{"id":192537,"date":"2019-12-18T06:21:45","date_gmt":"2019-12-17T22:21:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=192537"},"modified":"2019-12-17T19:21:54","modified_gmt":"2019-12-17T11:21:54","slug":"%e6%95%b0%e5%8d%81%e4%b8%87mofs%e4%b8%ad%e5%ae%9a%e8%83%bd%e6%89%be%e5%88%b0%e4%bd%a0%e7%9a%84%e6%9c%80%e7%88%b1%ef%bc%81%ef%bd%9c%e8%bf%91%e6%9c%9f%e9%a1%b6%e5%88%8a%e7%a0%94%e7%a9%b6%e9%80%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=192537","title":{"rendered":"\u6570\u5341\u4e07MOFs\u4e2d\u5b9a\u80fd\u627e\u5230\u4f60\u7684\u6700\u7231\uff01\uff5c\u8fd1\u671f\u9876\u520a\u7814\u7a76\u901f\u89c8"},"content":{"rendered":"<p>MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u591a\u7ef4\u5ea6\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5728\u50ac\u5316\u3001\u50a8\u80fd\u548c\u5206\u79bb\u7b49\u7b49\u4e2d\u90fd\u6709\u5e7f\u6cdb\u5e94\u7528\u3002\u81ea20\u4e16\u7eaa90\u5e74\u4ee3\uff0c\u7b2c\u4e00\u4ee3MOFs\u6750\u6599\u88ab\u5408\u6210\u51fa\u6765\uff0cMOFs\u5df2\u6210\u4e3a\u65e0\u673a\u5316\u5b66\u3001\u6709\u673a\u5316\u5b66\u7b49\u591a\u4e2a\u5316\u5b66\u5206\u652f\u7684\u91cd\u8981\u7814\u7a76\u65b9\u5411\u3002\u7b14\u8005\u68b3\u7406\u4e86\u8fd1\u671f\u6750\u6599\u7c7b\u7cfb\u5217\u520a\u4e2dMOFs\u7684\u76f8\u5173\u6587\u7ae0\uff0c\u4e00\u8d77\u4e86\u89e3\u4e0b\u76f8\u5173\u7814\u7a76\uff01<\/p>\n<p><strong><b>1 \u6e7f\u70df\u6c14CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u6355\u96c6\u5668-<\/b><\/strong><strong><b>&#8211;<\/b><\/strong><strong><b>MOF\u7684\u8bbe\u8ba1<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>Nature<\/b><\/strong><\/p>\n<p>\u9650\u5236\u5927\u6c14\u4e2dCO<sub>2<\/sub>\u7684\u589e\u52a0\u662f\u6211\u4eec\u8fd9\u4e00\u4ee3\u4eba\u9762\u4e34\u7684\u6700\u5927\u6311\u6218\u4e4b\u4e00\uff0c\u7531\u4e8e\u78b3\u6355\u96c6\u4e0e\u5c01\u5b58\u6280\u672f\u662f\u76ee\u524d\u4e3a\u6570\u4e0d\u591a\u7684\u80fd\u591f\u51cf\u5c11CO<sub>2<\/sub>\u6392\u653e\u7684\u53ef\u884c\u6280\u672f\u4e4b\u4e00\u3002\u5728\u8fd9\u65b9\u9762\u5f15\u8d77\u76f8\u5f53\u5927\u5174\u8da3\u7684\u53e6\u4e00\u7c7b\u6750\u6599\u662f\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\uff0c\u5176\u4e2d\u6709\u673a\u914d\u4f53\u4e0e\u91d1\u5c5e\u79bb\u5b50\u8282\u70b9\u7684\u7cbe\u786e\u7ed3\u5408\u53ef\u4ee5\u4ea7\u751f\u65e0\u6570\u7ed3\u6784\u548c\u5316\u5b66\u4e0a\u622a\u7136\u4e0d\u540c\u7684\u7eb3\u7c73\u591a\u5b54MOFs\u3002\u7136\u800c,\u00a0\u8bb8\u591a\u7ecf\u8fc7\u4f18\u5316\u7684\u7528\u4e8e\u4eceN<sub>2<\/sub>\u4e2d\u5206\u79bbCO<sub>2<\/sub>\u7684MOFs\u7528\u5728\u542bH<sub>2<\/sub>O\u7684\u5b9e\u9645\u70df\u9053\u6c14\u65f6\u6548\u679c\u4e0d\u4f73\uff0c\u56e0\u4e3aH<sub>2<\/sub>O\u4f1a\u4e0eCO<sub>2<\/sub>\u7ade\u4e89\u76f8\u540c\u7684\u5438\u9644\u4f4d\u70b9\uff0c\u4ece\u800c\u4f7f\u6750\u6599\u5931\u53bb\u9009\u62e9\u6027\u3002\u867d\u7136\u70df\u9053\u6c14\u4f53\u53ef\u4ee5\u5e72\u71e5\uff0c\u4f46\u8fd9\u4f7f\u5f97\u6355\u83b7\u8fc7\u7a0b\u7684\u6210\u672c\u9ad8\u5f97\u4ee4\u4eba\u671b\u800c\u5374\u6b65\u3002\u5728\u8fd9\u91cc\uff0c\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662Berend Smit\u3001Kyriakos C. Stylianou\uff0c\u8d6b\u745e\u74e6\u7279\u5927\u5b66Susana Garcia\uff0c\u6e25\u592a\u534e\u5927\u5b66Tom K. Woo\u7b49\u56e2\u961f\u5408\u4f5c\u5c55\u793a\u4e86\u4e00\u4e2a\u8d85\u8fc7300000 MOFs\u7684\u8ba1\u7b97\u7b5b\u9009\u5e93\u7684\u6570\u636e\u6316\u6398\u53ef\u4ee5\u8bc6\u522b\u4e0d\u540c\u79cd\u7c7b\u7684\u5f3aCO<sub>2<\/sub>\u7ed3\u5408\u4f4d\u70b9&#8211;\u79f0\u4e4b\u4e3a\u201c\u5438\u9644\u5242\u201d\u8d4b\u4e88MOFs\u5728\u6f6e\u6e7f\u70df\u9053\u6c14\u4f53\u4e2d\u6301\u4e45\u7684CO<sub>2<\/sub>\/N<sub>2<\/sub>\u9009\u62e9\u6027\u3002\u968f\u540e\uff0c\u5408\u6210\u4e86\u4e24\u79cd\u6700\u758f\u6c34\u6027\u5438\u9644\u5242\u7684\u6c34\u7a33\u6027MOFs\uff0c\u53d1\u73b0\u5b83\u4eec\u7684\u78b3\u6355\u83b7\u6027\u80fd\u4e0d\u53d7\u6c34\u7684\u5f71\u54cd\uff0c\u5e76\u4f18\u4e8e\u4e00\u4e9b\u5546\u7528\u6750\u6599\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cData-driven