{"id":193564,"date":"2019-12-30T06:30:28","date_gmt":"2019-12-29T22:30:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=193564"},"modified":"2019-12-29T18:28:42","modified_gmt":"2019-12-29T10:28:42","slug":"yury-gogotsi%e5%9b%a2%e9%98%9fsmall%ef%bc%9a%e5%af%bc%e7%94%b5%e8%81%9a%e5%90%88%e7%89%a9%e7%a2%b3%e5%8c%96%e9%92%9bmxene%e5%a4%8d%e5%90%88%e6%ad%a3%e6%9e%81%e5%8a%a9%e5%8a%9b%e8%b6%85%e9%ab%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=193564","title":{"rendered":"Yury Gogotsi\u56e2\u961fSmall\uff1a\u5bfc\u7535\u805a\u5408\u7269@\u78b3\u5316\u949bMXene\u590d\u5408\u6b63\u6781\u52a9\u529b\u8d85\u9ad8\u6027\u80fd\u975e\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"

\u5f15\u8a00<\/b><\/strong><\/h3>\n

\u8d5d\u7535\u5bb9\u7535\u5bb9\u5668\u662f\u4e00\u79cd\u4ecb\u4e8e\u7535\u6c60\u548c\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u4e4b\u95f4\u7684\u50a8\u80fd\u8bbe\u5907\uff0c\u5176\u901a\u8fc7\u8868\u9762\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6216\u8005\u79bb\u5b50\u63d2\u5c42\u6765\u5b9e\u73b0\u7535\u5316\u5b66\u80fd\u6e90\u7684\u5b58\u50a8\uff0c\u4e0d\u53d7\u6269\u6563\u63a7\u5236\u7684\u5236\u7ea6\uff0c\u56e0\u800c\u5177\u6709\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u8fd1\u4e9b\u5e74\u6765\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002MXenes\u662f\u4e00\u7c7b\u5177\u6709\u91d1\u5c5e\u5bfc\u7535\u5185\u6838\u548c\u7c7b\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u7684\u4e8c\u7ef4\u5c42\u72b6\u78b3\u5316\u7269\u6216\u8005\u6c2e\u5316\u7269\uff0c\u8fd9\u79cd\u7279\u6b8a\u7684\u7ed3\u6784\u8d4b\u4e88\u5176\u8d85\u9ad8\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u6bd4\u5982Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u00a0MXene\u6c34\u51dd\u80f6\u4f53\u79ef\u6bd4\u5bb9\u91cf\u53ef\u9ad8\u8fbe1500 F cm-3<\/sup>\u3002\u4f46\u7531\u4e8eMXene\u6613\u4e8e\u88ab\u6c27\u5316\uff0cMXene\u548cMXene\u57fa\u590d\u5408\u6750\u6599\u53ea\u80fd\u7528\u4f5c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u8d1f\u6781\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/h3>\n

