{"id":192267,"date":"2019-12-20T06:27:57","date_gmt":"2019-12-19T22:27:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=192267"},"modified":"2019-12-19T18:28:29","modified_gmt":"2019-12-19T10:28:29","slug":"%e7%be%8e%e5%9b%bd%e8%8a%9d%e5%8a%a0%e5%93%a5%e5%a4%a7%e5%ad%a6%e6%9e%97%e6%96%87%e6%96%8cj-am-chem-soc-%ef%bc%9a%e7%94%a8%e4%ba%8e%e6%af%94%e4%be%8b%e5%9e%8bph%e5%92%8c%e6%b0%a7%e6%b0%94%e4%bc%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=192267","title":{"rendered":"\u7f8e\u56fd\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658cJ. Am. Chem. Soc.\uff1a\u7528\u4e8e\u6bd4\u4f8b\u578bpH\u548c\u6c27\u6c14\u4f20\u611f\u7684\u591a\u529f\u80fd\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u5355\u5c42"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u5f00\u53d1\u7528\u4e8e\u76d1\u6d4b\u751f\u7406\u8fc7\u7a0b\u548c\u75c5\u7406\u751f\u7269\u5b66\u56e0\u7d20\u7684\u751f\u7269\u4f20\u611f\u5668\u5bf9\u75be\u75c5\u65e9\u671f\u8bca\u65ad\u975e\u5e38\u91cd\u8981\u3002\u5728\u8bf8\u591a\u751f\u7269\u4f20\u611f\u5668\u4e2d\uff0c\u8367\u5149\u63a2\u9488\u662f\u6700\u5e38\u7528\u7684\u7ec6\u80de\u6210\u50cf\u63a2\u9488\uff0c\u56e0\u4e3a\u5b83\u4eec\u53ef\u4ee5\u76f4\u63a5\uff0c\u5b9e\u65f6\u548c\u65e0\u6807\u8bb0\u5730\u68c0\u6d4b\u8bb8\u591a\u751f\u7269\u548c\u5316\u5b66\u5206\u6790\u7269\u3002\u5c24\u5176\u662f\u57fa\u4e8e\u7eb3\u7c73\u7c92\u5b50\u7684\u5149\u5b66\u751f\u7269\u4f20\u611f\u5668\u62e5\u6709\u5f3a\u5927\u7684\u6027\u80fd\uff0c\u53ef\u4ee5\u5bf9\u6d3b\u7ec6\u80de\u4e2d\u7684\u5206\u6790\u7269\u8fdb\u884c\u5fae\u76d1\u63a7\u3002\u5b83\u4eec\u4e3a\u5f00\u53d1\u591a\u529f\u80fd\u6bd4\u4f8b\u751f\u7269\u4f20\u611f\u5668\u63d0\u4f9b\u4e86\u57fa\u7840\uff0c\u4ee5\u7cbe\u786e\u76d1\u63a7\u5404\u79cd\u75c5\u7406\u5b66\u57fa\u7840\u7684\u751f\u7269\u548c\u5316\u5b66\u56e0\u7d20\u3002<\/p>\n<p>\u5728\u8fc7\u53bb\u7684\u5341\u5e74\u4e2d\uff0c\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08nMOF\uff09\u5728\u751f\u7269\u4f20\u611f\u548c\u76f8\u5173\u5e94\u7528\u4e2d\u663e\u793a\u51fa\u5de8\u5927\u6f5c\u529b\u3002\u901a\u8fc7\u540c\u65f6\u7ec4\u88c5\u5206\u5b50\u4f20\u611f\u5668\u548c\u53c2\u6bd4\u63a2\u9488\uff0c\u5e76\u5229\u7528\u6846\u67b6\u7ed3\u6784\u786e\u4fdd\u5176\u7a7a\u95f4\u9694\u79bb\u4ee5\u907f\u514d\u81ea\u6211\u731d\u706d\uff0cnMOFs\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u6676\u4f53\u5206\u5b50\u7eb3\u7c73\u6750\u6599\u5e73\u53f0\uff0c\u7528\u4e8e\u8bbe\u8ba1\u5177\u6709\u9ad8\u7075\u654f\u5ea6\u548c\u5206\u8fa8\u7387\u7684\u6bd4\u4f8b\u578b\u4f20\u611f\u5668\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u6865\u63