u7406\u8bba\u6539\u8fdb\uff0c\u57fa\u4e8e\u5927\u73af\u7684COMs\u7684\u7814\u7a76\u5c06\u5f88\u5feb\u8fdb\u5165\u4e00\u4e2a\u65b0\u7684\u65f6\u4ee3\u3002<\/p>\n

 <\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSupramolecular-Macrocycle-Based Crystalline Organic<\/a>\uff08Adv. Mater.<\/em> 2019,<\/strong> 1904824\uff09<\/p>\n

\u672c\u6587\u7531\u6211\u4ea6\u662f\u884c\u4eba\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/a><\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u51a0\u919a\u3001\u73af\u7cca\u7cbe\uff08CDs\uff09\u3001\u676f\u82b3\u70c3\u3001\u95f4\u82ef\u4e8c\u915a\u82b3\u70c3\u3001\u90bb\u82ef\u4e09\u915a\u82b3\u70c3\u3001\u846b\u82a6\u7d20\uff08CBs\uff09\u3001\u67f1\u82b3\u70c3\u3001\u7b49\u8d85\u5206\u5b50\u5927\u73af\u662f\u4e00\u7c7b\u5177\u6709\u5185\u5b54\u7684\u8d85\u5206\u5b50\u53d7\u4f53\u3002\u7531\u4e8e\u5b83\u4eec\u4e30\u5bcc\u7684\u5bbf\u4e3b\u2212…<\/p>\n","protected":false},"author":11455,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[4284],"class_list":["post-193574","post","type-post","status-publish","format-standard","hentry","category-zongshu","tag-4284"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/193574"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11455"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=193574"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/193574\/revisions"}],"predecessor-version":[{"id":200489,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/193574\/revisions\/200489"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=193574"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=193574"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=193574"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}