\u6700\u8fd1\uff0c\u7f8e\u56fdDrexel University\u7684Yury Gogotsi\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u9ad8\u6027\u80fd\u5bfc\u7535\u805a\u5408\u7269@\u78b3\u5316\u949bMXene\u590d\u5408\u6b63\u6781\u6750\u6599\u3002\u56e2\u961f\u7814\u7a76\u4eba\u5458\u9996\u5148\u4ee5PS\u7403\u4e3a\u6a21\u677f\u5236\u5907\u4e863D Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u8584\u819c\uff0c\u901a\u8fc7\u6d47\u7b51\u805a\u82ef\u80fa\u00a0(PANI)\u00a0\u5e76\u673a\u68b0\u538b\u7f29\u540e\uff0c\u5f97\u5230\u81ea\u652f\u6491PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u590d\u5408\u8584\u819c\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u53d1\u73b0\uff0c\u5f53Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u00a0MXene\u4e0ePANI\u6216\u8005PEDOT:PSS\u590d\u5408\u540e\uff0c\u590d\u5408\u8584\u819c\u7684\u8010\u7535\u5316\u5b66\u6c27\u5316\u80fd\u529b\u663e\u8457\u589e\u5f3a\uff0c\u8fd9\u4e3b\u8981\u662f\u7531\u4e8e\u590d\u5408\u6750\u6599\u66f4\u9ad8\u7684\u529f\u51fd\u6570\u5f15\u8d77\u7684\u7a33\u5b9a\u6027\u7684\u589e\u52a0\u3002\u6b64\u5916\uff0c\u7531\u4e8ePANI\u7684\u9ad8\u6bd4\u5bb9\u91cf\u548cTi3<\/sub>C2<\/sub>Tx<\/sub>\u7684\u9ad8\u7535\u5bfc\u6027\uff0cPANI@M-Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u590d\u5408\u6b63\u6781\u57283 M H2<\/sub>SO4<\/sub>\u7535\u89e3\u6db2\u4e2d\u8868\u73b0\u51fa\u521b\u7eaa\u5f55\u7684\u4f53\u79ef\u6bd4\u5bb9\u91cf\u00a0(10 mV s-1<\/sup>\u4e0b1632 F cm-3<\/sup>)\u00a0\u548c\u500d\u7387\u6027\u80fd\u00a0(5000 mV s-1<\/sup>\u4e0b827 F cm-3<\/sup>)\u3002\u6700\u540e\uff0c\u7814\u7a76\u4eba\u5458\u4ee5\u673a\u68b0\u538b\u7f29\u540e\u7684Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u00a0(M-Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>) \u4e3a\u8d1f\u6781\uff0c\u4ee5PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u4e3a\u6b63\u6781\uff0c\u6784\u5efa\u4e86\u4e00\u4e2a\u8d85\u9ad8\u6027\u80fd\u7684\u975e\u5bf9\u79f0\u8d5d\u7535\u5bb9\u5668\u3002\u8be5\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u6700\u9ad8\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u548c\u6700\u9ad8\u529f\u7387\u5bc6\u5ea6\u5206\u522b\u9ad8\u8fbe50.6 Wh L-1<\/sup>\u00a0\u548c127\u00a0kW L-1<\/sup>\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cAn Ultrafast Conducting Polymer@MXene Positive Electrode with High Volumetric Capacitance for Advanced Asymmetric Supercapacitors\u201d\u53d1\u8868\u4e8eSmall\u671f\u520a\u4e0a\uff0c\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u674e\u79d1\u548c\u738b\u96ea\u676d\u3002<\/p>\n

\u56fe\u6587\u5bfc\u56fe<\/b><\/strong><\/h3>\n

\u56fe\u4e00\u3001PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u7684\u5236\u5907\u793a\u610f\u56fe\u548c\u76f8\u5173\u5f62\u8c8c\u7ed3\u6784\u8868\u5f81\u56fe\u00a0<\/p>\n

\"\"<\/p>\n

(a-f)\u00a0PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u7684\u5236\u5907\u793a\u610f\u56fe<\/p>\n

(g)\u00a0Ti3<\/sub>C2<\/sub>Tx<\/sub>@PS\u8584\u819cSEM\u56fe<\/p>\n

(h)\u00a03D M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u8584\u819cSEM\u56fe<\/p>\n

(i)\u00a03D PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u8584\u819cSEM\u56fe<\/p>\n

(j)\u00a03D PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u8584\u819cEDS Mapping\u56fe<\/p>\n

(k)\u00a03D PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u8584\u819cTEM\u56fe<\/p>\n

(i)\u00a0PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u8584\u819cSEM\u56fe<\/p>\n

\u56fe\u4e8c\u3001PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a) PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0bCV\u66f2\u7ebf<\/p>\n

(b) \u4e0d\u540c\u8d1f\u8f7d\u91cfPANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u7684\u500d\u7387\u6027\u80fd<\/p>\n

(c) PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0bGCD\u66f2\u7ebf<\/p>\n

(d) \u4e0d\u540c\u8d1f\u8f7d\u91cf\u7684PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u7684b\u503c<\/p>\n

(e) PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u4e2d\u8868\u9762\u7535\u5bb9\u7684\u8d21\u732e<\/p>\n

(f) PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u00a0\u6b63\u6781\u4e0d\u540c\u7535\u538b\u4e0bEIS\u66f2\u7ebf<\/p>\n

\u56fe\u4e09\u3001DFT\u7406\u8bba\u8ba1\u7b97<\/p>\n

\"\"<\/p>\n

(a) \u8fd8\u539f\u6001PANI\u7ed3\u6784<\/p>\n

(b) Ti3<\/sub>C2<\/sub>(OH)2<\/sub>\u00a0\u7ed3\u6784<\/p>\n

(c) \u8fd8\u539f\u6001PANI@Ti3<\/sub>C2<\/sub>(OH)2<\/sub>\u590d\u5408\u6750\u6599\u7ed3\u6784<\/p>\n