a5\u914d\u4f53\u5bf9\u5bf9\u79f0\u6027\u7684\u4e25\u683c\u8981\u6c42\u548c\u5927\u591a\u6570nMOF\u7684\u76f8\u5bf9\u8f83\u5c0f\u7684\u5b54\/\u901a\u9053\uff0c\u56e0\u6b64\u53ea\u80fd\u5c06\u7b80\u5355\u7684\u5206\u5b50\u4f20\u611f\u5668\u6574\u5408\u5230nMOF\u4e2d\uff0c\u4ece\u800c\u4e25\u91cd\u9650\u5236\u4e86nMOF\u5728\u751f\u7269\u4f20\u611f\u4e2d\u7684\u666e\u904d\u6027\u3002nMOF\u7684\u5355\u5c42\u7248\u672c\uff0c\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u5355\u5c42\uff08nMOL\uff09\u53ef\u4ee5\u514b\u670dnMOF\u7684\u8fd9\u4e9b\u5c40\u9650\u6027\uff0c\u6210\u4e3a\u4e0b\u4e00\u4ee3\u7684\u4e8c\u7ef4\u7eb3\u7c73\u6676\u4f53\u5206\u5b50\u751f\u7269\u4f20\u611f\u5668\u3002nMOLs\u4e0d\u4ec5\u4fdd\u7559nMOF\u7684\u5206\u5b50\u6027\u8d28\uff0c\u7ed3\u6784\u89c4\u5219\u6027\u548c\u7ec4\u6210\u591a\u6837\u6027\uff0c\u800c\u4e14\u8fd8\u5177\u6709\u9ad8\u5bc6\u5ea6\u7684\u5f00\u653e\u4f4d\u70b9\uff0c\u4ee5\u5141\u8bb8\u5171\u4ef7\u5b89\u88c5\u590d\u6742\u7684\u5206\u5b50\u4f20\u611f\u5668\u5e76\u6613\u4e8e\u4f7f\u7528\u5927\u578b\u5206\u6790\u7269\u3002\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u57fa\u4e8enMOL\u7684\u751f\u7269\u4f20\u611f\u5668\u7684\u8bbe\u8ba1\uff0c\u7528\u4e8e\u7ebf\u7c92\u4f53\u4e2d\u7684pH\u548c\u6c27\u6c14\u6bd4\u4f8b\u6d4b\u5b9a\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong>\u7f8e\u56fd\u829d\u52a0\u54e5\u5927\u5b66\u7684\u6797\u6587\u658c\u6559\u6388<\/strong>\u62a5\u9053\u4e86\u7b2c\u4e00\u4e2a\u57fa\u4e8enMOL\u7684\u751f\u7269\u4f20\u611f\u5668\u7684\u8bbe\u8ba1\uff0c\u7528\u4e8e\u7ebf\u7c92\u4f53\u4e2dpH\u548c\u6c27\u6c14\u7684\u6bd4\u4f8b\u4f20\u611f\u3002\u9633\u79bb\u5b50Hf<sub>12<\/sub>-Ru nMOL\u662f\u901a\u8fc7\u5c06Hf<sub>12<\/sub>\u4e8c\u7ea7\u7ed3\u6784\u5355\u5143\uff08SBU\uff09\u4e0e\u5bf9\u6c27\u654f\u611f\u7684Ru(bpy)<sub>3<\/sub><sup>2+<\/sup>\u884d\u751f\u7684DBB-Ru\u914d\u4f53\uff08bpy=2,2&#8242;-\u8054\u5421\u5576\uff09\u6a2a\u5411\u8fde\u63a5\u6eb6\u5242\u70ed\u5408\u6210\u7684\u3002\u7136\u540e\u5c06Hf<sub>12<\/sub>-Ru nMOL\u4e0epH\u654f\u611f\u7684\u8367\u5149\u7d20\u5f02\u786b\u6c30\u9178\u916f\u548c\u4e0d\u4f9d\u8d56pH\/\u6c27\u7684\u82e5\u4e39\u660eB\u5f02\u786b\u6c30\u9178\u916f\u901a\u8fc7\u786b\u8132\u952e\u5171\u4ef7\u5b98\u80fd\u5316\uff0c\u4f5c\u4e3aHf<sub>12<\/sub>-Ru-F\/R\u7684\u7ebf\u7c92\u4f53\u9776\u5411\u6bd4\u7387\u4f20\u611f\u5668\uff0c\u7528\u4e8e\u68c0\u6d4b\u6d3b\u4f53\u5185\u7684pH\u548cO<sub>2<\/sub>\u3002\u7528Hf<sub>12<\/sub>-Ru-F\/R\u8fdb\u884c\u7684\u9ad8\u5206\u8fa8\u7387\u5171\u805a\u7126\u663e\u5fae\u955c\u6210\u50cf\u663e\u793a\uff0c\u7ebf\u7c92\u4f53\u4e2d\u7684pH\u4e0e