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loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-193225 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/6-10.png\" alt=\"\" width=\"680\" height=\"574\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/6-10.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/6-10-300x253.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" 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Mayoral\u535a\u58eb<\/b><\/strong>\u5408\u4f5c\u91c7\u7528\u4e00\u9505\u6c34\u70ed\u6cd5\u7ed3\u5408\u914d\u4f53\u4fdd\u62a4\u6761\u4ef6\u4e0b\u6c22\u6c14\u76f4\u63a5\u8fd8\u539f\u65b9\u6cd5\u5236\u5907\u4e86MFI\u578b\u5168\u7845\u5206\u5b50\u7b5b\u548cZSM-5\u8d1f\u8f7d\u7684Rh\u5355\u539f\u5b50\u50ac\u5316\u5242\uff08\u5373Rh@S-1-H\u548cRh@ZSM-5-H\uff09\u3002\u901a\u8fc7\u7403\u5dee\u6821\u6b63\u7535\u955c\u3001X\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u3001X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u7684\u7814\u7a76\u53d1\u73b0\uff0cRh@S-1-H\u4e2dRh\u5355\u539f\u5b50\u5168\u90e8\u88ab\u5305\u88f9\u4e8e\u5206\u5b50\u7b5b\u5185\u90e8\uff0c\u4f4d\u4e8e\u5176\u4e94\u5143\u73af\u4e2d\uff0c\u88ab\u9aa8\u67b6\u6c27\u7a33\u5b9a\u3002\u8be5\u5355\u539f\u5b50\u50ac\u5316\u5242\u5728700<sup>o<\/sup>C\u7684H<sub>2<\/sub>\u6c14\u6c1b\u4e2d\u4ecd\u80fd\u4fdd\u6301\u539f\u6709\u7ed3\u6784\uff1b\u5373\u4f7f\u5728700<sup>o<\/sup>C\u7684O<sub>2<\/sub>\u6c14\u6c1b\u548c600o<sup>o<\/sup>C\u7684\u6c34\u84b8\u6c14\u6c14\u6c1b\u4e2d\uff0cRh\u7684\u5c3a\u5bf8\u4e5f\u4ec5\u5206\u522b\u589e\u957f\u4e3a1.5\u548c1.0nm\u3002\u5c06Rh@S-1-H\u548cRh@ZSM-5-H\u5e94\u7528\u4e8e\u6c28\u787c\u70f7\u6c34\u89e3\u5236\u6c22\u53cd\u5e94\uff0c25<sup>o<\/sup>C\u6761\u4ef6\u4e0b\uff0c\u5176TOF\u5206\u522b\u4e3a432 and 699 molH<sub>2<\/sub>\u00a0molRh<sup>\u22121<\/sup><sup>\u00a0<\/sup>min<sup>\u22121<\/sup>\uff0c\u662f\u76ee\u524d\u62a5\u9053\u7684\u76f8\u5173\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u6700\u9ad8\u7684\u3002\u5f53Rh@S-1-H\u548cRh@ZSM-5-H\u7528\u4e8e\u4e32\u8054\u785d\u57fa\u82b3\u70c3\u4e32\u8054\u52a0\u6c22\u53cd\u5e94\u65f6\uff0c\u663e\u793a\u4e86\u6781\u9ad8\u7684\u53cd\u5e94\u6548\u7387\u548c\u62e9\u5f62\u6027\u80fd\u3002\u8be5\u9879\u7814\u7a76\u53d1\u5c55\u4e86\u4e00\u79cd\u7b80\u5355\u5b9e\u7528\u7684\u5206\u5b50\u7b5b\u5305\u88f9\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u65b9\u6cd5\uff0c\u800c\u4e14\u4e3a\u5355\u539f\u5b50\u50ac\u5316\u5242\u5728\u62e9\u5f62\u50ac\u5316\u9886\u57df\u7684\u5f15\u7528\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n<p>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/ange.201912367?af=R<\/p>\n<p><strong><b>7\u3001Nat. Commun.