(d) \u4e09\u79cd\u6750\u6599\u7684\u529f\u51fd\u6570<\/p>\n

\u56fe\u56db\u3001\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u7535\u5316\u5b66\u6027\u80fd<\/p>\n

\"\"<\/p>\n

(a) M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u8d1f\u6781\u548cPANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u6b63\u6781\u7684CV\u66f2\u7ebf<\/p>\n

(b) M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\/\/PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u975e\u5bf9\u79f0\u7535\u5bb9\u5668CV\u66f2\u7ebf<\/p>\n

(c) M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\/\/PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u975e\u5bf9\u79f0\u7535\u5bb9\u5668GCD\u66f2\u7ebf<\/p>\n

(d) \u4e0d\u540c\u8d1f\u8f7d\u91cfM-Ti3<\/sub>C2<\/sub>Tx<\/sub>\/\/PANI@M-Ti3<\/sub>C2<\/sub>Tx<\/sub>\u975e\u5bf9\u79f0\u7535\u5bb9\u5668\u80fd\u91cf\u548c\u529f\u7387\u5bc6\u5ea6<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/h3>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u5bfc\u7535\u805a\u5408\u7269@\u78b3\u5316\u949bMXene\u7684\u9ad8\u6027\u80fd\u6b63\u6781\u6750\u6599\uff0c\u5e76\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u9a8c\u8bc1\u4e86\u5176\u5728\u6b63\u5411\u7535\u538b\u4e0b\u66f4\u9ad8\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u7531\u4e8ePANI\u7684\u9ad8\u6bd4\u5bb9\u91cf\u548cMXene\u7684\u9ad8\u5bfc\u7535\u6027\uff0c\u590d\u5408\u6b63\u6781\u8868\u73b0\u51fa\u8d85\u9ad8\u7684\u4f53\u79ef\u6bd4\u5bb9\u91cf\u00a0(10 mV s-1<\/sup>\u4e0b1632 F cm-3<\/sup>)\u00a0\u548c\u500d\u7387\u6027\u80fd\u00a0(5000 mV s-1<\/sup>\u4e0b827 F cm-3<\/sup>)\u3002\u57fa\u4e8e\u7eaf\u00a0Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u8d1f\u6781\u548cPANI@M-Ti3<\/sub>C2<\/sub>Tx<\/i><\/sub><\/em>\u590d\u5408\u6b63\u6781\u7684\u975e\u5bf9\u79f0\u8d5d\u7535\u5bb9\u5668\u6700\u9ad8\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe50.6 Wh L-1<\/sup>\uff0c\u5373\u4f7f\u5728\u8d85\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6127\u00a0kW L-1<\/sup>\u4e0b\uff0c\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u4f9d\u65e7\u670924.4 Wh L-1<\/sup>\u3002\u8be5\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7\u5c06MXene\u4e0e\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4e14\u529f\u51fd\u6570\u66f4\u9ad8\u7684\u6750\u6599\u590d\u5408\uff0c\u53ef\u4f7fMXene\u5728\u6b63\u5411\u7535\u538b\u4e0b\u7a33\u5b9a\u5de5\u4f5c\u3002\u540c\u65f6\uff0c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u6750\u6599\u4e0eMXene\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u6709\u5229\u4e8e\u8fdb\u4e00\u6b65\u589e\u5f3a\u590d\u5408\u6750\u6599\u7684\u7efc\u5408\u6027\u80fd\u3002\u8be5\u7814\u7a76\u5f00\u62d3\u4e86\u4e00\u79cd\u8bbe\u8ba1\u9ad8\u6027\u80fdMXene\u57fa\u590d\u5408\u6b63\u6781\u6750\u6599\u7684\u65b9\u6cd5\uff0c\u5bf9\u7535\u5316\u5b66\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u9886\u57df\u7814\u7a76\u5177\u6709\u4e00\u5b9a\u7684\u6307\u5bfc\u610f\u4e49\u3002<\/p>\n

\u672c\u6587\u7531Yury Gogotsi\u56e2\u961f<\/strong>\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"

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