\u5c40\u90e8O<sub>2<\/sub>\u6d53\u5ea6\u5448\u6b63\u76f8\u5173\u3002\u8fd9\u4e2a\u5de5\u4f5c\u663e\u793a\u4e86\u57fa\u4e8enMOL\u7684\u6bd4\u4f8b\u751f\u7269\u4f20\u611f\u5668\u5728\u6d3b\u7ec6\u80de\u4e2d\u91cd\u8981\u751f\u7269\u5b66\u5206\u6790\u7269\u7684\u4f20\u611f\u548c\u6210\u50cf\u4e2d\u7684\u6f5c\u529b\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a<strong>\u201c<\/strong><strong>Multifunctional Nanoscale Metal\u2212Organic Layers for Ratiometric pH and Oxygen Sensing<\/strong><strong>\u201d<\/strong>\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong>J. Am. Chem. Soc.<\/strong><strong>\u4e0a<\/strong>\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong><strong>\u591a\u529f\u80fd<\/strong><strong>Hf<sub>12<\/sub>-Ru-F\/R<\/strong><strong>\u7684\u5408\u6210<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192268\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r1.jpg\" alt=\"\" width=\"600\" height=\"408\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r1-300x204.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u901a\u8fc7\u4ea4\u6362Hf<sub>12<\/sub> SBU\u4e0a\u7684TFA\u5c01\u7aef\u57fa\u4e0e\u5bf9\u6c28\u57fa\u82ef\u7532\u9178\u916f\u57fa\u8fdb\u884c\u8868\u9762\u4fee\u9970\uff0c\u5e76\u901a\u8fc7\u5f62\u6210\u786b\u8132\u952e\u5c06FITC\u548cRITC\u4e0eHf<sub>12<\/sub> SBU\u5171\u4ef7\u5076\u8054<\/p>\n<p>\uff08b\uff09FITC\uff0cRITC\u548cH<sub>2<\/sub>DBB-Ru\u7684\u5316\u5b66\u7ed3\u6784\u548c\u6fc0\u53d1\/\u53d1\u5c04\u5149\u8c31<\/p>\n<p>\uff08c\uff09\u5e26\u6b63\u7535\u7684Hf<sub>12<\/sub>-Ru-F\/R\u9776\u5411\u7ebf\u7c92\u4f53\uff0c\u5e76\u901a\u8fc7pH\u654f\u611f\u7684FITC\u4e0e\u4e0d\u4f9d\u8d56pH\u7684RITC\u548cO<sub>2<\/sub>\u654f\u611f\u7684DBB-Ru\u4e0eO<sub>2<\/sub>\u65e0\u5173\u7684RITC\u7684\u53d1\u5149\u6bd4\uff0c\u5bf9\u7ebf\u7c92\u4f53\u5185\u7684pH\u548c\u6c27\u6c14\u8fdb\u884c\u6bd4\u4f8b\u68c0\u6d4b<\/p>\n<p><strong>\u56fe<\/strong><strong>2.<\/strong><strong>\u63a2\u9488<\/strong><strong>Hf<sub>12<\/sub>-Ru-F\/R<\/strong><strong>\u7684\u8868\u5f81<\/strong><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192269\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r2.jpg\" alt=\"\" width=\"600\" height=\"1096\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r2-164x300.jpg 164w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r2-561x1024.jpg 561w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p>\uff08a-d\uff09Hf<sub>12<\/sub>-Ru\u7684TEM\uff0cHRTEM,\u548cAFM\u8868\u5f81\u7ed3\u679c\u3002<\/p>\n<p>\uff08e-f\uff09Hf<sub>12<\/sub>-Ru-F\/R\u7684TEM\u548cPXRD\u8868\u5f81\u7ed3\u679c\u3002<\/p>\n<p>\uff08g\uff09\u6d88\u89e3\u540e\u7684Hf<sub>12<\/sub>-Ru-F\/R\u7684\u9ad8\u5206\u8fa8\u8d28\u8c31\u8868\u5f81\u7ed3\u679c\uff0c\u8bc1\u660e\u4e86FITC\u548cRITC\u4e0eHf<sub>12<\/sub>SBU\u7684\u5171\u4ef7\u8fde\u63a5\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3.