\uff1aNi-Mo-N\/CFC\u7eb3\u7c73\u7247\u7535\u50ac\u5316\u5242\u7528\u4e8e\u540c\u65f6\u751f\u4ea7\u6c22\u6c14\u548c\u7532\u9178<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-193226 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/7-7.png\" alt=\"\" width=\"680\" height=\"424\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/7-7.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/7-7-300x187.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u7531\u4e8e\u65e5\u76ca\u4e25\u91cd\u7684\u73af\u5883\u6c61\u67d3\u548c\u80fd\u6e90\u5371\u673a\uff0c\u5f00\u53d1\u6e05\u6d01\u548c\u53ef\u518d\u751f\u80fd\u6e90\/\u8d44\u6e90\uff08\u4f8b\u5982\u592a\u9633\u80fd\uff0c\u98ce\u80fd\u548c\u6c22\u80fd\uff09\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u6c22\u6c14\u662f\u6709\u5438\u5f15\u529b\u6e05\u6d01\u80fd\u6e90\u3002\u901a\u8fc7\u7535\u50ac\u5316\u5206\u89e3\u6c34\u5236\u6c22\u662f\u4e00\u79cd\u6709\u6548\u4e14\u7ecf\u6d4e\u7684\u6280\u672f\uff0c\u4f46\u662f\u7531\u4e8e\u5176\u52a8\u529b\u5b66\u7f13\u6162\u548c\u4f4e\u9644\u52a0\u503c\u7684\u9633\u6781\u6790\u6c27\u53cd\u5e94\u800c\u53d7\u5230\u4e25\u91cd\u963b\u788d\u3002\u8fc7\u6e21\u91d1\u5c5e\u57fa\u6c2e\u5316\u7269\u901a\u5e38\u5177\u6709\u8f83\u4f4e\u7684\u7535\u963b\u548c\u8f83\u9ad8\u7684\u673a\u68b0\u7a33\u5b9a\u6027\uff0c\u88ab\u8ba4\u4e3a\u662f\u6709\u524d\u9014\u7684\u7535\u50ac\u5316\u5242\uff0c\u5e76\u4e14\u5728\u5404\u79cd\u53cd\u5e94\uff08\u4f8b\u5982OER\uff0cHER\u548cORR\uff09\u4e2d\u663e\u793a\u51fa\u9ad8\u7684\u6d3b\u6027\u3002\u8fd1\u65e5\uff0c<strong><b>\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u65bd\u5251\u6797\u3001<\/b><\/strong><strong><b>\u9648\u7acb\u677e<\/b><\/strong><strong><b>\u7b49<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u8d1f\u8f7d\u5728\u78b3\u7ea4\u7ef4\u5e03\uff08Ni-Mo-N\/CFC\uff09\u4e0a\u7684\u954d-\u6c2e\u5316\u94bc\u7eb3\u7c73\u7247\u50ac\u5316\u5242(Ni-Mo-N\/CFC)\uff0c\u8be5\u50ac\u5316\u5242\u5728\u4f4e\u6210\u672c\u7684\u78b1\u6027\u7518\u6cb9\u6eb6\u6db2\u4e2d\u53ef\u540c\u65f6\u7535\u89e3\u751f\u4ea7\u9ad8\u7eaf\u5ea6<strong><b>\u6c22<\/b><\/strong>\uff08\u9634\u6781\u4e0a\uff09\u548c\u9ad8\u9644\u52a0\u503c\u7684<strong><b>\u7532\u9178<\/b><\/strong>\uff08\u9633\u6781\u4e0a\uff09\u3002\u5f53\u5728\u9633\u6781\u548c\u9634\u6781\u90fd\u88c5\u8f7dNi-Mo-N\/CFC\u50ac\u5316\u5242\u65f6\uff0c\u6240\u5efa\u7acb\u7684\u7535\u89e3\u69fd\u53ea\u9700\u4f4e\u81f31.36 