design of metal\u2013organic frameworks for wet flue gas CO<sub>2<\/sub>\u00a0capture\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1038\/s41586-019-1798-7<\/p>\n<p>\u56fe1\u00a0[Al-PMOF]\u548c[Al-PyrMOF]\u7684CO<sub>2<\/sub>\u5438\u9644\u3001<sup>13<\/sup>C\u4ea4\u53c9\u6781\u5316\u8d28\u8c31\u548c\u7a81\u7834\u5b9e\u9a8c<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192538 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72471-25.png\" alt=\"\" width=\"680\" height=\"780\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72471-25.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72471-25-262x300.png 262w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>2<\/b><\/strong><strong><b>\u00a0\u5728\u591a\u5b54<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4e2d\u6355\u83b7<\/b><\/strong><strong><b>N<\/b><\/strong><strong><b>O<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u5e76\u8f6c\u5316\u4e3a\u785d\u9178<\/b><\/strong><strong><b>\uff5cNature<\/b><\/strong><strong><b>\u00a0C<\/b><\/strong><strong><b>hemistry<\/b><\/strong><\/p>\n<p>\u6c2e\u6c27\u5316\u7269\u9020\u6210\u7684\u7a7a\u6c14\u6c61\u67d3\u662f\u4e00\u4e2a\u4e3b\u8981\u95ee\u9898\uff0c\u8feb\u5207\u9700\u8981\u65b0\u7684\u6355\u6349\u548c\u6d88\u9664\u6280\u672f\u3002\u5728\u8fd9\u91cc\uff0c\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u6768\u56db\u6d77\u3001Martin Schr\u00f6der\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MFM-520)\uff0c\u5b83\u53ef\u4ee5\u6709\u6548\u5730\u9650\u5236NO<sub>2<\/sub>\u7684\u4e8c\u805a\u4f53\uff0c\u5176\u9ad8\u5438\u9644\u80fd\u529b\u4e3a4.2 mmol g<sup>-1<\/sup>\u00a0(298 K, 0.01 bar)\uff0c\u5177\u6709\u5b8c\u5168\u7684\u53ef\u9006\u6027\uff0c\u5176\u6781\u9ad8\u7684\u7a33\u5b9a\u6027\u5b9e\u73b0\u4e86\u6750\u6599\u7ed3\u6676\u6027\u548c\u5b54\u9053\u7684\u5b8c\u6574\u6027\u4e0b\u8d85\u8fc7\u767e\u6b21\u7684NO<sub>2<\/sub>\u7684\u6355\u6349\u4e0e\u8f6c\u5316\uff0c\u5728125\u4e2a\u5faa\u73af\u4e2d\u4e0d\u635f\u5931\u5bb9\u91cf\u3002\u5229\u7528\u7a7a\u6c14\u4e2d\u7684\u6c34\u5bf9NO<sub>2<\/sub>@ MFM-520\u8fdb\u884c\u5904\u7406\uff0c\u53ef\u4ee5\u5b9a\u91cf\u5730\u5c06\u6355\u83b7\u7684NO<sub>2<\/sub>\u8f6c\u5316\u4e3aHNO<sub>3<\/sub>(\u5316\u80a5\u751f\u4ea7\u7684\u91cd\u8981\u539f\u6599)\uff0c\u5e76\u5b8c\u5168\u518d\u751fMFM-520\u3002N<sub>2<\/sub>O<sub>4<\/sub>\u88ab\u9650\u5236\u5728\u7eb3\u7c73\u5b54\u5185\u662f\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u5efa\u7acb\u7684\uff0c\u5229\u7528\u5e72\u71e5\u548c\u6f6e\u6e7f\u7684NO<sub>2<\/sub>\u6c14\u4f53\u6d41\u8fdb\u884c\u7684\u52a8\u6001\u7a81\u7834\u5b9e\u9a8c\u9a8c\u8bc1\u4e86MFM-520\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u548c\u9009\u62e9\u6027\uff0c\u5e76\u8bc1\u5b9e\u4e86\u5176\u5728\u65e0\u8d35\u91d1\u5c5e\u8131\u785d\u6280\u672f\u65b9\u9762\u7684\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cCapture of nitrogen dioxide and conversion to nitric acid in a porous metal-organic framework\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Chemistry\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1038\/s41557-019-0356-0<\/p>\n<p>\u56fe2\u00a0\u5438\u9644\u3001\u9009\u62e9\u6027\u3001\u5206\u79bb\u548c\u7a33\u5b9a\u6027\u6570\u636e<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192539 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72472-22.png\" alt=\"\" width=\"680\" height=\"510\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72472-22.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72472-22-300x225.