{"id":191438,"date":"2019-12-12T06:25:08","date_gmt":"2019-12-11T22:25:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=191438"},"modified":"2019-12-11T14:25:18","modified_gmt":"2019-12-11T06:25:18","slug":"%e5%8d%97%e4%ba%ac%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e9%bb%84%e7%bb%b4%e9%99%a2%e5%a3%ab%e5%92%8c%e5%ae%89%e4%bc%97%e7%a6%8f%e6%95%99%e6%8e%88angew%ef%bc%9a%e6%97%a0%e5%ae%9a%e5%bd%a2%e7%a6%bb","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=191438","title":{"rendered":"\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u9ec4\u7ef4\u9662\u58eb\u548c\u5b89\u4f17\u798f\u6559\u6388Angew\uff1a\u65e0\u5b9a\u5f62\u79bb\u5b50\u805a\u5408\u7269\u5177\u6709\u989c\u8272\u53ef\u8c03\u7684\u8d85\u957f\u6709\u673a\u78f7\u5149"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

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\u5b9e\u73b0\u65e0\u5b9a\u5f62\u805a\u5408\u7269\u957f\u5bff\u547d\u78f7\u5149\u7684\u5173\u952e\u662f\u51cf\u5c11\u53d1\u8272\u56e2\u7684\u65e0\u8f90\u5c04\u8dc3\u8fc1\u3002\u5927\u90e8\u5206\u7b56\u7565\u901a\u8fc7\u5171\u4ef7\u952e\u3001\u6c22\u952e\u548c\u5176\u4ed6\u8303\u5fb7\u534e\u529b\u6765\u9650\u5236\u5206\u5b50\u8fd0\u52a8\u3002\u9664\u4e86\u8fd9\u4e9b\u529b\u5916\uff0c\u79bb\u5b50\u952e\u4f5c\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u5316\u5b66\u952e\u4e5f\u80fd\u6709\u6548\u6291\u5236\u53d1\u8272\u56e2\u7684\u8fd0\u52a8\uff0c\u589e\u5f3a\u805a\u5408\u7269\u7684\u78f7\u5149\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u5b89\u4f17\u798f\u6559\u6388\u548c\u9ec4\u7ef4\u9662\u58eb\u56e2\u961f\u62a5\u9053\u4e86\u79bb\u5b50\u5316\u7b56\u7565\u4f7f\u805a(4-\u4e59\u70ef\u5421\u5576) (PVP)\u884d\u751f\u7269\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u8d85\u957f\u6709\u673a\u78f7\u5149\u73b0\u8c61\u3002\u57281,4-\u4e01\u78fa\u9178\u5185\u916f\u79bb\u5b50\u5316\u540e\uff0cPVP-S\u78f7\u5149\u4f53\u7684\u8d85\u957f\u6709\u673a\u78f7\u5149\u5bff\u547d\u4e3a578.36 ms\uff0c\u662fPVP\u7684525\u500d\u3002\u6709\u8da3\u7684\u662f\uff0c\u5b83\u80fd\u5728\u4e0d\u540c\u6fc0\u53d1\u5149\u6ce2\u957f\u7684\u523a\u6fc0\u4e0b\u8868\u73b0\u51fa\u4ece\u84dd\u5149\u5230\u7ea2\u5149\u7684\u989c\u8272\u53ef\u8c03\u7684\u8d85\u957f\u6709\u673a\u78f7\u5149\u73b0\u8c61\uff0c\u8fd9\u5728\u76ee\u524d\u53d1\u8868\u7684\u6709\u673a\u53d1\u5149\u6750\u6599\u4e2d\u5f88\u5c11\u89c1\u3002\u4e0a\u8ff0\u6210\u679c\u53d1\u8868\u4e8e\u56fd\u9645\u671f\u520aAngew\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

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\"\"<\/p>\n

\u56fe2. PVP\u79bb\u5b50\u5316\u5236\u5907PVP-S\u7684\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