V\u7684\u7535\u6c60\u7535\u538b\u5c31\u80fd\u8fbe\u523010 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u6bd4\u78b1\u6027\u6c34\u6eb6\u6db2\u4f4e260 mV\u3002\u6b64\u5916\uff0c\u8be5\u50ac\u5316\u5242\u751f\u6210H<sub>2<\/sub>\u548c\u7532\u9178\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u5206\u522b\u9ad8\u8fbe99.7\uff05\u548c95.0\uff05\u3002\u8be5\u5de5\u4f5c\u5229\u7528\u975e\u8d35\u91d1\u5c5e\u7535\u50ac\u5316\u5242\u540c\u65f6\u5728\u9634\u6781\u548c\u9633\u6781\u751f\u4ea7\u9ad8\u4ef7\u503c\u4ea7\u54c1\u7684\u7b56\u7565\uff0c\u5bf9\u53ef\u518d\u751f\u80fd\u6e90\u6280\u672f\u7684\u53d1\u5c55\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n<p>https:\/\/www.nature.com\/articles\/s41467-019-13375-z<\/p>\n<p><strong><b>8\u3001JACS: TiO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>(110)\u8868\u9762\u50ac\u5316\u8131\u6c22\u7684\u754c\u9762\u6c22\u952e\u52a8\u529b\u5b66\u7814\u7a76<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-193227 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/8-8.png\" alt=\"\" width=\"680\" height=\"509\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/8-8.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/8-8-300x225.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u7406\u89e3\u91d1\u5c5e\u6c27\u5316\u7269\u4e0a\u754c\u9762\u6c34\u5206\u5b50\u7684\u8131\u6c22\u4f5c\u7528\u53ca\u5176\u76f8\u4e92\u4f5c\u7528\u7684\u672c\u8d28\u4f9d\u8d56\u4e8e\u8ffd\u8e2a\u5149\u548c\u6c22\u539f\u5b50\u7684\u8fd0\u52a8\u7684\u80fd\u529b\uff0c\u8fd9\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u76ee\u524d\uff0c\u5168\u7403\u4fe1\u606f\u6280\u672f\u6b63\u8de8\u5165\u4ee5\u91cf\u5b50\u6548\u5e94\u4e3a\u7279\u5f81\u7684\u201c\u540e\u6469\u5c14\u201d\u65f6\u4ee3\u3002\u5355\u5206\u5b50\u5c3a\u5ea6\u4f53\u7cfb\u5177\u6709\u4e30\u5bcc\u7684\u529f\u80fd\u7ed3\u6784\u548c\u72ec\u7279\u7684\u91cf\u5b50\u6027\u8d28\uff0c\u5c06\u6210\u4e3a\u91cf\u5b50\u8ba1\u7b97\u548c\u4fe1\u606f\u6280\u672f\u7269\u8d28\u8f7d\u4f53\u7684\u6700\u4f73\u9009\u62e9\u4e4b\u4e00\u3002<strong><b>\u4e2d\u79d1\u9662\u9662\u58eb\u3001\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6559\u6388\u4faf\u5efa\u56fd<\/b><\/strong>\u9886\u8854\u7684\u201c\u5355\u5206\u5b50\u5c3a\u5ea6\u7684\u91cf\u5b50\u8c03\u63a7\u7814\u7a76\u96c6\u4f53\u201d\u5bf9\u5355\u5206\u5b50\u5c3a\u5ea6\u4f53\u7cfb\u8fdb\u884c\u4e0d\u65ad\u7684\u63a2\u7d22\uff0c\u53d1\u5c55\u548c\u63d0\u5347\u4e86\u5355\u5206\u5b50\u5c3a\u5ea6\u91cf\u5b50\u6001\u7684\u63a2\u6d4b\u3001\u64cd\u7eb5\u53ca\u8c03\u63a7\u6280\u672f\uff0c\u7387\u5148\u5b9