<\/strong><strong>\u63a2\u9488\u7684\u5149\u8c31\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192270\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r3.jpg\" alt=\"\" width=\"600\" height=\"706\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r3-255x300.jpg 255w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Hf<sub>12<\/sub>-Ru\u548cHf<sub>12<\/sub>-Ru-F\/R\u572831.5 mol\uff05FITC\u548c10.1 mol\uff05RITC\u8d1f\u8f7d\u4e0b\u7684\u7d2b\u5916\u53ef\u89c1\u5149\u8c31<\/p>\n<p>\uff08b-f\uff09Hf<sub>12<\/sub>-Ru-F\/R\u7684\u53d1\u5149\u5149\u8c31\u5206\u522b\u663e\u793a\u5bf9\u5e94\u4e8eFITC\uff0cRITC\u548cDBB-Ru\u7684\u53d1\u5c04\u3002 \u901a\u8fc7\u8367\u5149\u6cd5\u83b7\u5f97\u7684Hf<sub>12<\/sub>-Ru-F\/R\u5728\u5e38\u6c27\u4e0b\u4e0d\u540cpH\u6216\u5728pH 7.04\u4e0b\u4e0d\u540cO<sub>2<\/sub>\u538b\u529b\u4e0b\u7684\u53d1\u5149\u5f3a\u5ea6\u3002\u901a\u8fc7IVIS\u6210\u50cf\u83b7\u5f97\u7684Hf<sub>12<\/sub>-Ru-F\/R\u7684pH\u548cO<sub>2<\/sub>\u7684\u6821\u51c6\u66f2\u7ebf\u3002\u5bf9\u4e8e\uff08b-f\uff09\uff0c\u57fa\u4e8eDBB-Ru\u7684Hf<sub>12<\/sub>-Ru-F\/R\u6d53\u5ea6\u4e3a10.0\u03bcM\uff0cHf<sub>12<\/sub>-Ru-F\/R\u7684FITC\u542b\u91cf\u4e3a1.1 mol\uff05\uff0cRITC\u542b\u91cf\u4e3a5.6 mol\uff05<\/p>\n<p><strong>\u56fe<\/strong><strong>4.Hf<sub>12<\/sub>-Ru<\/strong><strong>\u5728<\/strong><strong>CT26<\/strong><strong>\u7ec6\u80de\u4e2d\u7684\u65f6\u95f4\u4f9d\u8d56\u6027\u5b9a\u4f4d<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192271\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r4.jpg\" alt=\"\" width=\"600\" height=\"502\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r4-300x251.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>5.<\/strong><strong>\u7ec6\u80de\u6210\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192272\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r5.jpg\" alt=\"\" width=\"600\" height=\"205\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r5.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/r5-300x103.