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>3 <\/b><\/strong><strong><b>\u901a\u8fc7\u6c27\u5316\u526a\u5207\uff0c\u5b9e\u73b0\u9ad8\u5ea6\u5b9a\u5411\u523b\u8680MOF\u9897\u7c92\uff5cJ<\/b><\/strong><strong><b>ACS<\/b><\/strong><\/p>\n<p>\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u674e\u6d9b\u6559\u6388\u8bfe\u9898\u7ec4\u8054\u5408\u6ce2\u58eb\u987f\u5b66\u9662\u5b97\u5bb6\u6d38\u6559\u6388\u8bfe\u9898\u7ec4\u63d0\u51fa\u4e86\u4e00\u79cd\u6c27\u5316\u914d\u4f53\u526a\u5207(OLC)\u5de5\u827a\uff0c\u7528\u4e8e\u7cbe\u786e\u64cd\u4f5c\u5355\u6676MOFs\u9897\u7c92\u7684\u5b9a\u5411\u523b\u8680\u5de5\u827a\u3002\u8be5\u65b9\u6cd5\u901a\u8fc7\u6c27\u5316\u5f00\u73af\u53cd\u5e94\u5c062,5-\u4e8c\u7f9f\u57fa\u5bf9\u82ef\u4e8c\u7532\u9178\u914d\u4f53(DOBDC)\u9009\u62e9\u6027\u964d\u89e3\u6210\u5c0f\u5206\u5b50\u7247\u6bb5\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u9aa8\u67b6\u7684\u53ef\u63a7\u526a\u5207\u3002\u7531\u4e8eDOBDC\u6613\u53d7\u5230\u785d\u9178\u548c\u6d3b\u6027\u6c27\u79cd\u7684\u8fdb\u653b\u3002\u901a\u8fc7\u8c03\u63a7\u6c27\u5316\u7269\u8d28\u7684\u751f\u6210\u548c\u6269\u6563\uff0c\u6838\u5fc3MOFs\u5c06\u7ecf\u5386\u4e0d\u540c\u7684\u8680\u523b\u8def\u7ebf\uff0c\u4ea7\u751f\u4e00\u7cfb\u5217\u5355\u6676\u7a7a\u5fc3\u548c\u86cb\u9ec4\u58f3MOF\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u5f53\u5728MOF\u7684\u5185\u6838\u4e2d\u9884\u5148\u5305\u57cbPd NPs\uff0cOLC\u8fc7\u7a0b\u80fd\u591f\u5b9a\u70b9\u5730\u5728Pd\u8868\u9762\u6216\u8005\u5468\u56f4\u751f\u6210\u3002\u8fd9\u4f7f\u5f97\u523b\u8680\u88ab\u9650\u4e8e\u5728Pd\u9897\u7c92\u5468\u56f4\uff0c\u5bfc\u81f4\u591a\u4e2aNPs\u88ab\u5355\u72ec\u9650\u5236\u5728\u4e00\u4e2a\u5355\u6676MOF\u9897\u7c92\u5185\uff0c\u5373\u591a\u9ec4\u58f3\u7ed3\u6784\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u7ed3\u6784\u53ef\u4ee5\u6709\u6548\u5730\u4fdd\u62a4NPs\u4e0d\u53d7\u56e2\u805a\u7684\u5f71\u54cd\uff0c\u540c\u65f6\u5b9e\u73b0\u5c3a\u5bf8\u9009\u62e9\u6027\u50ac\u5316\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cDirectional Engraving within Single Crystalline Metal-Organic Framework Particles via Oxidative Linker Cleaving\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/jacs.9b10499<\/p>\n<p>\u56fe3\u00a0\u6838\u5fc3MOFs\u4e0d\u540c\u7684\u8680\u523b\u7684\u8868\u5f81\u53ca\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192540 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72473-18.png\" alt=\"\" width=\"680\" height=\"429\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72473-18.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72473-18-300x189.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>4 \u7535\u8377\u8f6c\u79fb\u5f00\u542f<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4e0a\u7684\u53ef\u89c1\u5149\u50ac\u5316C-H\u6c27\u5316<\/b><\/strong><strong><b>\uff5cJ<\/b><\/strong><strong><b>ACS<\/b><\/strong><\/p>\n<p>MOFs\u7684\u53ef\u8c03\u6574\u7ed3\u6784\u548c\u7535\u5b50\u7ed3\u6784\u6781\u5927\u5730\u4fc3\u8fdb\u4e86\u5b83\u4eec\u7684\u8c03\u5236\u5149\u6355\u83b7\u3001\u6c27\u5316\u8fd8\u539f\u80fd\u529b\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86\u5149\u50ac\u5316\u3002\u5728\u8fd9\u91cc\uff0c\u4e2d\u79d1\u5927\u6c5f\u6d77\u9f99\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u5229\u7528\u5178\u578b\u7684MOF: UiO-66\u4e30\u5bcc\u7684\u7f9f\u57fa\u4f4d\u70b9\uff0c\u5c06Fe<sup>3+<\/sup>\u7ed3\u5408\u5230Zr-oxo\u7ed3\u6784\u4e0a\uff0c\u83b7\u5f97Fe-UiO-66\uff0c\u57fa\u4e8e\u91d1\u5c5e\u5230\u96c6\u7fa4\u7535\u8377\u8f6c\u79fb(MCCT)\uff0c\u5b83\u5177\u6709\u6269\u5c55\u7684\u53ef\u89c1\u5149\u6536\u96c6\u529f\u80fd\u3002Fe-UiO-66\u5177\u6709\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u5f3a\u5927\u7684\u6c27\u5316\u80fd\u529b\uff0c\u5728\u53ef\u89c1\u5149\u7684\u9a71\u52a8\u4e0b\u53d1\u751f\u4e86\u6c34\u6c27\u5316\uff0c\u8fd9\u5bf9\u4e8e\u539f\u59cb\u7684UiO-66\u662f\u4e0d\u53ef\u80fd\u7684\u3002\u66f4\u5f15\u4eba\u6ce8\u76ee\u7684\u662f\uff0c\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0cFe-UiO-66\u4e0a\u4ea7\u751f\u7684\u7a7a\u7a74\u80fd\u591f\u5c06H<sub>2<\/sub>O\u72ec\u5bb6\u8f6c\u5316\u4e3a\u6c22\u6c27\u81ea\u7531\u57fa\uff0c\u5f15\u53d1\u5e76\u63a8\u52a8\u987d\u56fa\u7684C-H\u952e\u7684\u6d3b\u5316\uff0c