e\u73b0\u4e86\u56fd\u9645\u4e0a\u6700\u9ad8\u6c34\u5e73\u7684\u4e9a\u7eb3\u7c73\u5206\u8fa8\u7684\u5355\u5206\u5b50\u62c9\u66fc\u6210\u50cf\u3002\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u4faf\u5efa\u56fd\u9662\u58eb\u548c\u738b\u5175\u6559\u6388\u7b49\u4eba\u5408\u4f5c\u5229\u7528\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u5bf9TiO<sub>2<\/sub>(110)\u4e0a\u7684Ti\u4f4d\u70b9\u8868\u9762\u4fc3\u8fdb\u6c34\u8131\u6c22\u7684\u8fc7\u7a0b\u8fdb\u884c\u4e86\u7cbe\u786e\u7684\u6d4b\u91cf\u3002\u901a\u8fc7\u6d4b\u91cfH<sub>2<\/sub>O\u548cD<sub>2<\/sub>O\u7684\u6c22\u952e\u52a8\u529b\u5b66\uff0c\u53d1\u73b0\u632f\u52a8\u548c\u7535\u5b50\u6fc0\u53d1\u6001\u4e3b\u5bfc\u4e86\u4e24\u4e2aH (D)\u539f\u5b50\u4eceH<sub>2<\/sub>O (D<sub>2<\/sub>O)\u5206\u5b50\u5230\u76f8\u90bb\u8868\u9762\u6c27\u6d3b\u6027\u4f4d\u70b9\u7684\u9010\u6e10\u8f6c\u79fb\uff0c\u8868\u660e\u4e86\u8131\u6c22\u8fc7\u7a0b\u4e2d\u6c27\u5316\u8868\u9762\u7684\u91cd\u8981\u4f5c\u7528\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5316\u5b66\u8ba1\u91cf\u7684Ti5c\u4f4d\u70b9\u4e0a\uff0c\u5355\u4e2aH<sub>2<\/sub>O\u5206\u5b50\u5728\u80fd\u91cf\u4e0a\u4e0d\u5982\u89e3\u79bb\u5f62\u5f0f\u7a33\u5b9a\uff0c\u6839\u636e\u5b9e\u9a8c\u548c\u7406\u8bba\u7ed3\u679c\uff0c\u89e3\u79bb\u5f62\u5f0f\u7684\u52bf\u5792\u53ef\u80fd\u53ea\u6709\u5927\u7ea670~ 120meV\uff0c\u800c\u4e14\u754c\u9762\u6c22\u952e\u53ef\u4ee5\u6709\u6548\u5730\u8f85\u52a9H\u539f\u5b50\u5728\u8868\u9762\u7684\u8f6c\u79fb\u548c\u4ea4\u6362\u3002\u8be5\u5de5\u4f5c\u63ed\u793a\u7684\u5b9a\u91cf\u6c22\u952e\u52a8\u529b\u5b66\u4e3a\u6c34\u4e0e\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u76f8\u4e92\u4f5c\u7528\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u539f\u5b50\u673a\u5236\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n<p>https:\/\/doi.org\/10.1021\/jacs.9b09132<\/p>\n<p><strong><b>9\u3001Nat. Commun.\uff1a\u539f\u5b50\u5206\u6563\u7684Ni\u4f5c\u4e3a\u7532\u70f7\u5e72\u91cd\u6574\u7684\u8010\u7126\u70ad\u6d3b\u6027\u4e2d\u5fc3<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-193228 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/9-4.png\" alt=\"\" width=\"680\" height=\"626\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/9-4.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/9-4-300x276.