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fabrication of metal-organic frameworks with orderly distributed hierarchical porosity<\/strong>\u201d\u53d1\u8868\u5728\u5316\u5b66\u8457\u540d\u671f\u520aAngew. Chem. Int. Ed<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe\u4e00\uff1a<\/strong>HP-MOF<\/strong>\u7684\u751f\u957f\u793a\u610f\u56fe<\/strong><\/p>\n \u56fe\u4e8c\uff1a<\/strong>HP-MOF<\/strong>\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n \u56fe\u4e09\uff1a<\/strong>HP-MOF<\/strong>\u7684\u7406\u5316\u6027\u8d28<\/strong><\/p>\n \u6240\u5236\u5907\u4ea7\u54c1\u7684XRD\u56fe\u8c31\uff08A\uff09\uff0cTGA\u66f2\u7ebf\uff08B\uff09\uff0c\u6c2e\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff08C\uff09\u548c\u5b54\u5f84\u5206\u5e03\uff08D\uff09\uff1aa\uff09Cu-BTC\uff1b b\uff09HP-Cu-BTC-1\uff1b c\uff09HP-Cu-BTC-2\uff1b d\uff09HP-Cu-BTC-3\u3002\u6837\u54c1\u4e2dCu K\u8fb9\u7684XANES\uff08E\uff09\u548cEXAFS\uff08F\uff09\u5206\u6790\uff1aa\uff09Cu(NO3<\/sub>)2<\/sub>\u6eb6\u6db2\uff1bb\uff09\u6ca1\u6709\u914d\u4f53\u7684HP-Cu-BTC-3\u524d\u4f53\uff1bc\uff09Cu(OAc)2<\/sub>\u6eb6\u6db2\uff1bd\uff09\u6ca1\u6709\u914d\u4f53\u7684S-Cu-BTC-PVP\u524d\u4f53\u3002<\/p>\n \u56fe\u56db\uff1a<\/strong>HP-MOF<\/strong>\u7684\u5185\u90e8\u7ed3\u6784\u548c\u7a7a\u95f4\u5206\u5e03<\/strong><\/p>\n HP-MOF\u7684TEM\u56fe\u50cf\uff1aA\uff09Cu-BTC\uff1bB\uff09HP-CuBTC-1\uff1bC\uff09HP-Cu-BTC-2\uff1b D\uff09HP-Cu-BTC-3\u3002E\uff09HP-Cu-BTC-3\u4e2d\u9009\u5b9a\u6676\u4f53\u7684\u653e\u5927\u56fe\u50cf\uff0cF-J\uff09E\uff09\u4e2d\u6676\u4f53\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\u3002\u4e09\u7ef4\u7eb3\u7c73\u65ad\u5c42\u626b\u63cf\u7684K\uff09\u5168\u89c6\u91ce\u548cL\uff09\u6311\u9009\u7684\u5355\u4e2aHP-Cu-BTC-3\u7eb3\u7c73\u9897\u7c92\u3002<\/p>\n \u56fe\u4e94\uff1a\u4e0d\u540c\u751f\u957f\u6a21\u5f0f\u5bf9<\/strong>HP-MOFs<\/strong>\u5236\u5907\u7684\u5f71\u54cd<\/strong><\/p>\n TEM\u56fe\u50cf\uff08A-C\uff09\uff0c\u5236\u5f97\u7684\u4ea7\u54c1\u7684\u6c2e\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff08J\uff09\u548c\u5b54\u5f84\u5206\u5e03\uff08K\uff09\uff1aA\uff09, a) S-Cu-BTC\uff1bB\uff09, b) S-Cu-BTC-PVP\uff1b C\uff09, c) S-Cu-BTC-PVP-R\u3002D-H\uff09S-Cu-BTC-PVP-R\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\u3002<\/p>\n \u56fe\u516d\u3001<\/strong>MOFs<\/strong>\u6210\u6838\u548c\u751f\u957f\u7684\u7814\u7a76<\/strong><\/p>\n \u5236\u5907\u7684\u4ea7\u54c1\u7684FESEM\u56fe\u50cf\uff08A-B\uff09\uff0cTEM\u56fe\u50cf\uff08C-D\uff09\uff0c\u6c2e\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff08E\uff09\u548c\u5b54\u5f84\u5206\u5e03\uff08F\uff09\uff1aA\uff09\uff0cC\uff09\uff0ca\uff09MOF-505; B\uff09\uff0cD\uff09\uff0cb\uff09MOF-505-PVP\u3002<\/p>\n \u56fe<\/strong>\u4e03\u3001\u82ef\u4e59\u70ef\u50ac\u5316\u6c27\u5316\u5b9e\u9a8c<\/strong><\/p>\n <\/p>\n <\/p>\n \u539f\u59cbCu-BTC\u548cHP-Cu-BTC-3\u5728\u82ef\u4e59\u70ef\u6c27\u5316\u4e2d\u7684\u50ac\u5316\u6027\u80fd\uff1aA\uff09\u53cd\u5e94\u65b9\u7a0b\u5f0f\uff1bB\uff09\u8f6c\u6362\u7387\uff1bC\uff09\u50ac\u5316\u9009\u62e9\u6027\uff1bD\uff09HP-Cu-BTC-3\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u3002<\/p>\n \u3010\u603b\u7ed3\u5c55\u671b\u3011<\/strong><\/p>\n \u672c\u6587\u901a\u8fc7\u975e\u79bb\u5b50\u578b\u8868\u9762\u6d3b\u6027\u5242\uff08PVP\uff09\u6210\u529f\u5236\u5907\u4e86\u5177\u6709\u591a\u7ea7\u5b54\u7ed3\u6784\u7684MOF\u6750\u6599\u3002\u5e76\u5c06\u8be5\u65b9\u6cd5\u6210\u529f\u62d3\u5c55\u5e94\u7528\u4e8e\u5177\u6709\u8f6e\u6868\u7ed3\u6784\u7684Cu-MOF\u4e0a\uff0c\u5982Cu-BTC\u548cMOF-505\u3002\u8fd9\u4e9bHP-MOF\u4e0d\u4ec5\u8868\u73b0\u51fa\u591a\u79cd\u4e14\u5bbd\u7684\u5b54\u5f84\u5206\u5e03\uff0c\u800c\u4e14\u5176\u591a\u7ea7\u5b54\u6cbf\u5f84\u5411\u65b9\u5411\u5448\u73b0\u6709\u5e8f\u5206\u5e03\u72b6\u6001\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u6676\u4f53\u751f\u957f\u8fc7\u7a0b\u4e3b\u5bfc\u591a\u7ea7\u5b54\u6210\u5b54\u7684\u673a\u5236\u3002\u4e0e\u4f20\u7edf\u7684\u8868\u9762\u6d3b\u6027\u5242\u8f85\u52a9\u7684\u6a21\u677f\u6cd5\u4e0d\u540c\uff0c\u6a21\u677f\u4e0eMOF\u524d\u4f53\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u4e0d\u518d\u662f\u524d\u63d0\u6761\u4ef6\u3002\u76f8\u53cd\uff0c\u5f31\u76f8\u4e92\u4f5c\u7528\u53ef\u4fc3\u8fdb\u6676\u4f53\u751f\u957f\u8fc7\u7a0b\u4e2d\u6a21\u677f\u7684\u53bb\u9664\uff0c\u4ece\u800c\u4ea7\u751f\u66f4\u591a\u53ef\u7528\u7684\u591a\u7ea7\u5b54\u3002\u5c06HP-MOF\u7528\u4e8e\u82ef\u4e59\u70ef\u6c27\u5316\u65f6\uff0cHP-Cu-BTC\u8868\u73b0\u51fa\u663e\u8457\u589e\u5f3a\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8fd9\u5f52\u56e0\u4e8e\u66f4\u591a\u66b4\u9732\u7684\u6d3b\u6027\u4f4d\u70b9\u548c\u591a\u7ea7\u5b54\u9699\u7387\u8d4b\u4e88\u7684\u66f4\u5feb\u6269\u6563\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u79cd\u6676\u4f53\u751f\u957f\u4e3b\u5bfc\u7684\u6210\u5b54\u673a\u5236\u4e0d\u4ec5\u4e30\u5bcc\u4e86HP-MOF\u7684\u6210\u5b54\u673a\u7406\uff0c\u8fd8\u5c06\u4e3a\u65b0\u7684MOF\u590d\u5408\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u3002<\/p>\n
<\/a><\/p>\n
A) Cu-BTC; B) HP-CuBTC-1; C) HP-Cu-BTC-2; D) HP-Cu-BTC-3\u7684\u573a\u53d1\u5c04\u626b\u63cf\u7535\u955c\uff08FESEM\uff09\u56fe\u50cf\u3002<\/p>\n
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