\u5982\u7532\u82ef\u6c27\u5316\u3002\u7535\u5b50\u5c06O<sub>2<\/sub>\u8fd8\u539f\u4e3aO<sub>2<\/sub><sup>\u2022-<\/sup>\u81ea\u7531\u57fa\uff0c\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u6c27\u5316\u53cd\u5e94\u3002\u8be6\u7ec6\u7814\u7a76\u4e86\u5176\u50ac\u5316\u673a\u7406\u53ca\u6784\u6548\u5173\u7cfb\u3002\u8fd9\u4e0d\u4ec5\u662f\u4e00\u4efd\u5173\u4e8e\u6fc0\u6d3b\u201c\u60f0\u6027\u201dMOFs\u7528\u4e8e\u5149\u50ac\u5316C-H\u6d3b\u5316\u7684\u62a5\u544a\uff0c\u800c\u4e14\u4e5f\u662f\u901a\u8fc7\u5f15\u5165MCCT\u8fc7\u7a0b\u6765\u6269\u5c55\u5149\u6536\u96c6\u548c\u589e\u5f3aMOFs\u5149\u50ac\u5316\u7684\u7b2c\u4e00\u6b21\u5c1d\u8bd5\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cTurning on Visible-Light Photocatalytic C-H Oxidation over Metal\u2013Organic Frameworks by Introducing Metal-to-Cluster Charge Transfer\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1021\/jacs.9b09954<\/p>\n<p>\u56fe4\u00a0Fe-UiO-66\u5408\u6210\u3001MCCT\u8fc7\u7a0b\u53ca\u5149\u50ac\u5316C-H\u6c27\u5316\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192541 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72474-17.png\" alt=\"\" width=\"680\" height=\"556\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72474-17.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72474-17-300x245.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>5 \u7535\u6d41\u9a71\u52a8\u5408\u6210<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u819c\u7528\u4e8e<\/b><\/strong><strong><b>\u4e19\u70ef\/\u4e19\u70f7\u5206\u79bb<\/b><\/strong><strong><b>\uff5cScience<\/b><\/strong><strong><b>\u00a0Advances<\/b><\/strong><\/p>\n<p>MOF\u819c\u5728\u4e19\u70ef\/\u4e19\u70f7\u5206\u79bb\u65b9\u9762\u663e\u793a\u51fa\u826f\u597d\u7684\u524d\u666f\uff0c\u4f46\u7531\u4e8e\u5176\u56fa\u6709\u7684\u8fde\u63a5\u5242\u6d41\u52a8\u6027\uff0c\u76ee\u524d\u8fd8\u6ca1\u6709\u5b9e\u73b0\u5206\u5b50\u7b5b\u5206\u3002\u5728\u8fd9\u91cc\uff0c\u901a\u8fc7\u5feb\u901f\u7535\u6d41\u9a71\u52a8\u5408\u6210(FCDS)\u4e86\u5177\u6709\u6291\u5236\u8fde\u63a5\u5242\u8fc1\u79fb\u7387\u7684\u6cb8\u77f3\u578b\u54aa\u5511\u76d0\u9aa8\u67b6ZIF-8\u578b\u819c\u7b56\u7565\uff0c20min\u5185\uff0cZIF-8\u819c\u5728\u591a\u5b54\u57fa\u5e95\u4e0a\u7684\u5feb\u901f\u751f\u957f,\u8868\u73b0\u51fa\u4e19\u70ef\/\u4e19\u70f7\u5206\u79bb\u7684\u9510\u5316\u5206\u5b50\u7b5b\uff0c\u5206\u79bb\u7cfb\u6570\u5927\u4e8e300\u3002\u5728\u819c\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u76f4\u6d41\u7535\u4fc3\u4f7f\u91d1\u5c5e\u79bb\u5b50\u548c\u914d\u4f53\u4ee5ZIF-8_Cm(\u4e00\u79cd\u65b0\u53d1\u73b0\u7684ZIF-8\u7684\u53d8\u578b)\u7684\u5f62\u5f0f\u7ec4\u88c5\u6210\u5185\u90e8\u626d\u66f2\u548c\u8f83\u786c\u7684\u9aa8\u67b6\uff0c\u5360\u819c\u7ec4\u5206\u768460 ~ 70%\u3002\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u70b9\u3002\u5728\u4e19\u70ef\/\u4e19\u70f7\u5206\u79bb\u65b9\u9762\uff0cZIF-8_Cm\u4f18\u4e8eZIF-8\u666e\u901a\u7acb\u65b9\u76f8\uff0cFCDS\u5177\u6709\u5927\u89c4\u6a21\u751f\u4ea7\u9ad8\u8d28\u91cf\u8d85\u8584MOF\u819c\u7684\u5de8\u5927\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cParalyzed Membrane: Current-Driven Synthesis of a Metal-Organic Framework with Sharpened Propene\/Propane Separation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u00a0Advances\u4e0a \u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1126\/sciadv.aau1393<\/p>\n<p>\u56fe5\u00a0\u7535\u9a71\u52a8\u5408\u6210ZIF-8\u819c\u88c5\u7f6e\u3001\u00a0\u666e\u901aZIF-8\u4e0e\u7535\u9a71\u52a8\u5236\u5907\u521a\u6027ZIF-8\u5bf9\u6bd4\u56fe\u3001ZIF-8\u819c\u7684\u7f3a\u9677\u81ea\u4fee\u590d\u53ca\u521a\u6027ZIF-8\u76f8\u5728\u4e19\u70ef\u4e19\u70f7\u5206\u79bb\u8fc7\u7a0b\u4e2d\u7684\u4f18\u52bf\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192542 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72475-16.png\" alt=\"\" width=\"680\" height=\"505\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72475-16.