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>CO<sub>2<\/sub>\u548cCH<sub>4<\/sub>\u662f\u4e24\u79cd\u6700\u4e3b\u8981\u7684\u5927\u6c14\u6e29\u5ba4\u6c14\u4f53\uff08GHGs\uff09\uff0c\u4f46\u5b83\u4eec\u4e5f\u662f\u4e30\u5bcc\u4e14\u4f4e\u6210\u672c\u7684\u78b3\u6e90\uff1bCH<sub>4<\/sub>\u88ab\u8ba4\u4e3a\u662f\uff08\u76f8\u5bf9\uff09\u6e05\u6d01\u80fd\u6e90\uff0c\u53ef\u7528\u6765\u5b9e\u73b0\u4f4e\u78b3\u7ecf\u6d4e\u3002\u7532\u70f7\u5e72\u91cd\u6574\uff08DRM\uff09\u662f\u5c06\u7532\u70f7\uff08CH<sub>4<\/sub>\uff09\u548c\u4e8c\u6c27\u5316\u78b3\uff08CO<sub>2<\/sub>\uff09\u8f6c\u5316\u4e3a\u5408\u6210\u6c14\uff08H<sub>2<\/sub>+CO\uff09\u7684\u8fc7\u7a0b\uff0c\u8fd9\u662f\u4e16\u754c\u7ea7\u7684\u5927\u89c4\u6a21\u5de5\u4e1a\u8fc7\u7a0b\u548c\u80fd\u6e90\u8f6c\u5316\uff08\u4f8b\u5982\u8d39\u6258\u5408\u6210\uff08FT\uff09\uff0c\u7fb0\u57fa\u5316\uff0c\u52a0\u6c22\u7532\u9170\u5316\uff09\u4ee5\u53ca\u7528\u4e8e\u71c3\u6599\u548c\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1\u7684\u5408\u6210\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\u3002\u7ecf\u8fc7\u8fd130\u5e74\u7684\u6df1\u5165\u7814\u7a76\uff0cNi\u50ac\u5316\u5242\u56e0\u5176\u4f4e\u6210\u672c\u548c\u9ad8\u521d\u59cb\u6d3b\u6027\uff08\u4e0e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u76f8\u6bd4\uff09\u800c\u6210\u4e3a\u6700\u6709\u524d\u9014\u7684DRM\u5019\u9009\u7269\u3002\u7136\u800c\uff0c\u7531\u4e8e\u78b3\u6c89\u79ef\uff08\u7126\u5316\uff09\u548c\/\u6216\u70e7\u7ed3\u7684Ni\u7269\u79cd\u4f7f\u50ac\u5316\u5242\u5931\u6d3b\u95ee\u9898\uff0c\u8fc4\u4eca\u5c1a\u65e0\u5546\u4e1aDRM\u5de5\u827a\u3002\u8fd1\u65e5\uff0c<strong><b>\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u5f20\u6d9b\uff0c\u4e54\u6ce2\u6d9b<\/b><\/strong>\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u4e0eCe\u63ba\u6742\u7684\u7f9f\u57fa\u78f7\u7070\u77f3(HAP)\u76f8\u4e92\u4f5c\u7528\u800c\u7a33\u5b9a\u539f\u5b50\u5206\u6563\u7684Ni\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u8be5\u50ac\u5316\u5242\u4e2dCeO<sub>x<\/sub>\u63ba\u6742\u7684HAP\u7a33\u5b9a\u4e86\u5b64\u7acb\u7684Ni\u539f\u5b50\uff0c\u9632\u6b62\u50ac\u5316\u5242\u7684\u70e7\u7ed3\u548c\u5931\u6d3b\uff0c\u53ef\u9ad8\u6d3b\u6027\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u50ac\u5316DRM\u3002\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0c\u5b64\u7acb\u7684Ni\u539f\u5b50\u5177\u6709\u56fa\u6709\u7684\u8010\u7126\u70ad\u6027\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u72ec\u7279\u7684\u4ec5\u6fc0\u6d3bCH<sub>4<\/sub>\u4e2d\u7b2c\u4e00\u4e2aC-H\u952e\u7684\u80fd\u529b\uff0c\u4ece\u800c\u907f\u514d\u7532\u70f7\u6df1\u5ea6\u5206\u89e3\u6210\u78b3\u3002\u8be5\u5de5\u4f5c\u4e3a\u5927\u89c4\u6a21\u5f00\u53d1\u5730\u7403\u5bcc\u542b\u7684DRM\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n<p>https:\/\/www.nature.com\/articles\/s41467-019-13375-z<\/p>\n<p><strong><b>10\u3001Nano