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5728\u5e38\u6c27\uff0c\u4f4e\u6c27\u548c\u7f3a\u6c27\u6761\u4ef6\u4e0b\u4e0eHf<sub>12<\/sub>-Ru-F\/R\u5b75\u80b2\u540e\uff0cCT26\u7ec6\u80de\u7684\u6bd4\u4f8b\u53d1\u5149\u6210\u50cf<\/p>\n<p>\uff08b\uff09\u6563\u70b9\u56fe\u663e\u793aHf<sub>12<\/sub>-Ru-F\/R\u68c0\u6d4b\u5230\u7684\u7ebf\u7c92\u4f53\u4e2dpH\u548cp<sub>O2<\/sub>\u4e4b\u95f4\u5448\u6b63\u76f8\u5173<\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u4f5c\u4e3a\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08nMOFs\uff09\u7684\u5355\u5c42\u7248\u672c\uff0c\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u5355\u5c42\uff08nMOLs\uff09\u4ee3\u8868\u4e86\u65b0\u5174\u7684\u4e00\u7c7b\u9ad8\u5ea6\u53ef\u8c03\u7684\u4e8c\u7ef4\u6750\u6599\uff0c\u7528\u4e8e\u5206\u5c42\u529f\u80fd\u5316\u4ee5\u53ca\u5bf9\u5206\u6790\u7269\u7684\u68c0\u6d4b\u3002\u5728\u8fd9\u91cc\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u7b2c\u4e00\u4e2a\u57fa\u4e8enMOLs\u7684\u751f\u7269\u4f20\u611f\u5668\u7684\u8bbe\u8ba1\uff0c\u7528\u4e8e\u7ebf\u7c92\u4f53\u4e2dpH\u548c\u6c27\u6c14\u7684\u6bd4\u4f8b\u4f20\u611f\u3002\u5c06Hf<sub>12<\/sub>-Ru nMOL\u4e0epH\u654f\u611f\u7684\u8367\u5149\u7d20\u5f02\u786b\u6c30\u9178\u916f\u548c\u4e0d\u4f9d\u8d56pH\/\u6c27\u7684\u82e5\u4e39\u660eB\u5f02\u786b\u6c30\u9178\u916f\u901a\u8fc7\u786b\u8132\u952e\u5171\u4ef7\u5b98\u80fd\u5316\uff0c\u4f5c\u4e3aHf<sub>12<\/sub>-Ru-F\/R\u7684\u7ebf\u7c92\u4f53\u9776\u5411\u6bd4\u7387\u4f20\u611f\u5668\uff0c\u7528\u4e8e\u68c0\u6d4b\u6d3b\u4f53\u5185\u7684pH\u548cO<sub>2<\/sub>\u7ec6\u80de\u3002\u7528Hf<sub>12<\/sub>-Ru-F\/R\u8fdb\u884c\u7684\u9ad8\u5206\u8fa8\u7387\u5171\u805a\u7126\u663e\u5fae\u955c\u6210\u50cf\u663e\u793a\uff0c\u7ebf\u7c92\u4f53\u4e2d\u7684pH\u4e0e\u5c40\u90e8O<sub>2<\/sub>\u6d53\u5ea6\u5448\u6b63\u76f8\u5173\u3002\u8fd9\u4e2a\u5de5\u4f5c\u663e\u793a\u4e86\u57fa\u4e8enMOL\u7684\u6bd4\u4f8b\u751f\u7269\u4f20\u611f\u5668\u5728\u6d3b\u7ec6\u80de\u4e2d\u91cd\u8981\u751f\u7269\u5b66\u5206\u6790\u7269\u7684\u4f20\u611f\u548c\u6210\u50cf\u4e2d\u7684\u6f5c\u529b\u3002<\/p>\n<p><strong>\u5bfc\u5e08\u4ecb\u7ecd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-192273\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/lwb.jpg\" alt=\"\" width=\"200\" height=\"301\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/lwb.jpg 200w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/12\/lwb-199x300.jpg 199w\" sizes=\"(max-width: 200px) 100vw, 200px\" \/><\/p>\n<p>\u6797\u6587\u658c\uff0c\u7f8e\u56fd\u829d\u52a0\u54e5\u5927\u5b66\u5316\u5b66\u7cfb\u548c\u8f90\u5c04\u4e0e\u7ec6\u80de\u80bf\u7624\u7cfb\u7684James Franck\u8bb2\u5ea7\u6559\u6388\u3002\u6797\u6587\u658c\u6559\u6388\u5728\u5316\u5b66\u4e0e\u751f\u7269\u5316\u5b66\u53ca\u7eb3\u7c73\u533b\u5b66\u65b9\u9762\u6709\u91cd\u8981\u8d21\u732e\uff0c\u5728\u5305\u62ec<em>Nat. Biomed. Eng.<\/em><em>\uff0c<\/em><em>Nat. Chem.<\/em><em>\uff0c<\/em><em>Nat. Catal.