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72475-16-300x223.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>6 <\/b><\/strong><strong><b>\u4e8c<\/b><\/strong><strong><b>\u8302\u91d1\u5c5e\u690d\u5165<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u4e2d\u5b9e\u73b0<\/b><\/strong><strong><b>\u9ad8\u9009\u62e9\u6027CO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u7535\u8fd8\u539f<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>Nano E<\/b><\/strong><strong><b>nergy<\/b><\/strong><\/p>\n<p>\u5177\u6709\u53ef\u8c03\u5b54\u9699\u7387\u548c\u91d1\u5c5e\u4f4d\u70b9\u7684MOFs\u88ab\u8ba4\u4e3a\u662f\u7535\u5316\u5b66CO<sub>2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO<sub>2<\/sub>RR)\u7684\u826f\u597d\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0cMOFs\u8f83\u5dee\u7684\u7535\u5b50\u5bfc\u7535\u6027\u548c\u4f9b\u7535\u5b50\u80fd\u529b\u5236\u7ea6\u4e86\u50ac\u5316\u6548\u7387\u7684\u63d0\u9ad8\u3002\u5728\u6b64\uff0c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5170\u4e9a\u4e7e\u6559\u6388\u56e2\u961f\u901a\u8fc7\u7b80\u5355\u7684\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u65b9\u6cd5\u5728MOFs\u4e2d\u690d\u5165\u4e8c\u8302\u91d1\u5c5e\uff0c\u5f97\u5230\u7684\u50ac\u5316\u5242\u5177\u6709\u4f18\u5f02\u7684CO<sub>2<\/sub>RR\u7535\u50ac\u5316\u6027\u80fd\u3002\u4f8b\u5982\uff0cCoCp<sub>2<\/sub>\u00a0@ MOF-545-Co\u7684FECO\u5728-0.7 V\u65f6\u9ad8\u8fbe97%\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u4e8c\u8302\u91d1\u5c5e\u4e0e\u91d1\u5c5e\u535f\u5549\u4e4b\u95f4\u5b58\u5728\u8f83\u5f3a\u7684\u7ed3\u5408\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u4ee5\u5927\u5e45\u5ea6\u964d\u4f4eCO<sub>2<\/sub>\u7684\u5438\u9644\u80fd\u3002\u4e8c\u8302\u91d1\u5c5e\u7684\u5f15\u5165\u53ef\u4ee5\u4f5c\u4e3a\u7535\u5b50\u7ed9\u4f53\u548c\u8f7d\u4f53\uff0c\u5728MOFs\u4e2d\u5f62\u6210\u8fde\u7eed\u7684\u7535\u5b50\u4f20\u9012\u901a\u9053\uff0c\u5e76\u5728CO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2d\u4e0e\u91d1\u5c5e\u535f\u5549\u53d1\u751f\u5f3a\u70c8\u7684\u7ed3\u5408\u4f5c\u7528\uff0c\u589e\u5f3aCO<sub>2<\/sub>RR\u7684\u6d3b\u6027\u3002\u8be5\u65b9\u6cd5\u5bf9\u9ad8\u9009\u62e9\u6027CO<sub>2<\/sub>RR\u7535\u50ac\u5316\u5242\u7684\u5f00\u53d1\u5177\u6709\u4e00\u5b9a\u7684\u6307\u5bfc\u610f\u4e49\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMetallocene Implanted Metalloporphyrin Organic Framework for Highly Selective CO<sub>2<\/sub>\u00a0Electroreduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nano Energy\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1016\/j.nanoen.2019.104233<\/p>\n<p>\u56fe6\u00a0CoCp<sub>2<\/sub>\u00a0@ MOF-545-Co\u7684\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192543 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72476-15.png\" alt=\"\" width=\"680\" height=\"832\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72476-15.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72476-15-245x300.png 245w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>7 \u5168\u5171\u8f6d\u915e\u83c1\u94dc<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong><strong><b>\u957f\u65f6\u95f4\u5faa\u73af\u8010\u7528\u7684\u94a0\u7898\u7535\u6c60<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>AM<\/b><\/strong><\/p>\n<p>\u53ef\u5145\u7535\u94a0\u7898\u7535\u6c60\u4ee5\u5176\u8d44\u6e90\u4e30\u5bcc\u3001\u6210\u672c\u4f4e\u5ec9\u3001\u73af\u5883\u53cb\u597d\u3001\u7406\u8bba\u5bb9\u91cf\u9ad8\u3001\u7535\u5316\u5b66\u53ef\u9006\u6027\u597d\u7b49\u4f18\u70b9\uff0c\u8d8a\u6765\u8d8a\u53d7\u5230\u4eba\u4eec\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u7531\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f1a\u5728\u7535\u89e3\u6db2\u4e2d\u4e25\u91cd\u6eb6\u89e3\uff0c\u5bfc\u81f4\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\uff0c\u4e25\u91cd\u5f71\u54cd\u4e86\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5728\u6b64\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u51af\u65b0\u4eae\u6559\u6388\u8054\u5408\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u5f20\u5065\u6559\u6388\u56e2\u961f\u8bc1\u660e\u4e86\u5728\u5b8c\u5168\u5171\u8f6d\u7684\u915e\u83c1\u94dcMOF\u4e2d\uff0c\u53cc\u91d1\u5c5e(\u53cc\u7f9f\u57fa)\u7684\u539f\u5b50\u8c03\u5236\u53ef\u4ee5\u6291\u5236\u957f\u65f6\u95f4\u5faa\u73af\u7684\u94a0\u7898\u7535\u6c60\u5bf9\u805a\u7898\u5316\u7269\u7684\u6eb6\u89e3\u3002Fe<sub>2<\/sub>[(2,3,9,10,16,17,23,24-octahydroxy