Energy\uff1a\u81ea\u89e3\u79bb\u7ec4\u88c5\u8d85\u8584MOFs\u7eb3\u7c73\u7247\u9635\u5217\u7528\u4e8e\u9ad8\u6548\u6790\u6c27\u53cd\u5e94<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-193229 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/10-3.png\" alt=\"\" width=\"580\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/10-3.png 580w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/10-3-300x176.png 300w\" sizes=\"(max-width: 580px) 100vw, 580px\" \/><\/p>\n<p>\u9633\u6781\u4e0a\u7684\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u662f\u7535\u89e3\u6c34\u7684\u5173\u952e\u534a\u53cd\u5e94\uff0c\u4e3b\u8981\u6709\u8d35\u91d1\u5c5e\uff08\u5982RuO<sub>2<\/sub>\u3001IrO<sub>2<\/sub>\uff09\u30013d\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u7f9f\u57fa\u6c27\u5316\u7269\u3001\u9499\u949b\u77ff\u3001\u78f7\u5316\u7269\u3001\u6c2e\u5316\u7269\u3001\u4e8c\u5364\u5316\u7269\u3001\u91d1\u5c5e\u5408\u91d1\u7b49\u50ac\u5316\u5242\u3002\u8fd9\u4e9b\u6750\u6599\u4e0aOER\u8d28\u91cf\u6d3b\u6027\u666e\u904d\u4e00\u822c\u3001\u53cd\u5e94\u673a\u7406\u4e0d\u660e\u3002MOFs\u6750\u6599\u4f5c\u4e3a\u66ff\u4ee3\u6750\u6599\u5df2\u88ab\u5e7f\u6cdb\u7528\u4f5cOER\u50ac\u5316\u5242\u3002\u5c3d\u7ba1MOFs\u6750\u6599\u6d3b\u6027\u4f4d\u5747\u5300\u5206\u5e03\u3001\u6d3b\u6027\u4e2d\u5fc3\u660e\u786e\u3001\u6613\u56de\u6536\uff0c\u4f46\u662f\u76ee\u524d\u5927\u591a\u6570MOFs\u5747\u4e3a\u4e09\u7ef4\u7ed3\u6784\uff0c\u4f20\u8d28\u5dee\u3001\u5bfc\u7535\u7387\u4f4e\uff0c\u4e14\u4f53\u76f8\u91d1\u5c5e\u4f4d\u70b9\u88ab\u6709\u673a\u914d\u4f53\u5305\u88f9\u96be\u4ee5\u5f97\u5230\u6709\u6548\u5229\u7528\u3002\u4e8c\u7ef4MOFs\u53ef\u514b\u670d\u8fd9\u4e9b\u7f3a\u70b9\uff0c\u4f46\u7cbe\u51c6\u5408\u6210\u9ad8\u6548OER\u7684\u4e8c\u7ef4MOFs\u6750\u6599\u4ecd\u6781\u5177\u6311\u6218\u3002\u8fd1\u65e5\uff0c<strong><b>\u6765\u81ea<\/b><\/strong><strong><b>\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u8463\u7ecd\u4fca\u9662\u58eb<\/b><\/strong>\u8bfe\u9898\u7ec4\u91c7\u7528\u539f\u4f4d\u81ea\u89e3\u79bb\u7ec4\u88c5\u5408\u6210\u7b56\u7565\u5236\u5907\u4e86\u6ce1\u6cabCoNi\u5408\u91d1\u4e0a\u8d1f\u8f7d\u8d85\u8584CoNi-MOF\u7eb3\u7c73\u7247\u9635\u5217\u6750\u6599\uff08CoNi-MOFNA\uff09\u5e76\u7528\u4e8eOER\u3002\u8be5\u50ac\u5316\u5242\u5728\u78b1\u6027\u6761\u4ef6\u4e0b10mA cm<sup>-2<\/sup>\u65f6\uff0c\u63d0\u4f9b\u4e861.41 V\u7684\u6781\u4f4e\u542f\u52a8\u7535\u4f4d\u548c215 