<\/em><em>\uff0c<\/em><em>J. Am. Chem. Soc.<\/em><em>\uff0c<\/em><em>Angew. Chem. Int. Ed. <\/em>\u7b49\u4e16\u754c\u9876\u7ea7\u6742\u5fd7\u4e0a\u53d1\u8868\u6587\u7ae0\u8fd1350\u7bc7\uff0c\u6587\u7ae0\u88ab\u5e7f\u6cdb\u5f15\u7528\uff08h-index &gt;104\uff09\u30021999-2009 \u5e74\u5ea6\u6587\u7ae0\u5f15\u7528\u4e16\u754c\u524d\u5341\u4f4d\u5316\u5b66\u5bb6\u3002\u6c64\u68ee\u8def\u900f\u96c6\u56e22000-2010\u5e74\u5168\u7403\u9876\u5c16\u4e00\u767e\u5316\u5b66\u5bb6\u540d\u4eba\u5802\u699c\u5355\u7b2c54\u540d\u3002\u6797\u6587\u658c\u56e2\u961f\u7814\u53d1\u7684\u4e09\u4e2a\u6297\u764c\u836f\u7269\u5df2\u5728\u8fdb\u884c\u4e34\u5e8a\u8bd5\u9a8c\u5e76\u53d6\u5f97\u826f\u597d\u7684\u4e34\u5e8a\u7ed3\u679c\u3002<\/p>\n<p>\u8bfe\u9898\u7ec4\u7f51\u7ad9\u00a0 <a href=\"http:\/\/linlab.uchicago.edu\/\">http:\/\/linlab.uchicago.edu\/<\/a><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.9b11024\" target=\"_blank\" rel=\"noopener\">Multifunctional Nanoscale Metal\u2212Organic Layers for Ratiometric pH and Oxygen Sensing<\/a>. <em>J. Am. Chem. Soc., <\/em>\u00a0<strong>2019<\/strong>, DOI: 10.1021\/jacs.9b11024.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4tt\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002\u00a0<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5f00\u53d1\u7528\u4e8e\u76d1\u6d4b\u751f\u7406\u8fc7\u7a0b\u548c\u75c5\u7406\u751f\u7269\u5b66\u56e0\u7d20\u7684\u751f\u7269\u4f20\u611f\u5668\u5bf9\u75be\u75c5\u65e9\u671f\u8bca\u65ad\u975e\u5e38\u91cd\u8981\u3002\u5728\u8bf8\u591a\u751f\u7269\u4f20\u611f\u5668\u4e2d\uff0c\u8367\u5149\u63a2\u9488\u662f\u6700\u5e38\u7528\u7684\u7ec6\u80de\u6210\u50cf\u63a2\u9488\uff0c\u56e0\u4e3a\u5b83\u4eec\u53ef\u4ee5\u76f4\u63a5\uff0c\u5b9e\u65f6\u548c\u65e0&#8230;<\/p>\n","protected":false},"author":7336,"featured_media":192268,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2783],"class_list":["post-192267","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2783"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/192267"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7336"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=192267"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/192267\/revisions"}],"predecessor-version":[{"id":192849,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/192267\/revisions\/192849"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/192268"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=192267"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=192267"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=192267"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}