phthalocyaninato)Cu] MOF\u4e0eI<sub>2<\/sub>(Fe<sub>2<\/sub>\u2013O<sub>8<\/sub>\u2013PcCu\/I<sub>2<\/sub>)\u7ec4\u6210\uff0c\u53ef\u4f5c\u4e3a\u94a0\u7898\u7535\u6c60\u7684\u9634\u6781\uff0c\u57283200\u6b21\u5faa\u73af\uff0c\u5176\u7279\u6b8a\u5bb9\u91cf\u4e3a150 mAh g<sup>\u22121<\/sup>\uff0c\u6027\u80fd\u4f18\u4e8e\u6700\u5148\u8fdb\u7684\u94a0\u7898\u7535\u6c60\u9634\u6781\u3002\u901a\u8fc7\u7535\u5316\u5b66\u548c\u7535\u5316\u5b66\u52a8\u529b\u5b66\u5206\u6790\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u5e73\u9762\u7ed3\u6784Fe\u2013bis(dihydroxy) (Fe\u2013O<sub>4<\/sub>)\u5bf9\u805a\u7898\u4ee3\u70f7\u7684\u7ed3\u5408\u8d77\u5230\u4e86\u6291\u5236\u5176\u6eb6\u89e3\u4e8e\u7535\u89e3\u6db2\u7684\u4f5c\u7528\u3002\u9664\u4e86\u6709\u673a\u7535\u89e3\u8d28\u4e2d\u7684\u5355\u4ef7\u94a0\u79bb\u5b50\u7535\u6c60\u5916\uff0cFe<sub>2<\/sub>-O<sub>8<\/sub>-PcCu\/I<sub>2<\/sub>\u9634\u6781\u5728\u5176\u4ed6\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u5982\u591a\u4ef7\u950c\u79bb\u5b50\u7535\u6c60\u4e2d\u4e5f\u80fd\u7a33\u5b9a\u5de5\u4f5c\uff0c\u4e3a\u9ad8\u6027\u80fd\u91d1\u5c5e\u7898\u7535\u6c60\u7a33\u5b9a\u9634\u6781\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cFully Conjugated Phthalocyanine Copper Metal\u2013Organic Frameworks for Sodium\u2013Iodine Batteries with Long-Time-Cycling Durability\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/adma.201905361<\/p>\n<p>\u56fe7\u00a0PcCu-MOF\/I<sub>2<\/sub>\u590d\u5408\u6750\u6599\u7528\u4e8e\u94a0\u7898\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192544 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72477-14.png\" alt=\"\" width=\"680\" height=\"633\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72477-14.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72477-14-300x279.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>8 \u805a\u5421\u54af\u819c<\/b><\/strong><strong><b>\u4e0a\u7684M<\/b><\/strong><strong><b>OF\u7eb3\u7c73\u7ebf\u9635\u5217\u96c6\u6210\u5bfc\u7535\u7ed3\u6784<\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong><strong><b>\u5168\u56fa\u6001\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong><strong><b>\uff5c<\/b><\/strong><strong><b>AEM<\/b><\/strong><\/p>\n<p>\u5177\u6709\u591a\u5b54\u7ed3\u6784\u7684MOFs\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u50a8\u80fd\u6750\u6599\uff0c\u4f46\u5176\u4f4e\u5bfc\u7535\u6027\u9650\u5236\u4e86\u5176\u7535\u5316\u5b66\u50a8\u80fd\u7684\u5e94\u7528\u3002\u5728\u6b64\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u590f\u5b9d\u7389\u3001\u9f50\u9534\u6559\u6388\u8054\u5408\u97e9\u56fd\u6210\u5747\u9986\u5927\u5b66Ho Seok Park\u6559\u6388\u7b49\u4eba\u62a5\u544a\u4e86\u4e00\u79cd\u57fa\u4e8e\u81ea\u652f\u6491\u805a\u5421\u54af(PPy)\u819c\u4e0a\u7684\u672c\u8d28\u5bfc\u7535Cu-MOF\u7eb3\u7c73\u7ebf\u9635\u5217\u7684\u6df7\u5408\u7ed3\u6784\uff0c\u8be5\u7ed3\u6784\u7528\u4e8e\u96c6\u6210\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668(SC)\u7535\u6781\uff0c\u4e0d\u542b\u4efb\u4f55\u975e\u6d3b\u6027\u6dfb\u52a0\u5242\u3001\u7c98\u5408\u5242\u6216\u886c\u5e95\u3002\u5bfc\u7535\u7684Cu-MOFs\u7eb3\u7c73\u7ebf\u9635\u5217\u63d0\u4f9b\u4e86\u9ad8\u5bfc\u7535\u6027\u548c\u8db3\u591f\u6d3b\u8dc3\u7684\u8868\u9762\u79ef\u6765\u83b7\u5f97\u7535\u89e3\u8d28\uff0c\u800cPPy\u819c\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u673a\u68b0\u7075\u6d3b\u6027\u3001\u9ad8\u6548\u7684\u7535\u8377\u8f6c\u79fb\u9aa8\u67b6\u548c\u989d\u5916\u7684\u7535\u5bb9\u3002\u5168\u56fa\u6001\u7684\u7075\u6d3bSC\u4f7f\u7528\u96c6\u6210\u6df7\u5408\u7535\u6781\u663e\u793a\u826f\u597d\u7684\u9762\u79ef\u7535\u5bb9252.1mF