mV\u7684\u8fc7\u7535\u4f4d\uff0c\u4e14\u8fd0\u884c300h\u540e\u8fc7\u7535\u4f4d\u57fa\u672c\u65e0\u53d8\u5316\u3002CoNi-MOFNA\u7684\u8d28\u91cf\u6d3b\u6027\u662f\u5546\u4e1aRuO<sub>2<\/sub>\u768414\u500d\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5b9e\u9a8c\u7814\u7a76\u8bc1\u5b9eMOFs\u8868\u9762\u66b4\u9732\u7684\u914d\u4f4d\u4e0d\u9971\u548cCoO<sub>5<\/sub>\u00a0and NiO<sub>5<\/sub>\u91d1\u5c5e\u8282\u70b9\u662f\u8be5\u50ac\u5316\u5242\u4e0aOER\u7684\u672c\u5f81\u6d3b\u6027\u4f4d\u70b9\u3002DFT\u8ba1\u7b97\u7ed3\u679c\u8868\u660eNi\u548cCo\u4e4b\u95f4\u5b58\u5728\u5f3a\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u4e14CoNi-MOFNA\u4e2d\u7684Ni\u6d3b\u6027\u4f4d\u70b9\u66f4\u4e3a\u6d3b\u6cfc\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0cCoNi-MOFNA\u4e0aOER\u8fc7\u7a0b\u4e2d\u8868\u9762\u5747\u5300\u751f\u6210\u4e86\u8d85\u8584\u7f9f\u57fa\u6c27\u5316\u7269\u56e2\u7c07\uff0c\u4e0eMOF\u6742\u5316\u4e0d\u4ec5\u7a33\u5b9a\u4e86\u50ac\u5316\u5242\u7684\u7a7a\u95f4\u7ed3\u6784\uff0c\u4e5f\u4fdd\u62a4\u4e86\u6d3b\u6027\u4f4d\u70b9\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u7684\u539f\u4f4d\u81ea\u89e3\u79bb\u7ec4\u88c5\u5408\u6210\u7b56\u7565\u4e3a\u4e8c\u7ef4MOFs\u7eb3\u7c73\u7247\u9635\u5217\u7684\u5408\u6210\u5f00\u8f9f\u4e86\u65b0\u9014\u5f84\uff0c\u4e3a\u9ad8\u6548OER\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n<p>https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285519310031?dgcid=rss_sd_all#!<\/p>\n<p><strong><b>11\u3001Nat. Commun.\uff1a\u4e09\u7ef4\u5f00\u653e\u5f0f\u7eb3\u7c73\u7f51\u72b6\u7535\u50ac\u5316\u5242\u9ad8\u6548\u5168pH\u503c\u89e3\u6c34<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-193230 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/11-3.png\" alt=\"\" width=\"475\" height=\"451\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/11-3.png 475w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/11-3-300x285.png 300w\" sizes=\"(max-width: 475px) 100vw, 475px\" \/><\/p>\n<p>\u9ad8\u6548\u7535\u89e3\u6c34\u662f\u53ef\u6301\u7eed\u80fd\u6e90\u7684\u5173\u952e\u3002\u8fd1\u65e5\uff0c<strong><b>\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u3001\u9648\u6668\u3001<\/b><\/strong><strong><b>\u5f6d\u537f<\/b><\/strong><strong><b>\u7b49<\/b><\/strong>\u62a5\u9053\u4e86\u5728\u7535\u5316\u5b66\u6d4b\u8bd5\u8fc7\u7a0b\u4e2d\u901a\u8fc7\u539f\u4f4d\u8680\u523b\u4eceRuIrZnO<sub>x<\/sub>\u7a7a\u5fc3\u7eb3\u7c73\u76d2\u4e2d\u53bb\u9664\u4e24\u6027ZnO\u5f62\u6210\u7684\u9ad8\u6d3b\u6027\u548c\u8010\u7528\u7684RuIrO<sub>x<\/sub>\uff08x\u22650\uff09\u7eb3\u7c73\u7f51\u7b3c\u50ac\u5316\u5242\u3002\u5206\u6563-\u8680