(a)PVP-S\u7684\u5408\u6210\u8def\u7ebf<\/p>\n

(b) PVP\u548cPVP-S\u7684\u7ea2\u5916\u5149\u8c31\u56fe<\/p>\n

\u56fe3.\u56fa\u6001PVP-S\u7684\u5149\u7269\u7406\u6027\u80fd<\/p>\n

\"\"(a)\u5ba4\u6e29\u4e0bPVP-S\u88ab365nm\u7d2b\u5916\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u7684\u7a33\u6001\u5149\u81f4\u53d1\u5149\u548c\u78f7\u5149\u5149\u8c31<\/p>\n

(b) \u5ba4\u6e29\u4e0bPVP-S\u88ab460 nm\u7d2b\u5916\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u7684\u65f6\u95f4\u5206\u8fa8\u8870\u51cf\u66f2\u7ebf<\/p>\n

(c)\u5ba4\u6e29\u4e0bO2<\/sub>\uff08\u7ea2\uff09\u548c\u771f\u7a7a\uff08\u9ed1\uff09\u4e2dPVP-S\u7684\u8367\u5149\u5149\u8c31<\/p>\n

(d)\u5ba4\u6e29\u4e0bPVP-S\u7684\u6fc0\u53d1-\u53d1\u5c04\u78f7\u5149Mapping<\/p>\n

(e)77 K\u4e0bPVP-S\u88ab\u4e0d\u540c\u6ce2\u957f\u7d2b\u5916\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u7684\u78f7\u5149\u5149\u8c31\u3002\u63d2\u56fe\uff1a\u4ee5\u53ca\u5728\u4e0d\u540c\u6fc0\u53d1\u6ce2\u957f\u523a\u6fc0\u4e0b\u7684\u957f\u4f59\u8f89\u7167\u7247<\/p>\n

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\"\"<\/p>\n

(a) PVP\u548cPVP-S\u7684\u65e0\u8f90\u5c04\u8870\u51cf\u901f\u7387\u5e38\u6570\u548c\u78f7\u5149\u5bff\u547d\u7684\u5bf9\u6bd4<\/p>\n

(b\u3001c)77K\u4e0b\u56fa\u6001\uff08b\uff09\u548c\u6eb6\u80c0\u6001\uff08c\uff09\u7684PVP-S\u5728\u4e0d\u540c\u53d1\u5c04\u5149\u6ce2\u957f\u4e0b\u7684\u78f7\u5149\u6fc0\u53d1\u5149\u8c31<\/p>\n

(d) PVP-S\u7684\u4e8c\u7ef4\u63a0\u5165\u5c04\u5e7f\u89d2x\u5c04\u7ebf\u6563\u5c04\u56fe<\/p>\n

(e) PVP-S\u591a\u79cd\u805a\u96c6\u6001\u7684\u53d1\u5149\u673a\u7406<\/p>\n

\u56fe5. \u56fa\u6001PVP-B\u548cPVP-C\u7684\u5149\u7269\u7406\u6027\u80fd<\/p>\n

\n \"\"(a) PVP-B\u548cPVP-C\u7684\u5206\u5b50\u7ed3\u6784\u3002\u63d2\u56fe\uff1a365nm\u7684\u7d2b\u5916\u5149\u5f00\u542f\u548c\u5173\u95ed\u7684\u6761\u4ef6\u4e0bPVP-B\u548cPVP-C\u7684\u7167\u7247<\/p>\n

(b) \u5ba4\u6e29\u4e0bPVP-B\u548cPVP-C\u7684\u6fc0\u53d1-\u53d1\u5c04\u78f7\u5149Mapping<\/p>\n

\uff08c\u3001d\uff09\u5ba4\u6e29\u4e0bPVP-B\uff08d\uff09\u548cPVP-C\uff08c\uff09\u7684\u65f6\u95f4\u5206\u8fa8\u8870\u51cf\u66f2\u7ebf<\/p>\n

(e)\u5ba4\u6e29\u548c77K\u4e0bPVP-B\u548cPVP-C\u968f\u7740\u6fc0\u53d1\u5149\u6ce2\u957f\u53d1\u51fa\u7684\u78f7\u5149\u989c\u8272\u7684\u8272\u5ea6\u56fe<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAmorphous Ionic Polymers with Color\u2010Tunable Ultralong Organic Phosphorescence<\/a>\uff08Angew. Chem. Int. Ed.\uff0c2019\uff0c doi: 10.1002\/anie.201911331\u00a0\uff09<\/p>\n

\u672c\u6587\u7531kv1004\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

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