cm<sup>-2<\/sup>,\u80fd\u91cf\u5bc6\u5ea622.4 \u00b5Wh cm<sup>-2<\/sup>\u548c\u529f\u7387\u5bc6\u5ea61.1 mW cm<sup>-2<\/sup>, \u5728\u5e7f\u6cdb\u7684\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u5185\u4f34\u968f\u7740\u4e00\u4e2a\u5f88\u597d\u7684\u5faa\u73af\u6027\u80fd\u548c\u673a\u68b0\u7684\u7075\u6d3b\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u63d0\u51fa\u4e86\u4e00\u4e2a\u5f3a\u5927\u7684\u548c\u7075\u6d3b\u7684\u7535\u6781\u5bbd\u6e29\u5ea6\u8303\u56f4\u7684\u5de5\u4f5c\uff0c\u4f46\u4e5f\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u6982\u5ff5\uff0c\u6709\u5173\u8bbe\u8ba1\u7528\u4e8e\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u7cfb\u7edf\u7684\u57fa\u4e8eMOF\u7684\u6df7\u5408\u6750\u6599\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cIntegrated Conductive Hybrid Architecture of Metal Organic Framework Nanowire Array on Polypyrrole Membrane for All-Solid-State Flexible Supercapacitors\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AEM\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/aenm.201901892<\/p>\n<p>\u56fe8\u00a0Cu-CAT-NWAs\/PPy\u7684\u5236\u5907\u53caTEM\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192545 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72478-10.png\" alt=\"\" width=\"680\" height=\"564\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72478-10.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72478-10-300x249.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>9 <\/b><\/strong><strong><b>\u6c34\u7a33\u6027M<\/b><\/strong><strong><b>OF\u5177\u6709\u5149\u50ac\u5316\u6291\u83cc\u6d3b\u6027\uff0c\u7528\u4e8e\u81ea\u4e3b\u5ba4\u5185\u6e7f\u5ea6\u63a7\u5236<\/b><\/strong><strong><b>\uff5cAngew<\/b><\/strong><strong><b>.<\/b><\/strong><\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5177\u6709\u957f\u671f\u7a33\u5b9a\u6027\u548c\u53ef\u9006\u7684\u9ad8\u5438\u6c34\u6027\u80fd\uff0c\u662f\u96c6\u6c34\u548c\u5ba4\u5185\u6e7f\u5ea6\u63a7\u5236\u7684\u7406\u60f3\u9009\u62e9\u3002\u5728\u6b64\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u3001\u6797\u653f\u56fd\u6559\u6388\u7b49\u4eba\u62a5\u5bfc\u4e86\u4e00\u79cd\u65b0\u578b\u4ecb\u5b54\u4e14\u9ad8\u5ea6\u7a33\u5b9a\u7684MOF(BIT-66)\uff0c\u5177\u6709\u5ba4\u5185\u6e7f\u5ea6\u63a7\u5236\u80fd\u529b\u548c\u5149\u50ac\u5316\u6291\u83cc\u6548\u679c\u3002BIT-66: (V<sub>3<\/sub>(O)<sub>3<\/sub>(H<sub>2<\/sub>O)(BTB)<sub>2<\/sub>),\u5728\u76f8\u5bf9\u6e7f\u5ea6\u4e3a45% ~ 60%\u7684\u8303\u56f4\u5185\uff0c\u6c34\u5206\u53ef\u8c03\u6027\u663e\u8457\uff0c\u5438\u6c34\u7387\u548c\u5de5\u4f5c\u80fd\u529b\u5206\u522b\u4e3a71%\u548c55% wt%\uff0c\u5206\u522b\u5728\u6c34\u7684\u5438\u9644-\u89e3\u5438\u5faa\u73af\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u53ef\u56de\u6536\u6027\u548c\u4f18\u5f02\u7684\u6027\u80fd\u3002\u91cd\u8981\u7684\u662f\uff0cBIT-66\u5728\u53ef\u89c1\u5149\u4e0b\u8868\u73b0\u51fa\u72ec\u7279\u7684\u5149\u50ac\u5316\u6291\u83cc\u884c\u4e3a\uff0c\u53ef\u6709\u6548\u6539\u5584\u5438\u6c34\u6027\u6750\u6599\u4e2d\u7684\u7ec6\u83cc\u3001\u9709\u83cc\u6ecb\u751f\u95ee\u9898\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Hydrolytically Stable V(IV)-Metal-Organic Framework with Photocatalytic Bacteriostatic Activity for Autonomous Indoor Humidity Control\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI: 10.1002\/anie.201914762<\/p>\n<p>\u56fe9\u00a0BIT-66 N<sub>2<\/sub>\u7b49\u6e29\u7ebf\u5438\u9644\u66f2\u7ebf\u53ca\u6c34\u84b8\u6c14\u7b49\u6e29\u7ebf\u5438\u9644\u66f2\u7ebf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192546 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72479-9.png\" alt=\"\" width=\"680\" height=\"313\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72479-9.