\u523b-\u5b54\u6d1e\u7b56\u7565\u4f7f\u591a\u5b54\u7eb3\u7c73\u7f51\u67b6\u6d3b\u6027\u4f4d\u70b9\u66b4\u9732\uff0c\u5e76\u4e14\u6613\u4e8e\u5e95\u7269\u5206\u5b50\u63a5\u89e6\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u4e86\u7535\u5316\u5b66\u8868\u9762\u79ef\uff08ECSA\uff09\u3002\u5b9e\u9a8c\u53d1\u73b0\uff0c\u8be5\u7eb3\u7c73\u7f51\u7b3c\u50ac\u5316\u5242\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u8d85\u4f4e\u7684\u8fc7\u7535\u4f4d\uff0812 mV\uff0cpH = 0; 13 mV\uff0cpH=14\uff09\uff0c\u5373\u53ef\u8fbe\u523010 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u800c\u4e14\u5728\u5bbdpH\u8303\u56f4\uff080\u301c14\uff09\u5185\u5b9e\u73b0\u4e86\u9ad8\u6027\u80fd\u7684\u7535\u89e3\u6c34\uff0c\u8fbe\u523010 mA cm<sup>-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u8fc7\u7535\u4f4d\u4ec5\u4e3a1.45V\uff08pH=0\uff09\u62161.47V\uff08pH=14\uff09\u3002\u6b64\u5916\uff0c\u8be5\u7535\u50ac\u5316\u5242\u5177\u6709\u666e\u904d\u9002\u7528\u6027\uff0c\u53ef\u4ee5\u5c06\u5404\u79cd\u5bb9\u6613\u83b7\u5f97\u7684\u7535\u89e3\u8d28\uff08\u751a\u81f3\u5305\u62ec\u5e9f\u6c34\u548c\u6d77\u6c34\uff09\u76f4\u63a5\u7528\u4e8e\u5236\u6c22\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n<p>https:\/\/www.nature.com\/articles\/s41467-019-12885-0<\/p>\n<p>\u7531<strong>eric<\/strong>\u4f9b\u7a3f\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u201c\u50ac\u5316\u201d\u4e00\u8bcd\uff0c\u81ea19\u4e16\u7eaa\u4e0a\u534a\u53f6\u5c31\u5df2\u7ecf\u8bde\u751f\u5e76\u5f00\u59cb\u4f7f\u7528\u3002\u800c\u4eba\u4eec\u5bf9\u50ac\u5316\u4f5c\u7528\u7684\u53d1\u73b0\uff0c\u5219\u8fd8\u8981\u65e9\u5f97\u591a\u3002\u65e9\u57284000\u591a\u5e74\u4ee5\u524d\uff0c\u4eba\u4eec\u5c31\u5df2\u5b66\u4f1a\u7528\u542b\u9176\u7684\u9152\u66f2\u917f\u9152\uff0c\u8fd9\u5e94\u8be5\u662f\u6700\u65e9\u5b9e\u73b0\u7684&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":179054,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-193219","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/193219"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=193219"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/193219\/revisions"}],"predecessor-version":[{"id":193277,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/193219\/revisions\/193277"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/179054"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=193219"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=193219"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=193219"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}