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u72479-9-300x138.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong><b>10 \u534a\u5bfc\u4f53<\/b><\/strong><strong><b>2D MOF<\/b><\/strong><strong><b>\u00a0Cu<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>(C<\/b><\/strong><strong><sub><b>6<\/b><\/sub><\/strong><strong><b>O<\/b><\/strong><strong><sub><b>6<\/b><\/sub><\/strong><strong><b>)\u7684\u8868\u9762\u5408\u6210<\/b><\/strong><strong><b>\uff5cAngew<\/b><\/strong><strong><b>.<\/b><\/strong><\/p>\n<p>\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u6797\u5ff5\u6559\u6388\u8054\u5408\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66Li Huang\u6559\u6388\u7b49\u4eba\u5229\u7528\u82ef\u516d\u915a\u5206\u5b50\u5728Cu(111)\u57fa\u5e95\u4e0a\u5408\u6210\u4e862D MOF\u3002\u91c7\u7528\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u4e0e\u5149\u8c31\u5b66\u3001X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u5b66\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\uff0c\u786e\u5b9a\u4e86\u8be5\u6750\u6599\u7684\u7ed3\u6784Cu<sub>3<\/sub>(C<sub>6<\/sub>O<sub>6<\/sub>)\u7531O-Cu-O\u952e\u57fa\u5e8f\u7a33\u5b9a\u3002\u7814\u7a76\u53d1\u73b0\u5728Cu(111)\u4e0a\u5438\u9644\u540e\uff0c2D MOF\u5177\u6709\u534a\u5bfc\u4f53\u5e26\u7ed3\u6784\uff0c\u76f4\u63a5\u5e26\u9699\u4e3a1.5 eV\u3002O-Cu-O\u952e\u63d0\u4f9b\u4e86\u9ad8\u6548\u7684\u7535\u8377\u79bb\u57df\uff0c\u5728\u5e26\u5e95\u90e8\u5f62\u6210\u4e86\u4e00\u4e2a\u6709\u6548\u8d28\u91cf\u4e3a0.45 m<sub>e<\/sub>\u7684\u9ad8\u8272\u6563\u5bfc\u7535\u5e26\uff0c\u8fd9\u610f\u5473\u7740\u8be5\u6750\u6599\u5177\u6709\u9ad8\u7684\u7535\u5b50\u8fc1\u79fb\u7387\u3002\u8fd9\u4e9b\u7279\u6027\u4f7fCu<sub>3<\/sub>(C<sub>6<\/sub>O<sub>6<\/sub>) 2D MOF\u6210\u4e3a\u7535\u5b50\u548c\u5149\u7535\u5e94\u7528\u7684\u4e00\u4e2a\u6709\u524d\u9014\u7684\u5019\u9009\u6750\u6599\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cOn-surface Synthesis of a Semiconductinng 2D Metal Organic Framework Cu3(C6O6) Exhibiting Dispersive Electronic Bands\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aDOI:\u00a010.1002\/ange.201913698<\/p>\n<p>\u56fe10\u00a0STM\u5f62\u8c8c\u53caRT\u76f8HT\u76f8<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-192547 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u724710-9.png\" alt=\"\" width=\"680\" height=\"433\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u724710-9.png 680w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/\u56fe\u724710-9-300x191.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" 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tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>MOFs\u662f\u8fd1\u5341\u5e74\u6765\u53d1\u5c55\u8fc5\u901f\u7684\u4e00\u79cd\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5177\u6709\u591a\u7ef4\u5ea6\u7684\u5b54\u7ed3\u6784\uff0c\u81ea\u7ec4\u88c5\u5f62\u6210\u5177\u6709\u5468\u671f\u6027\u7f51\u72b6\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u6784\u6210\u7a7a\u95f43D\u5ef6\u4f38\uff0c\u7cfb\u6cb8\u77f3\u548c\u78b3\u7eb3\u7c73\u7ba1\u4e4b\u5916\u7684\u53c8\u4e00\u7c7b\u91cd\u8981\u7684\u65b0\u578b\u591a\u5b54&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":179218,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-192537","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/192537"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=192537"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/192537\/revisions"}],"predecessor-version":[{"id":192548,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/192537\/revisions\/192548"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/179218"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=192537"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=192537"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=192537"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}